• Title/Summary/Keyword: Precipitation method

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Immuno-Modulatory Activities of Polysaccharides separated from Chrysanthemum zawadskii var. latilobum in Macrophage Cells (구절초(Chrysanthemum zawadskii var. latilobum)에서 분리된 다당류의 대식세포 면역조절 활성)

  • Sung, Nak-Yun;Park, Yoo-Young;Kim, Yi-Eun;Cho, Eun-Ji;Kim, Mi-Hwan;Ryu, Gi-Hyung;Byun, Eui-Hong;Park, Youn-Je
    • The Korean Journal of Food And Nutrition
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    • v.29 no.3
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    • pp.431-437
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    • 2016
  • Macrophages play a pivotal role in the innate and adaptive immune systems. This study investigated the immuno-modulatory activities of polysaccharides separated from Chrysanthemum zawadskii var. latilobum (CZPS) in macrophages. Polysaccharides from Chrysanthemum zawadskii var. latilobum were extracted by the ethanol precipitation method. RAW 264.7 mouse macrophage cell line was treated with CZPS (4 to $128{\mu}g/mL$), and there was no cytotoxicity at a dose below $32{\mu}g/mL$. The levels of nitric oxide (NO) and pro-inflammatory cytokines (tumor necrosis factor (TNF)-${\alpha}$ and interleukin (IL)-6, IL-$1{\beta}$) production in the CZPS treated group ($32{\mu}g/mL$) were $6.5{\pm}0.12{\mu}m$ (NO), $1252.8{\pm}79.85$ (TNF-${\alpha}$), $305.4{\pm}29.41$ (IL-6), and $683.3{\pm}59.71$ (IL-$1{\beta}$), respectively, and they were significantly increased when compared to the control group; $2.2{\pm}0.03{\mu}m$ (NO), $452.3{\pm}38.34$ (TNF-${\alpha}$), $31.7{\pm}5.75$ (IL-6), and $184.1{\pm}11.52$ (IL-$1{\beta}$). Additionally, protein expression of inducible nitric oxide synthase (iNOS) and phosphorylation of MAPKs and NF-${\kappa}B$ expression were significantly increased upon CZPS treatment. Therefore, these results indicated that polysaccharides separated from Chrysanthemum zawadskii var. latilobum (CZPS) may have a potential immunomodulatory activity in macrophages through MAPKs and NF-${\kappa}B$ signaling, and this information is useful for the development of immune enhancing adjuvant materials using a natural ingredient.

Application of Very Short-Term Rainfall Forecasting to Urban Water Simulation using TREC Method (TREC기법을 이용한 초단기 레이더 강우예측의 도시유출 모의 적용)

  • Kim, Jong Pil;Yoon, Sun Kwon;Kim, Gwangseob;Moon, Young Il
    • Journal of Korea Water Resources Association
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    • v.48 no.5
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    • pp.409-423
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    • 2015
  • In this study the very short-term rainfall forecasting and storm water forecasting using the weather radar data were implemented in an urban stream basin. As forecasting time increasing, the very short-term rainfall forecasting results show that the correlation coefficient was decreased and the root mean square error was increased and then the forecasting model accuracy was decreased. However, as a result of the correlation coefficient up to 60-minute forecasting time is maintained 0.5 or higher was obtained. As a result of storm water forecasting in an urban area, the reduction in peak flow and outflow volume with increasing forecasting time occurs, the peak time was analyzed that relatively matched. In the application of storm water forecasting by radar rainfall forecast, the errors has occurred that we determined some of the external factors. In the future, we believed to be necessary to perform that the continuous algorithm improvement such as simulation of rapid generation and disappearance phenomenon by precipitation echo, the improvement of extreme rainfall forecasting in urban areas, and the rainfall-runoff model parameter optimizations. The results of this study, not only urban stream basin, but also we obtained the observed data, and expand the real-time flood alarm system over the ungaged basins. In addition, it is possible to take advantage of development of as multi-sensor based very short-term rainfall forecasting technology.

