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Behaviors of Desorption Agents During Removal of Cs From Clay Minerals and Actual Soil

  • Park, Chan Woo;Kim, Ilgook;Yoon, In-Ho;Yang, Hee-Man;Seo, Bum-Kyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.1
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    • pp.39-49
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    • 2021
  • The behaviors of various desorption agents were investigated during the desorption of cesium (Cs) from samples of clay minerals and actual soil. Results showed that polymeric cation exchange agents (polyethyleneimine (PEI)) efficiently desorbed Cs from expandable montmorillonite, whereas acidic desorption solutions containing HCl or PEI removed considerable Cs from hydrobiotite. However, most desorption agents could desorb only 54% of Cs from illite because of Cs's specific adsorption to selective adsorption sites. Cs desorption from an actual soil sample containing Cs-selective clay mineral illite (< 200 ㎛) and extracted from near South Korea's Kori Nuclear Power Plant was also investigated. Considerable adsorbed 137Cs was expected to be located at Cs-selective sites when the 137Cs loading was much lower than the sample's cation exchange capacity. At this low 137Cs loading, the total Cs amount desorbed by repeated washing varied by desorption agent in the order HCl > PEI > NH4+, and the highest Cs desorption amount achieved using HCl was 83%. Unlike other desorption agents with only cation exchange capabilities, HCl can attack minerals and induce dissolution of metallic elements. HCl's ability to both alter minerals and induce H+/Cs+ ion exchange is expected to promote Cs desorption from actual soil samples.

Probability subtraction method for accurate quantification of seismic multi-unit probabilistic safety assessment

  • Park, Seong Kyu;Jung, Woo Sik
    • Nuclear Engineering and Technology
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    • v.53 no.4
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    • pp.1146-1156
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    • 2021
  • Single-unit probabilistic safety assessment (SUPSA) has complex Boolean logic equations for accident sequences. Multi-unit probabilistic safety assessment (MUPSA) model is developed by revising and combining SUPSA models in order to reflect plant state combinations (PSCs). These PSCs represent combinations of core damage and non-core damage states of nuclear power plants (NPPs). Since all these Boolean logic equations have complemented gates (not gates), it is not easy to generate exact Boolean solutions. Delete-term approximation method (DTAM) has been widely applied for generating approximate minimal cut sets (MCSs) from the complex Boolean logic equations with complemented gates. By applying DTAM, approximate conditional core damage probability (CCDP) has been calculated in SUPSA and MUPSA. It was found that CCDP calculated by DTAM was overestimated when complemented gates have non-rare events. Especially, the CCDP overestimation drastically increases if seismic SUPSA or MUPSA has complemented gates with many non-rare events. The objective of this study is to suggest a new quantification method named probability subtraction method (PSM) that replaces DTAM. The PSM calculates accurate CCDP even when SUPSA or MUPSA has complemented gates with many non-rare events. In this paper, the PSM is explained, and the accuracy of the PSM is validated by its applications to a few MUPSAs.

A Fundamental Study on the Comparison and Analysis of Overseas Design Orders of Korea, China and Japan (한중일 해외설계수주액의 비교·분석 기초 연구)

  • Park, Hwan-Pyo;Han, Jae-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.195-196
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    • 2019
  • The purpose of this study is to analyze the scale of overseas design orders in Korea, China and Japan by region and type of work, and to draw implications. As a result of analyzing the overseas design sales market of Korea, China and Japan, all three countries have the highest percentage of overseas sales in the Asian market, and the overseas design sales are the highest in power generation, chemical plant and transportation sectors. In addition to the Middle East and Asian markets, Japan and China have also diversified their strategies to diversify their markets by taking orders in various regions such as Europe, Africa and the United States. In particular, China is promoting the "New Silk Road Project" (One belt, One road), linking land and sea to a total of 25 countries and actively supporting aid projects in Africa and Asia, have. In addition, Japan has been actively supporting the government's expansion of ODA projects to expand overseas market entry. Therefore, it is necessary for Korea to increase its market share through diversification of overseas design market and diversification of industrial type, and to participate in overseas design market by expanding customized R&D investment.

