• Title/Summary/Keyword: Pore structures

Search Result 516, Processing Time 0.028 seconds

Evaluation on Durability of High Performance Concrete with Expansive Additive and Shrinkage Reducing Admixture (팽창재와 수축저감제를 사용한 고성능 콘크리트의 내구성 평가)

  • Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Ryu, Gum-Sung
    • Journal of the Korea Concrete Institute
    • /
    • v.18 no.2 s.92
    • /
    • pp.205-211
    • /
    • 2006
  • The objective of this study was to evaluate the durability of low shrinkage high performance concrete(LSHPC), which was combined with expansive additives and shrinkage reducing admixtures. We tested for not only LSHPC but also high performance concrete(HPC) and normal concrete(NC) to be compared with the durability of LSHPC. HPC was made in the same water-binder ratio of LSHPC without expansive additives and shrinkage reducing admixture. As a result, it was found that LSHPC had higher compressive and tensile strength than that of HPC. LSHPC showed more excellent performance than HPC and NC in the case of resistance to chloride ion penetration and resistance to carbonation and also showed nearly 100 durability factor in the freeze-thawing test with 500 cycles. From the examination about the watertightness and the pore distribution, it was found that the durability of LSHPC was improved because its hardened cement paste is organized closer. So we can conclude that when LSHPC is applied to structures in field, it is possible to reduce the shrinkage and crack in concrete and improve the durability.

Numerical Analysis on Settlement Behavior of Seabed Sand-Coastal Structure Subjected to Wave Loads (파압에 의한 해안구조물-해저지반의 침하거동에 대한 수치해석)

  • Kang, Gi-Chun;Yun, Seong-Kyu;Kim, Tae-Hyung;Kim, Dosam
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.25 no.1
    • /
    • pp.20-27
    • /
    • 2013
  • Seabed settlement underneath a coastal structure may occur due to wave loading generated by storm surge. If the foundation seabed consists of sandy soil, the possibility of the seabed settlement may be more susceptible because of generation of residual excess pore-water pressure and cyclic mobility. However, most coastal structures, such as breakwater, quay wall, etc., are designed by considering wave load assumed to be static condition as an uniform load and the wave load only acts on the structure. In real conditions, however, the wave load is dynamically applied to seabed as well as the coastal structure. In this study, therefore, a real-time wave load is considered and which is assumed acting on both the structure and seabed. Based on a numerical analysis, it was found that there exists a significant effect of wave load on the structure and seabed. The deformation behavior of the seabed according to time was simulated, and other related factors such as the variation of effective stress and the change of effective stress path in the seabed were clearly observed.

Geochemical and Geophysical Characteristics of Shallow Gases in the Deep Sea Sediments, Southwestern Ulleung Basin (울릉분지 남서부 심해저 퇴적층에 분포하는 천부 가스의 지화학 및 지구물리 특성)

  • 김일수;이영주;유동근;류병재
    • Economic and Environmental Geology
    • /
    • v.36 no.3
    • /
    • pp.149-157
    • /
    • 2003
  • Deep sea core samples were taken in the southwestern part of the Ulleung Basin in order to characterize the properties of shallow gases in the sediment. Amount of shallow gases in the sediments were calculated by head space techniques, and chemical and isotopic compositions of hydrocarbon gases were analyzed. Geochemical analyses were carried out on the gas bearing sediments to find out relationship between natural gas contents and organic characteristics of the sediments. Seismic characteristics of shallow gases in the sediments were also examined in this study. The amount of the hydrocarbon gases in the sediments range from 0.01% to 11.25%. Calculation of volume of gas per volume of wet sediment varies from 0.1 to 82.0 ml HC/L wet sediment. Methane consists 98% of the total hydrocarbon gases except for two samples. Based on the methane content and isotopic composition$(\delta^{13}c)$: -94.31$\textperthousand$~-55.5$\textperthousand$), the hydrocarbon gases from the sediments are generated from bacterial activities of methanogenic microbes. Contents of hydrocarbon gases are variable from site to site. Volume of shallow gases in the sediments shows no apparent trends vs. either characteristics of organic matter or particle sizes of the sediments. Gas concentration is high in the area of seismic anomalies such as blanking zone or chimney structures in the section. Physicochemically the pore water and the formation water systems are saturated with gases in these areas. Concentration of hydrocarbon gases in the sediments in these area shows favorable condition for generation of gas hydrate, as far as the other conditions are satisfied.

