• Title/Summary/Keyword: Post-Heat treatment

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The Synthesis of (Y,Gd)$BO_3:Eu^{3+}$Phosphor by Ultrasonic Spray and Their Photoluminance Properties (초음파 분무에 의한 (Y,Gd)$BO_3:Eu^{3+}$ 형광체의 제조와 이의 발광 특성)

  • 김대수;김성우;이임렬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.107-110
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    • 1999
  • The ultrasonic spray method was employed to make (Y,Gd)BO$_3$:Eu Phosphor, and its optical properties under 147nm VUV and 254 nm UV excitations were characterized and then compared with that produced by the solid-state reaction. The mixed solution of acetate hydrates of Y, Gd, Eu and boric acid diluted in water or methanol was used as the precursor fur the spray. It was found that (Y,Gd)BO$_3$:Eu phosphor made by this ultrasonic spray had a spherical shape and fine particle size of 1${\mu}{\textrm}{m}$. The crystalline structure for the as-sprayed phosphor was amorphous, but it converted into the same polycrystalline phase of solid state reaction after post heat treatment at 110$0^{\circ}C$ for 2hr. The emitting intensity under VUV and UV excitations for the spray-formed (Y,Gd)BO$_3$:Eu phosphor, however, was inferior to the later one. The excitation spectra were also studied and compared under VUV and UV excitations to explain the change of emitting intensity with Gd substitution in (Y$_{1-x}$ Gd$_{x}$)BO$_3$:Eu Phosphors made by spray and solid state reaction.on.

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Effect of PWHT and stress ratio on fatigue behavior of welded joints in steel (강용접부의 피로거동에 미치는 용접후열처리 및 응력비의 영향)

  • 김경수;임재규;정세희
    • Journal of Welding and Joining
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    • v.5 no.3
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    • pp.53-61
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    • 1987
  • Post weld heat treatment(PWHT) is usually carried out to remove the residual stress and to improve the microstructure and mechanical properties of welded joints. By the way, welding structure transformed owing to PWHT and reheating for repair loads the random cycles fatigue as offshore welding structure of constant low cycle fatigue as pressure vessel, and then, pre-existing flaws or cracks exist in a structural component and those cracks grow under cyclic loading. Therefore, the effects of PWHT and stress ratio on fatigue crack growth behaviors were studied on the three regions such as HAZ, sub-critical HAZ and deposit metal of welded joints in SM53 steel. Fatigue crack growth behavior of as-weld depended on microstructure and fatigue crack growth rate of HAZ was the lowest at eac region, but after PWHT it was somewhat higher than that of as-wel. In case of applying the stress($10kg/mm^2$) during PWHT, fatigue crack growth resistance tended to increase in the overall range of .DELTA.K.

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Preparation of V2O5-Graphene Composites using Aerosol Process for Supercapacitors Application (에어로졸 공정을 이용한 오산화바나듐(V2O5)-그래핀 복합체 제조 및 슈퍼커패시터 응용)

  • Lee, Chongmin;Jang, Hee Dong
    • Particle and aerosol research
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    • v.16 no.4
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    • pp.95-105
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    • 2020
  • Vanadium Pentoxide (V2O5) has been emerged as alternative electrode materials for supercapacitors due to their low cost, natural abundance, and environmental friendliness. Graphene (GR) loaded with V2O5 can exhibit enhanced specific capacitance. In this study, we present three-dimensional (3D) crumpled graphene (CGR) decorated with V2O5. The V2O5-graphene composites were synthesized from a colloidal mixture of graphene oxide (GO) and Ammonium metavanadate (NH4VO3), via aerosol spray drying and post heat treatment process. The average size of composite was ranged from 1.82 to 4.6 ㎛. Morphology of the composite changed from a crumpled paper ball to spherical ball having relatively smooth surface as the content of V2O5 increased in the composites. The electrochemical performance of the V2O5-graphene composites was examined. The V2O5-graphene composite electrode showed the specific capacitance of 312 F/g. In addition, the device possessed acceptable cyclic stability, with 84% after 2000 cycles at 2 A/g. These outstanding properties are expected to make the composites prepared in this study as promising electrode materials for supercapacitor applications.

