• Title/Summary/Keyword: Precious Metals

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Catalytic Hydrolysis of Sodium Borohydride on LiCoO3 - Supported Pt, Ru Catalysts (LiCoO3에 담지된 Pt, Ru 촉매에 의한 NaBH4 가수분해반응)

  • Ahn, Jong-Gwan;Choi, Seung-Hoon;Lee, Su-Chol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.7
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    • pp.3261-3266
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    • 2012
  • Sodium borohydride($NaBH_4$) known as the material of hydrogen generation and storage can produce the hydrogen via catalytic hydrolysis. This protide chemical could be used in the hydrogen supply system for residential and mobile fuel cells, and thus many researches and developments regarding to these chemicals and decomposition reactions have been implemented. We experimented the hydrolysis of $NaBH_4$ alkaline solution by metal oxide-supported PGM(platinum group metal) catalysts and measured the generation rate of hydrogen which is product of decomposition reaction. We compared oxides as catalyst supports, and the precious metals, Pt and Ru for the catalysts and studied the effects of amounts of catalyst added and $NaBH_4$ concentrations on the hydrogen generation rates and patterns.

Application of Multivariate Statistics and Geostatistical Techniques to Identify the Distribution Modes of the Co, Ni, As and Au-Ag ore in the Bou Azzer-East Deposits (Central Anti-Atlas Morocco)

  • Souiri, Muhammad;Aissa, Mohamed;Gois, Joaquim;Oulgour, Rachid;Mezougane, Hafid;El Azmi, Mohammed;Moussaid, Azizi
    • Economic and Environmental Geology
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    • v.53 no.4
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    • pp.363-381
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    • 2020
  • The polymetallic Co, Ni, Cu, As, Au, and Ag deposits of Bou Azzer East are located in the western part of the Bou Azzer inlier in the Central Anti Atlas, Morocco. Six stages of emplacement of the mineralization have been identified. Precious metals (native gold and electrum) are present in all stages of this deposit except the early nickeliferous stage. From the Statistical analysis of the Co, As, Ni, Au, and Ag contents of a set of 501 samples, shows that the Pearson correlation coefficient between As-Co elements (0.966) is the highest followed by that of the Au-Ag couple (0.506). Principal component analysis (PCA) and hierarchical ascending classification (HAC) of the grades show, that Ni is associated with the pair (As-Co) and Cu is rather related to the pair (Au-Ag). The kriging maps show that the highest values of the Co, As and Ni appear in the contact of the serpentinite with other facies, as for those of Au and Ag, in addition to anomalous zones concordant with those of Co, Ni and As, they show anomalies at the extreme South and North of the study area. The development of the anomalous Au and Ag zones is mainly along the N40-50°E and N145°E directions.

Development of Mobile Camera Vision System and Build of Wire.Wireless Integration ERP System (모바일 카메라 비전 시스템 개발과 유.무선 통합 ERP 시스템 구축)

  • Lee, Hyae-Jung;Shin, Hyun-Cheol;Joung, Suck-Tae
    • Convergence Security Journal
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    • v.7 no.2
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    • pp.81-89
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    • 2007
  • Mobile computing environment that support so that can offer employees inside information that enterprise has always improves business productivity and fetches efficiency enlargement. In this paper, limit model that can process ERP information by real-time as easy and convenient always utilizing radio network and PDA, Mobile camera based on Mobile vision concept. Calculable information between seller and customer is supplied supplying real-time brand image and information by practical use of Enterprise Resource Planning doing based on Mobile. Technical development and commercialization that utilize mobility, enforcement stronghold, portability etc. that is advantage of Mobile communication are required. In this paper, mobility of precious metals.jewel field that use portable terminal equipment taking advantage of a Mobile technology is secured. Constructed Mobile vision system that satisfy photography and bar-code scan at the same time from Mobile camera.

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Design research of ornaments applying the formability of gem cuts -Focusing on line formability- (보석 커팅의 조형성을 응용한 장신구 디자인 연구 -선 조형성을 중심으로-)

  • Park, Jeong-cheol
    • Journal of Digital Convergence
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    • v.19 no.3
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    • pp.303-311
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    • 2021
  • The accessories growth according to the changes in each era and of course, jewelry processing technology has also improved, but in modern times, the frequency of use of jewelry has decreased, and it has been neglected compared to crafting and metal-related technologies. The beauty of crafted jewelry still remains, there are many problems to cover many age groups due to valuable and design problems. Accordingly, this researcher intends to conduct research to inform the formative beauty and value of processed jewelry. Jewelry designby mainly applying lines during the shaping of the jewelry cutting surface. Prior to the design, a theoretical approach to the design case and jewelry processing literature, and based on this, jewelry design applied in the form of jewelry cutting. This study is expected to promote the vitalization of jewelry research, which is currently marginalized in the field of precious metals, and to develop a number of designs using jewelry.

