• Title/Summary/Keyword: Preventing Deterioration

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Degradation Mechanisms of a Li-S Cell using Commercial Activated Carbon

  • Norihiro Togasaki;Aiko Nakao;Akari Nakai;Fujio Maeda;Seiichi Kobayashi;Tetsuya Osaka
    • Journal of Electrochemical Science and Technology
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    • v.14 no.4
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    • pp.361-368
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    • 2023
  • In lithium-sulfur (Li-S) batteries, encapsulation of sulfur in activated carbon (AC) materials is a promising strategy for preventing the dissolution of lithium polysulfide into electrolytes and enhancing cycle life, because instead of solid-liquid-solid reactions, quasi-solid-state (QSS) reactions occur in the AC micropores. While a high weight fraction of sulfur in S/AC composites is essential for achieving a high energy density of Li-S cells, the deterioration mechanisms under such conditions are still unclear. In this study, we report the deterioration mechanisms during charge-discharge cycling when the discharge products overflow from the AC. Analysis using scanning electron microscopy and energy-dispersive X-ray spectrometry confirms that the sulfur in the S/AC composites migrates outside the AC as cycling progresses, and it is barely present in the AC after 20 cycles, which corresponds to the capacity decay of the cell. Impedance analysis clearly shows that the electrical resistance of the S/AC composite and the charge-transfer resistance of QSS reactions significantly increase as a result of sulfur migration. On the other hand, the charge-discharge cycling performance under limited-capacity conditions, where the discharge products are encapsulated inside the AC, is extremely stable. These results reveal the degradation mechanism of a Li-S cell with micro-porous carbon and provide crucial insights into the design of a S/AC composite cathode and its operating conditions needed to achieve stable cycling performance.

Lateral Damper of Subway Vehicle for Preventing Abnormal Impact (지하철 전동차 비정상 충격 방지를 위한 횡댐퍼에 관한 연구)

  • Shin, Yujeong;You, Wonhee;Park, Joonhyuk;Hur, Hyunmoo;Jeon, Juyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.1
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    • pp.17-23
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    • 2013
  • In a subway vehicle, a lateral damper is used for compensating the lateral stiffness deterioration due to the air-spring as a secondary suspension. This lateral damper can reduce the lateral vibration of the carbody. When the damping force of the lateral damper is lowered, the running stability and ride quality of the subway vehicles worsens and the lateral motion of the carbody is increased. In this study, the lateral displacement variation of the carbody according to the damping force of the lateral damper was analyzed by multi-body dynamics to solve the abnormal impact problem during vehicle operation. Furthermore, the noise and vibration due to abnormal impact were considered. An adequate damping coefficient of the lateral damper for the subway vehicle treated in this paper was suggested for preventing abnormal impact.

Effect of Formic acid and Caproic acids on the Quality and Aerobic Deterioration of Reed Canarygrass Silage (Formic acid와 Caproic acid 첨가가 Reed Canarygrass Silage의 품질과 호기적 변패에 미치는 영향)

  • 김재황;고영두
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.14 no.2
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    • pp.132-141
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    • 1994
  • In order to study the effects of silage additive on the quality and in preventing aerobic deterioration, reed canarygrass silages were made with various levels of formic acid, caproic acid and a mixture of the two acids. Preparation of silages cutted into about 1.5 cm length with the forage cutter and packed in vinyl bags(50 kg of capacity, 0.1 mrn of thickness), and it also divided nine types of experimental treatments. Aerobic deterioration in the silages were investigated for 7 days of aerobic exposure periods, and the plastic vessel of diameter 25 cm, a height 30 cm used as a tool. The results obtained from this experiment are summarized as fellow. 1. Crude protein and NFE contents at the time if opening were increased in the silage with mixture of formic and caproic acids(P<0.01). Crude fiber and ADF contents during the 7 days of aerobic exposure periods were the decreased in the sslages with mixture of two acods treatment(P<0.01). 2. Temperature of the silage treated with fromic acid alone during the 2 days of aerobic exposure period reached$34.4^{\circ}C$, while that of the silage with caproic acid and mixture formic and caproic acids were not rapidly increased resulting by reduced aerobic deteriorarion. 3. The pH of silages treated with formic acid alone during 7 days of aerobic exposure was not effectively changed, while solages treated with caproic acid were effectively stabilized. 4. The ratio of amminia nitrogen to total nitrogen was significantly decreased in silages with formic acid>caproic acid>mixture of both in the order(P<0.01). 5. Microbiological population of the silage were positively changed during the 7 days of aerobic exposure period. Solages with formic acid were deteriorated at ensiling observed, while applicarion of 1.2% caproic acid was partially reduced deteriorarion by precenting of the growth moulds.