Real-time Transformation of FePt Nanoparticles to L10 Phase by the Gas Phase Synthesis (기상합성공정을 이용한 FePt 나노입자의 실시간 L10 상변화)

  • Lee, Ki-Woo;Lee, Chang-Woo;Kim, Soon-Gil;Lee, Jai-Sung
    • Korean Journal of Metals and Materials
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    • v.49 no.1
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    • pp.46-51
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    • 2011
  • Real-time formation of $L1_0$ phase of FePt nanoparticles in the gas phase during ultrasonic-spray pyrolysis is first discussed in the present study. Without any post heat treatment, $L1_0$ phase of FePt nanoparticles appeared at the temperature above $900^{\circ}C$ in the gas phase synthesis. X-ray diffractometry (XRD) and transmission electron microscopy (TEM) studies revealed that FePt nanoparticles less than 10 nm in size contained small volume of $L1_0$ fct phase. However, in other samples obtained at the temperature below $900^{\circ}C$, iron oxide phase co-existed and no evidence of phase transformation was found. Thus, it is anticipated that the time of flight of particles required for crystallization and phase transformation was extended according to the increase of the collision rate. Finally, magnetic properties represented by coercivity and saturation magnetization and functional groups on the particle surface were discussed based on VSM and FT-IR results.

Resistance, electron- and laser-beam welding of zirconium alloys for nuclear applications: A review

  • Slobodyan, Mikhail
    • Nuclear Engineering and Technology
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    • v.53 no.4
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    • pp.1049-1078
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    • 2021
  • The review summarizes the published data on the widely applied electron-beam, laser-beam, as well as resistance upset, projection, and spot welding of zirconium alloys for nuclear applications. It provides the results of their analysis to identify common patterns in this area. Great attention has been paid to the quality requirements, the edge preparation, up-to-date equipment, process parameters, as well as post-weld treatment and processing. Also, quality control and weld repair methods have been mentioned. Finally, conclusions have been drawn about a significant gap between the capabilities of advanced welding equipment to control the microstructure and, accordingly, the properties of welded joints of the zirconium alloys and existing algorithms that enable to realize them in the nuclear industry. Considering the ever-increasing demands on the high-burnup accident tolerant nuclear fuel assemblies, great efforts should be focused on the improving the welding procedures by implementing predefined heat input cycles. However, a lot of research is required, since the number of possible combinations of the zirconium alloys, designs and dimensions of the joints dramatically exceeds the quantity of published results on the effect of the welding parameters on the properties of the welds.

Super Duplex Stainless Steel Matrix Composites with High Strength and Favorable Ductility Achieved Through Laser Powder Bed Fusion and Powder Mixture

  • Yongjian Fang;Yali Zhang;Jonghwan Suhr
    • Composites Research
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    • v.37 no.2
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    • pp.94-100
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    • 2024
  • In order to evade the premature failure of super duplex stainless steels (SDSSs) in some harsh environments, the increase of their mechanical properties is a promising approach. In this study, based on the laser powder bed fusion (LPBF) technique, SDSS matrix composites without post heat treatment were fabricated by using the powder mixture of SDSSs, super austenitic stainless steels (SASSs) and micron-sized TiC particles. Many in-situ TiCxNy nanoparticles were found to be formed by using micron-sized TiC particles in as-built composites, and both fine ferrite and austenite grains were generated. The as-built composites exhibited an excellent combination of high ultimate tensile strength (UTS) (~1066 MPa) and good uniform elongation (UE) (~15.6%), showing a better mechanical property compared with other reported LPBF-fabricated SDSSs, which was mainly attributed to the fine grain, Orowan and dislocation strengthening mechanisms. In particular, the successful fabrication of SDSS matrix composites can set the stage for producing high-performance metallic parts via LPBF technique.

