• Title/Summary/Keyword: Precipitation Experiment

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[Retraction]Size measurement and characterization of ceria nanoparticles using asymmetrical flow field-flow fractionation (AsFlFFF)

  • Kim, Kihyun;Choi, Seong-Ho;Lee, Seungho;Kim, Woonjung
    • Analytical Science and Technology
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    • v.32 no.5
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    • pp.173-184
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    • 2019
  • As the size of semiconductors becomes smaller, it is necessary to perform high precision polishing of nanoscale. Ceria, which is generally used as an abrasive, is widely used because of its uniform quality, but its stability is not high because it has a high molecular weight and causes agglomeration and rapid precipitation. Such agglomeration and precipitation causes scratches in the polishing process. Therefore, it is important to accurately analyze the size distribution of ceria particles. In this study, a study was conducted to select dispersants useful for preventing coagulation and sedimentation of ceria. First, a dispersant was synthesized and a ceria slurry was prepared. The defoamer selection experiment was performed in order to remove the air bubbles which may occur in the production of ceria slurry. Dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) were used to determine the size distribution of ceria particles in the slurry. AsFlFFF is a technique for separating nanoparticles based on sequential elution of samples as in chromatography, and is a useful technique for determining the particle size distribution of nanoparticle samples. AsFlFFF was able to confirm the presence of a little quantities of large particles in the vicinity of 300 nm, which DLS can not detect, besides the main distribution in the range of 60-80 nm. AsFlFFF showed better accuracy and precision than DLS for particle size analysis of a little quantities of large particles such as ceria slurry treated in this study.

Isolation of Microorganisms for Optimization of Autonomous Crack Healing and Verification of Crack Healing (자발적 균열치유작용 최적화를 위한 미생물군 분리 및 균열치유작용 검증)

  • Byung-Jae Lee;Yeon-Jun Yu;Hyo-Sub Lee;Joo-Kyoung Yang;Yun Lee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.1
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    • pp.103-108
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    • 2023
  • In this study, basic research was conducted to secure microbial resources applicable to autonomous crack healing concrete. To this end, in this experiment, biomineral-forming microorganisms were separated from natural sources, and the ability of survival in cement and calcium carbonate precipitation were compared to secure suitable microbial resources. Bacillus-type bacteria forming endospores were isolated from the sample, and the amount of calcium carbonate produced by the six microorganisms identified by 16S rRNA sequencing was compared. Two types of microorganisms, Bacillus velezensis and Bacillus subtilis, with the highest calcium carbonate precipitation were selected, and the survival of the microorganisms was confirmed through phase contrast microscopy after being cured after being added to the mortar. In addition, it was confirmed that the autonomous crack healing capability by the crack healing material produced by microorganisms was confirmed by artificially generating cracks in the mortar.

Fatigue Characteristics and FEM Analysis of $18\%$Ni(200) Maraging Steel (18Ni 마르에이징강의 피로특성 및 유한요소해석)

  • Choi Byung Ki;Jang Kyeung Cheun
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.2
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    • pp.75-82
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    • 2005
  • Recently the needs of high reliable substances of high strength and high ductility are gradually increased with the development of aerospace industry. The characteristics of maraging steel has high ductililty, formability, corrosion resistant and high temperature strength and is easy to fabricate, weld and treat with heat, and maintain an invariable size even after heat treatment. e steels are furnished in the solution annealed condition and they achieve full properties through martensitic precipitation aging a relatively simple, low temperature heat treatment. As is true of the heat treating procedures, aging is a time/temperature dependent reaction. Therefore, the objective of this stud)'was consideration of fatigue characteristics according as Nb(niobium) content and time/temperature of heat treatment change. Also the stress analysis, fatigue lift, and stress intensity factor were compared with experiment results and FEA(finite element analysis) result. The maximum ftresses of)( Y, and Z axis direction showed about $2.12\times$10$^{2}$MPa, $4.40\times$10$^{2}$MPa and $1.32\times$10$^{2}$MPa respectively. The fatigue lives showed about $7\%$ lower FEA result than experiment result showing almost invariable error every analyzed cycle. Stress intensity factor of the FEA result was lower about $3.5~ 10\%$ than that of the experiment result showing that the longer fatigue crack ten添 the hi인or error. It considered that the cause for the difference was the modeled crack tip having always the same shape and condition regardless of the crack growth.

