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Thermally-activated Mactra veneriformis shells for phosphate removal in aqueous solution

  • Yeon-Jin, Lee;Jae-In, Lee;Chang-Gu, Lee;Seong-Jik, Park
    • Membrane and Water Treatment
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    • v.14 no.1
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    • pp.1-10
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    • 2023
  • This study explored the feasibility of calcium-rich food waste, Mactra veneriformis shells (MVS), as an adsorbent for phosphate removal, and its removal efficiency was enhanced by the thermal activation process. The CaCO3 in MVS was converted to CaO by thermal activation (>800 ℃), which is more favorable for adsorbing phosphate. Thermal activation did not noticeably influence the specific surface area of MVS. The MVS thermally activated at 800 ℃ (MVS-800), showed the highest phosphate adsorption capacity, was used for further adsorption experiments, including kinetics, equilibrium isotherms, and thermodynamic adsorption. The effects of environmental factors, including pH, competing anions, and adsorbent dosage, were also studied. Phosphate adsorption by MVS-800 reached equilibrium within 48h, and the kinetic adsorption data were well explained by the pseudo-first-order model. The Langmuir model was a better fit for phosphate adsorption by MVS-800 than the Freundlich model, and the maximum adsorption capacity of MVS-800 obtained via the Langmuir model was 188.86 mg/g. Phosphate adsorption is an endothermic and involuntary process. As the pH increased, the phosphate adsorption decreased, and a sharp decrease was observed between pH 7 and 9. The presence of anions had a negative impact on phosphate removal, and their impact followed the decreasing order CO32- > SO42- > NO3- > Cl-. The increase in adsorbent dosage increased phosphate removal percentage, and 6.67 g/L of MVS-800 dose achieved 99.9% of phosphate removal. It can be concluded that the thermally treated MVS-800 can be used as an effective adsorbent for removing phosphate.

Non-Gaussian feature of fluctuating wind pressures on rectangular high-rise buildings with different side ratios

  • Jia-hui Yuan;Shui-fu Chen;Yi Liu
    • Wind and Structures
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    • v.37 no.3
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    • pp.211-227
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    • 2023
  • To investigate the non-Gaussian feature of fluctuating wind pressures on rectangular high-rise buildings, wind tunnel tests were conducted on scale models with side ratios ranging from 1/9~9 in an open exposure for various wind directions. The high-order statistical moments, time histories, probability density distributions, and peak factors of pressure fluctuations are analyzed. The mixed normal-Weibull distribution, Gumbel-Weibull distribution, and lognormal-Weibull distribution are adopted to fit the probability density distribution of different non-Gaussian wind pressures. Zones of Gaussian and non-Gaussian are classified for rectangular buildings with various side ratios. The results indicate that on the side wall, the non-Gaussian wind pressures are related to the distance from the leading edge. Apart from the non-Gaussianity in the separated flow regions noted by some literature, wind pressures behind the area where reattachment happens present non-Gaussian nature as well. There is a new probability density distribution type of non-Gaussian wind pressure which has both long positive and negative tail found behind the reattachment regions. The correlation coefficient of wind pressures is proved to reflect the non-Gaussianity and a new method to estimate the mean reattachment length of rectangular high-rise building side wall is proposed by evaluating the correlation coefficient. For rectangular high-rise buildings, the mean reattachment length calculated by the correlation coefficient method along the height changes in a parabolic shape. Distributions of Gaussian and non-Gaussian wind pressures vary with side ratios. It is inappropriate to estimate the extreme loads of wind pressures using a fixed peak factor. The trend of the peak factor with side ratios on different walls is given.

A new extended Mohr-Coulomb criterion in the space of three-dimensional stresses on the in-situ rock

