• 콘크리트학회지
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• 제9권3호
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• pp.149-156
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• 1997

시멘트 모르타르의 압축강도 향상을 휘하여 분말혼화제를 제조하였으며,분말혼화재 사용에 따르는 유동성 감소를 억제하고자 고유동화제를 사용하였다. 분말혼화재(FAS)는 불산부생 II형 무수석고와 플라이애쉬 및 실리카흄을 혼합제조하여 시멘트 대신 각각10,20 wt% 씩 치환하였다. 물/고형분비(W/S)=0.40에서 FAS 로 치환된 시멘트 페이스트의 유동성은 저하되었고, 유동성 저하의 억제를 위한 고유동화제는 NSF와 NT-2가 효과적이었다. 시멘트 모르타르의 유동성은 II형 무수석고의 분말도가 미세할수록 증가하였고, 유동성저하는 FAS를 10 wt% 치환하였을 때 작게 나타났다. 압축강도는 10 wt%치환한 공시체가 20 wt%치환한 것보다 높게 나타났고 특히 $\gamma$ 를 10 wt%치환한 공시체( CI )에서 가장 높은 압축강도값을 나타내었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 봄 학술발표회 논문집
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• pp.66-71
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• 1995

This study reviews the internationally existing standards for fly ash and the other pozzolanic materials. The standards reviewed for this report covers the thirteen contries around the world including USA. It is found that the comparison of standards appeared to be different for technical test requirements from the country to country. This may be due to the different composition of fly ash produced in each different country as by-product. It is importantly shown that the four countries, including USA have standardized to compose the total 70% of $SiO_2+Al_2O_3+Fe_2O_3$. The other countries have required to have the individual chemical composition, such as 45% $SiO_2$ in Japan. The loss on ignition is generally in the range of 5-6%, but the maximum 12% was allowed in some countries. This depends on the quality of fly ash. The moisture content is generally less than 3% in all countries except India allows up to 12% The pozzolanic activity (as the compression) has been standardized that the 28 days curing in compression was subjected in all countries but 91 days curing in compression was tested in Japan. It is shown that KS L 5405 is almost identical to JIS A 6201.

• 한국광물학회지
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• 제17권3호
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• pp.277-288
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• 2004

알칼리-실리카반응은 시멘트 내의 알칼리와 화학적으로 불안정한 반응성 골재와의 화학반응으로서, 그 결과 콘크리트의 팽창과 균열을 발생하는 작용이다 본 연구에서는 우수한 포조란반응 특성을 나타내는 새로운 광물혼화재로 부각되고 있는 메타카오린의 알칼리-실리카반응 억제 효과에 대하여 연구하였다. 다양한 치환율로 메타카오린을 혼합한 모르타르 공시체를 제작하여, 알칼리-실리카 반응성 시험(ASTM C 1260), 압축강도 시험 및 유동성 시험을 실시하고, 시멘트 수화물에서의 구성성분 변화에 대한 XRD 정량분석을 실시하였다. 그 결과, 메타카오린의 혼합은 시멘트 페이스트내의 가용 포트랜다이트의 함량을 급속히 감소시키는 빠른 포조란반응 및 수화반응 특성을 나타내어, 알칼리-실리카 반응에 의한 팽창을 억제하고 우수한 압축강도를 발현하는 것으로 나타났다. 시멘트에 메타카오린의 혼합에 의한 알칼리-실리카 반응에 의한 팽창억제는 치환율 15% 이상, 즉 시멘트 페이스 내의 가용 포트랜다이트 함량이 약 10% 이하가 될 경우 효과적이다. 메타카오린의 혼합에 의한 알칼리-실리카 반응에 의한 팽창 억제는 유해성이 높은 알칼리-칼슘-실리카 겔의 형성이 억제된 결과와 포조란 효과에 의한 치밀하고 균질한 시멘트 페이스트 형성으로 인한 알칼리 용액의 침투가 억제된 결과에 의한 것으로 생각된다. 15% 이상의 메타카오린의 혼합은 보통의 모르타르보다 높은 초기강도를 발현하였으며, 후기강도는 전 치환율 범위에서 보통의 모르타르 이상의 아주 우수한 강도를 나타내었다. 강도발현 특징은 메타카오린에 의한 빠른 포조란반응 및 수화특성을 반영하고 있다.

• 한국건축시공학회지
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• 제7권1호
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• pp.71-77
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• 2007

This paper is to investigate the effect of the curing temperature on strength development of concrete incorporating cement kiln dust(CKD) and blast furnace slag (BS) quantitatively. Estimation of the compressive strength of the concrete was conducted using the equivalent age equation and the rate constant model proposed by Carino. Correction of Carino model was studied to secure the accuracy of strength development estimation by introducing correction factors regarding rate constant and age. An increasing curing temperature results in an increase in strength at early age, but with the elapse of age, strength development at high curing temperature decreases compared with that at low curing temperature. Especially, the use of BS has a remarkable strength development at early age and even at later age, high strength is maintained due to accelerated pozzolanic activity resulting from high temperature. Whereas, at low curing temperature, the use of BS leads to a decrease in compressive strength. Accordingly, much attention should be paid to prevent strength loss at low temperature. Based on the strength development estimation using equivalent age equation, good agreements between measured strength and calculated strength are obtained.

