• Title/Summary/Keyword: Process Cycle Efficiency

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Synthesis and Electrochemical Properties of Li3V2(PO4)3-LiMnPO4 Composite Cathode Material for Lithium-ion Batteries

  • Yun, Jin-Shik;Kim, Soo;Cho, Byung-Won;Lee, Kwan-Young;Chung, Kyung Yoon;Chang, Wonyoung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.433-436
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    • 2013
  • Carbon-coated $Li_3V_2(PO_4)_3-LiMnPO_4$ composite cathode materials are first reported in this work, prepared by the mechanochemical process with a complex metal oxide as the precursor and sucrose as the carbon source. X-ray diffraction pattern of the composite material indicates that both olivine $LiMnPO_4$ and monoclinic $Li_3V_2(PO_4)_3$ co-exist. We further investigated the electrochemical properties of our $Li_3V_2(PO_4)_3-LiMnPO_4$ composite cathode materials using galvanostatic charging/discharging tests, where our $Li_3V_2(PO_4)_3-LiMnPO_4$ composite electrode materials exhibit the charge/discharge efficiency of 91.9%, while $Li_3V_2(PO_4)_3$ and $LiMnPO_4$ exhibit the efficiency of 87.7 and 86.7% in the first cycle. The composites display unique electrochemical performances in terms of overvoltage and cycle stability, displaying a reduced gap of 141.6 mV between charge and discharge voltage and 95.0% capacity efficiency after $15^{th}$ cycles.

Thermodynamic Analysis on Organic Rankine Cycle Using Exhaust Gas of the Chimney in a Resource Recovery Facility (폐기물 소각시설 굴뚝의 배기가스를 이용한 유기랭킨사이클 시스템의 열역학적 해석)

  • Kim, Sunhee;Sung, Taehong;Kim, Kyung Chun
    • Journal of the Korean Institute of Gas
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    • v.21 no.5
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    • pp.27-35
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    • 2017
  • The amount and quality of waste heat from a resource recovery facility were measured. The temperature of exhaust gas was $176.6^{\circ}C$ and the amount of that was 13.8 kg/s. This research designed a waste heat recovery system whose working fluid is R-245fa. It simulated three study cases as follows. In simulation of a basic ORC system, the turbine power output and thermal efficiency were respectively 96.56 kW, 14.3%. In simulation of a superheater connection, 0.09% of efficiency could be improved due to the increase of enthalpy by overheating of working fluid, but the obtained output was decreased with 16.58kW because of the decrease of working fluid mass. In simulation of a process heater connection, efficiency was increased up to 38.51%.

Reprocessing of fluorination ash surrogate in the CARBOFLUOREX process

  • Boyarintsev, Alexander V.;Stepanov, Sergei I.;Chekmarev, Alexander M.;Tsivadze, Aslan Yu.
    • Nuclear Engineering and Technology
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    • v.52 no.1
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    • pp.109-114
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    • 2020
  • This work presents the results of laboratory scale tests of the CARBOFLUOREX (CARBOnate FLUORide EXtraction) process - a novel technology for the recovery of U and Pu from the solid fluorides residue (fluorination ash) of Fluoride Volatility Method (FVM) reprocessing of spent nuclear fuel (SNF). To study the oxidative leaching of U from the fluorination ash (FA) by Na2CO3 or Na2CO3-H2O2 solutions followed by solvent extraction by methyltrioctylammonium carbonate in toluene and purification of U from the fission products (FPs) impurities we used a surrogate of FA consisting of UF4 or UO2F2, and FPs fluorides with stable isotopes of Ce, Zr, Sr, Ba, Cs, Fe, Cr, Ni, La, Nd, Pr, Sm. Purification factors of U from impurities at the solvent extraction refining stage reached the values of 104-105, and up to 106 upon the completion of the processing cycle. Obtained results showed a high efficiency of the CARBOFLUOREX process for recovery and separating of U from FPs contained in FA, which allows completing of the FVM cycle with recovery of U and Pu from hardly processed FA.

