• 제목/요약/키워드: Pt$P_2S_2$

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Pt/Si/Ti P형 4H-SiC 오옴성 접합에서 낮은 접촉 저항에 관한 연구 (Low resistivity ohmic Pt/Si/Ti contacts to p-type 4H-SiC)

  • 양성준;이주헌;노일호;김창교;조남인;정경화;김은동;김남균
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.521-524
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    • 2001
  • In this letter. we report on the investigation of Ti. Pt/Si/Ti Ohmic contacts to p-type 4H-SiC. The contacts were formed by a 2-step vacuum annealing at $500^{\circ}C$ for 1h. $950^{\circ}C$ for 10 min respectively. The contact resistances were measured using the transmission line model method. which resulted in specific contact resistivities in the $3.5{\times}10^{-3}$ and $6.2{\times}10^{-4}ohm/cm^{2}$, and the physical properties of the contacts were examined using x-ray diffraction. microscopy. AES(auger electron spectroscopy). AES analysis has shown that, at this anneal temperature, there was a intermixing of the Ti and Si. migration of into SiC. Overlayer of Pt had the effect of decreasing the specific contact resistivity and improving the surface morphology of the annealed contact.

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Apo E Null mice에서 인삼 Ginsenosides (PD:PT = 1) 추출물의 지질개선 및 항산화 효과 (Hypolipidemic and Antioxidant Effects to Ginseng Extract (PD:PT = 1) in Apo E Null Mice)

  • 장수정;김성수;이명숙
    • Journal of Nutrition and Health
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    • 제41권7호
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    • pp.594-601
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    • 2008
  • Panax ginseng C.A. Meyer (Panax ginseng) has been used for several thousand years to prolong longevity in Asian countries. Ginsenosides are the most active components isolated from ginseng and belong to damarane saponin which are separated into protopanaxadiol and protopanaxtriol. To evaluate the complex effect of ginsenoside in apo E null mice, ginseng extract were intraperioneally (i.p.) injected and provided high-cholesterol diet for 12 weeks. Ginseng extract came from were i.p. injected with dose of 100 mg/kg/day for 4 weeks in the last experimental duration. Ginseng extract used experiment was abundant Rb1, Rc, Re, and Rg1 and PD:PT ratio was 1.2. The high-cholesterol diet induced liver damage was significantly reduced by ginseng extract. Results from plasma lipid profiles and atherogenic index were improved by ginseng extracts. The GE group significantly decreased plasma TG and TC by 73% and 61% compared to apo E (-/-) group. Also ginseng extract tend to decrease lipid profiles and lipidperoxidation contents in liver and heart. Ginseng extract with an abundant amount of Rg1 significantly suppressed the apoptosis induction of cardiac tissue. In conclusion, ginseng extract (PD:PT = 1) was improved lipid profiles and anti-oxidant effects.

오옴성 접합에서의 낮은 접촉 저항을 갖는 Pt/Ti/P형 4H-SiC (Low resistivity ohmic Pt/Ti contacts to p-type 4H-SiC)

  • 이주헌;양성준;김창교;조남인;정경화;신명섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 하계학술대회 논문집 C
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    • pp.1378-1380
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    • 2001
  • Ohmic contacts have been fabricated on p-type 4H-SiC using Pt/Ti. Low resistivitf Ohmic contacts of Pt/Ti to p-type 4H-SiC were investigated. Specific contact resistances were measured using the transmission line model method, and the physical properties of the contacts were examined using x-ray diffraction, scanning electron microscopy. Ohmic behavior with linear current-voltage characteristics was observed following anneals at $900^{\circ}C$ for 90sec at a pressure of $3.4{\times}10^{-5}$ Torr. The Pt/Si/Ti films was measured lower value of the specific contact resistance by the annealing process, and the contact resistances were improved more than one order compared to Ti contact the annealed sample. Scanning electron microscopy shows that the Pt layer effectively reduce the oxidation of Ti films. And results are obtained as $4.6{\times}10^{-4}$ ohm/$cm^2$ for a Pt/Ti metal structure after a vacuum annealing at $900^{\circ}C$ for 90sec. Titanium has a relatively high melting point, thus Ti-based metal contacts were attempted in this study.

