• Journal of the Korean Society for Precision Engineering
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• v.20 no.3
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• pp.165-171
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• 2003

In a structure, many components are fastened together using bolts, nuts and rivets through drilled holes. Not only do these fastened joints enable easy assembly and dismantling, they are also able to transfer as well as to distribute loads applied onto the structures. The major drawback of such connections, however, is that the fatigue life of the components is reduced by the presence of the hole since the stress concentration around the hole is increased. In addition, the hole drilling process itself may introduce defects or roughness at the surfaces of the hole that may cause further decrease in fatigue performance of the components. For applications where fatigue loadings are important, one way to compensate the decrease in fatigue life of the components is by introduction of beneficial compressive residual stress around the hole using cold working. The material used for this research were A12024-T351 and A17050-T7451 using the primary member of aircraft. We present, In this paper, the characteristics of coldworking by evaluation of the hole expansion ratio, residual stress distribution, and fatigue properties.

• Bulletin of the Korean Chemical Society
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• v.15 no.8
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• pp.644-649
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• 1994

The approximate rates and stoichiometry of reaction of excess dipyrrolinoaluminum hydride (DPAH) with selected organic compounds containing representative functional groups under standardized conditions (tetrahydrofuran, 0, reagent : compound=4 : 1) were examined in order to define the characteristics of the reagent for selective reductions. The reducing ability of DPAH was also compared with that of bis(diethylamino)aluminum hydride (BEAH). The reagent appears to be stronger than BEAH, but weaker than the parent reagent in reducing strength. DPAH shows a unique reducing characteristics. Thus, the reagent reduces aldehydes, ketones, esters, acid chlorides, epoxides, and nitriles readily. In addition to that, ${\alpha},\;{\beta}$-unsaturated aldehyde is reduced to the saturated alcohol. Quinone are reduced cleanly to the corresponding 1,4-reduction products. The examination for possibility of achieving a partial reduction to aldehydes was also performed. Both primary and tertiary aromatic carboxamides are converted to aldehydes with a limiting amount of DPAH. Finally, disulfides and sulfoxides are readily reduced to thiols and sulfides, respectively.

• Electronics and Telecommunications Trends
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• v.38 no.5
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• pp.90-99
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• 2023

Recently, with the trend of information technology convergence and electrification, batteries are being widely used in fields such as industry, transportation, and specific applications. By 2030, the secondary battery market is expected to grow explosively by more than eight times compared with 2020 to $351.7 billion owing to the expanding adoption of electric vehicles. Depending on the electrochemical reactions in the electrode, a primary battery can only discharge through an irreversible reaction, while a secondary battery can be repeatedly charged and discharged using reversible reactions. According to the type of charge carrier ions, secondary batteries may be classified into those made of lithium, sodium, potassium, magnesium, and aluminum ions. We analyze the current status and technological issues of lithium-ion batteries, lithium-sulfur batteries, and solid-state batteries, which are representative examples of lithium secondary batteries. In addition, research trends in lithium secondary batteries are discussed.

• Journal of Korea Foundry Society
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• v.43 no.6
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• pp.294-301
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• 2023

The effects of Cu on feeding and macro-porosity characteristics were investigated in hypo- (A356 and 319) and hypereutectic (391) aluminum-silicon alloys. T-section and Tatur tests showed that the feeding and macro-porosity characteristics were significantly different between the hypo- and hypereutectic alloys. The hole and the pipe in the T-section and the Tatur casting in hypereutectic alloy showed a rough and irregular shape due to the faceted growth of the primary silicon, while the results of the hypoeutectic alloys exhibited a rather smooth surface. However, the addition of Cu did not strongly affect the macro-feeding behavior. It is known that copper segregates and interferes the feeding process in the last stage of solidification, possibly leading to form more amount of micro shrinkage porosity by the addition of Cu. The macro porosity formation mechanism and feeding properties were discussed upon T-section and Tatur tests together with an alloying addition.

