• Title/Summary/Keyword: Pore rate

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Experimental Study on Corrosion Rate in Concrete

  • Jang, BongSeok;Oh, ByungHwan
    • Corrosion Science and Technology
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    • v.3 no.1
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    • pp.34-38
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    • 2004
  • The corrosion of reinforcement is a very important factor on the serviceability and safety of reinforced concrete structures. The corrosion rate influences directly the cover failure time of reinforced concrete structures because the corrosion rate is used to estimate the amount of corrosion and thus expansive pressure due to corrosion. In this study, several series of experiments are performed considering the chloride concentration in artificial pore solution. The potentials are measured according to the applied current density and then corrosion current densities are obtained from the Tafel plot for various chloride concentrations. The measured corrosion rates show good correlation with those of other researchers.

Fabrication of Macro-porous Carbon Foams from Spherical Phenolic Resin Powder and Furfuryl Alcohol by Casting Molding (구상 페놀수지 분말과 푸르프릴 알코올로부터 주형성형에 의한 매크로 다공성 카본 폼의 제조)

  • Jeong, Hyeondeok;Kim, Seiki
    • Journal of Powder Materials
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    • v.26 no.6
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    • pp.502-507
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    • 2019
  • Macro-porous carbon foams are fabricated using cured spherical phenolic resin particles as a matrix and furfuryl alcohol as a binder through a simple casting molding. Different sizes of the phenolic resin particles from 100-450 ㎛ are used to control the pore size and structure. Ethylene glycol is additionally added as a pore-forming agent and oxalic acid is used as an initiator for polymerization of furfuryl alcohol. The polymerization is performed in two steps; at 80℃ and 200℃ in an ambient atmosphere. The carbonization of the cured body is performed under Nitrogen gas flow (0.8 L/min) at 800℃ for 1 h. Shrinkage rate and residual carbon content are measured by size and weight change after carbonization. The pore structures are observed by both electron and optical microscope and compared with the porosity results achieved by the Archimedes method. The porosity is similar regardless of the size of the phenolic resin particles. On the other hand, the pore size increases in proportion to the phenol resin size, which indicates that the pore structure can be controlled by changing the raw material particle size.

Investigation on Relationship Between Pore Structure of Coating Layer and Ink Residual Behavior - Focused on the Effect of Pigments and Inks - (도공층의 공극성이 인쇄후 잉크의 잔류 거동에 미치는 영향 - 안료와 잉크의 효과 -)

  • 김병수;정현채;박종열
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.3
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    • pp.53-58
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    • 2002
  • This paper was performed to investigate the effect of pore structure on ink residual behavior. To prepare different coating structures as substrates against inks, fine, medium and coarse calcium carbonate were used in the coating color. It is well known ink properties can affect to print qualities. After printing on the coated paper, ink layer can consider as third structure addition to paper and coating layer. To compare effect of ink properties on the surface structure and print qualities, several properties of ink were also adopted as raw material. Particle size of pigment effect on gloss evaluation of coated paper increased with calendering. It was shown that ink transfer rate increased as surface of the sample was smooth. The ink contained low viscosity resin evaluated more print gloss. Finer pigment particle size, smaller pore size and higher porosity. Pore volume of coated paper was slightly decreased with printing as the coating was prepared with the finest particle size. However, it founded that ink resin could not affect on pore volume and distribution of printed paper

Analysis of permeability in rock fracture with effective stress at deep depth

  • Lee, Hangbok;Oh, Tae-Min;Park, Chan
    • Geomechanics and Engineering
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    • v.22 no.5
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    • pp.375-384
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    • 2020
  • In this study, the application of conventional cubic law to a deep depth condition was experimentally evaluated. Moreover, a modified equation for estimating the rock permeability at a deep depth was suggested using precise hydraulic tests and an effect analysis according to the vertical stress, pore water pressure and fracture roughness. The experimental apparatus which enabled the generation of high pore water pressure (< 10 MPa) and vertical stress (< 20 MPa) was manufactured, and the surface roughness of a cylindrical rock sample was quantitatively analyzed by means of 3D (three-dimensional) laser scanning. Experimental data of the injected pore water pressure and outflow rate obtained through the hydraulic test were applied to the cubic law equation, which was used to estimate the permeability of rock fracture. The rock permeability was estimated under various pressure (vertical stress and pore water pressure) and geometry (roughness) conditions. Finally, an empirical formula was proposed by considering nonlinear flow behavior; the formula can be applied to evaluations of changes of rock permeability levels in deep underground facility such as nuclear waste disposal repository with high vertical stress and pore water pressure levels.