  • Mohatsim Mahetaji;Jwngsar Brahma;Rakesh Kumar Vij
    • Geomechanics and Engineering
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    • v.32 no.1
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    • pp.49-68
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    • 2023
  • The three-dimensional failure criterion is essential for maintaining wellbore stability and sand production problem. The convenient factor for a stable wellbore is mud weight and borehole orientation, i.e., mud window design and selection of borehole trajectory. This study proposes a new three-dimensional failure criterion with linear relation of three in-situ principal stresses. The number of failure criteria executed to understand the phenomenon of rock failure under in-situ stresses is the Mohr-Coulomb criterion, Hoek-Brown criterion, Mogi-Coulomb criterion, and many more. A new failure criterion is the extended Mohr-Coulomb failure criterion with the influence of intermediate principal stress (σ2). The influence of intermediate principal stress is considered as a weighting of (σ2) on the mean effective stress. The triaxial compression test data for eleven rock types are taken from the literature for calibration of material constant and validation of failure prediction. The predictions on rock samples using new criteria are the best fit with the triaxial compression test data points. Here, Drucker-Prager and the Mogi-Coulomb criterion are also implemented to predict the failure for eleven different rock types. It has been observed that the Drucker-Prager criterion gave over prediction of rock failure. On the contrary, the Mogi-Coulomb criterion gave an equally good prediction of rock failure as our proposed new 3D failure criterion. Based on the yield surface of a new 3D linear criterion it gave the safest prediction for the failure of the rock. A new linear failure criterion is recommended for the unique solution as a linear relation of the principal stresses rather than the dual solution by the Mogi-Coulomb criterion.

Effect of fiber content on the performance of UHPC slabs under impact loading - experimental and analytical investigation

  • Muhammad Umar Khan;Shamsad Ahmad;Mohammed A. Al-Osta;Ali Husain Algadhib;Husain Jubran Al-Gahtani
    • Advances in concrete construction
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    • v.15 no.3
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    • pp.161-170
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    • 2023
  • Ultra-high-performance concrete (UHPC) is produced using high amount of cementitious materials, very low water/cementitious materials ratio, fine-sized fillers, and steel fibers. Due to the dense microstructure of UHPC, it possesses very high strength, elasticity, and durability. Besides that, the UHPC exhibits high ductility and fracture toughness due to presence of fibers in its matrix. While the high ductility of UHPC allows it to undergo high strain/deflection before failure, the high fracture toughness of UHPC greatly enhances its capacity to absorb impact energy without allowing the formation of severe cracking or penetration by the impactor. These advantages with UHPC make it a suitable material for construction of the structural members subjected to special loading conditions. In this research work, the UHPC mixtures having three different dosages of steel fibers (2%, 4% and 6% by weight corresponding to 0.67%, 1.33% and 2% by volume) were characterized in terms of their mechanical properties including facture toughness, before using these concrete mixtures for casting the slab specimens, which were tested under high-energy impact loading with the help of a drop-weight impact test setup. The effect of fiber content on the impact energy absorption capacity and central deflection of the slab specimens were investigated and the equations correlating fiber content with the energy absorption capacity and central deflection were obtained with high degrees of fit. Finite element modeling (FEM) was performed to simulate the behavior of the slabs under impact loading. The FEM results were found to be in good agreement with their corresponding experimentally generated results.

Aeroelastic modeling to investigate the wind-induced response of a multi-span transmission lines system

  • Azzi, Ziad;Elawady, Amal;Irwin, Peter;Chowdhury, Arindam Gan;Shdid, Caesar Abi
    • Wind and Structures
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    • v.34 no.2
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    • pp.231-257
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    • 2022
  • Transmission lines systems are important components of the electrical power infrastructure. However, these systems are vulnerable to damage from high wind events such as hurricanes. This study presents the results from a 1:50 scale aeroelastic model of a multi-span transmission lines system subjected to simulated hurricane winds. The transmission lines system considered in this study consists of three lattice towers, four spans of conductors and two end-frames. The aeroelastic tests were conducted at the NSF NHERI Wall of Wind Experimental Facility (WOW EF) at the Florida International University (FIU). A horizontal distortion scaling technique was used in order to fit the entire model on the WOW turntable. The system was tested at various wind speeds ranging from 35 m/s to 78 m/s (equivalent full-scale speeds) for varying wind directions. A system identification (SID) technique was used to evaluate experimental-based along-wind aerodynamic damping coefficients and compare with their theoretical counterparts. Comparisons were done for two aeroelastic models: (i) a self-supported lattice tower, and (ii) a multi-span transmission lines system. A buffeting analysis was conducted to estimate the response of the conductors and compare it to measured experimental values. The responses of the single lattice tower and the multi-span transmission lines system were compared. The coupling effects seem to drastically change the aerodynamic damping of the system, compared to the single lattice tower case. The estimation of the drag forces on the conductors are in good agreement with their experimental counterparts. The incorporation of the change in turbulence intensity along the height of the towers appears to better estimate the response of the transmission tower, in comparison with previous methods which assumed constant turbulence intensity. Dynamic amplification factors and gust effect factors were computed, and comparisons were made with code specific values. The resonance contribution is shown to reach a maximum of 18% and 30% of the peak response of the stand-alone tower and entire system, respectively.