Effects of Solvent on the Fabrication of Poly(L-lactide) Scaffold Membranes through Phase Inversion (상전이를 통한 Poly(L-lactide) 스캐폴드 막의 제조에서의 용매의 효과)

  • Cho, Yu Song;Kim, Young Kyoung;Koo, Ja-Kyung;Park, Jong Soon
    • Membrane Journal
    • /
    • v.24 no.2
    • /
    • pp.113-122
    • /
    • 2014
  • Porous poly(L-lactic acid)(PLLA) scaffold membranes were prepared via. phase separation process. Chloroform, dichloromethane and 1,4-dioxane were used as solvent and, ethyl alcohol was used as non-solvent. Morphologies, mechanical properties and mass transfer characteristics of the scaffold membranes were investigated through SEM, stress-strain test and glucose diffusion test. The scaffold membranes obtained from the casting solutions with chloroform and with dichloromethane showed similar morphologies. They showed sponge-like porous structure with the pore size in the range of $3-10{\mu}m$ and, their porosities were in 50-80% range. Using 1,4-dioxane as solvent, nano-fibrous scaffold membranes with porosities over 80% were fabricated. When the polymer content in the solution with 1,4-dioxane was lowered to 4%, highly porous, macroporous and nano-fibrous scaffold membranes were obtained. The size of the macropore was tens of the microns and the porosity was around 90%. These results indicate that the solvent has significant effect on the scaffold membrane structure and, that scaffold membranes with various structures can be fabricated through phase separation method by choosing solvent and by controlling polymer concentration in the casting solution.

Analysis on the Safety of Structure and Economics of Replacement Method Using Rock Debris in the Soft Ground - Case Study of Miho Stream Crossing Road in Cheongju City (연약지반 암버럭 치환공법의 구조물 안정성과 경제성 분석 - 청주시 미호천 횡단도로를 대상으로)

  • Heo, Kang Kug;Park, Hyung Keun;Ahn, Byung Chul;Min, Byeong Uk
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.36 no.4
    • /
    • pp.705-713
    • /
    • 2016
  • For the soft ground construction, the factors not considered in the design stage occurs in the construction stage so that they cause the increase of the construction cost due to the structural stability and the design change. The subject of the study is the construction section of the industrial complex access road made in the Ochang region of Chungcheongbuk-do. The study is concerned with selecting the soft ground handling method such as the replacement method using rock debris and the surcharge reflecting the service load as the soft ground handling measure and analyzing the effect of reducing the construction cost with the stability of structures and the reduction of the construction period. The soft ground in the study section consists of sandy and cohesive soil and is 2.4m to 5.5m deep. It is distributed unevenly between the 1.5m to 5.9m stratums under the ground surface. Settlement is not serious, but the future uneven settlement and difference are expected so that the future settlement behavior is estimated by analyzing the site measurement results after the soft ground treatment. Moreover, in consideration of the regional characteristics and economic efficiency, soil with good quality is replaced with rock debris as the replacement material so that 29% of the construction cost is reduced due to the increase of stability and the reduction of duration. If the estimation of the dispersion of the pore water pressure within the dam body and the change of the underground water level and the relation of the actually measured soft ground with consolidation is studied further on the basis of the study, it is expected that the behavior of the soft ground will be correctly estimated in various site conditions.