• Analytical Science and Technology
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• v.27 no.6
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• pp.357-363
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• 2014

Isoprene is a one of the biogenic volatile organic compounds (BVOCs) and it is known as a source of the tropospheric ozone and formaldehyde. In addition, isoprene is a trace component of the exhaled breath and it is a potential biomarker for the diagnosis of diseases such as lung cancer. In these regards, isoprene gas standards are required for the accurate measurement of isoprene in air samples. To establish a standard for isoprene gas, gravimetric preparation and characterization of primary gas standards were studied. The primary gas standards were produced independently in 4 aluminum cylinders and concentrations were examined by GC-FID. As a result, the uncertainty of the gravimetric preparations including purity of the raw material was 0.01% and reproducibility of the preparation of independent 4 cylinders was 0.08%. The primary gas standards for isoprene showed 14 months of long-term stability. The relative expended uncertainty of 2.8% (95% of confidence level, k=1.96) was assigned to the certified value of 10 ${\mu}mol$/mol level of isoprene based on the quantitative evaluation of the purity, weighing, reproducibility, adsorption and long-term stability.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.10
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• pp.1543-1548
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• 2010

Powder metallurgy processes are used to form Net-Shape products and have been widely used in the production of automobile parts to improve its manufacture productivity. Powder-forging technology is being developed rapidly because of its economic merits and because of the possibility of reducing the weight of automobile parts by replacing steel parts with aluminum ones, in particular while manufacturing automotive parts. In the powder-forging process, the products manufactured by powder metallurgy are forged in order to remove any pores inside them. Powderforging technology can help expand the applications of powder metallurgy; this is possible because powder-forging technology enables the minimization of flashes, reduction of the number of stages, and possible grain refinement. At present, powder forging is widely used for manufacturing primary mechanical parts as in combination with the technology of powder forging of aluminum alloy pistons.

• The Korean Journal of Physiology and Pharmacology
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• v.17 no.5
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• pp.427-433
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• 2013

Receptor activator of NF-${\kappa}B$ ligand (RANKL)-induced osteoclastogenesis is accompanied by intracellular $Ca^{2+}$ mobilization in a form of oscillations, which plays essential roles by activating sequentially $Ca^{2+}$/calmodulin-dependent protein kinase, calcineurin and NFATc1, necessary in the osteoclast differentiation. However, it is not known whether $Ca^{2+}$ mobilization which is evoked in RANKL-independent way induces to differentiate into osteoclasts. In present study, we investigated $Ca^{2+}$ mobilization induced by aluminum fluoride ($AlF_4^-$), a G-protein activator, with or without RANKL and the effects of $AlF_4^-$ on the osteoclastogenesis in primary cultured mouse bone marrow-derived macrophages (BMMs). We show here that $AlF_4^-$ induces intracellular $Ca^{2+}$ concentration ($[Ca^{2+}]_i$) oscillations, which is dependent on extracellular $Ca^{2+}$ influx. Notably, co-stimulation of $AlF_4^-$ with RANKL resulted in enhanced NFATc1 expression and formation of tartrate-resistant acid phosphatase (TRAP) positive multinucleated cells. Additionally, we confirmed that mitogen-activated protein kinase (MAPK) is also activated by $AlF_4^-$. Taken together, these results demonstrate that G-protein would be a novel modulator responsible for $[Ca^{2+}]_i$ oscillations and MAPK activation which lead to enhancement of RANKL-mediated osteoclastogenesis.

• Journal of the Korean Chemical Society
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• v.17 no.4
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• pp.275-285
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• 1973

The addition of one mole of aluminum chloride to three moles of sodium borohydride in tetrahydrofuran gives a turbid solution with enormously more powerful reducing properties than those of sodium borohydride itself. The reducing properties of this reagent were tested with 49 organic compounds which have representative functional groups. Alcohols liberated hydrogen immediately but showed no sign of hydrogenolysis of alkoxy group. Aldehydes and ketones were reduced rapidly within one hr. Acyl derivatives were reduced moderately, however, carboxylic acids were reduced much more slowly. Esters, lactones and epoxides were reduced readily than sodium borohydride or borane. Tertiary amide was reduced slowly, however, primary amide consumed one hydride for hydrogen evolution but reduction was sluggish. Aromatic nitrile was reduced much more readily than aliphatic nitrile. Nitro compounds were inert to this reagent but azo and azoxy groups were slowly attacked. Oxime was reduced slowly but isocyanate was only partially reduced. Disulfide and sulfoxide were attacked slowly but sulfide and sulfone were inert. Olefin was hydroborated rapidly.