Enhancement of oxygen evolution reaction of NiCo LDH nanocrystals using Mo doping (Mo 도핑을 이용한 NiCo LDH 나노결정의 산소발생반응 향상)

  • Kyoungwon Cho;Jeong Ho Ryu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.34 no.3
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    • pp.92-97
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    • 2024
  • To improve the efficiency of water splitting systems for hydrogen production, the high overvoltages of electrochemical reactions caused by catalysts in the oxygen evolution reaction (OER, Oxygen Evolution Reaction) must be reduced. Among them, LDH (Layered Double Hydroxide) compounds containing transition metal such as Ni, are attracting attention as catalyst materials that can replace precious metals such as platinum that are currently used. In this study, nickel foam, an inexpensive metallic porous material, was used as a support, and NiCo LDH (Layered Double Hydroxide) nanocrystals were synthesized through a hydrothermal synthesis process. In addition, changes in the shape, crystal structure, and water decomposition characteristics of the Mo-doped NiCo LDH nanocrystal samples synthesized by doping Mo to improve OER properties were observed.

Effect of Metal Ions on Iron Oxidation Rate of Thiobacillus ferrooxidans Used in a Bioleaching Process (Bioleaching에 사용되는 Thiobacillus ferrooxidans의 철산화 속도에 미치는 금속 이온의 영향)

  • 최문성;조경숙
    • KSBB Journal
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    • v.16 no.1
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    • pp.54-60
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    • 2001
  • The activity of microorganisms is an important factor that determines the efficiency of the bacterial recovery of precious metals from low-grade ore. Metal-leaching microorganisms must have a tolerance, within the concentration levels encountered to leached metals. In this study, the tolerance levels of Thiobacillus ferroxidans to the single and mixed metal ions systems, composed of $Zn^{2+}$, $Cu^{2+}$, $Ni^{2+}$, and $Cd^{2+}$ were investigated. When single metal ions of $Zn^{2+}$ (10~60 g/L), $Cu^{2+}$ (1~6 g/L), $Ni^{2+}$ (1~6 g/L), or $Cd^{2+}$ (1~6 g/L) were added to the growth medium of T. ferrooxidans, the iron oxidation rate of this bacterium was not significantly inhibited. The maximum inhibition percentage observed on the iron oxidation rate of T. ferrooxidans was approximately 50% in the medium supplemented with two or three mixed metal ions of $Cu^{2+}$, $Ni^{2+}$, and $Cd^{2+}$. However, when $Zn^{2+}$ was also added to the medium with the other metal ions, the inhibitory effect on the iron oxidation activity of T. ferroxidans was remarkably increased.

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Clinical remarks about esthetics in the case of full zirconia restoration utilizing Zirkonzahn Prettau® block (지르코잔 프레타우 블럭을 이용한 Full Zirconia 수복 시 심미에 관한 임상적 소견)

  • Park, Jong-Chan
    • Journal of the Korean Academy of Esthetic Dentistry
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    • v.22 no.1
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    • pp.30-46
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    • 2013
  • Porcelain fused to metal crown has been used mostly over the last 50 years for restorations in dentistry. However, the patients' awareness of aesthetic aspect, biocompatibility and the problems such as an allergy to metals led to the growing interest in the 'metal free restoration'. In particular, the price of the precious metals that have been mainly used to date has risen drastically, which made them impossible to play their role as oral restorative materials anymore, and in addition, the PFM restoration has intrinsic problems of chipping and fracture. Therefore, the CAD/CAM has been drawing more attention than ever due to the popular needs for the material that is more aesthetic and stronger for restoration of the molar implant. Considerations in carrying out the full zirconia restoration are as follows: 1) strength, 2) combination work, 3) light penetrability, 4) treatment of cracks, 5) the color reproducibility of the block, 6) the abrasivity of antagonistic tooth, 7) low temperature degradation. In this presentation, the color reproducibility of the block will be discussed. One of the biggest reasons for avoiding the full zirconia restoration is that it is difficult to reproduce the natural color compared to the conventional PFM restoration. Thus, many clinicians show reluctance due to the exposure of the ugly block when the coloring on the surface is removed after occlusal adjustment. From the experience of using blocks by Zirkonzahn for more than 4 years, it is considered that these problems can be addressed to some degrees. Accordingly, how to make restorations that are well in harmony with surrounding prosthesis or natural teeth will be discussed.

