• Title/Summary/Keyword: Primary air

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Investigation of Spherical LiMn2O4 Cathode Materials by Spray-drying with Different Electrochemical Behaviors at High Rate (분무건조법으로 제조한 구형 스피넬계 LiMn2O4 양극소재의 합성 조건에 따른 고출력 거동에 대한 연구)

  • Song, Jun Ho;Cho, Woosuk;Kim, Young Jun
    • Journal of the Korean Electrochemical Society
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    • v.19 no.2
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    • pp.50-56
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    • 2016
  • Spherical lithium manganese oxide spinel, $Li_{1.10}Mn_{1.86}Al_{0.02}Mg_{0.02}O_4$ was prepared by wet-milling, spray-drying, and sintering process. In the spray-drying process, solid content in slurry was varied from 20 to 30 wt%. In the sintering process, the precursors have been sintered under air or $O_2$ atmosphere. While the as-prepared samples exhibit excellent electrochemical properties at room temperature, the discharge voltage profiles at 5.0C are very different one from another. The origin for the difference especially at initial state of discharge is oxygen defect. The sample prepared in air has larger capacity related to the plateau at 3.3 V (vs. $Li/Li^+$) which is caused by the oxygen defects than the one prepared in $O_2$. The difference of discharge voltage profiles especially at the final state of discharge comes from different diffusion rate of $Li^+$ ions. The sample prepared from 30 wt% solid content of slurry shows twice higher diffusion rate than the samples prepared from 20 wt% solid content, which is attributed to better compactness between primary particles for the sample prepared from 30wt % solid content than the one prepared by 20 wt%.

Status of Packaging Materials for Frozen Foods and Analysis of Temperature Changes inside Packaging Materials during Frozen Process (냉동식품용 포장재 현황 및 냉동 과정 중 포장재 내부 온도 변화에 관한 연구)

  • Yoo, Seungwoo;Kwon, Sangwoo;Park, Su-il
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.25 no.1
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    • pp.11-16
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    • 2019
  • This study analyzed various packaging materials and types for frozen foods and the effects of packaging materials on temperature changes during frozen process. Pouches with different film thickness were prepared and placed in an IQF freezer, then the temperature inside pouches measured using a deep thermometer. The most common types of primary packaging for frozen foods in the market was plastic pouches with polyethylene or polyamide/polyethylene multilayer materials. The temperature change inside of packaging was delayed with film thickness increased. As the size of packaged food increased, the temperature change inside the food was slowed down. In addition, the pouches with air inside took more time to reach $-30^{\circ}C$ compared to pouches with less air during frozen process. This study provides information on packaging materials and types for frozen foods and preliminary data of temperature change by different types of packaging.

Experimental Study of Transition to Secondary Acoustic Instability at Downward-Propagating Premixed Flame in a Tube (튜브 내 하향 전파하는 예혼합 화염의 이차 열음향 불안정성 천이에 관한 실험적 연구)

  • Park, Juwon;Kim, Daehae;Park, Dae Geun;Yoon, Sung Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.7
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    • pp.915-921
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    • 2020
  • Thermoacoustic instability caused by air conditioning in a combustion chamber has emerged as a problem that must be solved to establish a stable combustion system. Thermoacoustic instability is largely divided into primary and secondary acoustic instability. In this study, an experimental study of the effects of heat losses was conducted to investigate the mechanism of secondary acoustic instability. To generate the secondary acoustic instability, a quarter-wavelength resonator with one open end and one closed end was used, and the inside of the resonator was filled with premixed gases. Subsequently, secondary acoustic instability with downward-propagating flames could be realized via thermal expansion on the burnt side. To control heat losses qualitatively, an additional co-axial tube was installed in the resonator with air or nitrogen supply. Therefore, additional diffusion flames can be formed at the top of the resonator depending on the injection of the oxidizer into the co-axial tube when rich premixed flames are used. Consequently, secondary acoustic instability could not be achieved by increasing heat losses to the ambient when the additional diffusion flame was not formed, and the opposite result was obtained with the additional diffusion flame.

