• Title/Summary/Keyword: Porosity distribution

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Microstructure and Strength Properties of Alkali-activated Binder mixed with Sea Water (해수를 사용한 알칼리 활성화 결합재의 미세구조 및 강도 특성)

  • Jun, Yubin;Oh, Jae-Eun
    • Journal of the Korea Concrete Institute
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    • v.28 no.3
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    • pp.299-308
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    • 2016
  • This paper presents an investigation of the mechanical and microstructural properties on hardened samples that were synthesized using blended binder(fly ash(FA) and blast furnace slag cement(BFSC)), alkali activator and sea water or distilled water. Binders were prepared by mixing the FA and BFSC in different blend weight ratios of 6:4, 7:3 and 8:2. Sodium hydroxide and sodium silicate were used 5 wt% of binder, respectively, as an alkaline activator. The compressive strength and absorption were measured at the age of 3, 7 and 28 days, and the XRD, TGA and MIP tests were performed at the age of 28 days. An increase in the content of BFSC leads to an increase in the quantities of ettringite and C-S-H formed, regardless of the type of mixing water. And it also shows higher strength due to the reduction of pores larger than ~50 nm. All hardened samples in this study have common hydration products of C-S-H, $Ca(OH)_2$ and calcite. Hydrocalumite of all reaction products formed was only present in hardened sample mixed with sea water. For each FA/BFSC mixing ratio, the compressive strength of hardened sample mixed with sea water was similar to that mixed with distilled water. It is proposed that the slight increase of strength of samples mixed with sea water is mainly due to the presence of hydrocalumite phase containing chlorine ion, contributing to the change of total porosity and pore size distribution in samples.

Physical property analysis of sediments for development of maritime archaeological survey techniques (수중문화재 탐사기법 개발을 위한 퇴적물 물성분석)

  • Kim, Sung-Bo;Ko, Eun-Ji;Jung, Yong-Hwa;Lee, Young-Hyun;Kim, Jin-Hoo
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.3
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    • pp.333-341
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    • 2014
  • Since distribution and preservation of cultural artifacts in the submarine sediments are directly affected by not only ocean currents and tides, but also their composition, it is very important to investigate geological characteristics of sediments and ocean-sediment interactions for maritime archaeological survey. Physical properties of submarine sediments, which are collected by grab sampler and vibro-corer, are analyzed in order to investigate effects of submarine environment on development of maritime archaeological survey techniques. Result of physical property analysis showed that bulk density, shear strength, and magnetic susceptibility increase with depth, while water contents and porosity decrease with depth. Since the magnetic susceptibility of bedrock is about 40 times that of submarine sediments, it might impact greatly on the response of magnetic survey. Physical properties of sediments with depth and sediment classification by Folk's ternary diagram indicate that submarine sediment mainly consists of silt, and cultural artifacts can not penetrate no deeper than 1.5 m in sediments.

Superconductor Preparation by use of YBa2Cu3Ox powder and BaPbO3 Additive (YBa2Cu3Ox 분말과 첨가제 BaPbO3를 이용한 초전도체 제작)

  • Chu, Soon-Nam;Park, Jung-Cheul
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.8
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    • pp.1771-1776
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    • 2011
  • In this paper, as an attempt to improve the preparation conditions of $YBa_2Cu_3Ox$ superconducting bulk samples, the properties of $YBa_2Cu_3Ox$ superconductor depending on the particle size of YBCO powder and $BaPbO_3$ as an additive have been investigated, and a study on the effects of additive to the density, grain alignment, and porosity of samples that affect the critical current of superconductor has been performed. In order to prepare superconductor, $YBa_2Cu_3Ox$ powder synthesized by sol-gel method, showing a size distribution of 0.2~1 ${\mu}m$ was used. The $BaPbO_3$ added to promote grain growth and to decrease porosities and weak links between grain boundaries of $YBa_2Cu_3Ox$ superconductors. In the samples prepared by sol-gel synthesized powder with 10, 20, and 30 wt% conductive $BaPbO_3$ additives, the sample with 20 wt% $BaPbO_3$ obtained the highest critical current of 4.74 A, showing 20 wt% higher critical current than that with solid state synthesized powder.

