• 한국신재생에너지학회:학술대회논문집
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• 2005.11a
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• pp.634-637
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• 2005

Hydrogen adsorption mechanism onto the porous metal-organic frameworks (MOFs) has been studied by density functional theory calculation. The selected functionals for the predict ion of interact ion energies between hydrogen and potential adsorption sites of MOF was utilized after the evaluation with the various functionals for interaction energy of $H_2C_6H_6$ model system the adsorption energy of hydrogen molecule into MOF was investigated with the consideration of the favorable adsorption sites and the orientations. We also calculated the second favorable adsorption sites by geometry optimization using every combination of two first absorbed hydrogen molecules. Based on the calculation of first and second adsorption sites and energies, the hydrogen adsorption into MOF follows a cooperative mechanism in which the initial metal sites initiate the propagation of the hydrogen adsorption on the whole frameworks. In addition, it was found that the interaction strength between the simple benzene ring with hydrogen is significantly reinforced when the benzene ring has been incorporated into the framework of MOFs.

• Journal of Electrical Engineering and information Science
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• v.2 no.3
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• pp.71-76
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• 1997

A lot of experiments and analyses have been done to determine the aging mechanism of mica-epoxy composite material used for large generator stator windings in order to estimate remaining life of the generator for last decades. After degrading artificially the mica-epoxy composite material, the surface analysis is performed to analyze breakdown mechanism of insulation in air and hydrogen atmosphere; i) In the case of air atmosphere, it is observed that an aging propagation from conductor to core by partial discharge effect and the formation of cracks between layers is widely carbonized surface. ii) In case of hydrogen atmosphere, the partial discharge effect is reduced by the hydrogen pressure (4kg/$\textrm{cm}^2$). Potassium ions forming a sheet of mica is replaced by hydrogen ions, which can lead to microcracks. It is confirmed that the sizes of crack by SEM analysis are 10∼20[$\mu\textrm{m}$] in length under air, and 1∼5[$\mu\textrm{m}$] in diameter, 10∼50[$\mu\textrm{m}$] in length under hydrogen atmosphere respectively. The breakdown mechanism of sttor winding insulation materials which are composed of mica-epoxy is analyzed by the component of materials with EDS, SEM techniques. We concluded that the postassium ions of mica components are replaced by H\ulcorner, H$_3$O\ulcorner at boundary area of mica-epoxy and/or mica-mica. It is proposed that through these phenomena, the conductive layers of potassium enable creation of voids and cracks due to thermal, mechanical, electrical and environmental stresses.

• Korean Chemical Engineering Research
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• v.47 no.5
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• pp.572-579
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• 2009

This study is to investigate experimentally the flame structure and propagation mechanism in dust explosions and to provide the fundamental knowledge. Upward propagating laminar dust flames in a vertical duct of 1.8 m height and 0.15 m square cross-section are observed and flame front is visualized using by a high-speed video camera. Also, the thicknesses of preheated and reaction zone have been determined by a schlieren, electrostatic probe and thermocouple. The thickness of preheated zone in lycopodium dust flame is observed to be 4~13 mm, about several orders of magnitude higher than that of premixed gaseous flames. From the experimental results by a PIV(Particle Image Velocimetry) system, a certain residence time of the unburned particle in preheated zone is needed to generate combustible gas from the particle. The residence time will depend on preheated zone thickness, particle velocity and flame propagation velocity.

• Geomechanics and Engineering
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• v.22 no.6
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• pp.529-540
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• 2020

Water inrush is a major hazard for mining and excavation in deep coal seams or rock masses. It can be attributed to the coalescence of rock fractures in rock mass due to the interaction of fractures, hydraulic flow and stress field. One of the key technical challenges is to understand the course and mechanism of fluid flows in rock joint networks and fracture propagation and hence to take measures to prevent the formation of water inrush channels caused by possible rock fracturing. Several case observations of fluid flowing in rock joint networks and coupled fracture propagation in underground coal roadways are shown in this paper. A number of numerical simulations were done using the recently developed flow coupling function in FRACOD which simulates explicitly the fracture initiation and propagation process. The study has demonstrated that the shortest path between the inlet and outlet in joint networks will become a larger fluid flow channel and those fractures nearest to the water source and the working faces become the main channel of water inrush. The fractures deeper into the rib are mostly caused by shearing, and slipping fractures coalesce with the joint, which connects the water source and eventually forming a water inrush channel.