New approach to calculate Weibull parameters and comparison of wind potential of five cities of Pakistan

  • Ahmed Ali Rajput;Muhammad Daniyal;Muhammad Mustaqeem Zahid;Hasan Nafees;Misha Shafi;Zaheer Uddin
    • Advances in Energy Research
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    • v.8 no.2
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    • pp.95-110
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    • 2022
  • Wind energy can be utilized for the generation of electricity, due to significant wind potential at different parts of the world, some countries have already been generating of electricity through wind. Pakistan is still well behind and has not yet made any appreciable effort for the same. The objective of this work was to add some new strategies to calculate Weibull parameters and assess wind energy potential. A new approach calculates Weibull parameters; we also developed an alternate formula to calculate shape parameters instead of the gamma function. We obtained k (shape parameter) and c (scale parameter) for two-parameter Weibull distribution using five statistical methods for five different cities in Pakistan. Maximum likelihood method, Modified Maximum likelihood Method, Method of Moment, Energy Pattern Method, Empirical Method, and have been to calculate and differentiate the values of (shape parameter) k and (scale parameter) c. The performance of these five methods is estimated using the Goodness-of-Fit Test, including root mean square error, mean absolute bias error, mean absolute percentage error, and chi-square error. The daily 10-minute average values of wind speed data (obtained from energydata.info) of different cities of Pakistan for the year 2016 are used to estimate the Weibull parameters. The study finds that Hyderabad city has the largest wind potential than Karachi, Quetta, Lahore, and Peshawar. Hyderabad and Karachi are two possible sites where wind turbines can produce reasonable electricity.

Predicting strength and strain of circular concrete cross-sections confined with FRP under axial compression by utilizing artificial neural networks

  • Yaman S. S. Al-Kamaki;Abdulhameed A. Yaseen;Mezgeen S. Ahmed;Razaq Ferhadi;Mand K. Askar
    • Computers and Concrete
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    • v.34 no.1
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    • pp.93-122
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    • 2024
  • One well-known reason for using Fiber Reinforced Polymer (FRP) composites is to improve concrete strength and strain capacity via external confinement. Hence, various studies have been undertaken to offer a good illustration of the response of FRP-wrapped concrete for practical design intents. However, in such studies, the strength and strain of the confined concrete were predicted using regression analysis based on a limited number of test data. This study presents an approach based on artificial neural networks (ANNs) to develop models to predict the strength and strain at maximum stress enhancement of circular concrete cross-sections confined with different FRP types (Carbone, Glass, Aramid). To achieve this goal, a large test database comprising 493 axial compression experiments on FRP-confined concrete samples was compiled based on an extensive review of the published literature and used to validate the predicted artificial intelligence techniques. The ANN approach is currently thought to be the preferred learning technique because of its strong prediction effectiveness, interpretability, adaptability, and generalization. The accuracy of the developed ANN model for predicting the behavior of FRP-confined concrete is commensurate with the experimental database compiled from published literature. Statistical measures values, which indicate a better fit, were observed in all of the ANN models. Therefore, compared to existing models, it should be highlighted that the newly developed models based on FRP type are remarkably accurate.

Adaptability of zirconia core fabricated by cold isostatic pressing (냉간 정수압 성형법으로 제작된 지르코니아 코어의 적합도에 관한 연구)

