• Title/Summary/Keyword: Proton exchange

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PVA/PAM/Zirconium phosphate Composite Membrane for Proton Exchange Membranes (PVA/PAM/Zirconium phosphate 복합막의 제조)

  • 황호상;임지원
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.199-202
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    • 2004
  • DMFC 성능을 개선시키기 위한 연구의 큰 영역은 고분자전해질막에 있으며 methanol crossover에 대한 영향을 최소화시킬 수 있는 소재개발이 우선적으로 요구되는 실정이다. 이러한 문제의 해결을 위해 Pivovar와 Cussler [1] 등은 투과증발 막분리공정에서 메탄올 저항체로 잘 알려진 폴리비닐알콜(poly vinyl alcohol, PVA)를 이용한 전해질막 연구를 하였다.(중략)

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Preparation and Characterization of Poly(styrenesulfonic acid)-grafted Fluoropolymer Membrane for Direct Methanol Fuel Cell

  • Choi, Jae-Hak;Kang, Phil-Hyun;Lim, Youn-Mook;Sohn, Joon-Yong;Shin, Jun-Hwa;Jung, Chan-Hee;Jeun, Joon-Pyo;Nho, Young-Chang
    • Korean Membrane Journal
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    • v.9 no.1
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    • pp.52-56
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    • 2007
  • A proton exchange membrane was prepared by ${\gamma}-irradiation-induced$ grafting of styrene into poly(tetrafluoro-ethylene-co-perfluoropropyl vinyl ether) (PFA) and subsequent sulfonation reaction. The degree of grafting (DOG) increased with an increase in the absorbed dose. The prepared membranes showed high ion exchange capacity reaching 3.0 meq/g, which exceeded the performance of commercially available perfluorosulfonic acid membranes such as Nafion. The proton conductivity of PFA-g-PSSA membrane increased with the DOG and reached 0.17 S/cm for the highest sample at room temperature. The DMFC performance of the prepared membranes with 50% DOG was comparable to that of Nafion membrane.

Performance Characteristics of PEMFC by flow Configurations and Operating Condition (유로형상 및 운전조건에 따른 고분자 전해질 연료전지의 성능 특성)

  • Lee, Pil-Hyong;Cho, Son-Ah;Han, Sang-Seok;Hwang, Sang-Soon
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3440-3445
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    • 2007
  • For proton exchange membrane fuel cell, it is very important to design the flow channel on separation plate optimally to maximize the current density at same electrochemical reaction surface and reduce the concentration polarization occurred at high current density. In this paper, three dimensional computation model including anode and cathode domain together was developed to examine effects of flow patterns and operation conditions such as humidity and operating temperature on performance of fuel cell. Results show that voltage at counter flow condition is higher than that at coflow condition in parallel and interdigitated flow pattern. And fuel cell with interdigitated flow pattern which has better mass transport by convection flow through gas diffusion layer has higher performance than with parallel flow pattern but its pressure drop is increased such that the trade off between performance and pressure drop should be considered for selection of flow pattern of fuel cell.

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Heat transport characteristics by heat generation of electrochemical reactions in proton exchange membrane fuel cell (고분자전해질 연료전지에서 전기화학반응 열생성에 의한 열전달특성)

  • Cho, Son-Ah;Lee, Pil-Hyong;Han, Sang-Seok;Hwang, Sang-Soon
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3377-3382
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    • 2007
  • In proton exchange membrane fuel cell, the heat is generated at the catalyst layer as result of exothermic electrochemical reaction. This heat increases temperature of gas diffusion layer and membrane whose conductivity is very sensitive to humidity, function of temperature. So it is very important to analysis heat transfer through fuel cell to maintain temperature at specified range. In this paper numerical simulation was done including reversible, irreversible, ionic resistance, water formation loss to source term of energy equation. Results show that irreversible and water formation loss contributes mainly to energy source term and as current density increases, all of energy source terms become increased and Nusselt number is increased as results of more heat generation. Particularly irreversible loss is found to be predominant among the all energy source and water formation at cathode channel influences the temperature distribution of fuel cell greatly.

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The study of proton exchange membrane fuel cell and Li-poly battery hybrid system (로봇용 연료전지 이차전지 하이브리드 시스템 연구)

  • Kwon, O-Sung;Lee, Sang-Cheol;Lee, Sang-Woo;Lee, Dong-Ha
    • Journal of the Korean Solar Energy Society
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    • v.32 no.spc3
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    • pp.282-288
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    • 2012
  • Proton exchange membrane fuel cell (PEMFC) is the most promising energy source for the robot applications because it has unique advantages such as high energy density, no power drop during operating, and easy to make compact size. However, PEMFC has intrinsic disadvantages which are delay to start up and difficulty to correspond drastic load changes. These disadvantages can be compensated by hybrid operating with a Li-poly battery. This study is focus to build and understand the hybrid system for the robot system. In this study, we build the PEMFC hybrid system using EOS-320 PEMFC stack, Li-poly battery and G-Philos FDX1-250BU dc-dc converter. The hybrid system is accurately monitored by CAN and RS485. The system was studied under two conditions such as non-loaded and loaded operating conditions. The results show that the system has delay to start up without hybrid operating and it can be compensated with the hybrid operating.

Properties and Fabrications of 5 Gbps level LiNbO$_3$ Optical Phase Modulator for a Broadband Optical Communications (광대역 광통신용 5 Gbps급 LiNbO$_3$광위상변조기 제작 및 특성)

  • 김성구;윤형도;윤대원;박계춘;강성준
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.11
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    • pp.91-99
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    • 1998
  • A 5Gbps LiNbO$_3$ optical phase modulator was designed, packaged and it's properties were characterized for optical communications. The APE(annealed proton exchange) method was employed for the optical waveguide and the electrode of ACPS (asymmetric coplanar strip) type was formed by electro-plating on LiNbO$_3$ for applying microwave signal with a dimension of width 18${\mu}{\textrm}{m}$, gap 9${\mu}{\textrm}{m}$ and length 50mm. The fabricated single-moded modulator operated at a 1550nm wavelength exhibits its modulation bandwidth, insertion loss and driving voltage of 7㎓, 3.0dB and 6V, respectively.

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Analysis of the Operating Point and Fault Current Contribution of a PEMFC as Distributed Generation (DG)

  • Moon, Dae-Seong;Kang, Gi-Hyeok;Chung, Il-Yop;Won, Dong-Jun
    • Journal of Electrical Engineering and Technology
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    • v.4 no.3
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    • pp.382-388
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    • 2009
  • Recently, hydrogen energy has been anticipated to change the paradigm of conventional power systems because it can expand sustainable energy utilization and conceptually provide remarkable flexibility to power system operation. Since hydrogen energy can be converted to electric energy through fuel cells, fuel cells are expected to play an important role in the future hydrogen economy. In this paper, a Proton Exchange Membrane Fuel Cell (PEMFC) is modeled as an equivalent circuit and its steady-state characteristics investigated using the model. PEMFCs can be connected to power systems through power conditioning systems, which consist of power electronic circuits, and which are operated as distributed generators. This paper analyzes the effects of the characteristics of the PEMFC internal voltages and investigated the dynamic responses of the PEMFC under fault conditions. The results show that the fault current contribution of the PEMFC is different from those of conventional generators and is closely related to its operating point.