• Journal of Korean Society of Transportation
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• v.22 no.4 s.75
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• pp.147-158
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• 2004

A class of SWP(Stochastic Wane Propagation) models microscopically mimics individual vehicles' stochastic behavior and traffic jam propagation with simplified car-following models based on CA(Cellular Automata) theory and macroscopically captures dynamic traffic flow relationships based on statistical physics. SWP model, a program-oriented model using both discrete time-space and integer data structure, can simulate a huge road network with high-speed computing time. However, the model has shortcomings to both the capturing of low speed within a jam microscopically and that of the density and back propagation speed of traffic congestion macroscopically because of the generation of spontaneous jam through unrealistic collision avoidance. In this paper, two additional rules are integrated into the NaSch model. The one is SMR(Stopping Maneuver Rule) to mimic vehicles' stopping process more realistically in the tail of traffic jams. the other is LAR(Low Acceleration Rule) for the explanation of low speed characteristics within traffic jams. Therefore, the CA car-following model with the two rules prevents the lockup condition within a heavily traffic density capturing both the stopping maneuver behavior in the tail of traffic jam and the low acceleration behavior within jam microscopically, and generates more various macroscopic traffic flow mechanism than NaSch model's with the explanation of propagation speed and density of traffic jam.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1995.10a
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• pp.419-422
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• 1995

In this paper, we propose two methods for AE source location on the material with unknown AE wave velocity. By this method, we can apply this method to arbitrary material of which properties are not known exactly. Also, in this paper, the mechanism of error generation in both methods are discussed and performances are compared by using computer simulation and experiments which uses a lead break as the AE source on the aluminum plate.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.10a
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• pp.167-170
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• 2004

In order to investigate the impact behaviors of 3-D braided glass/epoxy composites, the energy profiles and damage area were compared to the laminates of similar volume fraction and composition. The energy profiles showed different characteristics from each other which indicates they have distict energy absorption mechanisms. The image analysis on the damage projections visualized the crack propagation paths along the fiber direction.

• Journal of the Korean Society of Visualization
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• v.2 no.1
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• pp.52-56
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• 2004

Several visualization techniques of laser diagnostics are presented for combustion phenomena, including Mie scattering for flow, Rayleigh and Raman scattering spectroscopy for major species, laser-induced fluorescence for minor species, and laser-induced incandescence for soot. These techniques have been applied to understand the various combustion phenomena more clearly, including buoyancy-dominant flow system, diffusion flam oscillation, laminar and turbulent lifted flames, flame propagation along a vortex ring, and soot zone characteristics. The usefulness of laser diagnostics on a better understanding of physical mechanism is demonstrated.

• Proceedings of the Korean Geotechical Society Conference
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• 1993.06a
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• pp.73-82
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• 1993

Ground-borne vibration is one of the main causes of environmental impact from subway systems. The vibration resulting from track-train interaction is transuutted through the tunnel structure and the surrounding ground to adjacent buildings. This paper provides a summary of proposed noise and vibration criteria, a review of the ground vibration propagation mechanism and the theoretical isolation effectivenesss of each of the following underground transit systems : track, tunnel and vehicle itself.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07a
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• pp.155-160
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• 2005

Computer simulations of a pdp discharges provide unique information necessary for their analysis, unavailable otherwise. Statistical instability of the ramp discharge and the role of exoemission, nature of striations during sustain discharge, physical mechanism responsible for the propagation of the cathode ionization wave, and line loading effects are just a few examples when simulations can be successfully used.