Rapid Analysis of Boric Acid in Nickel Plating Solutions (니켈도금액중의 붕산 신속정량법)

  • 염희택
    • Journal of the Korean institute of surface engineering
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    • v.3 no.1
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    • pp.7-12
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    • 1970
  • Only mannitol or glycerine is generally used for the determination of boric acid in a nickel plating solution in order to make its acidic property so strong that it can be titrated with NaOH. However, these solutions give very amgiguous color change of indicator due to the precipitation of nickel salts . Therefore, only experienced dchemistsorwell trained workimen can accurately confirm the actual end point of the titratiion. For eliminating such interference of nickel salts and easily confirming the end point by any persons , the author attempted to find out a solution which produces no precipitates during the titration in these experiments, and also he tried to funish the reason for ambiguousness in titration. The following results were obtained after many experiments. (1) In any titrations which produce nickel salts such nI(oh)$_2$, the salt is formed umption very approximate to the end point, which shows some error by the consumption of titrant(NaOH) . Then, the pink color of phenolphthalein is absorbed by Ni(OH)$_2$ and the pH jumping at the end pint is also diminished to as little as less than 15% of the total phenophthalein ph range. (2) Known methods by complex salts of citrate,w hich do not produce precipitates of Ni(OH)$_2$, are also not very satisfactory, because, the pH jumping at the end point is only about 35% and the color change of phenolphthalein is form blue-green to purple-blue. (3) New method by complex salts of oxalate were attempted in these experiments. They also did not produce precipitates of Ni(OH)$_2$ and were very satisfactory in color change at the end of point was about 65% and the color change was from blue-green to purpled. In this methods, analytica cost was minimized by the use of less amounts of cheaper chemicals than the conventional citrates complex methods. The mixture of chemicals used was composed methods. The mixture of chemical used was composed of 37g/ι of sodium oxalate(Na$_2$C$_2$O$_4$$.$5H$_2$O), 2g/ι of phenolphthalein, and 400ml /ι of glycerin. The accuracy of analysis was within the error of 0.5%. (4) The procedure of analysis was as follows. One ml of nickel plating solution was taken out and to it were added 20ml of water and 20 ml of the above mixture for the indicator. The solution was titrated with 0.1N NaOH. The quantity of boric acid was calculated by the following equation. Boric acid (g/ι) = 6.184${\times}$F${\times}$ml .

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A study on the variation of design flood due to climate change in the ungauged urban catchment (기후변화에 따른 미계측 도시유역의 확률홍수량 변화에 관한 연구)

  • Hwang, Jeongyoon;Ahn, Jeonghwan;Jeong, Changsam;Heo, Jun-Haeng
    • Journal of Korea Water Resources Association
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    • v.51 no.5
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    • pp.395-404
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    • 2018
  • This research evaluated the change in rainfall quantile during S1, S2, and S3 by using Representative Concentration Pathways (RCP) 4.5 climate scenario HadGEM3-RA Regional Climate Model (RCM) produced by downscaling and bias correlation compared to the past standard observation data S0. Also, the maximum flood peak volume and flood area were calculated by using the urban runoff model and the impact of climate change was analyzed in each period. For this purpose, Gumbel distribution was used as an appropriate model based on the method of maximum likelihood. As a result, in the case of the 10 year-frequency which is the design of most urban drainage facilities, the rainfall quantile is in increased about 10% if we assume 50 years from now with the $3^{rd}$ quarter value and about 20% if we assume 70 years from now. This result implies that the installed urban drainage facility based on the currently set design flood volume cannot be met the design criteria in the future. Therefore, it is necessary to reflect future climate conditions to current urban drainage facilities.

Developing Forest Fire Occurrence Probability Model Using Meteorological Characteristics (기상자료(氣象資料)를 이용(利用)한 산불발생확률모형(發生確率模型)의 개발(開發))