The influence of accumulated clinical experience with Soyang-type patients on the conceptualization of the Soyang pathology (소양인(少陽人) 치험례(治驗例)가 소양인(少陽人) 병리관(病理觀) 형성과정에 미친 영향에 대한 고찰)

  • Kang, Mi-Jeong;Lee, Ji-Won;Lee, Jun-Hee;Koh, Byung-Hee;Lee, Eui-Ju
    • Journal of Sasang Constitutional Medicine
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    • v.23 no.3
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    • pp.275-284
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    • 2011
  • 1. Objective: This literary review investigates Lee Jema's clinical experiences with Soyang-type patients and their influence on his conceptualization of the Soyang physiology and pathology. 2. Methods: 1) The case reports in "Soyang constitutional type: Spleen Cold-based Exterior-Cold disease" were compared before and after the Sinchuk revision to explore the temporal change in the Sasang medical concepts. 2) The texts in Donguisusebowon (Gabo edition) and Donguisusebowon (Sasangchobongwon) were analyzed to investigate the pathological concepts appearing before the completion of the Donguisusebowon (Gabo edition). 3) The texts in Donguisusebowon (Sinchuk edition) was analyzed to investigate the pathological concepts formed between the Gabo and Sinchuk editions of Donguisusebowon. 3. Results and Conclusions: 1) Gabo edition : The Gabo edition divided the External-origin Exterior disease into Cold-dominant (Heat-moderate) and Heat-dominant (Cold-moderate) patterns and differentiated the severity of Exterior-based Exterior disease and Interior-based Interior disease into mild, moderate, severe, and critical conditions. Cold-damage Delirium disease pattern was categorized as an Interior-based Interior disease, and the treatment protocol using Baekho-tang (Baihu-tang) was established. The stool condition and bowel movement reflecting the patient's defecation habits, the prime indicator of health in the Soyang constitutional type, were emphasized on their importance. 2) Sinchuk edition: The Delirium disease pattern was moved into the Exterior-cold disease, and the treatment protocol applying Jihwangbaekho-tang (Dihuangbaihu-tang) and Hyeongbangsabaek-san (Jingfangxiebai-san), with variational usage of Gypsum, was newly established. The Seong-Jeong and basal disease patterns were suggested as important factors in treating the patients. Also, it was proposed that the symptoms and signs reflecting the condition of the life-preserving energy be assessed to understand the patient's current condition. The importance of post-acute rehabilitation and aftercare as well as the most appropriate acute-stage treatment were emphasized.

Study on Characteristics of SCC and AE Signals for Weld HAZ of HT-60 Steel (HT-60강 용접부의 SCC및 AE신호특성에 관한 연구)

  • Na, Eui-Gyun;Yu, Hyo-Sun;Kim, Hoon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.21 no.1
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    • pp.62-68
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    • 2001
  • In order to characterize the microscopic fracture behaviour of the weldment din stress corrosion cracking(SCC) phenomena, SCC and acoustic emission(AE) tests were carried out simultaneously and the correlation between mechanical paramenters obtained from SCC and AE tests was investigated. In the case of base metal, much more AE events were produced at -0.5V than at -0.8V because of the dissolution mechanism before the maximum load. Regardless of the applied voltages to the specimens, however, AE events decreased after the maximum load. In the case of weldment, lots of AE events with larger amplitude $range(40{\sim}100dB)$ were produced because of the singularities of weld HAZ in comparision to the base metal and post-weld heat-treated(PWHT) specimens. Numerous and larger cracks for the weldment were observed on the fractured surfaces by SEM examination. From these results, it was concluded that SCC for the weldment appeared most severely in synthetic seawater. Weld HAZ was softened by PWHT which also contributed to the reduced susceptibility to corrosive environment in comparison to the weldment.