Formation Processes of Fault Gouges and their K-Ar Ages along the Dongnae Fault (동래단층 지역 단층비지의 생성과정과 K-Ar 연령)

  • 장태우;추창오
    • The Journal of Engineering Geology
    • /
    • v.8 no.2
    • /
    • pp.175-188
    • /
    • 1998
  • This paper describes the internal structures and K-Ar ages of fault gouges collected from the Dongnae fault zone. This fault zone is internally zoned and occurs in the multiple fault cores. A fault core consists of thin gouge and narrow cataclastic zones that are bounded by a much thicker damage zone. Intensity of deformation and alteration increases from damage zone through cataclastic zone to gouge zone. It is thought that cataclasis of brittle deformation was the dominant strain-accomodation mechanism in the early stage of deformation to form the gouge zone and that crushed materials in the regions of maximum localization of fault slip subsequently moved by cataclastic flow. Deformation mechanism drastically changed from brittle processes to fluid-assisted flow along the gouge zone as the high porosity and permeability of pulverzied materials during faulting facilitated the influx of the hydrothermal fluids. Subsequently, the fluids reacted with gouge materials to form clay minerals. Fracturing and alteration could have repeatedly taken place in the gouge zone by elevated fluid pressures generated from the reduction of pore volume due to the formation of clay minerals and precipitation of other materials. XRD analysis revealed that the most common clay minerals of the gouge zones are illite and smectite with minor zeolite and kaolinite. Most of illites are composed of 1Md polytype, indicating the products of hydrothermal alteration. The major activities of the Dongnae fault can be divided into two periods based upon K-Ar age data of the fault gouges : 51.4∼57.5Ma and 40.3∼43.6Ma. Judging from the enviromental condition of clay mineral formation, it is inferred that the hydrothermal alteration of older period occured at higher temperature than that of younger period.

  • PDF

Developing an improved water discharge anchor & trap bolt to prevent basic salt penetration to harbor structures (해수 염기 침투방지를 위한 성능개선 형 물배출 앵커 및 트랩볼트 개발에 관한 연구)

  • Ock, Jong-Ho;Moon, Sang-Deok;Lee, Hwa-Sun;Shin, Kyung-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.19 no.4
    • /
    • pp.674-682
    • /
    • 2018
  • Large industrial motors require a large area because of the high risk of shutdown accidents and large industrial accidents due to the lowering of the dielectric strength of the armature windings and overheating problems. Therefore, there is a demand for a large-capacity motor that has small size, light weight, and excellent dielectric strength compared with conventional motors. Superconducting motors have advantages of high efficiency and output power, low size, low weight, and improved stability. This results from greatly increasing the magnetic field generation by using superconductive field coils in rotating machines such as generators and motors. It is very important to design and analyze the cooling system to lower the critical temperature of the wires to achieve superconducting performance. In this study, a field loss analysis and low-temperature heat transfer analysis of the cooling system were performed through the conceptual design of a 100-HP high-temperature superconducting synchronous motor. The field loss analysis shows that a uniform pore magnetic flux density appears when high-temperature superconducting wire is used. The low-temperature heat transfer analysis for gaseous neon and liquid neon showed that a flow rate of 1 kg/min of liquid neon is suitable for maintaining low-temperature stability of the high-temperature superconducting wire.

Characterization of the PVDF Fibers Fabricated by Hybrid Wet Spinning (하이브리드 습식 공정을 통한 PVDF 섬유의 제조 및 특성에 관한 연구)

  • Jeong, Kun;Kim, Seong-Su
    • Composites Research
    • /
    • v.29 no.4
    • /
    • pp.145-150
    • /
    • 2016
  • Polyvinylidene fluoride (PVDF) as a representative polymer with the piezoelectric property has been studied since the 1960s. Crystalline structure of poly(vinylidene fluoride) polymer is composed of five different crystal structure of the polymer as a semi-crystalline. Among the various crystal structures, ${\beta}-type$ crystal exhibits a piezoelectricity because the permanent dipoles are aligned in one direction. Generally ${\beta}-form$ crystal structure can be obtained through the transformation of the ${\alpha}-form$ crystal structure by the stretching and it can increase the amount through the after treatment as poling process after stretching. ${\beta}-form$ crystal structure the PVDF fibers produced by wet spinning is formed through a diffusion mechanism of a polar solvent in the coagulation bath. However, it has a disadvantage that the diffusion path of the solvent remains as pores in the fiber because the fiber solidification occurs simultaneously with the diffusion of the polar solvent. These pores play a role in reducing effect of poling process owing to effect of disturbances acting on the polarization by the electric field. In this work, the drying method using the microwave was introduced to remove more effectively the residual solvent and the pore within PVDF fibers produced through wet-spinning process and piezoelectric PVDF fibers was produced by transformation of the remaining ${\alpha}$ form crystal structure into ${\beta}-crystal$ structure through the stretching process.

