• Journal of the Korean Institute of Gas
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• v.9 no.1 s.26
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• pp.9-15
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• 2005

Hydrogen is considered to be the most important future energy carrier in many applications reducing significantly greenhouse gas emissions, but the safety issues associated with hydrogen applications need to be investigated and fully understood to be applicable as the carrier. Therefore, there is a considerable demand for further research concerning the dispersion of hydrogen/air mixture clouds and the possible consequences of their ignition. In this study, the dispersion of hydrogen gas in atmosphere has been analysed with atmospheric condition by concerning the buoyancy of hydrogen. The hazard ranges to wind direction increase with wind speed and the stability of atmosphere. The concentration of hydrogen at just above ground is nearly zero due to buoyancy of hydrogen gas. Therefore, the ignition probability of hydrogen gas cloud is low and the hazard of explosion or fire associated with hydrogen gas is relatively low comparing with the other fuel gas such as propane or butane.

• Journal of Sensor Science and Technology
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• v.27 no.4
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• pp.237-241
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• 2018

The real-time enrichment and detection of pathogens are serious issues and rapidly evolving field of research because of the ability of these pathogens to cause infectious diseases. In general, bacterial detection is accomplished by conventional colony counting or by polymerase chain reaction (PCR) after DNA extraction. As colony counting requires considerable time to cultivate, PCR is an attractive method for rapid detection. A small number of pathogens can cause diseases. Hence, a pretreatment process, such as enrichment is essential for detecting bacteria in an actual environment. Thus, in this study, we developed a microfluidic chip capable of performing rapid enrichment of bacteria and the extraction of their genes. A lectin, i.e., Concanavalin A (ConA), which shows binding affinity to the surface of most bacteria, was coated on the surface of magnetic particles to nonspecifically capture bacteria. It was subsequently concentrated through magnetic forces in a microfluidic channel. To lyse the captured bacteria, magnetic particles were irradiated by a wavelength of 532nm. The photo-thermal effect on the particles was sufficient for extracting DNA, which was consequently utilized for the identification of bacteria. Our device will help monitor the existence of bacteria in various environmental situations such as water, air, and soil.

• Journal of the Korean Ceramic Society
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• v.13 no.1
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• pp.25-29
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• 1976

The properties vary with quality of ferric-oxide that is major material of ferrites. In this point of view, a manufacturing method of pure and homogeneous fine ferric oxide is very important. The characters of this study are as follows: 1) Ferric oxide was made from waste pickling liquor of steel. 2) The crude ferric-oxide that is made by roasting the pickling liquor was dissolved in 20% HCI solution and then produced ferric chloride is purified by ethyl ether extraction. 3) The methanol solution of purified ferric chloride was sprayed into the refractory tube with compressed air and propane gas and then ignited leading to the ferric-oxide powder. 4) The produced oxide powder was introduced to the scrubber type vessel throught cooling system in order to collect the powder. 5) Crystalline phase of the powder was identified by X-ray diffraction and particle size, crystalline shape of the powder were investigated by settling method and electron microscope and the effects of concentration of ferric chloride in methanol on grain size were discussed. Results were obtained as fellows: 1) Total impurity in the ferric oxide produced from waste pickling liquor was 3.7%. 2) The solubilityof crude ferric oxide that was made from waste pickling liquor in HCI solution increased with the HCI concentration and reached to saturation range at 15% HCI concentration. 3) Extraction of FeCl3 increased with HCI concentration which is solvent. 4) Alpha ferric oxide obtained was very fine crystalline particles, the mean crystalline grain increased with the concentration of ferric chloride, and mean grain size distributed from 3.5$\mu$(at 0.5mole/l) to 0.5$\mu$(at 0.05mole/l).