Determination on the component arrangement of a hybrid rain garden system for effective stormwater runoff treatment (강우유출수 처리를 위한 하이브리드 빗물정원 시스템의 구성요소 배열 연구)

  • Flores, Precious Eureka D.;Geronimo, Franz Kevin F.;Alihan, Jawara Christian P.;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.19 no.3
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    • pp.271-278
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    • 2017
  • Low impact development (LID) technology has been recently applied for the treatment of nonpoint source pollutants. Rain garden is one of the widely used LIDs since it utilizes various mechanisms such as biological and physico-chemical treatment to reduce pollutants. However, problem such as clogging has been one of the issues encountered by the rain garden that do not undergo constant maintenance. Therefore, this research was conducted to develop and determine the component arrangement of a rain garden system for a more efficient volume and pollutant reduction. Two hybrid rain garden systems having different characteristics were developed and evaluated to determine the optimum design and arrangement of the system. The results showed that the components arranged in a series manner showed a volume reduction of 93% and a pollutant reduction efficiency of approximately 99%, 93% and 95% was observed for particulates, nutrients and heavy metals, respectively. While when the system is connected in a combined series-parallel, the volume and average pollutant reduction efficiency for the TSS, nutrients and heavy metals are 65%, 94%, 80% and 85%, respectively. Moreover, the component arrangement in the order of sedimentation tank, infiltration tank and plant bed exhibited a high pollutant reduction efficiency compared when the infiltration tank and plant bed were interchanged. The findings of this research will help in the further development and optimization of rain garden systems.

Microbial Leaching of Iron from Magnetite (미생물을 이용한 자철석으로부터 철 침출에 관한 연구)

  • Roh, Yul;Oh, Jong-Min;Seo, Yong-Jae;Jang, Hee-Dong
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.265-275
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    • 2006
  • It is in its infancy to use bacteria as a novel biotechnology for leaching precious and heavy metals from raw materials. The objective of this study was to investigate biogeochemical processes of iron leaching from magnetite reduction by iron-reducing bacteria isolated from intertidal flat sediments, southwestern part of Korea. Microbial leaching experiments were performed using commercial magnetite, Aldrich magnetite, in well-defined mediums with and without bacteria. Water soluble Fe production was determined by ICP analysis of bioleached samples in comparison to uninoculated controls, and the resulting precipitated solids were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The extent of iron leaching from magnetite in the aerobic conditions (Fe = 107 ppm) was higher than that in the anaerobic environments (Fe = 94 ppm). In the anaerobic conditions, Fe(III) in commercial magnetite was also reduced to Fe(II), but no secondary mineral phases were observed. Amorphous iron oxides formed in the medium under aerobic conditions where there was sufficient supply of oxygen from the atmosphere. SEM observation suggests that the reduction process involves dissolution-precipitation mechanisms as opposed to solid state conversion of magnetite to amorphous iron oxides. The ability of bacteria to leach soluble iron and precipitate amorphous iron oxides from crystalline magnetite could have significant implications for biogeochemical processes in sediments where Fe(III) in magnetite plays an important role in the largest pool of electron acceptor as well as the tool as a novel biotechnology for leaching precious and heavy metals from raw materials.

Microbial Leaching of Iron from Shinyemi Magnetite Ore (미생물을 이용한 신예미 자철광으로부터 철 침출에 관한 연구)

  • Roh, Yul;Oh, Jong-Min;Suh, Yong-Jae;Jang, Hee-Dong
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.4
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    • pp.357-366
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    • 2007
  • Microorganisms participate in a variety of geochemical processes such as weathering and formation of minerals, leaching of precious metals from minerals, and cycling of organic matter The objective of this study was to investigate biogeochemical processes of iron leaching from magnetite ore by iron-reducing bacteria isolated from intertidal flat sediments, southwestern part of Korea. Microbial iron leaching experiments were performed using magnetite ore, Shinyemi magnetite ore, in well-defined media with and without bacteria at room temperature for a month. Water soluble Fe and Mn during the leaching experiments were determined by ICP analysis of bioleached samples, and the resulting precipitated solids were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The extent of iron leaching from magnetite in the aerobic conditions (Fe = 15 mg/L and Mn = 3.41 mg/L) was lower than that in the anaerobic environments (Fe = 32.8 mg/L and Mn = 5.23 mg/L). The medium pH typically decreased from 8.3 to 7.2 during a month incubation. The Eh of the initial medium decreased from +144.9 mV to -331.7 mV in aerobic environments and from -2.3 mV to -494.6 mV in anaerobic environments upon incubation with the metal reducing microorganisms. The decrease in pH is due to glucose fermentation producing organic acids and $CO_2$. The ability of bacteria to leach soluble iron from crystalline magnetite could have significant implications for biogeochemical processes in sediments where Fe(III) in magnetite represents the largest pool of electron acceptor as well as to use as a novel biotechnology for leaching precious and heavy metals from raw materials.