• Title/Summary/Keyword: Primary decomposition

검색결과 173건 처리시간 0.029초

70 N급 하이드라진 추력기의 촉매대 형상(L/D) 최적화 연구 (An Approach to the Optimization of Catalyst-bed L/D Configuration in 70 N-class Hydrazine Thruster)

  • 정훈;김종현;김정수
    • 한국추진공학회지
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    • 제17권6호
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    • pp.30-37
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    • 2013
  • 우주비행체의 주 엔진 및 자세제어용 추력기로 적용 가능한 단일액체추진제 하이드라진 추력기의 촉매대 최적설계형상 도출을 위한 지상연소시험을 수행하였다. 추력, 비추력, 연소실 압력, 특성속도, 그리고 하이드라진 분해반응률 등을 추력실 길이변화에 따라 고찰하고, 추진제 공급압력과 성능변수가 갖는 상관관계를 제시한다. 성능평가결과, 시험조건 내에서의 촉매대 길이증가는 추력기의 성능저하를 야기하고, 공급압력 변이에 따른 추진제 소모 효율성 또한 떨어뜨리는 것이 확인되었다.

용융염 코팅이 열지에 미치는 영향 (Effect of Molten Salt Coating on Heat Papers)

  • 임채남;이정민;강승호;정해원
    • 한국전기전자재료학회논문지
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    • 제27권8호
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    • pp.528-534
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    • 2014
  • Thermal batteries are primary reserve batteries that use inorganic salt as electrolytes which are inactive at room temperature. The two principal heat sources that have been used in thermal batteries are heat paper and heat pellets. As soon as the heat paper, which is ignited by the initiator, in turn ignites the heat pellets, all the solid electrolytes are melted into excellent ionic conductors. However, the high combustion temperature by heat papers in thermal batteries causes thermal decomposition at the cathode, eventually leading to a thermal runaway. In this paper, we have attempted to prepare $Zr/BaCrO_4$ heat papers coated with KCl molten salt. We have also investigated the effect of a molten salt coating on the heat papers through the thermal characteristics such as calorimetric value, combustion temperature and burning rate. The calorimetric value and combustion temperature of heat papers were reduced with an increase in the molten salt coating. As a result, the molten salt coating on heat papers greatly reduced risk of a thermal runaway and improved the stability of thermal batteries.

Optical emission analysis of hybrid air-water discharges

  • Pavel, Kostyuk;Park, J.Y.;Han, S.B.;Koh, H.S.;Gou, B.K.;Lee, H.W.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.521-522
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    • 2006
  • In this paper, hybrid air-water discharges were used to develop an optimal condition for providing a high level of water decomposition for hydrogen yield. Electrical and optical phenomena accompanying the discharges were investigated along with feeding gases, flow rates, and point-to-plane electrode gap distance. The primary focus of this experiment was put on the optical emission of the near UV range, with the energy threshold sufficient for water dissociation and excitation. The $OH(A^{2+},'=0\;X^2,"=0$) band's optical emission intensity indicated the presence of plasma chemical reactions involving hydrogen formation. In the gaseous atmosphere saturated with water vapor the OH(A-X) band intensity was relatively high compared to the liquid and transient phases although the optical emission strongly depended on the flow rate and type of feeding gas. In the gaseous phase discharge phenomenon for Ar carrier gas transformed into a gliding arc via the flow rate growth. OH(A-X) band's intensity increased according to the flow rate or residence time of He feeding gas. Reciprocal tendency was acquired for $N_2$ and Ar carrier gases. The peak value of OH(A-X) intensity was observed in the proximity of the water surface, however in the cases of Ar and $N_2$ with 0.5 SLM flow rate peaks shifted to the region below the water surface. Rotational temperature ($T_{rot}$) was estimated to be in the range of 900-3600 K, according to the carrier gas and flow rate, which corresponds to the arc-like-streamer discharge.

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수크로스 함유 분무용액으로부터 분무열분해 공정에 의한 미세 Ba-Nd-Ti-O 분말 합성 (Synthesis of Fine Ba-Nd-Ti-O Powders by Spray Pyrolysis from Spray Solution with Sucrose)

  • 고유나;정대수;구혜영;강윤찬
    • 한국재료학회지
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    • 제20권3호
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    • pp.142-147
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    • 2010
  • Nano-sized $BaNd_2Ti_5O_{14}$ powders were prepared by the spray pyrolysis process. Sucrose used as the organic additive enabled the formation of nano-sized $BaNd_2Ti_5O_{14}$ powders. The powders prepared from the spray solution without sucrose had a spherical shape, dense structure and micron size before and after calcination. However, the precursor powders prepared from the spray solution with sucrose had a large size, and hollow and porous morphology. The precursor powders had an amorphous crystal structure because of the short residence time of the powders inside the hot wall reactor. The complete decomposition of sucrose did not occur inside the hot wall reactor. Therefore, the precursor powders obtained from the spray solution with sucrose of 0.5M had a carbon content of 39.2wt.%. The powders obtained from the spray solution with sucrose of 0.5M had a slightly aggregated structure of nano-sized primary powders of $BaNd_2Ti_5O_{14}$ crystalline phase after calcination at $1000^{\circ}C$. The calcined powders turned into nano-sized $BaNd_2Ti_5O_{14}$ powders after milling. The mean size of the $BaNd_2Ti_5O_{14}$ powders was 125 nm.