  • Choi, Kwan;Han, Sang Yoel
    • Journal of Korean Society of Forest Science
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    • v.85 no.1
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    • pp.15-23
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    • 1996
  • Preparing the era of forest resources management requires studies on forest fire. This study attempted to develop forest fire occurrence model using meteorological characteristics for the practical purposes of forecasting forest fire danger rate. To accomplish this goal, the relationships between forest fire occurrence and meteorological characteristics are estimated. In the process, the forest fire occurrence pattern of the study region(Taegu-Kyungpook) is categorized by employing qualification IV method. The study region was divided into three areas such as, Taegu, Andong and Pohang area. The meteorological variables emerged as affective to forest fire occurrence are relative humidity, longitude of sunshine, and duration of precipitation. To estimate the probability of forest fire danger, forest fire occurrence of three areas are regressed on the time series data of affective meteorological variables using logistic and probit model. The effectiveness of the models estimated are tested and showed acceptable degree of goodness. Those models developed would be helpful to increase the efficiency of forest fire management such as detection of forest fire occurrence and effective disposition of forest fire fight equipments.

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The Effect of Calcination Temperature on the Layered Li1.05Ni0.9Co0.05Ti0.05O2 for Lithium-ion Battery (리튬이온전지용 층상 Li1.05Ni0.9Co0.05Ti0.05O2에 대한 소성 온도의 영향)

  • Ko, Hyoung Shin;Park, Hyun Woo;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.718-724
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    • 2018
  • In this study, the $Ni_{0.9}Co_{0.05}Ti_{0.05}(OH)_2$ precursor was prepared by the concentration gradient co-precipitation method. In order to overcome the structural change due to oxygen desorption in the cathode active material with high nickel content, the physical and electrochemical analysis of the cathode active material according to the calcination temperature were investigated. Physical properties of $Li_{1.05}Ni_{0.9}Co_{0.05}Ti_{0.05}O_2$ were analyzed by FE-SEM, XRD and TGA. The electrochemical performance of the coin cell using a cathode active material and $LiPF_6$(EC:EMC=1:2 vol%) electrolyte was evaluated by the initial charge/discharge efficiency, cycle retention, and rate capabilities. As a result, the initial capacity and initial efficiency of cathode materials were excellent with 244.5~247.9 mAh/g and 84.2~85.8% at the calcination temperature range of $750{\sim}760^{\circ}C$. Also, the capacity retention exhibited high stability of 97.8~99.1% after 50cycles.

Synthesis and Application of cPSMA-PSMA Microcapsule Absorbent for Cement Mortars (시멘트 모르타르용 cPSMA-PSMA 마이크로캡슐 흡수제 제조 및 적용)

  • Hwang, Ki-Seob;Jang, Seok-Soo;Jung, Yong-Wook;Lee, Seung-Han;Ha, Ki-Ryong
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.216-222
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    • 2012
  • We synthesized microcapsule absorbent with crosslinked poly(styrene-$alt$-maleic anhydride) (PSMA) as a core and PSMA as a shell by a precipitation polymerization method for the delayed absorption of excess water in cement mortar. cPSMA-PSMAs with core-shell structure were synthesized with ratios of 1/1, 1/2 and 1/3 as core monomer mass to shell monomer mass to control shell thickness. We observed the hydrolysis of PSMA in cement-saturated aqueous solution by a FTIR spectrometer. We observed good core-shell structure microcapsules for 1/2(cPSMA #3), but observed incomplete core-shell structure for 1/1(cPSMA #2) and 1/3(cPSMA #4) of core/shell monomer ratios. The swelling ratio of cPSMA #3 in cement-saturated aqueous solution was increased until 20 min. After that it was decreased until 2 hrs swelling time, and they started to increase again. The viscosities of cement paste with cPSMA #3 microcapsules were very slowly increased until 1 hr and increased fast after 1.5 hrs. Cement mortar with 0.5 wt% cPSMA #1 having only core part showed about 5% increase in compressive strength compared to that of plain cement mortar. cPSMA #3 added cement mortar showed the highest compressive strength with 7% increase.