• 청정기술
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• 제7권2호
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• pp.109-117
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• 2001

고로슬래그를 콘크리트의 결합재 또는 혼화재로의 사용은 활성화되어 있으나, 수량을 극히 제한적으로 사용하는 콘크리트 2차제품에 적용한 예는 극히 적다. 본 연구는 고로슬래그의 재활용 용도를 다양화하기 위한 것으로 시멘트의 일부를 고로슬래그로 대체하여 제조한 콘크리트 2차제품의 강도 증진 메커니즘을 분석한 것이다. 연구의 결과 압축강도 $400kgf/cm^2$ 이상의 고강도 스페이서를 개발시 고로슬래그의 사용은 매우 효과적인 혼화재료라는 것을 확인하였다. 고로슬래그의 사용에 의한 압축강도 증진의 주요 메커니즘은 콘크리트 2차제품의 전체 입도 분포가 보다 최밀입도에 가깝게 분포하는 최밀입도이론과 포졸란계 재료가 시멘트 수화물인 $Ca(OH)_2$와 상온에서 장기간에 걸쳐 일으키는 포졸란 반응인 것을 확인할 수 있었다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2005년도 추계 학술논문 발표대회
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• pp.75-78
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• 2005

This raper investigates the effect of curing temperature on strength development of concrete incorporating cement kiln dust(CKD) and blast furnace slag (BS) quantitatively. Estimation of compressive strength of concrete was conducted using equivalent age equation and rate constant model. An increasing curing temperature results in an increase in strength at early age, but with the elapse of age, strength development at high curing temperature decreases compared with that at low curing temperature. Especially, the use of 35 has a remarkable strength development at early age and even at later age, high strength is maintained due to accelerated pozzolanic activity resulting from high temperature. Whereas, at low curing temperature, the use of BS leads to a decrease in compressive strength. Accordingly, much attention should be paid to prevent strength loss at low temperature. Based on the strength development estimation using equivalent age equation, good agreements between measured strength and calculated strength are obtained.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2004년도 학술대회지
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• pp.71-76
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• 2004

This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for $3\sim4$ replacement ratios under W/B ratios ranged from 0.40 to 0.55. Specimens were immersed in $3.6\%$ NaCl solution for 330 days, and penetration depth, water soluble chloride contents and acid soluble chloride contents were measured in 28, 91, 182 and 330 days. Then, diffusion coefficient were calculated using total chloride contents. As a results. the kinds of mineral admixture and replacement ratios had a great effect on the resistance property of the concrete to chloride ion invasion compared with the plain concrete. And the optimal replacement ratios of mineral admixture had a limitation for each admixtures. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures and the penetration depth from the concrete skin. Chloride diffusion coefficient of each concretes decreased with the time elapsed. and the diffusion coefficients of the concrete immersed salt water for 330 days had a establishment with the compressive strength measured before immersing.

• Computers and Concrete
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• 제13권6호
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• pp.739-748
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• 2014

In this article, by using experimental studies and artificial neural network has been tried to investigate the use of nano-silica as concrete admixture to reduce alkali-silica reaction. If there are reactive aggregates and alkali of cement with enough moisture in concrete, a gel will be formed. Then with high reactivity between alkali of cement and existence of silica in aggregates, this gel will expand by absorption of water, and causes expansive pressure and cracks be formed. At the time passes, this gel will reduce both durability and strength of the concrete. By reducing the size of silicate to nano, specific surface area of particles and number of atoms on the surface will be increased, which causes more pozzolanic activity of them. Nano-silica can react with calcium hydroxide ($Ca(OH)_2$) and produces C-S-H gel. In this study, accelerated mortar bar specimens according to ASTM C 1260 and ASTM C 1567, with different mix proportions were prepared using aggregates of Kerman, such as: none admixture and plasticizer, different proportions of nano-silica separately. By opening the moulds after 24 hour and curing in water at $80^{\circ}C$ for 24 hour, then curing in (1N NaOH) at $80^{\circ}C$ for 14 days, length expansion of mortar bars were measured and compared. It was noted that, the lowest length expansion of a specimens shows the best proportion of admixture based on alkali-silica reactivity. Then, prediction of alkali-silica reaction of concrete has been investigated by using artificial neural network. In this study the backpropagation network has been used and compared with different algorithms to train network. Finally, the best amount of nano silica for adding to mix proportion, also the best algorithm and number of neurons in hidden layer of artificial neural network have been offered.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 봄 학술발표회 논문집
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• pp.84-87
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• 1995

Production of high strength concrete requires a low water-cement ratio and this leads to the high cement content. Mineral admixture like fly ash(FA) is often cheaper than ordinary portland cement(OPC) and this factor in combination with possible improvement in workability and moderation of the heat evolution of the cement-rich mixes tends to encourage its use. The other mineral admisture that its use has been widly advocated is silica fume that increases compressive strength due to its pozzolanic reaction. The objective of this study is to assess the contribution of mineral admixtures(FA, SF) to the workability and the strength of concrete with low water-binder ratios. In this experimental study that investigates and analyzes the properties of fresh concrete. it is presented that using admixtures like flyash and silica fume as binding material increases properties of high strength flowing concrete having very low water cementitious ratios of 0.25 and 0.30.

• 한국세라믹학회지
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• 제27권3호
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• pp.437-443
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• 1990

The resistivity of cement paste and mortar for freezing and thawing was investigated for densifying the structure of cement paste and mortor, slag, diatomaceous earth and fly ash as blending materials and superplasticizer were used, and air entraining agent was added to absorb the volume expansion by freezing and thawing reaction. And then the specimens were subjected to freeze-thaw in water. When both of air entraining agent and superplasticizer as additives were mixed to specimens, their freeze-thaw resistance was enhanced by the air entraining effect and the water reduction effect. When 4% of slag were added to cement, freeze-thaw resistance was especially excellent. In addition, it was found that the specimens with blending materials were more influenced by curing periods than those without admixture. It is assumed that the curing periods contribute to exibit the potential hydraulicity and pozzolanic reactivity of blending materials and to densify their texture.