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Actual State and Characteristics of Indoor Noise Including Residents' Living in Apartment Units (아파트 단위주거 내부생활소음의 특성과 실태)

  • Choi, Yoon-Jung
    • Journal of the Korean housing association
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    • v.20 no.1
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    • pp.83-90
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    • 2009
  • The present study is a preliminary research improving the dwelling quality of apartment house as a kind of multi-family housing. The purpose of the study is to find out the actual state on characteristics of indoor noise including residents' living in apartment units. The method was field survey consisted of field measurements on equivalent noise level, observation on noise type, and interview on residents' responses. Field survey were carried out in 20 occupied apartment units from January to March 2007. The results are as follows. 1) Averages of indoor noise levels including residents' living noise were measured as $43.9{\sim}62.2\;dB(A)_{Leq5min}$, the average of each house except one was higher than the permissible level, 45 dB(A). 2) The noise types observed were mostly residents' living noise and classified into 'water hammer', 'living equipment noise', 'noise by family', 'hood noise', 'kitchen noise' in own unit, 'walking and talking noise in stairs and corridors', 'noise by neighborhood house', 'noise by the upper story' in building, and outdoor noise. 3) The residents showed slightly non-positive responses at 'noise by the upper story', 'noise by neighborhood house', 'water hammer', and 'noise by family'. Therefore, it is required to plan for preventing deterioration of the dwelling quality by residents' living noise in own unit as well as by neighborhood houses.

Influence of transient surface hydrogen on Aluminum catalyzed Silicon nanowire growth

  • Sin, Nae-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.125.2-125.2
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    • 2016
  • Semiconductor nanowires are essential building blocks for various nanotechnologies including energy conversion, optoelectronics, and thermoelectric devices. Bottom-up synthetic approach utilizing metal catalyst and vapor phase precursor molecules (i.e., vapor - liquid - solid (VLS) method) is widely employed to grow semiconductor nanowires. Al has received attention as growth catalyst since it is free from contamination issue of Si nanowire leading to the deterioration of electrical properties. Al-catalyzed Si nanowire growth, however, unlike Au-Si system, has relatively narrow window for stable growth, showing highly tapered sidewall structure at high temperature condition. Although surface chemistry is generally known for its role on the crystal growth, it is still unclear how surface adsorbates such as hydrogen atoms and the nanowire sidewall morphology interrelate in VLS growth. Here, we use real-time in situ infrared spectroscopy to confirm the presence of surface hydrogen atoms chemisorbed on Si nanowire sidewalls grown from Al catalyst and demonstrate they are necessary to prevent unwanted tapering of nanowire. We analyze the surface coverage of hydrogen atoms quantitatively via comparison of Si-H vibration modes measured during growth with those obtained from postgrowth measurement. Our findings suggest that the surface adsorbed hydrogen plays a critical role in preventing nanowire sidewall tapering and provide new insights for the role of surface chemistry in VLS growth.

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The Forecasting Model of the Repair Cost in Apartment Housing - Focused roof water proofing and Elevator work - (공동주택 공종별 수선비용 예측모델 연구 - 옥상방수 공사와 승강기 공사를 중심으로 -)

  • Lee, KangHee;Chae, ChangU
    • KIEAE Journal
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    • v.15 no.6
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    • pp.63-68
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    • 2015
  • Purpose: Most if buildings need various repair works for preventing or delaying the deterioration which gives rise to affect the living condition or function after constructed. Therefore, a long-term repair schedule should be planned and a repair cost is required. In this paper, it aimed at providing the statistical forecast model for a repair cost in roof water-proofing work and elevator work using statistical approach with three variables such as number of household, management area and a elapsed year. Data are collected in apartment housings which are located in Seoul area and conducted with interview and questionnaire sheet. Each analyzed work is divided into a partly work and fully work. Results of this study are shown that, first, the regression model takes a multiplying type like a Cobb-Douglas function and is changed into the log-linear type to include the three variable simultaneously. Second, the goodness-of-fit of the repair cost forecasting model has a good statistics in determinant's coefficient and Dubin-Watson value. Third, the management area is stronger factor than other the number of household and an elapsed year in roof water-proofing work and elevator work.