The Health Hazard Evaluation Program by NIOSH (NIOSH의 건강유해도 평가 프로그램)

  • Jeong, Jee Yeon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.10 no.1
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    • pp.147-159
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    • 2000
  • The NIOSH health hazard evaluation program (HHE program) was created in response to the mandate to determine the toxic effect and potential health hazard of workplace exposure, which is found in Occupational Safety and Health Act of 1970 and the Federal Mine Safety and Health Act of 1977, A primary benefit of HHE program is its ability to provide current health hazard data to employers and employees, which assists them in identifying solutions to occupational health and safety problems in their workplaces, The HHE program also stimulates research in the development and review of sampling methods and diagnostic tests and may prompt additional exposure assesment efforts and toxicological and epidemiological studies. HHE projects also provide human exposure-toxicity data that are used to asses the validity of existing occupational health standards and to support criteria for new standards of recommendation, The HHE request is classified into four categories: 1) category 1: As a administratively invalid, 2) category 2: These are valid requests for which a site visit is not essential to an appropriate response, 3) Category 3 : These are valid requests for which a site visit is necessary for an adequate evaluation, 4) These are valid request which present a complex problem or an opportunity for research, To carry out HHE program one or methods of investigation might be used: 1) direct observation and evaluation of production processes and employee work practices 2) employees exposure level and air contamination level 3) medical test or physical examinations of employees 4) private, confidential interviews with employees 5) review of employer's record of injuries and illness, employee exposure data, medical tests and job histories. After investigation and analysing the data, NIOSH issues a final report, giving finding and recommendation.

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Numerical Study on the Characteristics of High PM2.5 Episodes in Anmyeondo Area in 2009 (2009년 안면도 지역 고농도 PM2.5 특성에 관한 수치 연구)

  • Jeon, Won-Bae;Lee, Hwa Woon;Lee, Soon-Hwan;Park, Jae-Hyeong;Kim, Hyun-Goo
    • Journal of Environmental Science International
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    • v.23 no.2
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    • pp.249-259
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    • 2014
  • This paper investigates the characteristics of high $PM_{2.5}$ episodes occurred at Anmyeondo area in spring time, 2009. The monthly mean $PM_{2.5}$ concentration during April was the highest in the year and especially, high levels of $PM_{2.5}$ exceeding standard regulation level were sustained consecutively during 5 to 13 April. To analyze more detailed $PM_{2.5}$ characteristics, numerical simulations were carried out using CMAQ(Community Multi-scale Air Quality) with IPR(Integrated Process Rate) and DDM-3D(Decoupled Direct Method). $PM_{2.5}$ level was lower in daytime than that in nighttime due to vigorous vertical mixing during daytime. The chemical composition was showed that ratio of primary ion components such as sulfate($SO_4{^{2-}}$), nitrate($NO_3{^-}$) and ammonium($NH_4{^+}$) were nearly half of total amount of $PM_{2.5}$. Aerosol and transport process dominantly contributed to $PM_{2.5}$ concentration in Anmyeondo area and contribution rate of local emissions was nearly zero since Anmyeondo area has rare anthropogenic PM emission sources. DDM-3D analysis result showed that $PM_{2.5}$ in Anmyeondo area was influenced by emissions from Shanghai and Shandong region of China.

Nutritional Characteristics and Damage Mitigation Effects in Heavy-metals Exposure of Peking-Duck By-Product Extracts Added with Medicinal Herbs ( I ) Nutritional Profile of Peking-Duck Extracts Added with Medicinal Herbs (오리부산물과 한약재를 이용한 추출액의 영양성분 및 중금속 노출에 대한 피해 완화 효과 (1) 오리부산물과 한약재를 이용한 추출액의 영양학적 특성)