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Dietary effects of protected fat, glycerol, and soybean meal on performance, physiological parameters, carcass characteristics, and behavioral measurements of late-fattening Hanwoo steers under heat stress conditions

  • Jun Sik Woo;Gyeong Rim Ryu;Jeong Hoon Kim;Sun Sik Jang;Hong Gu Lee;Keun Kyu Park
    • Animal Bioscience
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    • v.37 no.7
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    • pp.1303-1315
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    • 2024
  • Objective: This study aimed to determine the effects of increasing energy and protein levels in diets by including protected fat (PF), glycerol (GL), and soybean meal (SBM) on growth performance, physiological parameters, carcass characteristics, and behavioral measurements of late-fattening Hanwoo steers under heat stress conditions. Methods: Thirty-six steers (initial body weight, 724.9±58.3 kg; age, 25.5±0.4 month) were assigned into control (total digestible nutrient [TDN] 76%, crude protein [CP] 15%), PF (TDN 83.6%, CP 15%), PF+GL (TDN 83.6%, CP 15%) and PF+GL+SBM (TDN 83.6%, CP 16.5%) by randomized complete block design for a total of 16 weeks with division of 4-week periods. The average temperature-humidity index was 87.0 (1st period; severe), 82.8 (2nd; moderate), 71.4 (3rd; comfort), and 68.1 (4th; comfort). Results: The dry matter intake (DMI) showed no treatments differences during the whole experiment. However, DMI in 1st and 2nd period decreased by approximately 30% and 10% compared to 4th period, respectively. Higher average daily gain and feed conversion ratio were noted for treatments compared to control at both 1st and 2nd period (p<0.05). There were no treatment effects on rectal temperature (RT), cortisol, and behaviors during the entire experiment. However, both RT and cortisol in 0, 1st and 2nd period were higher than those of 3rd and 4th period (p<0.05). Carcass yield and grade remained unaffected by increasing TDN and CP levels. Behavioral changes in the hot season (1st period) included reduced lying (43%), increased standing (48%), decreased walking (62%), and decreased eating (38%) (p<0.05), with an increase in drinking by 54%. Rumination during standing was 53% higher, while rumination during lying was about 33% lower compared to the post-hot season (3rd period) (p<0.05). Conclusion: Dietary supplementation of protected fat in late-fattening Hanwoo steers under heat stress had a positive effect on preventing a reduction in performance.

Proteome analysis of chickens fed with tissue culture medium waste after harvest of Korean wild ginseng (산삼 배양액을 급여한 육계에서 근육의 프로테옴 분석)

  • Seol, Jae-Won;Hwang, In Ho;Chae, Joon-Seok;Kang, Hyung-Sub;Ryu, Kyeong-Seon;Kang, Chun-Seong;Park, Sang-Youel
    • Korean Journal of Veterinary Research
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    • v.45 no.2
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    • pp.155-161
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    • 2005
  • Proteomics is a useful approach to know protein expression, post-translational modification and protein function. We investigated the protein expression pattern and identity in chickens fed with the tissue culture medium waste after harvest of Korean wild ginseng (TCM-KWG) (Panax ginseng). Two groups (n=60/group) of day old broiler chickens were administered with 0 (control) and 0.8% (treatment) TCM-KWG through drinking water. After 5 weeks, we examined the protein expression pattern of fibularis longus and superficial pectoral muscle by Two-dimensional electrophoresis analysis. Interestingly, TCM-KWG treatment significantly increased five spot's density, and markedly reduced five spot's density in the muscles. We identified 10 proteins (desmin, myosin light chain 1, heat shock 25 kDa protein, collapsin response mediator protein-2A, alpha enolase, vimentin, actin alpha 1, my023 protein, pyruvate kinase and troponin T) by the matrix-assisted laser desorption ionization time of flight (MALDI-TOF).