• Title/Summary/Keyword: Properties of Aluminium

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Property change of organic light-emitting diodes using a TCNQ (TCNQ를 사용한 유기 발광 소자의 특성 변화)

  • Na, Su-Hwan;Lee, Won-Jae;Hong, Jin-Woong;Chung, Dong-Hoe;Han, Wone-Keun;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.275-276
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    • 2009
  • We have studied physical properties of organic light-emitting diodes (OLEDs) in a device with 7,7,8,8-tetracyanoquinodimethane (TCNQ). Since the TCNQ has a high electron affinity, it is widely used for a charge-transport and injection layer. And the TCNQ-derivatives have also been used to control the conductivity of the materials. It is known that a charge injection and transport in OLEDs with a TCNQ-derivative enhances a performance of the devices such as operating voltage and efficiency. To see how the TCNQ affects on the device performance, we have made a reference device in a structure of ITO(170nm)/TPD(40nm)/$Alq_3$(60nm)/LiF(0.5nm)/Al(100nm). And several type of devices were manufactured by doping TCNQ either in TPD or $Alq_3$ layer. The TCNQ layer was also formed in between the organic layers. N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD), tri(8-hydroxy quinoline) aluminium ($Alq_3$), and TCNQ layers were formed by thermal evaporation at a pressure of $10^{-6}$ torr. The deposition rate was $1.0{\sim}1.5\;{\AA}/s$ for TPD, and $1.0{\sim}1.5\;{\AA}$ for $Alq_3$. The LiF was thermally evaporated at a deposition rate of $0.2\;{\AA}/s$ successively. The device with TCNQ-derivative improved the turn-on voltage compared to the one without TCNQ-derivative.

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Al2TiO5-machinable Ceramics Made by Reactive Sintering of Al2O3 and TiO2 (Al2O3와 TiO2의 반응소결로 제조한 Al2TiO5-기계가공성 세라믹스)

  • Park, Jae-Hyun;Lee, Won-Jae;Kim, Il-Soo
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.498-502
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    • 2010
  • Aluminium titanate($Al_2TiO_5$) has extremely anisotropic thermal expansion properties in single crystals, and polycrystalline material spontaneously microcracks in the cooling step after sintering process. These fine intergranular cracks limit the strength of the material, but provide an effective mechanism for absorbing strain energy during thermal shock and preventing catastrophic crack propagation. Furthermore, since machinable BN-ceramics used as an insulating substrate in current micro-electronic industry are very expensive, the development of new low-cost machinable substrate ceramics are consistently required. Therefore, cheap $Al_2TiO_5$-machinable ceramics was studied for the replacement of BN ceramics. $Al_2O_3-Al_2TiO_5$ ceramic composite was fabricated via in-situ reaction sintering. $Al_2O_3$ and $TiO_2$ powders were mixed with various mol-ratio and sintered at 1400 to $1600^{\circ}C$ for 1 h. Density, hardness and strength of sintered ceramics were systematically measured. Phase analysis and microstructures were observed by XRD and SEM, respectively. Machinability of each specimens was tested by micro-hole machining. The results of research showed that the $Al_2TiO_5$-composites could be used for low-cost machinable ceramics.

Comparing the Dyeing Properties of Synthetic Mordants and Hwangsu Spring

  • Ahn, In-Yong;Suh, Hwa-Jin;Song, Eun-Young;Lee, Kyung-Ok;Kim, Jung-Su;Park, Young-Mi;Kwon, Oh-Oun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.121-121
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    • 2012
  • To evaluate the Hwangsu spring as natural mordants effect on dyeing. The natural mordant effect of Hwangsu spring was analyzed by pH, temperature, trace elements and organic matter. Hwangsu spring having pH 2.42 and $14.4^{\circ}C$ was harvested at the end of September, 2011, in Yeongcheon(Gyeongbuk Province, Korea) and left on a $0^{\circ}C$ and $25^{\circ}C$ before use. The Result of ICP analysis, it contain bned Fe(414.9 ppm), Al(88.9 ppm), Mn(4.9 ppm). Dyeing and post-mordant procedure; Fabrics(cotton, silk, rayon) were dyed with natural colorants(Sopbora Japonica L., Caesalpinia sappan L., Allium cepa L.) for 20 min at $80^{\circ}C$. Hwangsu spring, aluminium sulfate $14-18H_2O(Al_2(SO_4)_3{\cdot}14-18H_2O)$, iron sulfate peptahydrate($FeSO_4{\cdot}7H_2O$), copper sulfate pentahydrate($CuSO_4{\cdot}5H_2O$) were used by post mordants. But in the case of Caesalpinia sappan L. was dyed after pre-mordanting with Al(II). The fabrics were dyed with each mordant solutions at $25^{\circ}C$ for 10min. The colorless also was measured by color-differnce meter. Comparison with a synthetic mordants, the K/S values of cotton fabrics dyed with Hwangsu sping were increased.

