• Title/Summary/Keyword: Proton exchange membrane electrolyser

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Effect of Electrolyte Concentration Difference on Hydrogen Production during PEM Electrolysis

  • Sun, Cheng-Wei;Hsiau, Shu-San
    • Journal of Electrochemical Science and Technology
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    • v.9 no.2
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    • pp.99-108
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    • 2018
  • Proton exchange membrane (PEM) water electrolysis systems offer several advantages over traditional technologies including higher energy efficiency, higher production rates, and more compact design. In this study, all the experiments were performed with a self-designed PEM electrolyser operated at 1 atm and $25^{\circ}C$. Two types of electrolyte were used: (i) potassium hydroxide (KOH), and (ii) sulfuric acid ($H_2SO_4$). In the experiments, the voltage, current, and time were measured. The concentration of the electrolyte significantly affected the electrolyser performance. Overall the best case was with 15 wt% $H_2SO_4$ at the anode channel and 20 wt% at the cathode channel with. In addition, increasing the difference in concentration of the sulfuric acid had an effect on the diffusion. The diffusion flux became larger when the difference in concentration became larger, increasing electrolyser efficiency without the addition of extra energy.

Evaluation of the Performance of Water Electrolysis Cells and Stacks for High-Altitude Long Endurance Unmanned Aerial Vehicle (고고도 무인기용 수전해 셀 및 스택의 제작 및 성능 평가)

  • JUNG, HYE YOUNG;LEE, JUNYOUNG;YOON, DAEJIN;HAN, CHANGHYUN;SONG, MINAH;LIM, SUHYUN;MOON, SANGBONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.4
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    • pp.341-348
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    • 2016
  • The experiments related on structure and water electrolysis performance of HALE UAV stack were conducted in this study. Anode catalyst $IrRuO_2$ was prepared by Adam's fusion methods as 2~3 nm nano sized particles, and the cathode catalyst was used as commercial product of Premetek. The MEA (membrane electrode assembly) was manufactured by decal methods, anode and anode catalytic layers were prepared by electro-spray. HALE stack was composed of 5 multi-cells as $0.2Nm^3/hr$ hydrogen production rate with hydrogen pressure as 10 bar. The water electrolysis performance was investigated at atmospheric pressure and temperature of $55^{\circ}C$. Best performance of HALE UAV stack was recorded as cell voltage efficiency as 86%.

Performance change according to the catalyst intrusion rate in the MEA for the PEM water electrolysis (고분자전해질 수전해용 MEA의 촉매침투도에 따른 성능변화)

  • Kim, Hong-Youl
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.254-256
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    • 2009
  • The performances of proton exchange membrane (PEM) water electrolysis depend on many factors such as materials, geometries, fabrication methods, operating conditions, and so forth. The fabrication method is concerned, membrane electrode assemblies (MEA) are a most important part to show different performances by different fabrication methods. The performance change of PEM water electrolysis was experimentally measured according to the fabrication differences of the anode electrodes. One point of view is the catalyst intrusion rate to the anode gas diffusion layer (GDL), and the other point of view is the catalyst loading distribution in depth of the anode GDL. Results show that the performances of MEA with deep intrusion of the catalysts are better in the range of low current densities but worse at higher current densities. The catalyst loading distribution does not affect significantly to the performance of PEM water electrolyser.

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Performance Change according to the Catalyst Intrusion Rate in the MEA for the PEM Water Electrolysis (고분자전해질 수전해용 MEA의 촉매침투도에 따른 성능변화)

  • Kim, Hong-Youl;Lee, Ji-Jung;Lee, Jae-Young;Lee, Hong-Ki
    • New & Renewable Energy
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    • v.5 no.4
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    • pp.75-78
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    • 2009
  • The performances of proton exchange membrane (PEM) water electrolysis depend on many factors such as materials, geometries, fabrication methods, operating conditions, and so forth. The fabrication method is concerned, membrane electrode assemblies (MEA) are a most important part to show different performances by different fabrication methods. The performance change of PEM water electrolysis was experimentally measured according to the fabrication differences of the anode electrodes. One point of view is the catalyst intrusion rate to the anode gas diffusion layer (GDL), and the other point of view is the catalyst loading distribution in depth of the anode GDL. Results show that the performances of MEA with deep intrusion of the catalysts are better in the range of low current densities but worse at higher current densities. The catalyst loading distribution does not affect significantly to the performance of PEM water electrolyser.

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