Limit analysis of rectangular cavity subjected to seepage forces based on Hoek-Brown failure criterion

  • Yang, X.L.;Qin, C.B.
    • Geomechanics and Engineering
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    • v.6 no.5
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    • pp.503-515
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    • 2014
  • On the basis of Hoek-Brown failure criterion, a numerical solution for the shape of collapsing block in the rectangular cavity subjected to seepage forces is obtained by upper bound theorem of limit analysis. The seepage forces obtained from the gradient of excess pore pressure distribution are taken as external loadings in the limit analysis, and the pore pressure is easily calculated with pore pressure coefficient. Thus the seepage force is incorporated into the upper bound analysis as a work rate of external force. The upper solution of the shape of collapsing block is derived by virtue of variational calculation. In order to verify the validity of the method proposed in the paper, the result when the pore pressure coefficient equals zero, and only hydrostatic pressure is taken into consideration, is compared with that of previous work. The results show good effectiveness in calculating the collapsing block shape subjected to seepage forces. The influence of parameters on the failure mechanisms is investigated.

Microstructural Changes of AlOOH Doped $UO_2$ Pellet during the Annealing Process

  • Hosik Yoo;Lee, Shinyoung;Lee, Seungjae;Kwenho Kang;Kim, Hyoungsu
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.209-213
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    • 2000
  • Microstructural changes of AlOOH doped UO$_2$pellet after annealing up to 216h have been observed and they were compared with those of the standard pellet. Grain and pore size of UO$_2$pellet increased with the addition of AlOOH and its effect was still validated during annealing. Densification rate was reduced by the addition of AlOOH and it was attributed to coarsened pores with spherical shape. Grain and pore growth was stopped and density increase was the least after 144h of annealing. The variation of pore size resulting from annealing has a linear relationship with that of grain size.

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Thermal stress and pore pressure development in microwave heated concrete

  • Akbarnezhad, A.;Ong, K.C.G.
    • Computers and Concrete
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    • v.8 no.4
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    • pp.425-443
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    • 2011
  • Most previous studies have generally overlooked the contribution of thermal stresses generated within the concrete mass when subjected to microwave heating and reported on pore-pressure as being the dominant cause of surface spalling. Also, the variation in electromagnetic properties of concrete and its effects on the microwave heating process have not been studied in detail. In this paper, finite element modeling is used to examine the simultaneous development of compressive thermal stresses and pore-pressure arising from the microwave heating of concrete. A modified Lambert's Law formulation is proposed to estimate the microwave power dissipation in the concrete mass. Moreover, the effects of frequency and concrete water content on the concrete heating rate and pattern are investigated. Results show high compressive stresses being generated especially in concrete with a high water content when heated by microwaves of higher frequencies. The results also reveal that the water content of concrete plays a crucial role in the microwave heating process.

Study on the Time Dependent Stress-Strain Behavior of Clay (점성토의 시간의존적 응력 - 변형 특성에 관한 연구)