Analysis of Flight Performance and Efficiency according tothe Number of Consecutive Flight of Navy Pilots (해군 고정익조종사의 비행 훈련 주기에 따른 비행 효과 분석)

  • JungBong Lee
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.31 no.2
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    • pp.66-71
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    • 2023
  • In the case of the Navy, if some of the co-pilots are included in the long-term promotion process due to the limited number of co-pilots, operational flight and administrative tasks will be added to the co-pilots not included in the rest of the Pilot in commander process. Therefore, to solve this problem, the co-pilot who has passed the PQS step-by-step process minimizes the personnel gap in the flight operation unit through a system that evaluates whether it is possible to perform its duties as a co-pilot through actual flight after entering the school. The advantage of the PQS course is that you can control flight plans on your own and minimize gaps in flight and ground work while carrying out the curriculum, but you can't focus on education or improve your skills due to irregular training flight cycles. Therefore, in this study, after collecting opinions on effective flight cycles through a survey of pilots of P-3C, the Navy's fixed-wing aircraft representative, we will analyze the association of aircraft volume performance by flight cycle to derive the optimal flight cycle of the P-3C pilot course.

Analysis of Pre-construction Processes and Development of KMS Prototype of LNG Plant Projects (해외 LNG Plant 프로젝트 초기 프로세스 분석 및 지식관리시스템 프로토타입 구축)

  • Won, Seo-Kyung;Lee, Jun-Bok;Han, Choong-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.6
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    • pp.151-159
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    • 2009
  • Recently, overseas construction projects have been increasing in the Middle East and Southeast Asia regions. These projects require various licenses and technologies for the manufacturing and handling processes. Additionally, the efficiency of the entire process management life cycle determines the success or failure of the business. Nonetheless, there exist various risks involved in the whole life cycle process due to a lack of experience and knowledge of management techniques. The objective of this paper is to analyze the business process of a LNG plant throughout the pre-construction and procurement phases, and to identify the knowledge and information needed for the development of the KMS. The study also plans to build a comprehensive knowledge management system throughout the whole life cycle as its final objective.

A Study on the Treatment of Swine Wastewater by Using Intermittently Aerated Activated Sludge Process (간헐폭기법에 의한 돈사 폐수 처리에 관한 연구)

  • Yang, Tae-Du;Lee, Mi-Kyung;Chung, Yoon-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.4
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    • pp.86-96
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    • 1998
  • In this study, an intermittently aerated activated sludge process, modified process from conventional activated sludge process, was developed to treat high strength swine wastewater, which has been blamed as major pollutant for stream pollution. Therefore, the optimum cycle for oxic and anoxic period, SRT, and OLR were studied as design parameters. The effects of different time interval for oxic and anoxic period on nitrification and denitrification were examined by operating two reactors with 60/60min and 60/90min as oxic/anoxic period. Although the reactor with 60/60min showed complete denitrification of $NO_x-N$ generated during oxic period, the reactor with 60/90min showed incomplete nitrification due to the inactivity of nitrifier by accumulated $NH_3-N$ toxicity during anoxic period. Therefore, it is recommended to operate same interval for oxic and anoxic period. In order to determine the optimum cycle for oxic/anoxic period, four different reactors with 30/30, 60/60, 90/90 and 120/120min were examined. The reactor operation with 90/90min was optimum to get the most stable results in this study. However, the optimum cycle for oxic and anoxic period should be changed with characteristics of influent wastewater and operating conditions. According to lie operation results of three reactors with SRT of 15, 20 and 30days. The reactor with 2Odays SRT showed best removal efficiency of T-N. The optimum OLR would be $2.5Kg\;COD/m^3/day$ which showed the most stable nitrification and denitrification. Since characteristics of influent wastewater in the real system has a severe fluctuation, so it is very difficult to determine each interval for oxic and anoxic period. Therefore, ORP curves, describing the change of oxidation/reduction potential in reactor, can be used as a control parameter for automatic control of oxic and anoxic period. In other words, bending point (Nitrate Knee) of ORP curve during anoxic period could be used as a starting point of oxic period.