Case study of landslide types in Korea (우리나라 산사태의 형태분류에 따른 사례)

  • 김원영;김경수;채병곤;조용찬
    • The Journal of Engineering Geology
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    • v.10 no.2
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    • pp.18-35
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    • 2000
  • The most dominant type of landslide in Korea is debris flows which mostly take place along mountain slopes during the rainy season, July to August. The landslides have been reported to begin activation when rainfall is more than 200mm within 2days. The debris flows are usually followed by translational slips which occur upper part of mountain slopes and they transit to debris flow as getting down to the valleys. Lithology, location, slope inclination, grain size distribution of soil, permeability, dry density and porosity have been proved as triggering factor causing translational slides. The triggering data taken from mapping are statistically analysed to get landslide potential quantitatively. Rock mass creeps mostly occur on well bedded sedimentary rocks in Kyeongsang Basin. Although the displacement of rock mass creep is relatively small about 1m, the creep can cause severe hazards due to relatively large volume of the involved rock mass. Examples are rock mass creep occurred in the mouth of Hwangryongsan Tunnel, in Chilgok and in Sachon in 1999. Although the direct factor of the creeps are due to slope cutting at the foot area, more attention is required A rotational slide occurring within thick soil formation or weathered rock is also closely related to bottom part of slope cutting. It is propagated circular or semi-circular type. Especially in korea, the rotational slide may be frequently occurred in Tertiary tuff area. Because they are mainly composed of volcanic ash and pyroclastic materials, well developed joints and high degree of swelling and absorption can easily cause the slide. The landslide among the Pohang-Guryongpo national road is belong to this type of slide.

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Estimation of Countermeasures and Efficient Use of Volume of Artificial Reefs Deployed in Fishing Grounds (어초어장으로 시설된 사각형어초의 수량 산정 및 유효공용적 평가)

  • Kim, Ho-Sang;Lee, Jeong-Woo;Kim, Jong-Ryeol;Yoon, Han-Sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.3
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    • pp.181-187
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    • 2009
  • To estimate the status and volume of artificial reefs(ARs) deployed at the sea bottom in fishing grounds, this study assessed the initial volume of ARs, the cubic volume of AR groups, and the porosity of each AR using image data collected during a survey using a multi-beam echo sounder(MBES) and a side scan sonar(SSS). These results were compared with data collected during diver surveys and used to develop a new method and prediction formulas for countermeasures, facility volume, and efficient use of volume for deployed ARs(cubic concrete). The field survey results for nine ARs deployed in the Busan Sea region were calculated, and the average value of coefficient k(indicating the efficient use of volume ratio) among ARs was 0.753, and the correlation between coefficient k and year(Yr) of deployment was calculated as k=0.0023Yr+0.725. The relationship between these two factors was poor. In years following the deployment of artificial reefs, coefficient k and year of deployment were not correlated, in spite of the hardening ground due to subsidence and the reduced distance between ARs. Consequently, it is reasonable to suppose that coefficient k was defined by bottom surface conditions and initial deployment conditions.

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The Preparation of Activated Carbon from Coffee Waste: ZnCl2-Activation (커피폐기물을 이용한 활성탄의 제조: ZnCl2-활성화)

  • You, S.H.;Kim, H.H.
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.509-515
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    • 1998
  • Activated coffee chars were prepared from coffee waste by chemical activation with zinc chloride. In this study, the following processes were carried out ; roasting step, carbonization step, chemical activation step, and washing and drying step. The roasting step of coffee waste was carried out at $300{\sim}400^{\circ}C$ for 10 minutes. The optimum condition of carbonization was at $650^{\circ}C$ for 1 hour. The most important parameter in chemical activation of coffee char was found to be the chemical ratio of activation agents. Activated coffee chars prepared by various activation methods were characterized in terms of the nitrogen BET surface area, the BJH pore volume and pore size distribution at 77 K. The $N_2$-BET surface areas and total pore volume of coffee chars prepared by the chemical activation with $ZnCl_2$ were determined as about $1110{\sim}1580m^2/g$ and $0.51{\sim}0.81cm^3/g$, respectively. Scanning Electron Microscopy (SEM) was used to observe the porosity and surface of activated coffee chars. From the results of SEM analysis, it was shown that active surface and many pores were formed after the chemical activation. The preparation of the activated coffee char from coffee waste was successfully carried out, which previews a possibility for exploitation of resources by recycling the waste.

