• Title/Summary/Keyword: Probe angle

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Surface free-energy and hydrophobicity of MWCNT using glow plasma at low pressure (저진공 글로플라즈마를 이용한 탄소나노튜브의 표면 자유에너지와 소수성 특성)

  • Cho, Soon-Gook;Lee, Kun-A;Kim, Jung-Won;Ko, Kwang-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.123-123
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    • 2010
  • The hydrophobic coating for multi-walled nanotubes was treated with toluene and trimethylchlorosilane glow discharge plasma under low pressure, and the hydrophobic surface of the treated MWCNT was investigates. In order to investigate the effects of -CH components from the toluene and TMCS glow plasma, we conducted on the total surface free energies of the MWCNT powder, which was calculated by measuring the contact angle between the cushion of MWCNT powder and the probe liquids. The total surface free energies were determined by Owens-Wendt equation and drastically decreased.

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An investigation on flow characteristics of two dimensional inclined wall attaching offset jet (단이 진 경사벽면에 부착되는 2차원 제트유동에 관한 연구)

  • 송흥복;심재경;윤순현
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.1
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    • pp.52-66
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    • 1998
  • An experimental study on the flow characteristics was performed for a two-dimensional turbulent wall attaching offset jet at different oblique angles to a surface. The flow characteristics were investigated by using a split film probe with the modified Stock's calibration method. The jet mean velocity, turbulent intensity, wall static pressure coefficient profiles, and time-averaged reattachment point were measured at the Reynolds number Re (based on the nozzle width, D) ranging from 17700 to 53200, the offset ratio H/D from 2.5 to 10, and the inclined angle .alpha. from 0.deg. C to 40.deg. C. The Correlations between the maximum pressure position, minimum pressure position, and reattachment point and offset ratios, and inclined angles are presented.

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Generation of hydrophobicity on the surfaces of nano and other materials using atmospheric plasmas

  • Kim, Jeong-Won;Cho, Soon-Gook;Ko, Kwang-Cheol;Woo, Hyun-Jong;Chung, Kyu-Sun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.256-256
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    • 2011
  • Using plasmas, hydrophobic surfaces are made on various substances such as polyimide films, filter paper, cotton clothes and multi-walled carbon nanotube (MWCNT) with hexamethyldisiloxane (HMDSO), trimethylchlorosilane (TMCS) and toluene reagents. Plasmas are easily and rapidly to change surface of hydrophilic materials into hydrophobic. We have also optimized processing time and maximized contact angle for super-hydrophobicity of MWCNT. Contact angles have been calculated by measuring between substance and probe liquid, and total surface free energies are determined by the Owens-Wendt equation. Figure 1 shows the measured contact angles with time and ratio of reagents on MWCNT.

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The Orientation of CO in Heme Proteins Determined by Time-Resolved Mid-IR Spectroscopy: Anisotropy Correction for Finite Photolysis of an Optically Thick Sample

  • Lim, Man-Ho
    • Bulletin of the Korean Chemical Society
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    • v.23 no.6
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    • pp.865-872
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    • 2002
  • A systematic way of determining the equilibrium orientation of carbon monoxide (CO) in heme proteins using time-resolved polarized mid-IR spectroscopy is presented. The polarization anisotropy at pump-probe delay time of zero in the limit of zero photolysis and the angular distrbution function of CO are required to obtain the equilibrium orientation of CO. An approach is developed for determining the polarization anisotropy in the zero-photolysis limit from the anisotropy measured under finite photolysis conditions in an optically thick sample where the fraction of molecules photolyzed decreased as the pump pulse passes through and is absorbed by the sample. This approach is verified by measuring the polarization anisotropy of CO of carbonmonoxy myoglobin at various levels of photolysis. This method can be readily applied to other photoselection experiments determining precise angle between transition dipoles.

Real-time X-ray Scattering as a Nanostructure Probe for Organic Photovoltaic Thin Films

  • Lee, Hyeon-Hwi;Kim, Hyo-Jeong;Kim, Jang-Ju
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.181-181
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    • 2013
  • Recently, nanostructure and the molecular orientation of organic thin films have been largely paid attention due to its importance in organic electronics such as organic thin film transistors (OTFTs), organic light emitting diodes (OLEDs), and organic photovoltaics (OPVs). Among various methods, the diffraction and scattering techniques based on synchrotron x-rays have shown powerful results in organic thin film systems. In this work, we introduce the in-situ annealing system installed at PLS-II (Pohang Light Source II) for organic thin films by simultaneously conducting various x-ray scattering measurements of x-ray reflectivity, conventional x-ray scattering, grazing incidence wide angle x-ray scattering (GI-WAXS) and so on. Using the in-situ measurement, we could obtain real time variation of nanostructure as well as molecular orientation during thermal annealing in metal-phthalocyanine thin films. The variation of surface and interface also could be simultaneously investigated by the x-ray reflectivity measurement.