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A Study on the standardize the characteristic evaluation of DC magnetron sputtered silver coatings for engineering purposes (D.C. magnetron sputter를 이용한 Ag layer 건식 도금층의 특성 평가 국제 표준화에 대한 연구)

  • Gyawali, Gobinda;Choi, Jinhyuk;Lim, Tae Kwan;Jung, Myoung Joon;Lee, Soo Wohn
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.249-249
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    • 2015
  • Silver films have been of considerable interest for years due to their better performance relative to other metal films for engineering applications. A series of multi-layer silver coatings with different thickness (i.e. 0.3 um to 1.5 um) were prepared on Aluminium substrate containing copper undercoat by direct current (DC) magnetron sputtering method. For the comparative purpose, similar thickness silver coatings were prepared by electrolytic deposition method. Microstructural, morphological, and mechanical characteristics of the silver coatings were evaluated by means of scanning electron microscope (SEM), X-ray diffraction (XRD), Surface roughness test, microhardness test and nano-scratch test. From the results, it has been elucidated that the silver films prepared by DC magnetron sputtering method has superior properties in comparison to the wet coating method. On the other hand, DC magnetron sputtering method is relatively easier, faster, eco-friendly and more productive than the electrolytic deposition method that uses several kinds of hazardous chemicals for bath formulation. Therefore, a New Work Item Proposal (NWIP) for the test methods standardization of DC magnetron sputtered silver coatings has recently been proposed via KATS, Korea and a NP ballot is being progressed within a technical committee "ISO/TC107-metallic and other inorganic coating".

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One-Dimensional Modeling of Hydrogen Generator (수소발생기의 일차원 모델링)

  • Park, Jae Hyun;Lee, Hyojin;Valderrama, Edgar Willy Rimarachin;Yim, Chungsik;Yang, Heesung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.2
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    • pp.74-86
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    • 2018
  • This paper presents the one-dimensional model of a hydrogen generator, where the alkali solution was supplied from the top to the dry aluminum powders. Hydrogen was produced as the solution moved downward and reacted with aluminum. The species conservation equations were considered for the hydrogen gas and alkali solution, while the energy conservation equation was applied to the gas-liquid-solid mixture as a single medium. The gas rising velocity and liquid penetration velocity were also included in the theoretical approach. The developed code was validated with the experimental data of the hydrogen production amount and collector pressure. Additionally, the model successfully predicted the various reactor properties, such as the concentrations, volume fractions, and temperatures, and is expected to help significantly in the design of a novel hydrogen generator.

Analysis of Residual Stresses Induced by Cold Expansion Using Finite Element Method (유한요소법을 이용한 홀 확장 잔류응력 해석)

  • Kim, Cheol;Yang, Won-Ho;Heo, Seong-Pil;Jeong, Gi-Hyeon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.2
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    • pp.46-51
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    • 2002
  • Cold expansion of fastener holes is a mechanical process widely used in the aerospace industry. This treatment leads to an improvement of fatigue behavior due to the developed compressive residual stresses on the hole surface. The residual stress profile depends on the parameters of cold expansion, which are expanding rate, inserting direction of mandrel, material properties dtc. Despite its importance to aerospace industiries, little attention has been devoted to the accurate modeling of the process. In this paper, three-dimensional finite element simulations have been conducted for the cold expansion in an aluminium plate in order to predict the magnitude and distribution of the residual stress. To prove the results of FE analysis, the residual strain was measured by strain gage in cold expansion test. Maximum compressive residual stress could be increase about 7 percentage using the 2-step cold expansion method.

Beam Spoiler-dependent Total Body Irradiation Dose Assessment (전신방사선조사 시 선속 스포일러에 따른 선량 분포 및 영향 평가)