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Application of Conditional Spectra to Seismic Fragility Assessment for an NPP Containment Building based on Nonlinear Dynamic Analysis (조건부스펙트럼을 적용한 원전 격납건물의 비선형 동적 해석 기반 지진취약도평가)

  • Shin, Dong-Hyun;Park, Ji-Hun;Jeon, Seong-Ha
    • Journal of the Earthquake Engineering Society of Korea
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    • v.25 no.4
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    • pp.179-189
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    • 2021
  • Conditional spectra (CS) are applied to the seismic fragility assessment of a nuclear power plant (NPP) containment building for comparison with a relevant conventional uniform hazard response spectrum (UHRS). Three different control frequencies are considered in developing conditional spectra. The contribution of diverse magnitudes and epicentral distances is identified from deaggregation for the UHRS at a control frequency and incorporated into the conditional spectra. A total of 30 ground motion records are selected and scaled to simulate the probability distribution of each conditional spectra, respectively. A set of lumped mass stick models for the containment building are built considering nonlinear bending and shear deformation and uncertainty in modeling parameters using the Latin hypercube sampling technique. Incremental dynamic analysis is conducted for different seismic input models in order to estimate seismic fragility functions. The seismic fragility functions and high confidence of low probability of failure (HCLPF) are calculated for different seismic input models and analyzed comparatively.

A Review of Rear Axle Steering System Technology for Commercial Vehicles

  • Khan, Haroon Ahmad;Yun, So-Nam;Jeong, Eun-A;Park, Jeong-Woo;Yoo, Chung-Mok;Han, Sung-Min
    • Journal of Drive and Control
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    • v.17 no.4
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    • pp.152-159
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    • 2020
  • This study reviews the rear or tag axle steering system's concepts and technology applied to commercial vehicles. Most commercial vehicles are large in size with more than two axles. Maneuvering them around tight corners, narrow roads, and spaces is a difficult job if only the front axle is steerable. Furthermore, wear and tear in tires will increase as turn angle and number of axles are increased. This problem can be solved using rear axle steering technology that is being used in commercial vehicles nowadays. Rear axle steering system technology uses a cylinder mounted on one of rear axles called a steering cylinder. Cylinder control is the primary objective of the real axle steering system. There are two types of such steering mechanisms. One uses master and slave cylinder concept while the other concept is relatively new. It goes by the name of smart axle, self-steered axle, or smart steering axle driven independently from the front wheel steering. All these different types of steering mechanisms are discussed in this study with detailed description, advantages, disadvantages, and safety considerations.

Ammonia Adsorption Capacity and Breakthrough Curve of Zeolitic Materials Synthesized from Coal Fly Ash (석탄 비산재로부터 합성된 제올라이트의 암모니아의 흡착용량 및 파과특성)

  • Park, Jong-Won;Lee, Chang-Han
    • Journal of Environmental Science International
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    • v.31 no.10
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    • pp.833-844
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    • 2022
  • A zeolite material with a Si/Al molar ratio of 1.2 was synthesized by changing the NaOH/CFA ratio of coal fly ash (CFA) via a fusion/hydrothermal reaction in the HD thermal power plant. The change in the crystal structure of the zeolite was confirmed using XRD and SEM, and the ammonia adsorption capacities of the synthesized zeolitic materials and a commercial zeolite (Na-A zeolite) were analyzed via an ammonia temperature-programmed desorption (NH3-TPD) process. The SEM and XRD results revealed out the zeolitic materials from the coal fly ash maintained a hexagonal Linde-type crystal structure similar to that of Na-A zeolite, but the crystallinity of the synthesized zeolitic material was reduced due to impurities. The NH3 adsorption capacity, determined from the NH3-TPD analysis of was 1.122 mmol/g of the synthesized zeolitic material, which was lower than the NH3 adsorption capacity of the Na-A zeolite.

Evaluation of Ammonia Adsorption Capacity Using Various Metal Ion-Exchanged Zeolitic Materials Synthesized from Coal Fly Ash (금속 이온이 교환된 석탄 비산재 유래 합성 제올라이트 물질의 암모니아 흡착성능 평가 )

  • Jong-Won Park;Joo-Young Kwak;Chang-Han Lee
    • Journal of Environmental Science International
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    • v.32 no.5
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    • pp.343-353
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    • 2023
  • A zeolite material (ZCH) was synthesized from coal fly ash in an HD thermal power plant using a fusion/hydrothermal method. ZCH with high crystallinity could be synthesized at the NaOH/CFA ratio of 0.9. Ion-exchanged ZCH adsorbents for ammonia removal were prepared by ion-exchanging various cation (Cu2+, Co2+, Fe3+, and Mn2+) on the ZCH. They were used to evaluate the ammonia adsorption breakthrough curves and adsorption capacities. The ammonia adsorption capacities of the ZCH and ion-exchanged ZCHs were high in the order of Mn-ZCH > Cu-ZCH ≅ Co-ZCH > Fe-ZCH > ZCH according to NH3-TPD measurements. Mn-ZCH ion-exchanged with Mn has more Brønsted acid sites than other adsorbents. The ion-exchanged Cu2+, Co2+, Fe3+, or Mn2+ ions uniformly distributed on the surface or in the pores of the ZCH, and the number of acidic sites increased on the alumina sites to form the crystal structure of zeolite material. Therefore, when the ion-exchanged ZCH was used, the adsorption capacity for ammonia gas increased.