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금속과 그 산화물 전극으로 된 전지 계들의 열역학적 성질 (Thermodynamic Properties of the Cell Systems made of the Metal and Its Oxide Electrodes)

  • 노권선;이은석;;;여철현
    • 대한화학회지
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    • 제37권7호
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    • pp.635-641
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    • 1993
  • 고체 전해질의 특성을 조사하기 위해 전기화학전지, $Pt|ar(PO_2=5.3{\times}10^{-3}atm)|Zr_{0.85}Ca_{0.15}O_{1.85}|air(PO_2=0.21atm)|Pt$을 제작하고 600~1000${\circ}$C의 온도구간에서 기전력의 온도 의존성을 측정하였다. 고체 전해질은 산소 음이온에 의한 순수한 이온성 전기전도도를 나타낸다. Fe-FexO, Co-CoO, Ni-NiO, 및 $Cu_2_O-CuO$전극들은 금속과 금속산화물을 1:1 몰비로 혼합한 후 800${\circ}$C에서 6h 동안 열처리하여 제조하였다. 전기 화학전지 Pt|M(s), $MO(s)|Zr_P{0.85}Ca_{0.15}O_{1.85}|air(PO_2=0.21atm)|Pt$을 제작하고 같은 온도 구간에서 기전력의 온도 의존성을 측정하였다 .그 전지들의 기전력과 기전력의 온도 의존성을 사용하여 금속산화물의 생성에 대한 열역학적 상태함수 변화들을 계산한다. 그 함수 변화들로 이들 산화물계의 물성을 논의하였다.

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상부전극에 따른 SCT 세라믹 박막의 전기적 특성 (Electrical Properties of SCT Ceramic Thin Film with Top Electrode)

  • 조춘남;김진사;신철기;최운식;김충혁;박용필;유영각;이준응
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1501-1503
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    • 1999
  • The $(Sr_{0.85}Ca_{0.15})TiO_3$(SCT) thin films are deposited on Pt-coated electrode$(Pt/TiO_2/SiO_2/Si)$ using RF sputtering method. Ag, Cu, Al, Pt films for the formation of top eletrode were doposited on SCT thin films by thermal evaporator and sputtering. The effects of top electodes have be studied on SCT samples with a variety of top electrode materials.

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Improved Tri-iodide Reduction Reaction of Co-TMPP/C as a Non-Pt Counter Electrode in Dye-Sensitized Solar Cells

  • Kim, Jy-Yeon;Lee, Jin-Kyu;Han, Sang-Beom;Lee, Young-Woo;Park, Kyung-Won
    • Journal of Electrochemical Science and Technology
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    • 제1권2호
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    • pp.75-80
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    • 2010
  • We report Co-tetramethoxyphenylporphyrin on carbon particles (Co-TMPP/C) as a non-Pt catalyst for tri-iodide reduction in dye-sensitized solar cells (DSSCs). The presence of well-dispersed carbon and cobalt source in the catalyst surface is confirmed by transmission electron microscopy, scanning electron microscopy, and energy dispersive X-ray analysis. In the C 1s, Co 2p, and N 1s peaks measured by X-ray photoelectron spectroscopy, the C-N, Co-$N_4$, and N-C are assigned to the component at 285.7, 781.8, and 401 eV, respectively. Especially, the Co-TMPP/C shows improved current density, diffusion coefficient, and charge-transfer resistance in the ${I_3}^-/I^-$ redox reaction compared to conventional catalysts. Furthermore, in the DSSCs performance, the Co-TMPP/C shows increased short circuit current density, higher open circuit voltage, and improved cell efficieny in comparison with Pt/C.

새로운 Platinum (II) Complex [Pt (II)(trans-d-dach)(DPPE)] $(NO_3)_2$의 항암효과 및 신독성에 관한 연구 (Antitumor Activity and Nephrotoxicity of the Novel Platinum(II) Coordination Complex)