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A Study on a Quantitative Measurement of Contact Pressure Between two Rough Flat SurFaces by Means of Ultrasonic Waves. (초음파를 이용한 이체 평면접촉부의 정량적인 접촉압력 측정에 관한 연구)

  • 김경모;정인성
    • Journal of the Korean Society of Safety
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    • v.5 no.3
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    • pp.8-26
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    • 1990
  • It is important to have exact information about the contact pressure distribution in the design of connected parts of machines and structures. In previous works, stress analyses on a two body contact problem have been carried out in large numbers. Besides, the measurement of contact stress is important to confirm the adequateness of the theoretical analysis, to verify appropriateness of Hertzian contact theory and to know the practical pressure distribution, but an excellent measuring method con't be found at present. Therefore, a quantitative measurement of contact pressure by means of ultrasonic waves using a normal probe and an angle has been proposed to measure the contact pressure distribution between two rough flat surfaces. At first, in a new proposed calibration method, the relation between mean contact pressure and sound pressure of reflected waves is obtained by using calibration blocks with various surface roughnesses made of the same material as the rectangular section beams And then, this experimental results are compared with the analytical ones, and the utility of this method is discussed.

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Experimental Study on Flame Stabilization and $NO_{x}$ Reduction in a Non-Premixed Burner with Sawtooth Mixer

  • Fujimoto, Yohei;lnokuchi, Yuzo;Orino, Minoru;Yamasaki, Nobuhiko
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.485-490
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    • 2004
  • Sawtooth mixing device used in a non-premixed burner is evaluated for flame stabilization and NO$_{x}$ reduction. Three mixers with different blade angles are tested. Methane is delivered through the fuel jet and air passes through the co-flow annulus. The flame mode changes (attached flame, lifted flame and extinction) against the fuel flow speed are measured, and the stability diagram is drawn. Moreover, by traversing thermocouple and sampling probe in the flame, the distribution of temperature and NO$_{x}$ mole fraction are measured. With the change in blade angle, flame shape, flame stabilization, the distribution of temperature and NO$_{x}$ mole fraction are changed considerably.rably.

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Effect of Particle Dispersion on Physical Properties of Ni-CNT Composite Coatings (입자분산이 Ni-CNT 복합도금막의 특성에 미치는 영향)

  • Cheon, Young-Hoon;Bae, Kyoo-Sik
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.2
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    • pp.91-95
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    • 2011
  • Ni-CNT(carbon nanotubes) composite coating is often used for the surface treatment of electronic/mechanical devices to improve the properties of the exisiting Ni electroplating. For this, the dispersion of CNT particle is a critical process. In this study, ball milling and additive called sodium dodecyl sulfate(SDS) are employed for dispersion. Electroplated Ni-CNT films were examined by SEM-EDX, AES, microhardness tester, 4-point probe and contact angle measurement to find the optimum dispersion conditions. Ni-CNT coatings formed by ball milling for 9 hrs and with addition of SDS 12 times of CNT contents showed the highest hardness, reasonable resistivity and non-stick characteristics.

Prediction and Analysis of Bobbin ECT Signals generated by Tube Defects near Support Plate (지지대 부근의 전열관 결함으로 인해 발생되는 보빈 와전류신호의 예측 및 분석)

  • Shin, Young-Kil;Lee, Yun-Tai
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.942-944
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    • 2005
  • In this study, eddy current signals from various anomalous defects in the heat exchanger tube are predicted af their signal slope characteristics no analyzed. The signal changes due to frequency increase are also observed. Based in the accumulated knowledge, the analysis of superimposed signal is attempted which includes the effects of support plate. Both differential and absolute bobbin probe signals are analyzed. For the prediction of signals, axisymmetric finite element modeling is used and this leads us to the utilization of slope angle analysis of the signal. Results show that differential signals are useful to locate the position of defect under the support plate and absolute signals no easy to predict and analyze even though they no superimposed signals. Combined use of these two types of signals will accomplish a reliable inspection.

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Tropospheric Ozone Retrieval Algorithm Based on the TOMS Scanning Geometry

  • Kim, Jae-Hwan;Na, Sun-Mi;Newchurch, M.J.
    • Korean Journal of Remote Sensing
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    • v.19 no.1
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    • pp.11-19
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    • 2003
  • This paper applies the Scan-Angle Method (SAM) to the Total Ozone Mapping Spectrometer (TOMS) aboard Earth Probe (EP) satellite for determining tropospheric ozone based on TOMS scan geometry. In the northern tropical Africa burning season, the distribution of the SAM-derived tropospheric ozone presents a tropospheric ozone enhancement related to biomass burning. This distribution is consistent with that of fire counts observed from Along Track Scanning Radiometer (ATSR) and that of carbon monoxide, the tropospheric ozone precursor, observed from Measurements of Pollution In The Troposphere (MOPITI). However, this feature is not shown in the distribution of tropospheric ozone derived from other TOMS-based algorithms for the northern burning season. In the high latitudes, the influence of pollution in the SAM results is seen over the northern continents in agreement with carbon monoxide for northern summer when the dynamical activity is weak in the northern hemisphere.