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Durability Evaluation of Cement Concrete Using Ferrosilicon Industrial Byproduct (페로실리콘 산업부산물 활용 시멘트 콘크리트의 내구성능 평가)

  • Chang-Young Kim;Ki Yong Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.89-96
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    • 2023
  • In this paper, a ferrosilicon by-product was evaluated to confirm the feasibility of recycling it as supplementary cementitious material of ordinary Portland cement in concrete. Three different levels of replacement ratio (10 %, 20 % and 30 % of total binder) were applied to find which is the most beneficial to be used as a binder. Ferrosilicon concrete was initially assessed at setting time and compressive strength. Durability was evaluated by the resistance to chloride penetration test(RCPT) and alkali-silica reaction(ASR) with a comparison to silica fume concrete due to their similarity in chemical composition. The porosimetry and X-ray diffraction analysis along with energy dispersive X-ray spectroscopy give information on the microstructural characteristics of the ferrosilicon concrete. It was found that 10 % ferrosilicon concrete has higher strength while 20 %, 30 % have lower strength than OPC concrete. However, chemical resistance to chloride attack is higher when replacement is increased. Compared to silica fume, the durability of ferrosilicon might be less efficient however, it is obviously beneficial than OPC. High SiO2 content in ferrosilicon results in producing more C-S-H gel which could make denser pore structure. Most of the risk of alkali silica reaction to silicate binders through length change tests was less than 0.2 %, and both mortar using ferrosilicon and silica fume showed better resistance to alkali silica reaction as the substitution rate increased.Reuse of industrial waste rather than producing highly refined additives might reduce environmental load during manufacture and save costs.

Unconfined Compressive Strength of Fiber-reinforced Cemented Sands by Fiber Reinforcement Form (섬유의 보강 형태에 따른 섬유-시멘트 혼합토의 일축압축강도특성)

  • Park, Sung-Sik;Kim, Young-Su;Lee, Jong-Cheon
    • Journal of the Korean Geotechnical Society
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    • v.23 no.8
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    • pp.159-169
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    • 2007
  • The behavior of fiber-reinforced cemented sands (FRCS) was studied to improve a brittle failure mode observed in cemented sands. Nak-dong River sand was mixed with ordinary Portland cement and a Polyvinyl alcohol (PVA) fiber. A PVA fiber is widely used in concrete and cement reinforcement. It has a good adhesive property to cement and a specific gravity of 1.3. A PVA fiber has a diameter of 0.1 mm that is thicker than general PVA fiber for reinforced cement. Clean Nak-dong River sand, cement and fiber at optimum water content were compacted in 5 layers giving 55 blows per layer. They were cured for 7 days. Cemented sands with a cement/sand ratio of 4% were fiber-reinforced at different locations and tested for unconfined compression tests. The effect of fiber reinforcement form and distribution on strength was investigated. A specimen with evenly distributed fiber showed two times more strength than not-evenly reinforced specimen. The strength of fiber-reinforced cemented sands increases as fiber reinforcement ratio increases. A fully reinforced specimen was 1.5 times stronger than a specimen reinforced at only middle part. FRCS behavior was controlled not only by a dosage of fiber but also by fiber distribution methods or fiber types.

Running to Change Prejudice into Hope - A Qualitative Case Study on Academically talented Children in Residential Care - (편견을 희망으로 바꾸는 달리기 - 학업성취 우수 시설보호아동에 관한 질적 사례연구 -)

  • Kim, Seohyun;Yang, Eunbyeor;Chung, Ick-Joong
    • Korean Journal of Social Welfare
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    • v.69 no.4
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    • pp.177-202
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    • 2017
  • We usually expect that children in residential care are not able to have excellent academic achievement, even though their school achievement in adolescence is crucial as a part of whole lifespan development. The purpose of this study is to carefully understand characteristics and experiences of only a few academically talented children in residential care and to find out the practical suggestion to support the academic performance of children in residential care. For this purpose, we had interviewed eight children in depth and analyzed the data using a qualitative case study method. As a result, we found a total of 21 subcategories and 5 categories. The categories included that 'always being faithful despite being not fast', 'believing myself when I face limitations', 'conflict in high support and high expectation', 'sometimes refusing to support on me, but I am leaning on my mind', 'relieving anxiety by studying'. In conclusion, we found that the central theme of 'running to change prejudice into hope' were found through the cases with excellent academic achievement. Based on the results, we suggested the guidelines to consider when developing and providing the academic support services for children in residential care.

