• Title/Summary/Keyword: Pressurized reaction

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Effects of High-Pressure, Microbial Transglutaminase and Glucono-δ-Lactone on the Aggregation Properties of Skim Milk

  • Lee, Sang Yoon;Choi, Mi-Jung;Cho, Hyung-Yong;Davaatseren, Munkhtugs
    • Food Science of Animal Resources
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    • v.36 no.3
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    • pp.335-342
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    • 2016
  • The object in this study is to investigate the effects of high pressure and freezing processes on the curdling of skim milk depending on the presence of transglutaminase (TGase) and glucono-δ-lactone (GdL). Skim milk was treated with atmospheric freezing (AF), high pressure (HP), pressure-shift freezing (PSF) and high pressure sub-zero temperature (HPST) processing conditions. After freezing and pressure processing, these processed milk samples were treated with curdling agents, such as TGase and GdL. Pressurized samples (HP, PSF and HPST) had lower lightness than that of the control. In particular, PSF had the lowest lightness (p<0.05). Likewise, the PSF proteins were the most insoluble regardless of whether they were activated by TGase and GdL, indicating the highest rate of protein aggregation (p<0.05). Furthermore, the TGase/GdL reaction resulted in thick bands corresponding to masses larger than 69 kDa, indicating curdling. Casein bands were the weakest in PSF-treated milk, revealing that casein was prone to protein aggregation. PSF also had the highest G' value among all treatments after activation by TGase, implying that PSF formed the hardest curd. However, adding GdL decreased the G' values of the samples except HPST-treated samples. Synthetically, the PSF process was advantageous for curdling of skim milk.

Multi-function Control of Hydraulic Variable Displacement Pump with EPPR Valve (전자비례감압밸브를 이용한 가변용량형 유압펌프의 다기능 제어)

  • Jung, Dong-Soo;Kim, Hyong-Eui;Kang, E-Sok
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.6
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    • pp.160-170
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    • 2006
  • If hydraulic pump controlled by mechanical type regulator has more than one control function, the construction of regulator will be very complicated and control performance falls drastically. It is difficult to have more than one control function for hydraulic pump controlled by electronic type hydraulic valve due to the inconsistency of controllers. This paper proposes a multi-function control technique which controls continuously flow, pressure and power by using EPPR(Electronic Proportional Pressure Reducing) valve in swash plate type axial piston pump. Nonlinear mathematical model is developed from the continuity equation for the pressurized control volume and the torque balance for the swash plate motion. To simplify the model we make the linear state equation by differentiating the nonlinear model. A reaction spring is installed in servo cylinder to secure the stability of the control system. We analyze the stability and disturbance by using the state variable model. Finally, we review the control performances of flow, pressure and power by tests using PID controller.

The flow characteristics of a Main Cooling Water System for Nuclear Fuel Test Loop Installed in HANARO (하나로 핵연료 시험루프의 주냉각수 계통 유동해석)

  • Park, Young-Chul;Lee, Young-Sub;Chi, Dai-Yong;Ahn, Seong-Ho;Kim, Yong-Ki
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.444-447
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    • 2008
  • A nuclear fuel test loop (after below, FTL) is installed in IR1 of an irradiation hole in HANARO for testing neutron irradiation characteristics and thermo hydraulic characteristics of a fuel loaded in a light water power reactor (PWR) or a heavy water power reactor (CANDU). There is an in-pile section (IPS) and an out-pile section (OPS) in this test loop. When HANARO is normally operated, the fuel loaded in the IPS has a nuclear reaction heat generated by a neutron irradiation. To remove the generated heat and to maintain an operation condition of the test fuel, a main cooling water system (MCWS) is installed in the OPS of the FTL. The pump can not continuously suck a fluid and not pressurize the fluid during a cold function test. To verify the flow characteristics of the MCWS, a flow net work analysis has been conducted. When the higher elevation pipelines wholly filled with coolant, it was confirmed through the analysis results that the pump pressurized the coolant normally. And the analysis results described the system characteristics with operation temperature and pressure variation satisfactorily.

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Operating Conditions of Proton Exchange Membrane Fuel Cell Using Grafoil$^{TM}$ as Bipolar Plates (그라포일 분리판을 이용한 고분자 전해질 연료전지의 운전 조건에 관한 연구)

  • Park, Taehyun;Chang, Ikwhang;Lee, Yoon Ho;Lee, Juhyung;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.85.1-85.1
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    • 2011
  • In this study, Grafoil$^{TM}$ which has comparable electric resistance and chemical stability but is flexible, fragile, and cheap material was adopted as bipolar plates for proton exchange membrane fuel cell(PEMFC) having only one straight line flow channel. Because of its flexibility, pressurizations of cell with various pressures showed different operating characteristics compared to ordinary graphite-used PEMFC. While performances of both cells decreased as these were pressurized, investigation of ohmic and faradaic resistance by electrochemical impedance measurement indicated different tendency of change. Ohmic resistance of graphite-used cell increased with increasing pressure, which is reversed in Grafoil$^{TM}$-used cell. It is speculated that effective chemical reaction area is decreased with increasing pressure in case of graphite-used one, but because of flexible property of Grafoil$^{TM}$, gas diffusion layer in Grafoil$^{TM}$-used cell was well-activated. Different rate of change of faradaic resistances in both cells support this supposition. However, although optimum point of pressurization is found, it is required to investigate other operating conditions because of low performance compared to graphite-used cell.