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The Effect of Intake and Exhaust Pulsating Flow on the Volumetric Efficiency in a Diesel Engine (디젤기관의 흡.배기관 맥동류가 체적효율에 미치는 영향)

  • Lee, S.D.;Kang, H.Y.;Koh, D.K.;Ahn, S.K.
    • Journal of Power System Engineering
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    • v.10 no.3
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    • pp.11-16
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    • 2006
  • The pressure fluctuation in the intake and exhaust pipe of 4 stroke-cycle diesel engine is caused by reciprocating motion of piston for suction of fresh air and exhaust of burned gas. this gas dynamic effect can be utilized for increase the volumetric efficiency. Many empirical studies have been carried out to investigate the effects of intake pulsating flow on the volumetric efficiency. However, when the gas dynamic effects are utilized for the variable speed engine to increase its performance, The speed range in which the maximum volumetric efficiency is limited and there occurs some difficulties in lay-out of intake system because it become too long. During induction process, as waves travel both directions, they are reflected and interacted each other and pressure waves are transmitted through it. Hence, the flow becomes more complex and unsteady flow. These pressure waves act upon intake pulsating flow and affects on the volumetric efficiency. In this paper the effects of pulsating flow of intake and exhaust pipes on volumetric efficiency were examined and evaluated. It was found that volumetric efficiency was affected by pulsating flow of intake and exhaust pipes.

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Effect of Carbon Capture Using Pre-combustion Technology on the Performance of Gas Turbine Combined Cycle (연소전 처리를 이용한 탄소포집이 가스터빈 복합화력 플랜트의 성능에 미치는 영향)

  • YOON, SUKYOUNG;AHN, JIHO;CHOI, BYEONGSEON;KIM, TONGSEOP
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.571-580
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    • 2016
  • In this paper, performance of the gas turbine combined cycle(GTCC) using pre-combustion carbon capture technology was comparatively analysed. Steam reforming and autothermal reforming were used. In the latter, two different methods were adopted to supply oxygen for the reforming process. One is to extract air form gas turbine compressor (air blowing) and the other is to supply oxygen directly from air separation unit ($O_2$ blowing). To separate $CO_2$ from the reformed gas, the chemical absorption system using MEA solution was used. The net cycle efficiency of the system adopting $O_2$ blown autothermal reforming was higher than the other two systems. The system using air blown autothermal reforming exhibited the largest net cycle power output. In addition to the performance analysis, the influence of fuel reforming and carbon capture on the operating condition of the gas turbine and the necessity of turbine re-design were investigated.

Preliminary design and performance analysis of a radial inflow turbine (유기랭킨사이클용 반경류터빈의 예비설계 및 성능분석)

  • Kim, Do-Yeop;Kang, Ho-Keun;Kim, You-Taek
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.7
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    • pp.735-743
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    • 2015
  • The major component with a significant impact on the thermodynamic efficiency of the organic Rankine cycle is the turbine. Many difficulties occur in the turbine design of an organic Rankine cycle because the expansion process in an organic Rankine cycle is generally accompanied by a dramatic change in the working fluid properties. A precise preliminary design for a radial inflow turbine is hard to obtain using the classic method for selecting the loading and flow coefficients from the existing performance chart. Therefore, this study proposed a method to calculate the loading and flow coefficient based on the number of rotor vanes and thermodynamic design requirements. Preliminary design results using the proposed models were in fairly good agreement with the credible results using the commercial preliminary design software. Furthermore, a numerical analysis of the preliminary design results was carried out to verify the accuracy of the proposed preliminary design models, and most of the dependent variables, with the exception of the efficiency, were analyzed to meet the preliminary design conditions.

Efficiency and Exergy Analysis of New Liquefaction Cycles Applied for LNG FPSO (LNG FPSO에 적용가능한 신액화 사이클의 효율 및 엑서지 분석)

  • Yoon, Jung-In;Son, Chang-Hyo;Baek, Seung-Moon;Kwag, Jin-Woo;Shim, Gyu-Jin
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.5
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    • pp.574-579
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    • 2012
  • This paper presents the new cascade liquefaction cycles using $CO_2-C_2H_6-N_2$ and $CO_2-N_2$. The performance and exergy of cascade liquefaction cycles are analyzed using HYSYS software and then confirmed the possibility of these cycles for LNG-FPSO ship. From the comparison of performance and exergy loss of these cycles, the cascade liquefaction cycles using $CO_2-C_2H_6-N_2$ showed higher performance and the cycle using $CO_2-N_2$ presented higher exergy loss. The cascade liquefaction cycle using $CO_2-N_2$ is lower efficiency and higher compressor work compared to the optimized cascade liquefaction cycle using $C_3H_8-C_2H_4-C_1H_4$. But, if the efficiency of $N_2$ cycle in these liquefaction cycles is improved, it is possible to apply the cascade liquefaction cycle using $CO_2-C_2H_6-N_2$ and $CO_2-N_2$ to LNG-FPSO ship due to the simple composition device of these cycles.