• Title/Summary/Keyword: Pre-polymer

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Coalescence behavior of dispersed domains in binary immiscible fluid mixtures having bimodal size distributions under steady shear flow

  • Takahashi Yoshiaki;Kato Tsuyoshi
    • Korea-Australia Rheology Journal
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    • v.17 no.3
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    • pp.125-130
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    • 2005
  • Coalescence process of binary immiscible fluid mixtures having bimodal size distributions, prepared by mixing two pre-sheared samples at different shear rates, ${\gamma}_{pre1}\;and\;{\gamma}_{pre2}$, under shear flow at a final shear rate, ${\gamma}_f$, are examined by transient shear stress measurements and microscopic observations in comparison with the results for simply pre-sheared samples having narrow size distributions (unimodal distribution samples). Component fluids are a silicone oil (PDMS) and a hydrocarbon-formaldehyde resin (Genelite) and their viscosities are 14.1 and 21.0 $pa{\cdot}sec$ at room temperature $(ca.\;20^{\circ}C)$, respectively. The weight ratio of PDMS: Genelite was 7:3. Three cases, $({\gamma}_{pre1}=7.2sec^{-1},\;{\gamma}_{pre2}=12.0sec^{-1}\;and\;{\gamma}_f=2.4sec^{-1}),\;({\gamma}_{pre1}=0.8sec^{-1},\;{\gamma}_{pre2}=4.0sec^{-1}\;and\;{\gamma}_f=2.4sec^{-1}),\;and\;({\gamma}_{pre1}=7.2sec^{-1},\;{\gamma}_{pre2}=12.0^sec^{-1}\;and\;{\gamma}_f=7.2sec^{-1})$ the first case, transient shear stress did not show any significant difference but domains larger than the initial state are observed at short times. In the latter cases, there exist undershoot of shear stress, reflecting existence of deformed large domains, which is confirmed by the direct observation. It is concluded that coalescence between large and small domains more frequently occur than coalescence between the domains with similar size in the bimodal distribution samples.

Development of the Strengthening Method of Telegraph Pole using Chemically Prestressed Fiber Reinforcement Polymer (화학적 프리스트레싱에 의한 노후화 전신주 FRP 보강기법 개발)

  • Han, Jae-Won;Hong, Ki-Nam;Han, Sang-Hoon;Woo, Sang-Kyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.501-502
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    • 2009
  • This paper presents a strengthening technique of weakened telegraph pole using an inflating agent to adjust chemical pre-stressing. The strengthening technique increases only resisting capacity and ductility of telegraph but also limited quantity and application ability of FRP. The chemical pre-stressing and the resisting capacity are investigated experimentally. From the results, it is confirmed that it is possible to control the degree of applied pre-stressing by controlling the amount of inflating agent. In addition, the pre-stressing can increase resisting capacity up to three times compared with no pre-stressing.

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Relationship between Compressive Strength of Geo-polymers and Pre-curing Conditions

  • Kim, Hyunjung;Kim, Yooteak
    • Applied Microscopy
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    • v.43 no.4
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    • pp.155-163
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    • 2013
  • Meta-kaolin (MK) and blast furnace slag (BS) were used as raw materials with NaOH and sodium silicate as alkali activators for making geo-polymers. The compressive strength with respect to the various pre-curing conditions was investigated. In order to improve the recycling rate of BS while still obtaining high compressive strength of the geo-polymers, it was necessary to provide additional CaO to the MK by adding BS. The specimens containing greater amounts of BS can be applied to fields that require high initial compressive strength. Alkali activator(s) are inevitably required to make geo-polymers useful. High temperature pre-curing plays an important role in improving compressive strength in geo-polymers at the early stage of curing. On the other hand, long-term curing produced little to no positive effects and may have even worsened the compressive strength of the geo-polymers because of micro-structural defects through volume expansion by high temperature pre-curing. Therefore, a pre-curing process at a medium range temperature of $50^{\circ}C$ is recommended because a continuous increase in compressive strength during the entire curing period as well as good compressive strength at the early stages can be obtained.

Phase Behaviors of Binary Protein Systems: Consideration of Structural Effects

  • Kim, Sang-Gon;Kong, Sung-Ho;Bae, Young-Chan;Kim, Sun-Joon
    • Macromolecular Research
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    • v.11 no.4
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    • pp.241-249
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    • 2003
  • A molecular-thermodynamic model to describe the salt-induced protein precipitation is developed based on the perturbation theory. We employed the modified perturbed hard-sphere-chain (PHSC) equation of state for copolymer mixtures to take into account the pre-aggregation effect among protein particles. Hypothetical pressure-composition diagrams are computed with various size differences and salt concentrations. The precipitation behaviors are also studied for various types of pre-aggregation effect for the given systems.