  • 박성혜;박성진;임흥렬;한종현
    • Journal of the East Asian Society of Dietary Life
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    • v.13 no.3
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    • pp.176-184
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    • 2003
  • This experiment was planned to develop a functional supplements by food resources to prevent and lessen the bad effects caused by the environmental pollution such as bad food, air, water and heavy metals exposed to people these days. As for Its primary stage, the nutrient profile and sensory characteristics of the duck-extract were evaluated in this study. The duck-extract was formulated by the mixture of bone and internal organs of ducks and 6 medicinal herbs which were able to be used as foods and known to help the excretion and the repression of the poison inside the body for a long time. As we compared the six medicinal herbs mentioned above to the vegetable herbs, the nutrient profile of the medicinal herbs were superior to the vegetable herbs. The duck-extract was composed of protein 49.92%, carbohydrate 37.02%, dietary fiber 20.99%, lipid 7.60% and ash 5.46%. The ratio of Ca to P was 1 : 1.4, which was a suitable ratio for absorption, the contents of Na and K were low and those of micro-elements such as Fe, Mn, Zn and Cu high compared to other meat extracts. The essential amino acids accounted for 30.91% of total amino acids. The result of sensory evaluation was better in overall preferences than the ones which are already in the market. From these results, the nutrient profile of the duck-extract was estimated to be able to supply enough nutrients to the people whose nutritional balance was destroyed these days. This study also showed the effective way of using duck-extract and its application to the oriental medicine.

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Comparison of Real Time Water Soluble Organic Carbon Measurements by Two PILS-TOC Analyzers (PILS-TOC를 이용한 실시간 대기 중 수용성 유기탄소 비교 측정)

  • Park, Da-Jeong;Kang, Seokwon;Lee, Taehyoung;Shin, Hye-Jung;Shon, Zang-Ho;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.633-641
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    • 2016
  • Two identical Particle Into Liquid Samplers-Total Organic Carbon (PILS-TOC) were operated to measure fine particle Water Soluble Organic Carbon (WSOC) for one week on Feb. in 2016. The dual instrument operations provided validated WSOC concentrations to have a continuous WSOC measurement during the sample analysis period. Both PILS-TOC instruments were operated downstream of an carbon denuder to remove positive adsorption artifacts associated with semi-volatile organic compounds. Comparison of WSOC showed good agreement each other. The linear regression had a coefficient of determination ($r^2$) of 0.92 and a regression slope of 1.01 for the first period. The lower collection efficiency due to lower steam temperature is discussed. In addition, the potential primary source related to WSOC based on the comparison of black carbon (BC) concentrations is explained. The results of good agreement between two PILS-TOC measurements can provide the validation of WSOC cooperations and knowledge regarding the origins of WSOC and their behaviors.

Effect of Hydrocarbon Additives on SNCR DeNOx Characteristics under Oxidizing Diesel Exhaust Gas Conditions

  • Nam, Changmo
    • Journal of Environmental Science International
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    • v.27 no.10
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    • pp.809-820
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    • 2018
  • DeNOx experiments for the effects of hydrocarbon additives on diesel SNCR process were conducted under oxidizing diesel exhaust conditions. A diesel-fueled combustion system was set up to simulate the actual cylinder and head, exhaust pipe and combustion products, where the reducing agent $NH_3$ and $C_2H_6/diesel$ fuel additives were separately or simultaneously injected into the exhaust pipe, used as the SNCR flow reactor. A wide range of air/fuel ratios (A/F=20~40) were maintained, based on engine speeds where an initial NOx level was 530 ppm and the molar ratios (${\beta}=NH_3/NOx$) ranged between 1.0~2.0, together with adjusting the amounts of hydrocarbon additives. Temperature windows were normally formed in the range of 1200~1350K, which were shifted downwards by 50~100K with injecting $C_2H_6/diesel$ fuel additives. About 50~68% NOx reduction was possible with the above molar ratios (${\beta}$) at the optimum flow #1 ($T_{in}=1260K$). Injecting a small amount of $C_2H_6$ or diesel fuel (${\gamma}=hydrocarbon/NOx$) gave the promising results, particularly in the lower exhaust temperatures, by contributing to the sufficient production of active radicals ($OH/O/HO_2/H$) for NOx reduction. Unfortunately, the addition of hydrocarbons increased the concentrations of byproducts such as CO, UHC, $N_2O$ and $NO_2$, and their emission levels are discussed. Among them, Injecting diesel fuel together with the primary reductant seems to be more encouraging for practical reason and could be suggested as an alternative SNCR DeNOx strategy under diesel exhaust systems, following further optimization of chemicals used for lower emission levels of byproducts.