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Characteristics Analysis of Mudstone Weathered Soils in the landslide Area using Statistical Technique (통계기법에 의한 산사태발생지역 이암 풍화토층의 토질특성 분석)

  • Hwang, Eui-Soon;Chung, Dae-Seouk;Kim, Kyeong-Su;Lee, Moon-Se;Song, Young-Suk
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.3
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    • pp.31-41
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    • 2013
  • In this study, the properties of mudstone weathered soils related to landslides were analyzed at the area of landslide induced by heavy rainfall in Pohang. The soil tests were carried out to the soils obtained from landslide and non landslide sites, and the soil properties were investigated. The correlation between soil properties and landslides were analyzed using statistical technique, and then the soil factors were extracted from the correlation analysis. The correlation equation which can calculate the coefficient of permeability influenced on landslides was proposed using the soil factors. As the result of analysis, the porosity and unit weight of soils from the landslide area is smaller than those of soils from the non landslide area. The soils with poor grain size distribution and loose unit weight are prone to landslides because the soils have a large void ratio and a low unit weight. The permeability of soils from the landslide area is larger than that of soils from the non landslide area. According to the result of correlation analysis, the effective grain size, the saturated unit weight and silt and clay contents are evaluated as the influence factors. These factors were considered to estimate the coefficient of permeability of mudstone weathered soils.

Glass-alumina Composites Prepared by Melt-infiltration: Ⅰ. Effect of Alumina Particle Size (용융침투법으로 제조한 유리-알루미나 복합체: Ⅰ. 알루미나 입도 효과)

  • Lee, Deuk-Yong;Jang, Ju-Woong;Kim, Dae-Joon;Park, Il-Seok;Lee, Jun-Kwang;Lee, Myung-Hyun;Kim, Bae-Yeon
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.799-805
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    • 2001
  • Two commercial alumina powders having different particle size of $0.5{\mu}m$ and 3${\mu}$m were presintered at 1120$^{\circ}$C for 2h and then lanthanum aluminosilicate glass was infiltrated at 1100$^{\circ}$C for up to 4h to obtain the densified glass-alumina composites. The effect of alumina particle size on packing factor, microstructure, wetting, porosity and pore size, and mechanical properties of the composite was investigated. The optimum mechanical properties and compaction behavior were observed for the 3${\mu}$m alumina particle dispersed composite. The 3${\mu}$m alumina particle size and distribution for he preform were within 0.1 to 48${\mu}$m and bimodal and random orientation. The strength and the fracture toughness of the composite having 3${\mu}$m alumina particles were 519MPa and $4.5MPa{\cdot}m^{1/2}$, respectively.

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An Experimental Study on the Engineering Properties of Lightweight Aggregate Concrete (경량골재 콘크리트의 공학적 성질에 관한 실험적 연구)