Coalition based Optimization of Resource Allocation with Malicious User Detection in Cognitive Radio Networks

  • Huang, Xiaoge;Chen, Liping;Chen, Qianbin;Shen, Bin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제10권10호
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    • pp.4661-4680
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    • 2016
  • Cognitive radio (CR) technology is an effective solution to the spectrum scarcity issue. Collaborative spectrum sensing is known as a promising technique to improve the performance of spectrum sensing in cognitive radio networks (CRNs). However, collaborative spectrum sensing is vulnerable to spectrum data falsification (SSDF) attack, where malicious users (MUs) may send false sensing data to mislead other secondary users (SUs) to make an incorrect decision about primary user (PUs) activity, which is one of the key adversaries to the performance of CRNs. In this paper, we propose a coalition based malicious users detection (CMD) algorithm to detect the malicious user in CRNs. The proposed CMD algorithm can efficiently detect MUs base on the Geary'C theory and be modeled as a coalition formation game. Specifically, SSDF attack is one of the key issues to affect the resource allocation process. Focusing on the security issues, in this paper, we analyze the power allocation problem with MUs, and propose MUs detection based power allocation (MPA) algorithm. The MPA algorithm is divided into two steps: the MUs detection step and the optimal power allocation step. Firstly, in the MUs detection step, by the CMD algorithm we can obtain the MUs detection probability and the energy consumption of MUs detection. Secondly, in the optimal power allocation step, we use the Lagrange dual decomposition method to obtain the optimal transmission power of each SU and achieve the maximum utility of the whole CRN. Numerical simulation results show that the proposed CMD and MPA scheme can achieve a considerable performance improvement in MUs detection and power allocation.

합금성분변화와 균질화처리에 따른 M2 고속도강의 탄화물 형성거동 (Effect of Alloying Elements and Homogenization Treatment on Carbide Formation Behavior in M2 High Speed Steels)

  • 하태권;양은익;정재영;박신화
    • 대한금속재료학회지
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    • 제48권7호
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    • pp.589-597
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    • 2010
  • In the present study, the effect of variation in alloying elements on the carbide formation behavior during casting and homogenization treatment of M2 high speed steels was investigated. M2 high speed steels of various compositions were produced by vacuum induction melting. Contents of C, Cr, W, Mo, and V were varied from the basic composition of 0.8C, 0.3Si, 0.2Mn, 4.0Cr, 6.0W, 5.0Mo, and 2.0V in weight percent. Homogenization treatment at $1150^{\circ}C$ for 1.5 hr followed by furnace cooling was performed on the ingots. Area fraction and chemical compositions of eutectic carbide in as-cast and homogenized ingots were analyzed. Area fraction of eutectic carbide appeared to be higher in the ingots with higher contents of alloying elements the area fraction of eutectic carbide also appeared to be higher on the surface regions than in the center regions of ingots. As a result of the homogenization treatment, $M_2C$ carbide, which was the primary eutectic carbide in the as-cast ingots, decomposed into thermodynamically stable carbides, MC and $M_6C$. The latter carbide was found to be the main one after homogenization. Fine carbides uniformly distributed in the matrix was found to be MC type carbide and coarsened by homogenization.

수중 유전체 장벽 방전 플라즈마를 이용한 페놀의 분해 특성 (Characteristics of phenol degradation by using underwater dielectric barrier discharge plasma)

  • 신관우;최승규;김진수;주천;원경자;이상일
    • 상하수도학회지
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    • 제33권4호
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    • pp.243-250
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    • 2019
  • This objective of this study was to investigate the degradation characteristics of phenol, a refractory substance, by using a submerged dielectric barrier discharge (DBD) plasma reactor. To indirectly determine the concentration of active species produced in the DBD plasma, the dissolved ozone was measured. To investigate the phenol degradation characteristics, the phenol and chemical oxygen demand (COD) concentrations were evaluated based on pH and the discharge power. The dissolved ozone was measured based on the air flow rate and power discharged. The highest dissolved ozone concentration was recorded when the injected air flow rate was 5 L/min. At a discharge power of 40W as compared to 70W, the dissolved ozone was approximately 2.7 - 6.5 times higher. In regards to phenol degradation, the final degradation rate was highest at about 74.06%, when the initial pH was 10. At a discharged power of 40W, the rate of phenol decomposition was observed to be approximately 1.25 times higher compared to when the discharged power was 70W. It was established that the phenol degradation reaction was a primary reaction, and when the discharge power was 40W as opposed to 70W, the reaction rate constant(k) was approximately 1.72 times higher.