Preparation and Characterization of NiZn-Ferrite Nanofibers Fabricated by Electrospinning Process (전기방사법에 의한 NiZn 페라이트 나노섬유의 제조 및 특성 연구)

  • Joo, Yong-Hui;Nam, Joong-Hee;Cho, Jeong-Ho;Chun, Myoung-Pyo;Kim, Byung-Ik;Ko, Tae-Gyung
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.74-80
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    • 2009
  • Electrospinning process is the useful and unique method to produce nanofibers from metal precursor and polymer solution by controlled viscosity. In this study, the NiZn ferrite nanofibers were prepared by electrospinning with a aqueous metal salts/polymer solution that contained polyvinyl pyrrolidone and Fe (III) chloride, Ni (II) acetate tetrahydrate and zinc acetate dihydrate in N,N-dimethylformamide. The applied electric field and spurting rate for spinning conditions were 10 kV, 2 ml/h, respectively. The obtained fibers were treated at $250^{\circ}C$ for 1 h to remove the polymer. Finally, the NiZn ferrite fibers were calcined at $600^{\circ}C$ for 3 h and annealed at $900{\sim}1200^{\circ}C$ in air. By tuning the viscosity of batch solution before electrospinning, we were able to control the microstructure of NiZn ferrite fiber in the range of $150{\sim}500\;nm$ at 770 cP. The primary particle size in $600^{\circ}C$ calcined ferrite fiber was about 10 nm. The properties of those NiZn ferrite fibers were determined from X-ray diffraction analysis, electron microscopy, energy dispersive spectroscopy, Fourier transform infrared spectroscopy, thermal analysis, and magnetic measurement.

Analysis of Microbial Contamination in Poultry Slaughtering Operations for the Application of HACCP (HACCP 적용을 위한 도계처리 공정내 미생물 오염의 분석)

  • 홍종해;권혁무;고주언
    • Journal of Environmental Health Sciences
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    • v.22 no.1
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    • pp.45-50
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    • 1996
  • The application of HACCP system, which was adopted by Codex Alimentarius Committee for the safe meat and poultry production, is one of the urgent task for competing in the world trade markets. But there have been no useful analytical studies to identify the causes of contamination in the poultry meat processing plants in Korea. This study was conducted to investigate the potential hazards during the operations by the microbiological examination for the poultry meat processing plant (20,000 birds capacity a day) located in Kangwon province. In spite of air contamination of work places, it may not directly affect the surface contamination of poultry meats. But the risk of Campylobacter jejuni/coli contamination was high. The number of total count was decreased about ten times, but remarkable changes of microbial contamination could not be recognized in each procedure during the operations. The washing water was already contaminated as much as $10^{3-6}CFU/ml$ in SPC before the operations. It means that to keep water tanks hygienic is a primary step to prevent the occurrences of microbial contamination. The overflow and recirculation of water in scalding, washing, and chilling was aslo an important factor for a hygienic control. Based on this study, the followings could be regarded as an important factors for hygenic control in the poultry slaughtering plants on a small scale. The temperature of water used for scalding should be constantly maintained on a required temperature, and the overflow rate of 1~1.5 liter per bird. The carcass surface and the body cavity should be washed thoroughly and the cross-contamination due to facilities, workers, and tools should be prevented. The chilling water sholud be maintained under 5$\circ$C of temperature with ice and overflow, and residual chlorine level of 50 ppm.

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