A Study on the Treatment of the Acid Mine Drainage using the Steel Mill Slag (제강 슬래그를 애용한 산성광산배수(AMD)의 처리에 관한 연구)

  • 권순동;김선준
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.4
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    • pp.206-212
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    • 1999
  • In order to evaluate the applicability of steel mill slag as a AMD (Acid Mine Drainage) neutralizer and to compare capacity of slag with that of limestone lab scale experiments were conducted. The fixed treatment experiments of AMD with slag and limestone separately for 24 hours under the stagnant condition showed that slag has higher capacity of pH increase and removal of Fe. Al and other trace elements. During the 10 days continuous step experiment the pH has been maintained and any decrease in the removal capacity of Fe and Al has not bun observed. In the trace element removal experiment slag showed higher capacity for removal of Ni, Co. Cu and Zn than limestone. The removal of trace element was more effective in AMD than in distilled water that the pH was adjusted to the same level of AMD (synthetic acid solution). It means that Fe and Al in AMD adsorbed trace elements during or after precipitation as oxide forms. In the size effect experiment, the slag of the smaller size with larger specific surface area exhibited higher capacity of pH increase and removal efficiencies of Fe. Al and other trace elements.

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Effects of infectious bursal disease virus(IBDV) and newcastle disease virus(NDV) vaccines on performance of broiler chicks

  • Kwon, Jung-taek;Kim, Tae-joong;Ryu, Kyeong-seon;Song, Hee-jong
    • Korean Journal of Veterinary Research
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    • v.39 no.4
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    • pp.738-742
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    • 1999
  • The objective of this experiment was to investigate the effect of Newcastle disease virus (NDV) and infectious bursal disease virus (IBDV) vaccination on performance of broiler chicks for five weeks. Two types of poultry houses and three patterns of vaccination ($NDV^-/IBDV^-$, $NDV^+/IBDV^-$ and $NDV^+/IBDV^+$) were factorially assigned to six treatments. NDV, B1 strain and IBDV, Bursin-2 vaccine were orally administered at 5, 14 and 7, 18 days, respectively. Forty eight hundred chicks were grouped into four replications with two hundnyd hybro $\times$ hybro chicks per each treatment. Weight gain, feed conversion ratio (FCR), mortality and product index were surveyed at the end of experiment. Bursa index and IBDV antibody titer of chicks were weekly measured. Weight gain of chicks vaccinated with $NDV^+/IBDV^+$ was significantly increased compared to that of other treatments at both window and windowless poultry houses (p<0.05). Chicks vaccinated with $NDV^+/IBDV^+$ also showed significantly improving the FCR and mortality compared to those of other treatments at both poultry houses (p<0.05). The bursa indecies of both poultry houses were high from one-day- to three-weeks-old, but were low for the rest of two weeks. IBDV antibody of all chicks was detected 100% by agar gel precipitation (AGP) test at one day old, but was not detected in $NDV^-/IBDV^-$ and $NDV^+/IBDV^-$ treatments at four weeks old. However, it showed 100% in $NDV^+/IBDV^+$ treatment. Antibody titer using ELISA showed similar trend to that of AGP test. The results of this experiment confirmed that IBDV and NDV combined vaccine significantly improved the performance of broiler chicks.