• Asian Journal of Atmospheric Environment
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• v.9 no.2
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• pp.146-157
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• 2015

Emissions of ozone precursors ($NO_x$ and VOCs) and photochemical ozone creation potentials (POCPs) of VOC emission sources were investigated in the largest port city (i.e., Busan), Korea during the year 2011. This analysis was performed using the Clean Air Policy Support System (CAPSS) national emission inventory provided by the National Institute of Environmental Research (NIER), Korea. For $NO_x$, the emissions from off-road mobile sources in Busan were the most dominant (e.g., $31,202ton\;yr^{-1}$), accounting for about 60% of the total $NO_x$ emissions. The emission from shipping of off-road mobile sources (e.g., $24,922ton\;yr^{-1}$) was a major contributor to their total emissions, amounting to 47% of the total $NO_x$ emissions due to the port-related activities in Busan. For VOCs, the emission source category of solvent usage was predominant (e.g., $36,062ton\;yr^{-1}$), accounting for approximately 82% of the total VOC emissions. Out of solvent usages, the emission from painting was the most dominant ($22,733ton\;yr^{-1}$), comprising 52% of the total emissions from solvent usages. The most dominant VOC species emitted from their sources in Busan was toluene, followed by xylene, butane, ethylbenzene, n-butanol, isopropyl alcohol, and propane. The major emission sources of toluene and xylene were found to be painting of coil coating and ship building, respectively. The value of POCP for the off-road mobile source (61) was the highest in ten major activity sectors of VOC emissions. Since the POCP value of ship transport of off-road mobile source (72) was also high enough to affect ozone concentration, the ship emission can play a significant role in ozone production of the port city like Busan.

• Proceedings of the Korea Society for Industrial Systems Conference
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• 2002.06a
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• pp.356-360
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• 2002

Polluting the air with such pollutants as CO, H₂S and SO₂, industrial development huts increased the danger of gas toxication. Futhermore, as the: living standard goes higher, the consumption of explosive hydrocarbonic gases such as butane(C₄H/sub 10/) or propane(C₃H/sub 8/) has been soaring, which results in the danger of a gas explosion. As measures to cope with such dangers, the development of highly sensitive gas sensors, gas detectors adopting gas-sensing technologies, and gas recognition systems are urgently required. The objective of the present research is to develop a gas recognition system that is capable of identifying specific types of selected gases by formulating a semiconductor-typed gas sensor array, which not only improves the selectivity of semiconductor-typed gas sensors but also minimizes the erect of drifts on a single sensor signal, and applying the input pattern data of gases detected by the array to a neural network.

• Journal of Advanced Marine Engineering and Technology
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• v.32 no.4
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• pp.534-541
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• 2008

This paper deals with the heat transfer characteristics of R-290 (Propane), R-600a (Iso-butane) and R-1270 (Propylene) as an environment friendly refrigerant and R-22 as a HCFC's refrigerant for evaporating. The experimental apparatus has been set-up as conventional vapor compression type refrigeration and air-conditioning system. The test section is a horizontal double pipe heat exchanger. Evaporating heat transfer measurements were performed for smooth tube with the outer diameters of 12.70, 9.52 and 6.35 mm and micro-fin tube 12.70 mm, respectively. For the smooth and micro-fin tubes measured in this study, the evaporating heat transfer coefficient was enhanced according to the increase of the mass flux and decrease of the tube diameter. The local evaporating heat transfer coefficients of hydrocarbon refrigerants were superior to those of R-22 and the maximum increasing rate of heat transfer coefficient was found in R-1270. The average evaporating heat transfer coefficients in hydrocarbon refrigerants showed 20 to 28% higher values than those of R-22. Also, the evaporating heat transfer coefficients of R-22 in the tube diameter of the 12.70 mm smooth and micro-fin tube were compared. Generally, the local heat transfer coefficients for both types of tubes increased with an increase of the mass flux. The heat transfer enhancement factor (EF) between smooth and micro-fin tube varied from 1.9 to 2.7 in all experimental conditions.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.40 no.1
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• pp.11-19
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• 2003

A micro sensor array with 4 discrete sensors integrated on a microhotplate was developed for identifying the kinds and quantities of explosive gases. The sensor array consisited of four tin oxide-based thin films with the high and broad sensitivity to the tested explosive gases and uniform thermal distribution on the plate. The microhotplate, using silicon substrate with N/O/N membrane, dangling in air by Al bonding wires, and controlling the thickness by chemical mechanical process (CMP), has been designed and fabricated. By employing the sensitivity signal of the sensor array at 40$0^{\circ}C$, we could reliably classily the kinds and quantities of the explosive gases like butan, propane, LPG, and carbon monoxide within the range of threshold limit values (TLVs), employing principal component analysis (PCA).