  • Lee, Dong-Yeon;Kim, Jung-Hoon
    • Journal of radiological science and technology
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    • v.41 no.2
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    • pp.141-148
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    • 2018
  • This study examined the properties of photons and the dose distribution in a human body via a simulation where the total body irradiation(TBI) is performed on a pediatric anthropomorphic phantom and a child size water phantom. Based on this, we tried to find the optimal photon beam energy and material for beam spoiler. In this study, MCNPX (Ver. 2.5.0), a simulation program based on the Monte Carlo method, was used for the photon beam analysis and TBI simulation. Several different beam spoiler materials (plexiglass, copper, lead, aluminium) were used, and three different electron beam energies were used in the simulated accelerator to produce photon beams (6, 10, and 15 MeV). Moreover, both a water phantom for calculating the depth-dependent dosage and a pediatric anthropomorphic phantom for calculating the organ dosage were used. The homogeneity of photon beam was examined in different depths for the water phantom, which shows the 20%-40% difference for each material. Next, the org an doses on pediatric anthropomorphic phantom were examined, and the results showed that the average dose for each part of the body was skin 17.7 Gy, sexual gland 15.2 Gy, digestion 13.8 Gy, liver 11.8 Gy, kidney 9.2 Gy, lungs 6.2 Gy, and brain 4.6 Gy. Moreover, as for the organ doses according to materials, the highest dose was observed in lead while the lowest was observed in plexiglass. Plexiglass in current use is considered the most suitable material, and a 6 or 10 MV photon energy plan tailored to the patient condition is considered more suitable than a higher energy plan.

An Experimental Study on the Fire Risk Assessment & Calculation Breakthrough Time through Permeation Test of Chemical Protective Clothing (화학보호복의 화재위험성 및 화학적 투과시험을 통한 파과시간산정에 관한 실험적 연구)

  • Ko, Jae-Sun;Park, Pyoung-Kyu
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.21-30
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    • 2010
  • We have test chemical resistance and flame retardant properties of chemical protective clothing Fabrics by the ASTM and ISO standard methods. The flame retardant test results show that polyethylene is poor in flame resistance but fluoroelastomer add to decabrom is excellent in flame resistance. Especially, nowadays heat protective clothing for firefighters, which is aluminized film layers laminated to aramid fabric, show the excellent flame resistance. However, the chemical resistance test results show that aluminium is high corrosive in 4M NaOH solution alone. The problem of corrosion can be overcome by employing multiple barrier film. Also, based on the result of flame retardant test, duel skin of polymer barrier film add to aluminum film and single skin of fluorinated rubber with flame retardant materials seems to be fit for the chemical protective clothing. Also the thermal protection and heat transfer test results show that TPP and HTI is increased assured that the continued study on fire risk assessment & chemical resistance of chemical protective clothing fabrics will contribute to the upgrade the performances of chemical protective clothing fabrics.

Fabrication and Characterization of Zirconia-Alumina Composites by Organic-Inorganic Solution Technique (유기물-무기물 용액법을 이용한 지르코니아-알루미나 복합체의 제조 및 특성)

  • Kim, Youn Cheol;Bang, Moon-Soo;Lee, Sang Jin
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.628-634
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    • 2005
  • Zirconia-alumina polymer precursor was prepared from zirconium acetylacetonate (ZA). paluminium nitrate (AN), polyethylene glycol (PEG), and ethyl alcohol via an organic-inorganic solution technique. The thermal properties and viscosity of the polymer precursor were measured by differential scanning calorimetry (DSC), thermograbimetric analyzer (TGA), and dynamic viscometer. The vigorous exothermic reaction with volume expansion occurred at $140^{\circ}C$. The volume expansion was caused by abrupt decomposition of the organic group in metal compounds and the metal ions-PEG reaction. The evidences for these reactions were confirmed by FT-IR and $^{13}C$ solid NMR results. The peak intensity at N-O, O-H and C=C decreased with increasing temperature. This indicated that the decomposition of metal compounds and the metal ions-PEG reaction occurred during the vigorous exothermic reaction. At $800^{\circ}C$ for 2 h, the porous powders transformed to the crystalline $ZrO_2-Al_2O_3$ composites.

Powder Metallurgy for Light Weight and Ultra-Light Weight Materials

  • Kieback, B.;Stephani, G.;Weiβgarber, T.;Schubert, T.;Waag, U.;Bohm, A.;Anderson, O.;Gohler, H.;Reinfried, M.
    • Journal of Powder Materials
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    • v.10 no.6
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    • pp.383-389
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    • 2003
  • As in other areas of materials technology, the tendency towards light weight constructions becomes more and more important also for powder metallurgy. The development is mainly driven by the automotive industry looking for mass reduction of vehicles as a major factor for fuel economy. Powder metallurgy has to offer a number of interesting areas including the development of sintered materials of light metals. PM aluminium alloys with improved properties are on the way to replace ferrous pars. For high temperature applications in the engine, titanium aluminide based materials offer a great potential, e.g. for exhaust valves. The PM route using elemental powders and reactions sintering is considered to be a cost effective way for net shape parts production. Furthermore it is expected that lower costs for titanium raw materials coming from metallurgical activities will offer new chances for sintered parts with titanium alloys. The field of cellular metals expands with the hollow sphere technique, that can provide materials of many metals and alloys with a great flexibility in structure modifications. These structures are expected to be used in improving the safety (crash absoption) and noise reduction in cars in the near future and offer great potential for many other applications.