Evaluation of dissolution characteristics of magnetite in an inorganic acidic solution for the PHWR system decontamination

  • Ayantika Banerjee ;Wangkyu Choi ;Byung-Seon Choi ;Sangyoon Park;Seon-Byeong Kim
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1892-1900
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    • 2023
  • A protective oxide layer forms on the material surfaces of a Nuclear Power Plant during operation due to high temperature. These oxides can host radionuclides, the activated corrosion products of fission products, resulting in decommissioning workers' exposure. These deposited oxides are iron oxides such as Fe3O4, Fe2O3 and mixed ferrites such as nickel ferrites, chromium ferrites, and cobalt ferrites. Developing a new chemical decontamination technology for domestic CANDU-type reactors is challenging due to variations in oxide compositions from different structural materials in a Pressurized Water Reactor (PWR) system. The Korea Atomic Energy Research Institute (KAERI) has already developed a chemical decontamination process for PWRs called 'HyBRID' (Hydrazine-Based Reductive metal Ion Decontamination) that does not use organic acids or organic chelating agents at all. As the first step to developing a new chemical decontamination technology for the Pressurized Heavy Water Reactor (PHWR) system, we investigated magnetite dissolution behaviors in various HyBRID inorganic acidic solutions to assess their applicability to the PHWR reactor system, which forms a thicker oxide film.

Limiting conditions prediction using machine learning for loss of condenser vacuum event

  • Dong-Hun Shin;Moon-Ghu Park;Hae-Yong Jeong;Jae-Yong Lee;Jung-Uk Sohn;Do-Yeon Kim
    • Nuclear Engineering and Technology
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    • v.55 no.12
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    • pp.4607-4616
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    • 2023
  • We implement machine learning regression models to predict peak pressures of primary and secondary systems, a major safety concern in Loss Of Condenser Vacuum (LOCV) accident. We selected the Multi-dimensional Analysis of Reactor Safety-KINS standard (MARS-KS) code to analyze the LOCV accident, and the reference plant is the Korean Optimized Power Reactor 1000MWe (OPR1000). eXtreme Gradient Boosting (XGBoost) is selected as a machine learning tool. The MARS-KS code is used to generate LOCV accident data and the data is applied to train the machine learning model. Hyperparameter optimization is performed using a simulated annealing. The randomly generated combination of initial conditions within the operating range is put into the input of the XGBoost model to predict the peak pressure. These initial conditions that cause peak pressure with MARS-KS generate the results. After such a process, the error between the predicted value and the code output is calculated. Uncertainty about the machine learning model is also calculated to verify the model accuracy. The machine learning model presented in this paper successfully identifies a combination of initial conditions that produce a more conservative peak pressure than the values calculated with existing methodologies.

Comparative Analysis of Effective Dose Evaluation forTritium in Animal Product Ingestion According to Domestic and International Evaluation Methodologies Using Data from the Republic of Korea (대한민국의 데이터를 활용한 국내·외 평가 방법론에 따른 축산물 취식 시 삼중수소 유효선량 평가 비교·분석)

  • JeWan Park;YongMin Kim
    • Journal of Radiation Industry
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    • v.17 no.4
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    • pp.437-442
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    • 2023
  • This study conducted a comparative analysis of dose evaluations for ingestion of animal products based on data from nuclear power plants in the Republic of Korea, using methodologies from the Republic of Korea, 'IAEA TRS-472', and 'CSA N288.1:14'. The research focused on tritium, the most significant constituent among the gaseous and liquid radioactive emissions. The combined evaluation of tritium, in the form of tritiated water (HTO) and organically bound tritium (OBT), yielded results of 1.143 μSv y-1 for the Republic of Korea, 0.965μSv y-1 for 'TRS-472', and 0.886μSv y-1 for 'N288.1:14'. Despite the Republic of Korea's guidelines not considering OBT, the evaluation results for the Republic of Korea were higher compared to other methodologies. This discrepancy was attributed to the unique approach of not considering the moisture content per individual in the calculations of plant and feed concentration in the Republic of Korea and the simultaneous consideration of specific-activity model and transfer model. The study highlights the necessity of developing dose evaluation models tailored to regional characteristics and underscores the importance of including OBT in these evaluations.