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Development of an Oxide Reduction Process for the Treatment of PWR Spent Fuel (PWR 사용후핵연료 처리를 위한 금속전환공정 개발)

  • Hur, Jin-Mok;Hong, Sun-Seok;Jeong, Sang-Mun;Lee, Han-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.1
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    • pp.77-84
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    • 2010
  • Reduction of oxides has been investigated for the volume reduction and recycling of the spent oxide fuel from commercial nuclear power plants. Various oxide reduction methods were proposed and KAERI (Korea Atomic Energy Research Institute) is currently developing an electrochemical reduction process using a LiCl-$Li_2O$ molten salt as a reaction medium. The electrochemical reduction process, the front end of the pyroprocessing, can connect the PWR (Pressurized Water Reactor) oxide fuel cycle to a metal fuel cycle of the sodium cooled fast reactor. This paper summarizes KAERI efforts on the development, improvement, and scale-up of the oxide reduction process.

A Study of Alkali Metal Vapor Adsorption Behavior by Using Pressurized Reactor (가압반응기를 이용한 알칼리금속증기 흡착특성에 관한 연구)

  • 전수한;최병철;김형택
    • Journal of Energy Engineering
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    • v.11 no.2
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    • pp.114-121
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    • 2002
  • Alkali metal compounds existed in original coal or sorbents are exhausted as vapor or small particle at the outlet of combustor when operating PFBC power plant. These compounds can be removed with dust removal equipment, but total generation efficiency will be decreased because of lower operating temperature of dust removal equipment. Alkali metal contained in vapor phase is initially deposited onto turbine blade results in serious corrosion. The concentration of alkali vapor in the PFBC flue gas is 20∼40 ppm which is dependent on mineral characteristics and composition as well as operating condition of PFBC. However, the allowance limit of alkali metal vapor is assigned as less than 50 ppb for gas turbine when coal or oil is used as fuel. Therefore, alkali metal vapor in PFBC or IGCC process should be removed by solid sorbents to prevent corrosion of turbine blade and improve plant efficiency. In the present investigation, powder of Bauxite, Kaolinite and Limestone is used in the preparation of cylinder-type pellet which is inserted into the pressurized alkali removal reactor for the alkali absorption experiment. Experimental results showed that the alkali removal efficiency in the order of Bauxite, Kaolinite and Limestone. Alkali vapor removal efficiency is related with reaction temperature, porosity of pellet and alkali vapor concentration of flue gas.

Study on the Dissolution of Sandstones in Gyeongsang Basin and the Calculation of Their Dissolution Coefficients under CO2 Injection Condition (이산화탄소 지중 주입에 의한 경상분지 사암의 용해반응 규명 및 용해 반응상수값 계산)

  • Kang, Hyunmin;Baek, Kyoungbae;Wang, Sookyun;Park, Jinyoung;Lee, Minhee
    • Economic and Environmental Geology
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    • v.45 no.6
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    • pp.661-672
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    • 2012
  • Lab scale experiments to investigate the dissolution reaction among supercritical $CO_2$-sandstone-groundwater by using sandstones from Gyeongsang basin were performed. High pressurized cell system (100 bar and $50^{\circ}C$) was designed to create supercritical $CO_2$ in the cell, simulating the sub-surface $CO_2$ storage site. The first-order dissolution coefficient ($k_d$) of the sandstone was calculated by measuring the change of the weight of thin section or the concentration of ions dissolved in groundwater at the reaction time intervals. For 30 days of the supercritical $CO_2$-sandstone-groundwater reaction, physical properties of sandstone cores in Gyeongsang basin were measured to investigate the effect of supercritical $CO_2$ on the sandstone. The weight change of sandstone cores was also measured to calculate the dissolution coefficient and the dissolution time of 1 g per unit area (1 $cm^2$) of each sandstone was quantitatively predicted. For the experiment using thin sections, mass of $Ca^{2+}$ and $Na^+$ dissolved in groundwater increased, suggesting that plagioclase and calcite of the sandstone would be significantly dissolved when it contacts with supercritical $CO_2$ and groundwater at $CO_2$ sequestration sites. 0.66% of the original thin sec-tion mass for the sandstone were dissolved after 30 days reaction. The average porosity for C sandstones was 8.183% and it increased to 8.789% after 30 days of the reaction. The average dry density, seismic velocity, and 1-D compression strength of sandstones decreased and these results were dependent on the porosity increase by the dissolution during the reaction. By using the first-order dissolution coefficient, the average time to dissolve 1 g of B and C sandstones per unit area (1 $cm^2$) was calculated as 1,532 years and 329 years, respectively. From results, it was investigated that the physical property change of sandstones at Gyeongsang basin would rapidly occur when the supercritical $CO_2$ was injected into $CO_2$ sequestration sites.