The Management Method for Preventing Frequent Defect about Each Inspection Part from The Data Analysis of Pre-qualification of Residential Building Reconstruction (주택 재건축 예비평가 자료분석을 통한 분야별 주요결함 발생현황 및 유지관리방안 고찰)

  • Bae, Cheol-Hak;Lee, Sung-Ok;Ji, Myoung-Ho
    • Journal of the Korean housing association
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    • v.21 no.6
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    • pp.71-80
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    • 2010
  • The purpose of this study is to classify defects of the residential building by analyzing the defect specified by prequalification of residential building reconstruction and to suggest the solution of the problem which can be arisen during each stage of plan, construction and maintenance. By sorting the main defects which is specified by pre-qualification of residential building reconstruction for three years from August 2006 to August 2009 into 4 catagories and analyzing the cause of the defects, we draw the way of maintenance to prevent the defects and make pleasant residential environment. The reason for the frequent defects from residential building is mainly deterioration. It occured on the finishing more than on the structure, which means that residents can find defects easier on the finishing than the structure and clear the demand for repair. The result of analyzing of pre-qualification of residential building reconstruction is that the defects mostly caused small, masonry constructed and lower apartment. The apartment which is not into legal right for maintenance naturally have more defects than the others. In conclusion, it is necessary to establish a law of obligation duty of the maintenance of small apartment.

A Study on the Life Time of RCD in Coastal Area (해안지역에서의 저압용 누전차단기 교체주기 연구)

  • Kim, Chong-Min;Choi, Myeong-Il;Shong, Kil-Mok;Seo, Jung-Youl;Shin, Jin-Yong;Kim, Chang-Hwan
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.1
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    • pp.85-92
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    • 2011
  • The role of RCDs(Residual Current Protective Device) that are installed before the load is very important for preventing electric shock and electrical fire. However, although fault rate of RCD is increasing due to deterioration and long period usage, the RCD is permanently used without a checking of performance evaluation and it causes the electrical accident. In this paper, the amount of airborne chloride is researched in domestic costal area and the accelerated life test is conducted using a salt water spray tester in order to decide the life time of RCD. Aa a result of an accelerated life test, the MTTF(Mean Time To Failure) of RCD is 110.81 hours and B10 life time of RCD is 45.81 hours for the all samples. when an accelerated life test result is applied to within 2 km costal area, the life time of RCD is predicted about 5 years.

Theoretical Study on Interfacial Stresses at RC Beam Repair-Purpose Overlayed by Latex Modified Concrete (LMC로 덧씌우기 보수된 RC보의 계면응력에 관한 연구)

  • Kim, Hyun-Oh;Kim, Seong-Hwan;Kim, Dong-Ho;Lee, Bong-Hak
    • Journal of Industrial Technology
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    • v.24 no.A
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    • pp.179-184
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    • 2004
  • Each year, new technological advancements for repair-purpose are being introduced to overlay the old deterioration of RC bridge deck at highway by latex-modified concrete. The days may come when this old problem will be successfully resolved. While the experimental works and researches are very active at both laboratory and field, only a few theoretical studies were performed on interfacial problems, especially on stress distribution and concentration of RC beam overlayed by latex-modified concrete. The repaired and strengthened structures would induce a premature failure due to the stress concentration at the adhesive layer of different material before the design expected failure. This paper investigated and proposed an analytical model for predicting interfacial shear and normal stresses of RC beam repair-purpose overlayed by latex-modified concrete. This would be used for predicting interfacial stresses and preventing premature failure at interfaces. This study modified Smith-Teng method for applying to cementitious repairing material, which was based on a direct governing equation and linear-elastic approach for interfacial normal and shear stresses. The proposed theoretical model was verified using commercial FEA program, LUSAS, in terms of interfacial stresses predicted by the proposed model and calculated by LUSAS.

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Studies on Chemical Composition, Amino Acid, Minerals of Venison (사슴육의 일반성분,아미노산,무기질 함량에 관한 연구)

  • 박창일;김영직;김영길;김덕진;유춘발;안종호
    • Journal of the East Asian Society of Dietary Life
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    • v.10 no.3
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    • pp.222-228
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    • 2000
  • The experiment was conducted to investigate the physico-chemical characteristics of vacuum and aerobically packed meat from Elk deer weighing 170 $\pm$ 10kg of 28 to 30 months old, chilled at 4$^{\circ}C$for 10days. The moisture content, crude protein, crude fat and crude ash in deer loin were 74.46%, 22.11%, 1.27% and 1.13%: the leg parts had 75.47%, 22.68%, 1.58% and 1.27%, respectively. The decrease in moisture content was greater in aerobic packaging than in vacuum packaging. The lysine content of loin and leg parts were 2,380mg% and 2,270mg% and the glutamate content of loin and leg parts were 4,145mg% and 3,987.5mg% respectively. On the whole, the loin contained more amino acids than leg part. Of the mineral contents, phosphorus, potassium and sodium were present in large amounts and mineral content was decreased with longer chilling period. The leg parts contained more potassium, sodium, phosphorus, zinc, magnesium and calcium than loin parts. In conclusion, vacuum packaging is considered more advantageous in preventing meat color change and microbial deterioration for consumers interest.

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