Formation Mechanism of Pores in Ni-P Coated Carbon Fiber Prepared by Electroless Plating Upon Annealing (무전해 니켈-인 도금법을 이용하여 도금된 탄소 섬유의 열처리 과정에서 나타나는 다공성 구조 생성 메커니즘 분석)

  • Ham, Seung Woo;Sim, Jong Ki;Kim, Young Dok
    • Applied Chemistry for Engineering
    • /
    • v.24 no.4
    • /
    • pp.438-442
    • /
    • 2013
  • In the present work, electroless plating was used for coating thin films consisting mainly of Ni and P on carbon fiber. Structural changes appeared upon the post-annealing at various temperatures of the Ni-P film on carbon fiber was studied using various analysis methods. Scanning, a flat surface structure of Ni-P film on carbon fiber was found after electroless plating of Ni-P film on carbon fiber without post-annealing, whereas annealing at $350^{\circ}C$ resulted the formation of porous structures. With increasing the annealing temperature to $650^{\circ}C$ with an interval of $50^{\circ}C$, the pore size increased, but the density decreased. X-ray diffraction (XRD) showed the existence of metallic Ni, and Ni-P compounds before post-annealing, whereas the post-annealing resulted in the appearance of NiO peaks, and the decrease in the intensity of the peak of metallic Ni. Using X-ray photoelectron spectroscopy (XPS), phosphorous oxides were detected on the surface upon annealing at $650^{\circ}C$, and $700^{\circ}C$, which can be attributed to the phosphorous compounds originally existing in the deeper layers of the Ni films, which undergo sublimation and escape from the film upon annealing. Escape of phosphorous species from the bulk of Ni-P film upon annealing could leave a porous structure in the Ni films. Porous materials can be of potential applications in diverse fields due to their interesting physical properties such as high surface area, and methods for fabricating porous Ni films introduced here could be easily applied to a large-scale production, and therefore applicable in diverse fields such as environmental filters.

Geophysical Investigation of Gas Hydrate-Bearing Sediments in the Sea of Okhotsk (오호츠크해 가스하이드레이트 퇴적층의 지구물리 탐사)

  • Jin, YoungKeun;Chung, KyungHo;Kim, YeaDong
    • Journal of the Korean Geophysical Society
    • /
    • v.7 no.3
    • /
    • pp.207-215
    • /
    • 2004
  • As the sea connecting with the East Sea, the Sea of Okhotsk is the most potential area of gas hydrates in the world. In other to examine geophysical structures of gas hydrate-bearing sediments in the Sea of Okhotsk, the CHAOS (hydro-Carbon Hydrate Accumulation in the Okhotsk) international research expedition was carried out in August 2003. In the expedition, high-resolution seismic and geochemical survey was also conducted. Sparker seismic profiles show only diffusive high-amplitude reflections without BSRs at BSR depth. It means that BSR appears to be completely different images on seismic profiles obtained using different frequencies. Many gas chimneys rise up from BSR depth to seafloor. The chimneys can be divided into two groups with different seismic characteristics; wipe-out (WO) and enhanced reflection (ER) chimneys. Different seismic responses in the chimneys would be caused by amount of gas and gas hydrates filling in the chimneys. In hydroacoustic data, a lot of gas flares rise up several hundreds meters from seafloor to the water column. All flares took placed at the depths within gas hydrate stability zone. It is interpreted that gas hydrate-bearing sediments with low porosity and permeability due to gas hydrate filling in the pore space make good pipe around gas chimneys in which gas is migrating up without loss of amount. Therefore, large-scale gas flare at the site on gas chimney releases into the water column.

  • PDF