The Antioxidant Effect of Hot Water Extract from the Dried Radish (Raphanus sativus L.) with Pressurized Roasting (가압볶음 무말랭이 열수 추출물의 항산화 효과)

  • Song, Yeong-Bok;Choi, Jeong-Sun;Lee, Ji-Eun;Noh, Jeong-Sook;Kim, Mi-Jeong;Cho, Eun-Ju;Song, Yeong-Ok
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.8
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    • pp.1179-1186
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    • 2010
  • The antiradical property of hot water extract from dried radish (DR) or dried radish roasted with pressure (DRRP) was investigated in vitro and in LLC-PK1 cell system. The contents of total free amino acid and reducing sugar in DR were decreased by 72.86% and 3.17%, respectively, after pressurized roasting. In vitro test, $IC_{50}$ for DR and DRRP for DPPH radical scavenging activity were 646.70 and $135.45\;{\mu}g/mL$, 896.10 and $566.98\;{\mu}g/mL$ for superoxide anion radical, and 722.26 and $531.84\;{\mu}g/mL$ for hydroxy radical, respectively. The radical scavenging effects of DRRP was significantly greater than those for DR (p<0.001). These radical scavenging effects of DR and DRRP were confirmed in LLC-$PK_1$ at which oxidative stresses were induced by superoxide, nitric oxide and peroxynitrite generated in the treatment of pyrogallol, SNP, and SIN-1, respectively. Cell viability was increased in the presence of DR or DRRP, dose dependently (p<0.05), and TBARS formation was decreased. The protective effects of DRRP against oxidative damage in LLC-$PK_1$ were greater than those of DR at the same concentration tested (p<0.05). This superior antiradical activity of DRRP might be due to the products produced during the pressurized roasting in addition to the antioxidative compounds originally present in the radish. 5-hydroxyl methyl furfural (5-HMF) known as an intermediate product of the maillard reaction was detected in DRRP (0.57 mg/g), but not from DR. In conclusion, daily consumption of DRRP may prevent oxidative damage by retarding oxidative stress.

High Pressure Inactivation of Candida tropicalis and Its Effects on Ultrastructure of the Cells (고압처리에 의한 Candida tropicalis의 불활성화 및 세포구조의 변화)

  • Sohn, Kyung-Hyun;Chang, Cheong-Kook;Kong, Un-Young;Lee, Hyung-Joo
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.587-592
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    • 1996
  • Effects of high pressure on the inactivation and microstructure of Candida tropicalis (C. tropicalis) were in vestigated. High pressure inactivation of C. tropicalis was a first order reaction. The decimal reduction time (D value) at 400 MPa was 1.4 min at $25^{\circ}C$ and z value was 100 MPa. The effect of high pressure treatment was higher when treated at $45^{\circ}C$ than at $25^{\circ}C$. Damages in mitochondrial membrane and cell wall of C. Tropicalis were observed when it was pressurized at 400 MPa for 10 min. It indicates that high pressure affects the membrane system of the cell and causes the inactivation of C. tropicalis.

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Degradation of Organic Component in MSW by Super-heated Steam (과열(過熱) 증기(蒸氣)를 이용한 국내 폐기물(廢棄物) 유기성(有機性) 성분의 분해(分解) 특성 연구)

  • Kim, Woo-Hyun;Roh, Seon-Ah;Min, Tai-Jin;Sung, Hyun-Je;Park, Seong-Bum;Jang, Ha-Na
    • Resources Recycling
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    • v.18 no.6
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    • pp.10-17
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    • 2009
  • Degradation of the organic component in the waste were carried out by superheated steam in a pressurized vessel. The effects of waste characteristics, reaction temperature and residence time on the degradation rate have been determined. The biodegradable organic components such as food and paper waste have been degraded, and plastics, wood and metal were remained without degradation. The degradation efficiency is decided by the desizing rate of the waste, and the waste mixture with 23% biodegradable organic component shows higher desizing rate than that of the 43% of the biodegradable organic component in a short residence time and the desizing rate is found to be 90% in the maximum condition.