Control of Wettability Using Regularly Ordered Two-Dimensional Polymeric Wavy Substrates

  • Yi, Dong Kee
    • Nano
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    • v.13 no.10
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    • pp.1850120.1-1850120.9
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    • 2018
  • Two-dimensional poly(dimethylsiloxane) (PDMS) films with wavy patterns were studied in order to investigate reversible and irreversible wetting effects. Pre-strained, surface oxidized layers of PDMS were used to form relieved wavy geometries, on which hydrophobic functionalization was carried out in order to produce irreversible wetting effects. Wavy-patterned PDMS films showed time-dependent reversible wetting effects. The degree of surface wettability could be tuned by the choice of wavy groove geometries. And the groove geometries were controlled via $O_2$ plasma treatment and mechanical pre-straining. The pre-strained, buckled PDMS films were applied to the fabrication of hydrophobic polystyrene nano-patterns using colloidal self-assembly, where the colloids were arrayed in two-dimensional way. The wavy polystyrene films were found to be more hydrophobic relative to flat polystyrene films. The grooving methodology used in this study could be applied to enhancing the hydrophobicity of other types of polymeric thin films, eliminating the need for chemical treatment.

Flexural strengthening of RCC beams using FRPs and ferrocement - a comparative study

  • Ganesan, N.;Bindurania, P.;Indira, P.V.
    • Advances in concrete construction
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    • v.10 no.1
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    • pp.35-48
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    • 2020
  • This paper deals with a comparative study among three different rehabilitation techniques, namely, (i) carbon fibre reinforced polymer (CFRP), (ii) glass fibre reinforced polymer (GFRP) and (iii) ferrocement on the flexural strengthening of reinforced cement concrete (RCC) beams. As these different techniques have to be compared on a level playing field, tensile coupon tests have been carried out initially for GFRP, CFRP and ferrocement and the number of layers required in each of these composites in terms of the tensile strength. It was found that for the selected constituents of the composites, one layer of CFRP was equivalent to three layers of GFRP and five layers of wiremesh reinforcement in ferrocement. Rehabilitation of RCC beams using these equivalent laminates shows that all the three composites performed in a similar way and are comparable. The parameters selected in this study were (i) the strengthening material and (ii) the level of pre-distress induced to the beams prior to the rehabilitation. It was noticed that, as the levels of pre-distress decreases, the percentage attainment of flexural capacity and flexural stiffness of the rehabilitated beams increases for all the three selected composites used for rehabilitation. Load-deflection behavior, failure modes, energy absorption capacity, displacement ductility and curvature ductility were compared among these composites and at different distress levels for each composite. The results indicate that ferrocement showed a better performance in terms of ductility than other FRPs, and between the FRPs, GFRP exhibited a better ductility than the CFRP counterpart.

A Design and Control of Rapid Electric Vehicle Charging System for Lithium-Ion Battery (전기자동차용 리튬이온 배터리 급속충전장치 설계와 제어)

  • Kang, Taewon;Suh, Yongsug;Park, Hyeoncheol;Kang, Byungik;Kim, Simon
    • The Transactions of the Korean Institute of Power Electronics
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    • v.18 no.1
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    • pp.26-36
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    • 2013
  • This paper presents a simple and cost-effective stand-alone rapid battery charging system of 30kW for electric vehicles. The proposed system mainly consists of active front-end rectifier of neutral point clamped 3-level type and non-isolated bi-directional dc-dc converter of multi-phase interleaved half-bridge topology. The charging system is designed to operate for both lithium-polymer and lithium-ion batteries. The complete charging sequence is made up of three sub-interval operating modes; pre-charge mode, constant-current mode, and constant-voltage mode. The pre-charge mode employs the stair-case shaped current profile to accomplish shorter charging time while maintaining the reliable operation of the battery. The proposed system is specified to reach the full-charge state within less than 16min for the battery capacity of 8kWh by supplying the charging current of 78A. Owing to the simple and compact power conversion scheme, the proposed solution has superior module-friendly mechanical structure which is absolutely required to realize flexible power expansion capability in a very high-current rapid charging system.

A Study on Development of New Repair Method by High Pressure Spray (고압 스프레이 방식 신보수공법의 개발에 관한 연구)

  • Woo, Jong-Tae;Jang, Suk-Hwan;Kim, Yong-Chul
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.7 no.1
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    • pp.279-288
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    • 2003
  • This study is the development of method on repairing concrete structure for progressing the durability of reinforced concrete. This method is wet spray method which compress and conduct mortar pre-mixed with polymer powder to hose by high pressure pump and spray it on the section of concrete structure through nozzle made specially. Characters of this method are that materials are selected with the sort of structure and the cause of deterioration and macro pores are removed in repaired section by conducting with high pressure and spraying with high velocity for progressing the durability of concrete structure. This study has carried out that the minimum capacity of rebound was measured with various condition and physical properties of sample made by spray method were estimated in comparing with sample made by previous hand method. Also, properties of long-term have carried out after this method was applied on site. According to experimental study, the capacity of rebound showed below 5% and physical properties of sample made by spray method were superior to that of sample made by hand method and physical and durable properties of long-term showed excellence.