A Study on Electromagnetic Properties in OPC Mortar with Different Chloride Content (염화물을 혼입한 OPC 모르타르의 전자기 특성에 대한 연구)

  • Kwon, Seung-Jun;Na, Ung-Jin;Feng, M.Q.
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.4A
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    • pp.565-571
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    • 2008
  • Recently, the evaluation technique using NDT (Nondestructive Technique : NDT) is widely utilized because it makes little damage on RC (Reinforced Concrete : RC) structures. The techniques using electromagnetic properties (EM properties) are also attempted for the evaluation of the performance of concrete which is nonmetallic. For the economic manufacturing of concrete material, sea-sand is often used as aggregate, however, chloride ion in concrete has direct effects on steel corrosion and EM properties. In this study, OPC mortar specimens with 5 different chloride amount (0.0, 0.6, 1.2, 2.4, and $3.6kg/m^3$) and 3 different water-cement ratios (45%, 55%, and 65%) are prepared in order to investigate the EM properties corresponding to concrete properties. The EM properties of conductivity and dielectric constant are measured in the frequency range over 0.2~20 GHz. To facilitate the comparison of EM properties with chloride content, average values are taken respectively for the conductivity and dielectric constant measured over the 5~20 GHz frequency range. According to the results of this experiment, dielectric constant and conductivity are increased with lower W/C ratio and larger amount of chloride content.

Unconfined Compressive Strength of Cemented Sand Reinforced with Short Fibers (단섬유를 사용한 시멘트 혼합토의 일축압축강도 특성)

  • Park, Sung-Sik;Kim, Young-Su;Choi, Sun-Gyu;Shin, Shi-Eon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.4C
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    • pp.213-220
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    • 2008
  • A study on cemented sand reinforced with short fibers was carried out to improve its unconfined compressive strength and brittle behavior. Nak-dong River sand was mixed with Portland cement and polyvinyl alcohol (PVA) fibers. A PVA fiber widely used for concrete reinforcement is randomly distributed into cemented sand. Nak-dong River sand, cement and fibers with optimum water content were compacted in 5 layers and then cured for 7 days. The effect of fiber reinforcement rather than cementation was emphasized by using a small amount of cement. Weakly cemented sand with a cement/sand ratio less than 8% was fiber-reinforced with different fiber ratios and tested for unconfined compression tests. The effect of fiber ratio and cement ratio on unconfined compressive strength was investigated. Fiber-reinforced cemented sand with 2% cement ratio showed up to six times strength to non-reinforced cemented sand. Because of ductile behavior of fiber-reinforced specimens, an axial strain at peak stress of specimens with 2% cement ratio increases up to 7% as a fiber ratio increases. The effect of 1% fiber addition into 2% cemented sand on friction angle and cohesion was analyzed separately. When the fiber reinforcement is related to friction angle increase, the 8% of applied stress transferred to 1% fibers within specimens.

Chloride Threshold Value for Steel Corrosion considering Chemical Properties of Concrete (콘크리트의 화학적 특성을 고려한 철근 부식 임계 염소이온 농도)

  • Song, Ha-Won;Jung, Min-Sun;Ann, Ki Yong;Lee, Chang-Hong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.1A
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    • pp.75-84
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    • 2009
  • The present study assesses the chloride threshold level for corrosion of steel in concrete by examining the properties of four different binders used for blended concrete in terms of chloride binding, buffering of cement matrix to a pH fall and the corrosion behaviour. As binders, ordinary Portland cement (OPC), 30% pulverised fuel ash (PFA), 60% ground granulated blast furnace slag (GGBS) and 10% silica fume (SF) were used in a concrete mix. Testing for chloride binding was carried out using the water extraction method, the buffering of cement matrix was assessed by measuring the resistance to an artificial acidification of nitric acid, and the corrosion rate of steel in mortar with chlorides in cast was measured at 28 days using an anodic polarisation technique. Results show that the chloride binding capacity was much affected by $C_{3}A$ content and physical adsorption, and its order was 60% GGBS>30% PFA>OPC>10% SF. The buffering of cement matrix to a pH fall was varied with binder type and given values of the pH. From the result of corrosion test, it was found that the chloride threshold ranged 1.03, 0.65, 0.45 and 0.98% by weight of cement for OPC, 30% PFA, 60% GGBS and 10% SF respectively, assuming that corrosion starts at the corrosion rate of $0.1-0.2{\mu}A/cm^{2}$. The mole ratio of [$Cl^{-}$]:[$H^{+}$], as a new presentation of the chloride threshold, indicated the value of 0.008-0.009, irrespective of binder, which would be indicative of the inhibitive characteristic of binder.

Influence of Mineral Admixtures on the Diffusion Coefficient for Chloride Ion in Concrete (광물질 혼화재가 콘크리트의 염소이온 확산계수에 미치는 영향)

  • Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong;Choi, Sung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.4A
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    • pp.347-353
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    • 2009
  • The qualitative factors influencing the ingress of chloride ion into concrete are water-binder (W/B) ratio, cement type, age, chloride ion concentration of given environment, wet and dry conditions, etc. Thus, an objective of this experimental research is to investigate the effects of cement types and environmental conditions on the chloride ion diffusion characteristics in concrete through the chloride ion diffusion test. For this purpose, the diffusion coefficients for chloride ion in concrete with three types of cement such as ordinary portland cement (OPC), binary blended cement (BBC), and ternary blended cement (TBC), were measured for the concrete specimens with W/B ratios of 32%, 38%, and 43%, respectively. The diffusion coefficients for chloride ion were also measured for the concrete specimens with W/B ratio of 43%, which were subjected to standard curing and field exposure conditions. It was observed from the test results that the resistance against chloride ion penetration increased with decreasing W/B ratio and those of BBC and TBC concretes were greater than that of OPC concrete. Therefore, it was revealed that the use of these cements containing mineral admixtures is required to extend the service life of RC structures exposed to chloride environment. On the other hand, it was noted that the resistance against chloride ion penetration of field exposure test specimens was slightly lower than that of standard curing test specimens due to the penetration of chloride ion under the irregular ambient temperature, splash of wave, and cycle of wet and dry.