염 보조 초음파 분무 열분해 공정으로 합성된 TiO2 나노입자의 특성에 열분해 온도가 미치는 영향 (Effect of Pyrolysis temperature on TiO2 Nanoparticles Synthesized by a Salt-assisted Ultrasonic Spray Pyrolysis Process)

  • 유재현;지명준;박우영;이영인
    • 한국분말재료학회지
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    • 제26권3호
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    • pp.237-242
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    • 2019
  • In this study, ultrasonic spray pyrolysis combined with salt-assisted decomposition, a process that adds sodium nitrate ($NaNO_3$) into a titanium precursor solution, is used to synthesize nanosized titanium dioxide ($TiO_2$) particles. The added $NaNO_3$ prevents the agglomeration of the primary nanoparticles in the pyrolysis process. The nanoparticles are obtained after a washing process, removing $NaNO_3$ and NaF from the secondary particles, which consist of the salts and $TiO_2$ nanoparticles. The effects of pyrolysis temperature on the size, crystallographic characteristics, and bandgap energy of the synthesized nanoparticles are systematically investigated. The synthesized $TiO_2$ nanoparticles have a size of approximately 2-10 nm a bandgap energy of 3.1-3.25 eV, depending on the synthetic temperature. These differences in properties affect the photocatalytic activities of the synthesized $TiO_2$ nanoparticles.

수문기상자료의 웨이블렛 변환에 의한 비선형 동역학적 성분의 추출 (Extraction of Nonlinear Dynamical Component by Wavelet Transform in Hydro-meteorological Data)

  • 진영훈;박성천
    • 대한토목학회논문집
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    • 제26권5B호
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    • pp.439-446
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    • 2006
  • 본 연구에서는 강수량 및 기온과 같은 수문기상자료의 비선형 동역학적 성분을 추출하기 위해 웨이블렛 변환을 적용하여 대상자료를 재현기간별 성분으로 분리하였다. 변환을 위한 기저함수로는 Daubechies의 9번 ('db9') 웨이블렛 함수를 사용하였다. 또한 웨이블렛 변환의 스케일의 증가에 따른 각 분리단계에서 추출된 상세성분과 근사성분이 비선형 동역학적 특성을 지니는지를 판단하기 위하여 상관차원분석을 이용하였다. 즉 수문기상자료내에 비선형 동역학적 성질을 지니는 성분을 추출하기 위한 방법론으로써 웨이블렛 변환과 상관차원분석의 결합을 제안하였으며, 도출된 결과는 일반적으로 원자료를 이용할 경우에는 파악하기 어려운 대상자료의 시간에 따른 비선형적 변화를 분리 추출하기 위해 본 연구에서 제안한 방법이 적합함을 보이고 있다.

초음파 분무 열분해법에 의한 $BaTiO_3$ 미분말의 합성 및 형성기구 규명 (The synthesis and formation mechanism of the fine $BaTiO_3$ powders by ultrasonic spray pyrolysis)

  • 허화범;신건철
    • 한국결정성장학회지
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    • 제4권2호
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    • pp.178-189
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    • 1994
  • $BaTiO_3$ 미분말은 여러종류의 0.05 M 출발용액으로부터 초음파 분무 열분해법으로 합성하였다. 이때, 유속은 0.5 cm/sec, 저온로는 $300^{\circ}C$, 고온로는$700^{\circ}C$로 고정하였다. 입자의 형성과정은 반응 단계별로 포집된 분말을 SEM으로 직접 관찰하였고 또한, 반응기내에서의 입자의 거동을 이론적으올 고찰하고자 하였다. 순수한 $BaTiO_3$ 미분말은 출발용액이 nitrate aqueous solution인 경우에 합성이 가능하였다. 합성된 미분말은 19.1 nm의 일차입자들로 구성된 porous한 약 $0.42 {mu}m$크기의 구형의 이차임자였다. 형성과정은 건조단계에서 입자의 크기가 감소한 후 열분해 초기단계에서 증가하고 반응이 진행됨에 따라 점차 다시 감소하여 최종 $0.42 {mu}m$의 고화된 입자로 되었고 입도분포는 반응이 진행됨에 따라 점차 넓어졌다. 또한, 반응기내에서 입자들의 이론적 거동은 반응기 중심쪽으로 향하여 진행된다.

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