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Determination of Sowing Date for Silage Corn Based on Growing Degree Days and Soil Temperature (유효적산온도에 의한 싸이리지옥수수의 파종기결정)

  • Choe, Zhin-Ryong;Joo, Young-Kuk;Song, Moon-Tae;Oh, Ho-Sang;Ann, Dong-Won
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.35 no.3
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    • pp.254-258
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    • 1990
  • In order to investigate the effect of sowing dates on some agronomical characters and yield of corn in southern part of Korea. a field experiment was carried out at Gyeongnam Provincial Livestock Breeding Station in chinju. Single cross hybrid corn (cv. Suwon #19) was sown from April 13 to June 2 with five-day interval in 1984 and 1984. The relationship between herbage and grain yield and various meterological measurements was evaluated. As the sowing dates were delayed. the days from sowing to seedling emergence were shortened, as more closely affected by the soil temperature at seedling emergence. growth period and was dependent on precipitation and temperature during the growth period. Based on the relationship between herbege dry matter yield of corn and soil temperature at seedling emergence, the estimated critical sowing date for corn in the southern Korea was March 23${\pm}$3.6 days.

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Remediation Process by using Lime and Calcium Carbonate for Heavy Metal Contaminated Groundwater Originated from Landfills (소석회$(Ca(OH)_2)$와 탄산칼슘$(CaCO_3)$을 이용한 매립장 주변 중금속 오염 지하수 정화)

  • Song Nain;Lee Yesun;Lee Minhee
    • Economic and Environmental Geology
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    • v.38 no.3 s.172
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    • pp.273-284
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    • 2005
  • Coagulation and precipitation process by using lime$(Ca(OH)_2)$ and calcium carbonate $(CaCO_3)$ were applied to remove heavy metals from groundwater in laboratory scale. From results of batch tests, by the addition of $0.3\;wt.\%$ lime, more than $90\%$ of As and Mn were removed and $70-80\%$ of Cd and Zn were removed by using $0.5\;wt.\%$ of lime. Removal efficiency of Pb almost reached $100\%$ with only $0.1\;wt.\%$ of calcium carbonate and more than $93\%$ of Cd were removed by the addition of $0.1\;wt.\%$of calcium carbonate. Pilot scale column experiments were performed to remove heavy metals in the separation process of precipitated Hoc to supernatant after the coagulation/ precipitation. For lime as a coagulant, more than $99\%$of As were removed from artificial groundwater and removal efficiencies of Cd, Mn, and Zn were over $80\%$. By using calcium carbonate, more than $95\%$ of Cd and Pb were removed in column experiment. Fe and Mn contaminated groundwater taken from a real landfill site, Ulsan was used for the column experiment and more than $99\%$ of Fe and Mn were removed by the addition of $1\;wt.\%$ lime in column experiment, suggesting that the coagulation/precipitation process by using lime and calcium carbonate have a great possibility to remove heavy metals from contaminated groundwater.

Agroclimatology of North Korea for Paddy Rice Cultivation: Preliminary Results from a Simulation Experiment (생육모의에 의한 북한지방 시ㆍ군별 벼 재배기후 예비분석)

  • Yun Jin-Il;Lee Kwang-Hoe
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.2 no.2
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    • pp.47-61
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    • 2000
  • Agroclimatic zoning was done for paddy rice culture in North Korea based on a simulation experiment. Daily weather data for the experiment were generated by 3 steps consisting of spatial interpolation based on topoclimatological relationships, zonal summarization of grid cell values, and conversion of monthly climate data to daily weather data. Regression models for monthly climatological temperature estimation were derived from a statistical procedure using monthly averages of 51 standard weather stations in South and North Korea (1981-1994) and their spatial variables such as latitude, altitude, distance from the coast, sloping angle, and aspect-dependent field of view (openness). Selected models (0.4 to 1.6$^{\circ}C$ RMSE) were applied to the generation of monthly temperature surface over the entire North Korean territory on 1 km$\times$l km grid spacing. Monthly precipitation data were prepared by a procedure described in Yun (2000). Solar radiation data for 27 North Korean stations were reproduced by applying a relationship found in South Korea ([Solar Radiation, MJ m$^{-2}$ day$^{-1}$ ] =0.344 + 0.4756 [Extraterrestrial Solar Irradiance) + 0.0299 [Openness toward south, 0 - 255) - 1.307 [Cloud amount, 0 - 10) - 0.01 [Relative humidity, %), $r^2$=0.92, RMSE = 0.95 ). Monthly solar irradiance data of 27 points calculated from the reproduced data set were converted to 1 km$\times$1 km grid data by inverse distance weighted interpolation. The grid cell values of monthly temperature, solar radiation, and precipitation were summed up to represent corresponding county, which will serve as a land unit for the growth simulation. Finally, we randomly generated daily maximum and minimum temperature, solar irradiance and precipitation data for 30 years from the monthly climatic data for each county based on a statistical method suggested by Pickering et a1. (1994). CERES-rice, a rice growth simulation model, was tuned to accommodate agronomic characteristics of major North Korean cultivars based on observed phenological and yield data at two sites in South Korea during 1995~1998. Daily weather data were fed into the model to simulate the crop status at 183 counties in North Korea for 30 years. Results were analyzed with respect to spatial and temporal variation in yield and maturity, and used to score the suitability of the county for paddy rice culture.