• Bulletin of the Korean Chemical Society
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• v.13 no.2
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• pp.199-207
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• 1992

The approximate rates and stoichiometry of the reaction of excess sodium diethyldihydroaluminate (SDDA) with 68 selected organic compounds containing representative functional groups were examined under standard conditions (THF-toluene, $0^{\circ}C$ in order to compare its reducing characteristics with lithium aluminum hydride (LAH), aluminum hydride, and diisobutylaluminum hydride (DIBAH) previously examined, and enlarge the scope of its applicability as a reducing agent. Alcohols, phenol, thiols and amines evolve hydrogen rapidly and quantitatively. Aldehydes and ketones of diverse structure are reduced rapidly to the corresponding alcohols. Reduction of norcamphor gives 11% exo-and 89% endo-norborneol. Conjugated aldehydes such as cinnamaldehyde are rapidly and cleanly reduced to the corresponding allylic alcohols. p-Benzoquinone is mainly reduced to hydroquinone. Hexanoic acid and benzoic acid liberate hydrogen rapidly and quantitatively, however reduction proceeds very slowly. Acid chlorides and esters tested are all reduced rapidly to the corresponding alcohols. However cyclic acid anhydrides such as succinic anhydride are reduced to the lactone stage rapidly, but very slowly thereafter. Although alkyl chlorides are reduced very slowly alkyl bromides, alkyl iodides and epoxides are reduced rapidly with an uptake of 1 equiv of hydride. Styrene oxide is reduced to give 1-phenylethanol quantitatively. Primary amides are reduced very slowly; however, tertiary amides take up 1 equiv of hydride rapidly. Tertiary amides could be reduced to the corresponding aldehydes in very good yield ( > 90%) by reacting with equimolar SDDA at room temperature. Hexanenitrile is reduced moderately accompanying 0.6 equiv of hydrogen evolution, however the reduction of benzonitrile proceeds rapidly to the imine stage and very slowly thereafter. Benzonitrile was reduced to give 90% yield of benzaldehyde by reaction with 1.1 equiv of hydride. Nitro compounds, azobenzene and azoxybenzene are reduced moderately at $0^{\circ}C$, but nitrobenzene is rapidly reduced to hydrazobenzene stage at room temperature. Cyclohexanone oxime is reduced to the hydroxylamine stage in 12 h and no further reaction is apparent. Pyridine is reduced sluggishly at $0^{\circ}C$, but moderately at room temperature to 1,2-dihydropyridine stage in 6 h; however further reaction is very slow. Disulfides and sulfoxides are reduced rapidly, whereas sulfide, sulfone, sulfonic acid and sulfonate are inert under these reaction conditions.

• Economic and Environmental Geology
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• v.29 no.3
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• pp.315-323
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• 1996

An apatite drain was constructed on September 30, 1994 at the Green Valley Abandoned Coal Mine site near Terre Haute in west central Indiana. The primary objective of this experiment is to evaluate the long-term ability of the apatite drain to mitigate acid mine drainage (AMD) under field conditions. The drain 9 m long, 3.3 m wide, and 0.75 m deep, contain 95 rum to No. 30 mesh-size apatite ore (francolite) and receive AMD seepage from reclaimed gob piles, and designed according to the laboratory testing. The apatite drain was covered with limestone riprap and filter fabric to protect the drainage system from stormwater and siltation. The drain consists of about 50 metric tons of apatite ore obtained from a phosphate mine in Florida. A gabion structure was constructed downstream of the apatite drain to create a settling pond to collect precipitates. Apatite effectively removed iron up to 4,200 mg/l, aluminum up to 830 mg/l and sulfate up to 13,430 mg/l. The pH was nearly constant for the influent and effluent, ranging between 3.1 and 4.3. Flow rate measured at the gabion structure ranged from 3 to 4.5 l/m. Precipitates of iron and aluminum phosphate (yellow and white suspendid solids) continued to accumulate in the settling pond.