  • ;R. N. Swanmy
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.1
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    • pp.75-82
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    • 1997
  • 건설기술과 산업의 발전에 따라 구조물은 대형화되어 가고, 건설공사의 급격한 팽창으로 골재 수용량이 급증함에 따라 천연골재자원은 점차 부족현상을 면치 못할 처지에 있다. 또한, 무리한 천연골재의 채취는 자연환경을 훼손시킬 뿐만 아니라 자연보호 측면에서도 심각한 공해문제로 대두되고 있어 공급량 부족현상은 날로 심화되고 있다. 이에 세계 몇몇 나라에세는 산업부산물을 이용한 골재 생산으로 공해예방과 폐기물 활용방법을 연구하고 있다. 산업부산물중 플라이 애쉬 생산량은 전 세계적으로 매년 약 2억여톤에 달하고 있으나 이중 일부만 활용되고 있는 실정이다. 이와같은 부산물을 활용하기 위한 일환으로 산업부산물인 PFA(Pulverized Fuel Ash)로 만든 인공경량골재의 년생산량이 영국은 600,000$m^3$, 미국은 300,000$m^3$이며, 매년 증가주세에 있다. 고성능 경량골재 콘크리트는 단위중량의 증가없이 내구성과 강도를 향상시켜 실용화 측면에서 경제적인 효과가 있으며, 플라이 애쉬로 만든 경량골재는 시멘트와의 친화력이나 접착면에서 우수한 것으로 알려져 있다. 본 시험에 사용한 골재는 플라이 애쉬로 만든 인공경량 조골재와 강모래이고, 결합제로서 프틀랜드 시멘트를 사용하였다. 부수적인 결합재로서는 플라이 애쉬, 슬래그, 실리카 흄을 사용하였으며, 고성능 경량골재 콘크리트를 개발코자 재령 28일과 180일의 압축강도가 각각 50MPa와 60MPa가 되도록 배합설계를 하였다. 본 연구에서는 플라이 애쉬, 슬래그, 시리카 흄과 같은 산업부산물을 혼입했을때 경량골재 콘크리트의 압축강도, 휨강도, 동탄성계수, 공극체적, 공극률, 단위중량, 공극 크기별 분포등의 변화를 실험적으로 구명하여 재반 구조용 콘크리트에 활용하기 위한 기초자료를 마련코저 한다.있어 특정한 발육단계의 난포 사망기전을 연구하기 어렵다. 또한 난포는 생체 내에서 다양한 호르몬을 동시에 분비하기 때문에 특정한 난소국부호르몬이 사망기전에 미치는 영향을 조사하기 힘든 점이 있다. 최근 들어 난포체외배양이 다양하게 개발되면서, 이러한 어려운 점을 극복할 수 있게 되었다. 본 논문은 각 발육단계의 난포를 절단해 체외배양하면서, apoptosis DNA 절단 현상을 이용하여 각종 난소국부 호르몬들이 난포발육단계별로 사망기전에 미치는 영향을 요약해 보였다. 난포는 발육하면서 점차 복잡한 호르몬 경로를 생존을 위해 필요로 한다. Prevulatory난포생존에 필요한 난소국부호르몬들은 early antral 단계의 난포에서는 그 미치는 영향이 감소되다가 preantral단계의 난포에서는 영향을 전혀 미치지 못했다. 단지 예외는 cGMP처리로써, 세포내 cGMP수준을 일정하게 유지시켜주는 것이 난포발육단계에 무관하게 생존에 중요한 인자로, 장래 연구는 난포 세포내의 cGMP수준을 조절하는 기작을 규명하는데 있을 것이다.인정되지 않았다. 7. 농지보전 처리구인 배수구와 초생수로구는 비처리구에 비해 낮은 침두 유출량과 낮은 토양유실량을 나타내었다.구보다 14% 절감되는 것으로 나타났다.작용하는 것으로 사료된다.된다.정량 분석한 결과이다. 시편의 조성은 33.6 at% U, 66.4 at% O의 결과를 얻었다. 산화물 핵연료의 표면 관찰 및 정량 분석 시험시 시편 표면을 전도성 물질로 증착시키지 않고, Silver Paint 에 시편을 접착하는 방법으로도 만족한 시험 결과를 얻을 수 있었다.째, 회복기 중에 일어나는 입자들의 유입은 자기폭풍의 지속시간을 연장시키는 경향을 보이며 큰 자기폭풍일수록 현저했다. 주상에서 관측된 이러한 특성은 서브스톰 확장기 활동이 자기폭풍의 발달과 밀접한 관계가

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Effect of Green Microstructure on Sintered Microstructure and Mechanical Properties of Reaction-Bonded Silicon Carbide (성형미세구조가 반응소결 탄화규소체의 소결미세구조 및 기계적 특성에 미치는 영향)

  • 박현철;김재원;백운규;최성철
    • Journal of the Korean Ceramic Society
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    • v.36 no.1
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    • pp.97-105
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    • 1999
  • In the binary system of SiC and carbon, porosity and pore size distribution of green body was controlled by varying pH, by the addition of polyelectrolyte dispersants, and by using different particle size of starting powders. The preforms having different green microstructure were fabricated by slip casting from suspensions having different dispersion condition. The reaction bonding process was carried out for these preforms. The condition of reaction bonding was 1600$^{\circ}C$ and 20 min. under vacuum atmosphere. The analyses of optical and SEM were studied to investigate the effect of green microstructure on that of reaction bonded silicon carbide and subsequently the mechanical properties of sintered body was investigated. Different green microstructures were obtained from suspensions having different dispersion condition. It was found that the pore size could be remarkably reduced for a fine SiC(0.5$\mu\textrm{m}$). The bimodal microstructure was not found in the present study, which is frequently observed in the typical reaction bonded silicon carbide. It is considered that the ratio between SiC and C was responsible for the formation of bimodal microstructure. For the preform fabricated from the well dispersed suspension, the 3-point bending strength of reaction-bonded silicon carbide was 310${\pm}$40 MPa compared to the specimen fabricated from relatively agglomerated particles having lower value 260${\pm}$MPa.

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