  • 정지창;이문호;장성구;노영수
    • 대한약리학회지
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    • 제31권1호
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    • pp.103-114
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    • 1995
  • 일부 malignant tumor에 Pt-complex의 일상 응용 과정에서 신장독성등의 심한 부작용이 문제점으로 지적되고 있다. 이 연구에서는 기존의 cisplatin보다 항암효과는 우수하면서, 부작용을 감소시킨 새로운 Pt-complex의 개발에 역점을 두었다. 본 연구에서 합성한 Pt(Ⅱ) complex는 carrier ligand로서 1,2-diaminocyclohexane(dach)을 사용하였고, leaving group으로는 diophosphine류인 1,2-bisdiphenylphosphinoethane(DPPE)을 도입하였으며, 물에 대한 용해도를 높이기 위해 dinitrate로 만들었다. 새로이 합성한 [Pt(Ⅱ)(trans-d-dach)(DPPE)]$(NO_3)_2$는 원소 분석, IR 및 $^{13}C-NMR$ 분석 data에 의하여 위의 물질임이 확인되었다. MTT assay method에 의한 항암활성 연구를 통하여 P-388, L-1210 lymphocytic leukemia cell과 SK-OV3 난소암세포에서 항암효과가 인정되었으며, 이 항암효과는 대조 약물로 사용된 cisplatin과 유사하였다. 토끼의 신세뇨관 세포와 인체의 신피질 세포를 이용한 cytotoxity 및 thymidine 섭취율과 인체 신피질 조직 배양을 이용한 glucose consumption 실험을 통하여 모두 cisplatin보다 신장독성이 현저히 감소되었다. 이상의 결과로 보아 Pt(Ⅱ)complexes는 carrier ligand와 leaving group의 선택에 따라 항암활성의 증가와 신독성의 감소를 일으키는 요인으로 보여지며, 이 연구에서 만들어진 Pt(Ⅱ)complex는 앞으로 다각적인 검토를 거쳐 새로운 항암화학요법제로 개발될 가능성이 있을 것으로 생각된다.

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Pt(111) 표면 위에 증착된 Fe 초박막의 산소 흡착에 관한 연구 (Oxygen Chemisorption on the Fe Ultrathin Films on Pt(111) Surface)

  • 박경훈;조성국;남창우
    • 한국진공학회지
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    • 제17권3호
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    • pp.183-188
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    • 2008
  • 내각준위 X선 광전자 분광법을 이용하여 Pt(111) 표면 위에 증착된 Fe 초박막의 산소 흡착에 대한 연구를 수행하였다. 6개 단층 이하의 두께를 갖는 Fe 초박막을 상온에서 산소에 노출시켜 산소 원자가 화학흡착된 것을 확인하고, 후열처리 과정에 따른 탈착 및 Fe층의 변화를 살펴보았다. 흡착된 산소 원자는 $600{\sim}700K$에서 부분적으로 탈착되고, 700 K 이상에서 Fe 원자들이 Pt 기판 안으로 섞여 들어감을 내각준위 스펙트럼 세기들로부터 알 수 있었다. Fe 원자들과 Pt 원자들 간의 섞임은 산소가 흡착되지 않은 경우와 거의 동일한 경향을 보였으며, 섞임에 의한 Fe-Pt 합금의 형성은 Fe $2p_{3/2}$ 광전자 스펙트럼의 속박에너지의 변화로부터 확인할 수 있었다. 탈착되지 않고 남은 산소의 양은 전체의 1/2로서 속박에너지가 $600{\sim}700K$ 사이에서 탈착된 산소보다 약 1.3 eV 커서 Fe층 위에 흡착된 산소들과는 다른 상임을 알 수 있었다. 이들 산소 원자는 1000 K에서야 탈착되었다.

Rocking response of self-centring wall with viscous dampers under pulse-type excitations

  • Zhang, Lingxin;Huang, Xiaogang;Zhou, Zhen
    • Earthquakes and Structures
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    • 제19권3호
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    • pp.215-226
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    • 2020
  • A self-centering wall (SCW) is a lateral resistant rocking system that incorporates posttensioned (PT) tendons to provide a self-centering capacity along with dampers to dissipate energy. This paper investigates the rocking responses of a SCW with base viscous dampers under a sinusoidal-type pulse considering yielding and fracture behaviour of the PT tendon. The differences in the overturning acceleration caused by different initial forces in the PT tendon are computed by the theoretical method. The exact analytical solution to the linear approximate equation of motion is also provided for slender SCWs. Finally, the effects of the ductile behaviour of PT tendons on the rocking response of a SCW are analysed. The results demonstrate that SCWs exhibit two overturning modes under pulse excitation. The overturning region with Mode 1 in the PT force cases separates the safe region of the wall into two parts: region S1 with an elastic tendon and region S2 with a fractured tendon. The minimum overturning acceleration of a SCW with an elastic-brittle tendon becomes insensitive to excitation frequency as the PT force increases. After the plastic behaviour of the PT tendon is considered, the minimum overturning acceleration of a SCW is increased significantly in the whole range of the studied wg/p.