An Experimental Study on the Carbonation Depth of Cement Paste Using Carbonation Reaction Accelerator (탄산화 반응 촉진제를 이용한 시멘트 페이스트의 탄산화 깊이에 관한 실험적 연구)

  • Seok-Man Jeong;Wan-Hee Yang;Dong-Cheol Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.349-354
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    • 2023
  • This study wa s conducted a s pa rt of ma ximizing the use of ca rbon dioxide by a pplying CCU(Ca rbon Ca pture, Utiliza tion) a mong technologies for reducing CO2 in the cement industry. In a carbon dioxide curing environment, changes in carbonation depth and changes in basic physical properties by age due to the mixing of carbonation reaction accelerators were usually targeted at Portland cement paste. In addition, in order to check the fixed amount of CO2 in the concrete field, a thermal analysis method was applied to evaluate CaCO3 decarbonization at high temperatures. As a result of the evaluation, it was confirmed that the carbonation depth in the cured body significantly increased due to the incorporation of CRA in the carbonation depth diffusion performance. In addition, it was confirmed that the weight reduction rate increased by 23.8 % and 40.77 %, respectively, compared to Plain, in the order of curing conditions for constant temperature and humidity and curing conditions for carbonation chambers, so it was confirmed that the amount of excellent CaCO3 produced by the addition of CRA increased as the concentration of CO2 increased.

Applying deep learning based super-resolution technique for high-resolution urban flood analysis (고해상도 도시 침수 해석을 위한 딥러닝 기반 초해상화 기술 적용)

  • Choi, Hyeonjin;Lee, Songhee;Woo, Hyuna;Kim, Minyoung;Noh, Seong Jin
    • Journal of Korea Water Resources Association
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    • v.56 no.10
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    • pp.641-653
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    • 2023
  • As climate change and urbanization are causing unprecedented natural disasters in urban areas, it is crucial to have urban flood predictions with high fidelity and accuracy. However, conventional physically- and deep learning-based urban flood modeling methods have limitations that require a lot of computer resources or data for high-resolution flooding analysis. In this study, we propose and implement a method for improving the spatial resolution of urban flood analysis using a deep learning based super-resolution technique. The proposed approach converts low-resolution flood maps by physically based modeling into the high-resolution using a super-resolution deep learning model trained by high-resolution modeling data. When applied to two cases of retrospective flood analysis at part of City of Portland, Oregon, U.S., the results of the 4-m resolution physical simulation were successfully converted into 1-m resolution flood maps through super-resolution. High structural similarity between the super-solution image and the high-resolution original was found. The results show promising image quality loss within an acceptable limit of 22.80 dB (PSNR) and 0.73 (SSIM). The proposed super-resolution method can provide efficient model training with a limited number of flood scenarios, significantly reducing data acquisition efforts and computational costs.

Setting and Micro-structures of the Cement Pastes Using Sugar-Based Super Retarding Agents (당류계 초지연성 혼화제를 사용한 시멘트 페이스트의 응결 및 미시구조 특성)

  • Jeong, Yeong-Jin;Hyun, Seung-Yong;Han, Jun-Hui;Kim, Jong;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.703-714
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    • 2023
  • This research conducts a series of tests to investigate the setting retarding properties and strength development in cement pastes incorporating various types and dosages of sugar-based super retarding agents. Six such agents, including Sucrose, Sugar powder, Saccharin, Aspartame, Stevioside, and Mogroside, commercially available, were selected for evaluation. The study also examines the micro-structural properties of these cement pastes. The test mixtures were prepared using a 27.5% water-to-cement ratio and ordinary Portland cement. Micro-structural analyses were conducted using Scanning Electron Microscopy(SEM), X-Ray Diffraction(XRD), and Energy Dispersive Spectroscopy(EDS). The findings reveal that the incorporation of sucrose, sugar powder, and stevioside significantly retards the setting time. Particularly, adding 0.1% sucrose extended the setting time by approximately two-fold compared to the control(Plain) mixture. Most mixtures, barring those with sugar powder and stevioside, exhibited compressive strength comparable to the Plain mixture. Notably, with 0.2% sucrose, strength measurements were not feasible at 1 day, but at 3 days, the strength gains aligned with the Plain mixture. XRD, SEM, and EDS analyses confirmed the hydration delay(set retarding) of C3S due to sucrose, with further quantitative corroboration provided by EDS. SEM was used to verify the presence or absence of hydration products. The study concludes that sucrose, as a sugar-based retarder, offers effective set retarding capabilities and compressive strength development in concrete.