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.3
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• pp.589-597
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• 1992

The effect of pressure on soot formation in premixed propane-air combustion is investigated at high pressures over the pressure range of 1 to 5 MPa by using a specially designed constant volume combustion bomb. The combustiom chamber of disk type with eight spark plugs located on the circumference at an interval of 45deg is 100mm in diameter by 14mm thick. The end gases are compressed to high pressures by the eight converging flames. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in-situ laser extinction technique, and the burnt gas temperature during the same period is measured by the two-color method. It is found that the soot yield rises with 50 to 100% for the respective equivalence ratio range of 1.9-2.2 at an interval of 0.1 when the combustion pressure is increased from 1 to 5 MPa, and that the turbulent flames decrease in the soot yield as compared with the laminar flames because the burnt gas temperatures increase with the drop of heat loss.

• Journal of the Korean Institute of Gas
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• v.5 no.2 s.14
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• pp.22-29
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• 2001

The number of gas containers and the period of exchanging gas containers are vsy important in designing liquefied petroleum gas(LPG) supply system for small capacity domain. And also the evaluation of remaining LPG in containers to be exchanged is very useful information in commerce. However seldon has been studied on calculating method about those with respect to gas consumption pattern. In this study, a simulation method was developed to estimate the evaporation capacity of LPG container, the mass gas flow rate from LPG container, the temperature and vapor pressure of LPG, and the remained LPG at containers to be exchange by using LPG property equations, mass balance equation, and heat balance equation. The simulation results were correlated well with experimental data. The overall heat transfer coefficient from air to LPG is approximately $9{\~}13 kcal/m^2{\cdot}hr{\cdot}^{\circ}C$ and does not strongly affect on the evaporation capacity of LPG container. The mass gas flow rate from LPG container is constant when the vapor pressure of LPG is within pressure regulator's control range. While, out of range, it suddenly reduce to a evaporation rate which is balanced with heat transfer from air. The evaporation capacity of LPG container increased with surrounding temperature and the composition of propane, and decreased drastically with continuous gas consumption. The number of gas containers divided the number of houses using gas supply system was reduced by using automatic gas feeding device.

• Clean Technology
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• v.25 no.1
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• pp.81-90
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• 2019

A dielectric barrier discharge (DBD) plasma reactor packed with $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst was used for the dry ($CO_2$) reforming of propane (DRP) to improve the production of syngas (a mixture of $H_2$ and CO) and the catalyst stability. The plasma-catalytic DRP was carried out with either thermally or plasma-reduced $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst at a $C_3H_8/CO_2$ ratio of 1/3 and a total feed gas flow rate of $300mL\;min^{-1}$. The catalytic activities associated with the DRP were evaluated in the range of $500{\sim}600^{\circ}C$. Following the calcination in ambient air, the ${\gamma}-Al_2O_3$ impregnated with the precursor solution ($Ni(NO_3)_2$ and $Ce(NO_3)_2$) was subjected to reduction in an $H_2/Ar$ atmosphere to prepare $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst. The characteristics of the catalysts were examined using X-ray diffraction (XRD), transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectrometry (EDS), temperature programmed reduction ($H_2-TPR$), temperature programmed desorption ($H_2-TPD$, $CO_2-TPD$), temperature programmed oxidation (TPO), and Raman spectroscopy. The investigation revealed that the plasma-reduced $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst exhibited superior catalytic activity for the production of syngas, compared to the thermally reduced catalyst. Besides, the plasma-reduced $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst was found to show long-term catalytic stability with respect to coke resistance that is main concern regarding the DRP process.