• Title/Summary/Keyword: Porosity ceramics

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Porous Alumina/Mullite Layered Composites with Unidirectional Pore Channels and Improved Compressive Strength (일축배향 기공채널과 향상된 압축강도를 갖는 다공질 알루미나/뮬라이트 층상 복합체)

  • Kim, Kyu Heon;Kim, Tae Rim;Kim, Dong Hyun;Yoon, Seog Young;Park, Hong Chae
    • Journal of the Korean Ceramic Society
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    • v.51 no.1
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    • pp.19-24
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    • 2014
  • Three-layer porous alumina-mullite composites with a symmetric gradient porosity are prepared using a controlled freeze/gel-casting method. In this work, tertiary-butyl alcohol (TBA) and coal fly ash with an appropriate addition of $Al_2O_3$ were used as the freezing vehicle and the starting material, respectively. When sintered at $1300-1500^{\circ}C$, unidirectional macro-pore channels aligned regularly along the growth direction of solid TBA were developed. Simultaneously, the pore channels were surrounded by less porous structured walls. A high degree of solid loading resulted in low porosity and a small pore size, leading to higher compressive strength. The sintered porous layered composite exhibited improved compressive strength with a slight decrease in its porosity. After sintering at $1500^{\circ}C$, the layered composite consisting of outer layers with a 50 wt% solid loading showed the highest compressive strength ($90.8{\pm}3.7MPa$) with porosity of approximately 26.4%.

Studies on the Control of Porosity and Mean Pore Size in Cordierite Ceramics (Cordierite의 기공률 및 기공경조절에 관한 연구)

  • Yang, Jin
    • Journal of the Korean Ceramic Society
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    • v.35 no.4
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    • pp.399-405
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    • 1998
  • The effect of each factor on the porosity and mean pore size of cordierite(2Mg$.$2{{{{ {Al}_{2 } {O }_{3 } }}$.$5{{{{ {SiO}_{2 } }}) ceram-ics which have been mainly used for hot gas filter was investigated by using orthogonal array. The poros-ity was observed to increase with the content of graphite added as pore-forming material and decrease with increasing talc size. The effects of the other factors the graphite size sintering temperature and hold-ing time at sintering temperature were observed to be small relatively. In case of mean pore size the ef-fect of talc size on the mean pore size of cordierity was investigated to be the largest. The mean pore size was observed to increase with increasing talc size.

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Computer Simulation for Microstructure Development in Porous Sintered Compacts (다공질 소결체의 조직형성에 관한 컴퓨터 시뮬레이션)

  • Shin, Soon-Ki;Matsubara, Hideaki
    • Journal of the Korean Ceramic Society
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    • v.43 no.4 s.287
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    • pp.213-219
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    • 2006
  • A Monte Carlo simulation based on Potts model in a three dimensional lattice was studied to analyze and design microstructures in porous sintered compacts such as porosity, pore size, grain (particle) size and contiguity of grains. The effect of surface energy of particles and the content of additional fine particles to coarse particles on microstructure development were examined to obtain fundamentals for material design in porous materials. It has been found that the larger surface energy enhances sintering (necking) of particles and increases contiguity and surface energy does not change pore size and grain size. The addition of fine particles also enhances sintering of particles and increases contiguity, but it has an effect on increment of pore size and grain size. Such a simulation technique can give us important information or wisdom for design of porous materials, e.g., material system with high surface energy and fine particle audition are available for higher strength and larger porosity in porous sintered compacts with applications in an automobile.

Simulation and modeling for stability analysis of functionally graded non-uniform pipes with porosity-dependent properties

  • Peng Zhang;Jun Song;Tayebeh Mahmoudi
    • Steel and Composite Structures
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    • v.48 no.2
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    • pp.235-250
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    • 2023
  • The present paper examines the stability analysis of the buckling differentiae of the small-scale, non-uniform porosity-dependent functionally graded (PD-FG) tube. The high-order beam theory and nonlocal strain gradient theory are operated for the mathematical modeling of nanotubes based on the Hamilton principle. In this paper, the external radius function is non-uniform. In contrast, the internal radius is uniform, and the cross-section changes along the tube length due to these radius functions based on the four types of useful mathematical functions. The PD-FG material distributions are varied in the radial direction and made with ceramics and metals. The governing partial differential equations (PDEs) and associated boundary conditions are solved via a numerical method for different boundary conditions. The received outcomes concerning different presented parameters are valuable to the design and production of small-scale devices and intelligent structures.