  • Seo, Yoon-Jeong;Yun, Kwi-Dug;Kim, Hyun-Seung;Park, Sang-Won
    • The Journal of Korean Academy of Prosthodontics
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    • v.48 no.2
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    • pp.143-150
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    • 2010
  • Purpose: The purpose of this study is to fabricate the new zirconia block (CNU block) and to evaluate fit of core and porcelain veneered zirconia crown. Material and methods: The experimental blocks were fabricated from the commercial ytrria-stabilized zirconia powder (KZ-3YE Type A). The powder was uniaxial pressing and the green bodies were conducted using the Cold Isostatic Pressing. The zirconia blocks were presintered at $1040^{\circ}C$ and the final sintering was performed at $1450^{\circ}C$. The Kavo Everest ZS $blank{(R)}$ (KaVo, Biberach/ $Ri{\beta}$.) was used as a control group. The linear shrinkage of CNU block and Kavo block were compared. Twenty-one cores for porcelain veneered crowns were fabricated with CAD/CAM system ($Everest{(R)}$, Biberach/ $Ri{\beta}$.). Group I; seven cores fabricated from Kavo blocks, Group II; seven cores fabricated from CNU blocks, Group III; seven cores from CNU blocks and porcelain veneering for crowns. All specimens were cemented and sectioned into two planes; diagonal and bucco-lingual. The measurement of the marginal, internal, and occlusal fit was carried out using SEM ($S-4800^{(R)}$) at $30{\times}$. The results were analyzed by one-way ANOVA test. Results: The linear shrinkage of the CNU block and the KaVo block was 19.00% and 20.09%. The marginal gap of cores ($29.67{\pm}6.58{\mu}m$) fabricated from CNU blocks showed significantly smaller than that of the cores of Kavo blocks ($36.84{\pm}7.18{\mu}m$) (P < .05). The internal gaps of the porcelain veneered crowns ($32.23{\pm}6.33{\mu}m$) were larger than those of the other two groups ($37.57{\pm}6.81{\mu}m$ and $38.14{\pm}6.81{\mu}m$). Conclusion: No statistically significant difference was found in between experimental groups and control group. The experimental groups in marginal gap showed significantly smaller than the control group.

Analysis of Fire Risk Assessment Indicators of Publicly-Used Establishments using Delphi/AHP (Delphi/AHP를 활용한 다중이용업 신종업종의 화재위험평가지표 분석)

  • Kim, Myung-Cheol;Kim, Hak-Joong;Park, Kyung-Hwan;Youn, Hae-Kwon;Lee, Seung-Ho
    • Fire Science and Engineering
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    • v.33 no.6
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    • pp.87-94
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    • 2019
  • Through a press release dated July 17, 2018, the Anti-Corruption and Civil Rights Commission recommended that the National Fire Agency develop preventive measures against fire in the "Indoor Archery Ground" and "Room Escape Café" etc., which were originally excluded from the category of "Publicly Used Establishments." This study developed the hierarchy of domains and indicators of measurement for fire risk assessment of the new business of publicly used establishments through the Delphi Method. It analyzed the goodness of fit scores (over 3.00) and secured an average score of 4.25. Using AHP analysis, the ratio of consistency for the domains of measurement of fire risk assessment was found to be 4.0%, which was lower than CR ≤ 0.1 (10%). The consistency of subsequent measurement indicators were distributed in the range of 0.1%~3.6%, and they were identified as being commonly consistent. The indicators of measurement appeared as follows in order of importance and priority: Type of Internal Passage of Establishment and Evacuation Capacity of Exit (0.316), Control of Ignition Source (0.141), Inherent Risk (0.106), Appropriateness and Adaptiveness of Fire Detection System (0.097), Control of Inflammables/Combustibles (0.084), Guides and Facilities helping Evacuation (0.075), Fire Resistant Structure and Finishing Materials (0.060), Compartmentalization and Emergency Exit (0.049), Risk of Fire Expansion (0.046), and Appropriateness and Adaptiveness of Fire Extinguishing Facilities (0.026). The findings of this study are expected to be expansively used as data for future research on the development of fire risk assessment indicators.

A Study on the Secondary Optimization Analysis based on the Result of Primary Structure Analysis for the Die Thickness (금형두께에 대한 1차 구조해석 결과를 기반으로 한 2차 최적화 해석에 관한 연구)

  • Lee, Jong-Bae;Kim, Sang-Hyun;Woo, Chang-Ki
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.3448-3454
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    • 2014
  • Generally existing structure analysis was applied to elastic analysis basically in practice. Considering the nonlinear material and the nonlinear geometric to be a more precise analysis, for this reason, The necessity for a structual analysis have been constantly required. Therefore, after optimization is performed, designed a simple model which is applied the principle of nonlinear in this study, a structural analysis of existing experienced users, have a aims at presenting theory and a method in order to perform anyone the analysis easily. In this study, the proposed model applied to die ribs, Regarding the shear load, less strain and stress was generated but strength was sufficient. The initial strain and stress was reconfigured to fit the size and shape, A hyperstudy in conjunction with Abaqus with nonlinear structural analysis, revealed an acceptable maximum and minimum range of stress and under the conditions of minimum strain, the plate made with a constant increment. In the experimental models, the plate thickness was given a power of 40 Newton, according to the thickness of the press die through an iterative process. When the stress and strain was applied to the die thickness, 7-8mm thickness could be obtained by optimizing.