  • 지인택;강우묵
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.30 no.4
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    • pp.134-153
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    • 1988
  • This paper was carried out to investigate the existence of a unique stress- strain behavior by obtaining some factors influencing the time dependent stress- strain behavior of clay. The results obtained from this study were summarized as follows ; 1. The relationship between stress ratro and strain in normally consolidated clay was in- dependent on pre-shear consolidation pressure. Therefore, shear strain could be expressed as a function with stress ratio. 2. The constitutive equation of shear strain on Modified Carn Clay Model coincided better with the observed value than Cam Clay Model. 3. The relationships between deviator stress and shear strain, between pore water pressure and shear strain were unified by the mean equivalent pressure. 4. The shear strain contour in norrnally consolidated clay was increased linearly through origin, but that in overconsolidated clay was not in accordance with the result of the former. 5. Because the effective stress path of normally consolidated clay was unified by the mean equivalent pressure, state boundary surface in (e,p,q) space was transformed into two dimensional surface. But it was considered to be suitable that the unified stress- strain in overconsolidated clay be expressed by a function with overconsolidation ratio. 6. The deviator for constant strain was increased linearly with increment of strain rate ($\varepsilon$) on semi-log scale, but pore water pressure was decreased. 7. The behavior of stress relaxation was transformed from linear to curvilinear with inc - rement of strain rate before stress relaxation test, and pore water pressure was increased in total range. 8. The strain of creep was increased linearly with increment of time on semi-log scale. The greater the strain rate before creep test became, the greater the increment of strain of creep became. And the pore water pressure during creep test was increased generally with increment of time on semi-log scale.

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Fragmentation and energy absorption characteristics of Red, Berea and Buff sandstones based on different loading rates and water contents

  • Kim, Eunhye;Garcia, Adriana;Changani, Hossein
    • Geomechanics and Engineering
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    • v.14 no.2
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    • pp.151-159
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    • 2018
  • Annually, the global production of construction aggregates reaches over 40 billion tons, making aggregates the largest mining sector by volume and value. Currently, the aggregate industry is shifting from sand to hard rock as a result of legislation limiting the extraction of natural sands and gravels. A major implication of this change in the aggregate industry is the need for understanding rock fragmentation and energy absorption to produce more cost-effective aggregates. In this paper, we focused on incorporating dynamic rock and soil mechanics to understand the effects of loading rate and water saturation on the rock fragmentation and energy absorption of three different sandstones (Red, Berea and Buff) with different pore sizes. Rock core samples were prepared in accordance to the ASTM standards for compressive strength testing. Saturated and dry samples were subsequently prepared and fragmented via fast and dynamic compressive strength tests. The particle size distributions of the resulting fragments were subsequently analyzed using mechanical gradation tests. Our results indicate that the rock fragment size generally decreased with increasing loading rate and water content. In addition, the fragment sizes in the larger pore size sample (Buff sandstone) were relatively smaller those in the smaller pore size sample (Red sandstone). Notably, energy absorption decreased with increased loading rate, water content and rock pore size. These results support the conclusion that rock fragment size is positively correlated with the energy absorption of rocks. In addition, the rock fragment size increases as the energy absorption increases. Thus, our data provide insightful information for improving cost-effective aggregate production methods.

Influence of Carbon Fiber on Corrosion Behavior of Carbon Steel in Simulated Concrete Pore Solutions

  • Tang, Yuming;Dun, Yuchao;Zhang, Guodong;Zhao, Xuhui;Zuo, Yu
    • Corrosion Science and Technology
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    • v.16 no.4
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    • pp.175-182
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    • 2017
  • Galvanic current measurement, polarization curves, electrochemical impedance spectroscopy and weight loss test were used to study the corrosion behavior of carbon steel before and after carbon fibers coupling to the carbon steel in simulated concrete pore solutions, and the film composition on the steel surface was analyzed using XPS method. The results indicate that passive film on steel surface had excellent protective property in pore solutions with different pH values (13.3, 12.5 and 11.6). After coupling with carbon fibers (the area ratio of carbon steel to carbon fiber was 12.31), charge transfer resistance $R_{ct}$ of the steel surface decreased and the $Fe^{3+}/Fe^{2+}$ value in passive film decreased. As a result, stability of the film decreased and the corrosion rate of steel increased. Decreasing of the area ratio of steel to carbon fiber from 12.3 to 6.15 resulted in the decrease in $R_{ct}$ and the increase in corrosion rate. Especially in the pore solution with pH 11.6, the coupling leads the carbon steel to corrode easily.