Fabrication and Characterization of UV-curable Conductive Transparent Film with Polyaniline Nanofibers (폴리아닐린 나노섬유를 이용한 광경화형 전도성 투명필름의 제조 및 특성)

  • Kim, Sung-Hyun;Song, Ki-Gook
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.531-535
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    • 2012
  • Conductive polyaniline (PANI) nanofibers in UV-curable resin were used for a transparent conductive film. The emeraldine-salt PANI (ES-PANI) nanofibers were prepared by chemical oxidation polymerization of aniline, which could be changed into emeraldine-base PANI by dedoping. EB-PANI nanofibers as a precursor for conductive fillers were thereby transformed into re-dpoed PANI (rES-PANI) by dodecylbenzenesulfonic acid in the UV-curable resin solution. rES-PANI nanofibers have high conductivity and long-term stability in the solution without a defect of nanostructure. The resulting conductive resin solution was proved to be highly stable where no precipitation of rES-PANI fillers was observed over a period of 3 months. The transparent film was spin-casted on a poly(methyl methacrylate) sheet of thickness ca. $5{\mu}m$. A surface resistance of $6.5{\times}10^8{\Omega}/sq$ and transmittance at 550 nm of 91.1% were obtained for the film prepared with a concentration of 1.4 wt% rES-PANI nanofibers in the solution. This transformation process of rES-PANI from ES-PANI by dedoping-redoping can be an alternative method for the preparation of an antistatic protection film with controllable surface resistance and optical transparencies with the PANI concentration in UV-curable solution.

Evapotranspiration Measurements using an Eddy Covariance Technique in a Mixed Forest and a rice paddy in Korea (에디 공분산으로 관측된 혼효림과 논에서의 증발산)

  • Kwon, Hyou-Jung;Kang, Min-Seok;Kim, Joon;Lee, Jung-Hoon;Jung, Sung-Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2010.05a
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    • pp.565-570
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    • 2010
  • Evapotranspriation (ET) was measured by eddy covariance method in two key ecosystems in Korea: the Seolmacheon site (a mixed forest in a complex terrain, SMK) and the Cheongmicheon site (a homogeneous rice paddy, CRK). By using the multi-year observations (SMK: Sep. 2007 - Dec. 2009, CRK: Aug. 2008 - Dec. 2009), we quantified ET and analyzed its temporal variations and control mechanisms based on the radiatively coupled combination equation. During the study period, the accumulated precipitation was about 3213 mm for the SMK site, of which about 30% (i.e., 990 mm), returned to the atmosphere as ET. At the CRK site from Jan. - Dec., 2009, the annual ET was 553 mm, which was about 40% of the annual rainfall (of 1401 mm). Both sites showed a characteristic seasonality with mid-season depression in ET that are associated with the reduced amount of available energy during the monsoon season. The decoupling parameter (${\Omega}^*$), which indicates the measure of interaction between vegetation and the atmosphere, averaged about 0.4 for the SMK site and the CRK site during the growing season. The ET from both sites was more influenced by air saturation deficit and surface conductance than available energy.

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Development and assessment of framework for selecting multi-GCMs considering Asia monsoon characteristics (아시아 몬순특성을 고려한 다중 GCMs 선정방법 개발 및 평가)

  • Kim, Jeong-Bae;Kim, Jin-Hoon;Bae, Deg-Hyo
    • Journal of Korea Water Resources Association
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    • v.53 no.9
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    • pp.647-660
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    • 2020
  • The objectives of this study are to develop a framework for selecting multi-GCMs considering Asia monsoon characteristics and assess it's applicability. 12 climate variables related to monsoon climates are selected for GCM selection. The framework for selecting multi-GCMs includes the evaluation matrix of GCM performance based on their capability to simulate historical climate features. The climatological patterns of 12 variables derived from individual GCM over the summer monsoon season during the past period (1976-2005) and they are compared against observations to evaluate GCM performance. For objective evaluation, a rigorous scoring rule is implemented by comparing the GCM performance based on the results of statistics between historical simulation derived from individual GCM and observations. Finally, appropriate 5 GCMs (NorESM1-M, bcc-csm1-m, CNRM-CM5, CMCC-CMS, and CanESM2) are selected in consideration of the ranking of GCM and precipitation performance of each GCM. The selected 5 GCMs are compared with the historical observations in terms of monsoon season and monthly mean to validate their applicability. The 5 GCMs well capture the observational climate characteristics of Asia for the 12 climate variables also they reduce the bias between the entire GCM simulations and the observational data. This study demonstrates that it is necessary to consider various climate variables for GCM selection and, the method introduced in this study can be used to select more reliable climate change scenarios for climate change assessment in the Asia region.