Microwave Dielectric Properties of the 0.7Mg4Ta2O9-0.3SrTiO3 Ceramics with Sintering Temperature (소결온도에 따른 0.7Mg4Ta2O9-0.3SrTiO3 세라믹스의 마이크로파 유전특성)

  • Kim, Jae-Sik;Choi, Eui-Sun;Lee, Moon-Kee;Lee, Young-Hie;Bae, Seon-Gi
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.6
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    • pp.538-542
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    • 2005
  • The structural and microwave dielectric properties of $0.7Mg_4Ta_2O_9-0.3SrTiO_3$ ceramics with sintering temperature were investigated. All the sample of the $0.7Mg_4Ta_2O_9-0.3SrTiO_3$ ceramics were prepared by conventional miked oxide method and the sintering temperature was $1425\~1500^{\circ}C$. The hexagonal phase of $Mg_4Ta_2O_9$ and the cubic phase of $SrTiO_3$ were coexisted. The porosity of $0.7Mg_4Ta_2O_9-0.3SrTiO_3$ ceramics were reduced with increasing sintering temperature. In the case of $0.7Mg_4Ta_2O_9-0.3SrTiO_3$ ceramics sintered at $1475^{\circ}C$, dielectric constant, quality factor and temperature coefficient of resonant frequency were 14.51, 82,596 GHz and $-3.14\;ppm/^{\circ}C$, respectively.

Fabrication of porous clay ceramics using sufactant (계면활성제를 이용한 점토질 다공체 세라믹스 제조에 관한 연구)

  • 김윤주;배옥진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.1
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    • pp.56-61
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    • 2002
  • Porous clay ceramics was fabricated using the surfactant as a foaming agent in the secondary-clay produced at Young-Am area in Chun-Nam province. The concentration of surfactant in ceramic slurry was the key factor controlling the pore characteristics and physical properties of the porous ceramics. The more increase of the surfactant concentration increase the more foaming ability and the stability of foamed layer were improved, but the foaming ability was limited within 6.0 wt% of surfactant because the initial viscosity of the slurry increased with increasing the amounts of surfactant. The formed specimen were sintered at both $1150^{\circ}C$ and $1200^{\circ}C$, the porous ceramics showed 0.9 of specific gravity, 50% of water absorption, 45% of apparent porosity, 14% of shrinkage and 70 kg/$\textrm{cm}^2$ of compressive strength.

Synthesis of Microcellular Cordierite Ceramics Derived from a Preceramic Polymer (Preceramic Polymer를 이용한 마이크로셀룰라 코디어라이트 세라믹스의 합성)

  • Song, In-Hyuck;Kim, Young-Mi;Kim, Hai-Doo;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.44 no.5 s.300
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    • pp.184-189
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    • 2007
  • In this study, a novel-processing route for producing microcellular cordierite ceramics has been developed. The proposed strategy for making the microcellular cordierite ceramics involves three steps: (i) fabricating ceramic-filled preceramic foams by heating a mixture of polysiloxane, expandable microspheres, talc, and alumina in a mold, (ii) cross-linking the foamed body, and (iii) transforming the body into microcellular cordierite ceramics by sintering. Cu jig was used for near net shaping in the foaming step. The experimental variables such as the shape of foaming jig and the content of expendable microsphere were investigated. By controlling the content of expendable microsphere, it was possible to make the porous cordierite ceramics with cell density of ${\sim}1.0{\times}10^9\;cells/cm^3$.

Properties and Synthesis of Porous Cordierite from Fly Ash (플라이 애쉬를 이용한 다공성 코디어라이트의 합성 및 특성)

  • Kim, Sung-Jin;Bang, Hee-Gon;Park, Sang-Yeup
    • Journal of the Korean Ceramic Society
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    • v.43 no.6 s.289
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    • pp.344-350
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    • 2006
  • Porous cordierite was synthesized by the mechano-chemical processing using fly ash. The phase evolution of cordierite was investigated as a function of processing variables such as milling time and sintering temperature. In this study, the phase transition path of cordierite from fly ash was followed by sapprine/spinel ${\to}$ mullite/spinel ${\to}{\alpha}$-cordierite. Porous cordierite fabricated after 32 h of milling time and sintering at $1150^{\circ}C$ showed relatively low thermal expansion coefficient ($2.5{\times}10^{-6}/^{\circ}C\;(25{\sim}1000^{\circ}C$)) and high porosity (75%).