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Geostatistical Downscaling of Coarse Scale Remote Sensing Data and Integration with Precise Observation Data for Generation of Fine Scale Thematic Information (고해상도 주제 정보 생성을 위한 저해상도 원격탐사 자료의 지구통계학기반 상세화 및 정밀 관측 자료와의 통합)

  • Park, No-Wook
    • Korean Journal of Remote Sensing
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    • v.29 no.1
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    • pp.69-79
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    • 2013
  • This paper presents a two-stage geostatistical integration approach that aims at downscaling of coarse scale remote sensing data. First, downscaling of the coarse scale sedoncary data is implemented using area-to-point kriging, and this result will be used as trend components on the next integration stage. Then simple kriging with local varying means that integrates sparse precise observation data with the downscaled data is applied to generate thematic information at a finer scale. The presented approach can not only account for the statistical relationships between precise observation and secondary data acquired at the different scales, but also to calibrate the errors in the secondary data through the integration with precise observation data. An experiment for precipitation mapping with weather station data and TRMM (Tropical Rainfall Measuring Mission) data acquired at a coarse scale is carried out to illustrate the applicability of the presented approach. From the experiment, the geostatistical downscaling approach applied in this paper could generate detailed thematic information at various finer target scales that reproduced the original TRMM precipitation values when upscaled. And the integration of the downscaled secondary information with precise observation data showed better prediction capability than that of a conventional univariate kriging algorithm. Thus, it is expected that the presented approach would be effectively used for downscaling of coarse scale data with various data acquired at different scales.

Biogeochemical Effects of Hydrogen Gas on the Behaviors of Adsorption and Precipitation of Groundwater-Dissolved Uranium (지하수 용존 우라늄의 수착 및 침전 거동에서 수소 가스의 생지화학적 영향)

  • Lee, Seung Yeop;Lee, Jae Kwang;Seo, Hyo-Jin;Baik, Min Hoon
    • Economic and Environmental Geology
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    • v.51 no.2
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    • pp.77-85
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    • 2018
  • There would be a possibility of uranium contamination around the nuclear power plants and the underground waste disposal sites, where the uranium could further migrate and diffuse to some distant places by groundwater. It is necessary to understand the biogeochemical behaviors of uranium in underground environments to effectively control the migration and diffusion of uranium. In general, various kinds of microbes are living in soils and geological media where the activity of microbes may be closely connected with the redox reaction of nuclides resulting in the changes of their solubility. We investigated the adsorption and precipitation behaviors of dissolved uranium on some solid materials using hydrogen gas as an electron donor instead of organic matters. Although the effect of hydrogen gas did not appear in a batch experiment that used granite as a solid material, there occurred a reduction of uranium concentration by 5~8% due to hydrogen in an experiment using bentonite. This result indicates that some indigenous bacteria in the bentonite that have utilized hydrogen as the electron donor affected the behavior (reduction) of uranium. In addition, the bentonite bacteria have showed their strong tolerance against a given high temperature and radioactivity of a specific waste environment, suggesting that the nuclear-biogeochemical reaction may be one of main mechanisms if the natural bentonite is used as a buffer material for the disposal site in the future.