• Title/Summary/Keyword: Pore Control

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The Development of Rail-Transport Operation Control using the Variation of Slope Stability under Rainfall (강우시 사면안전율 변화를 이용한 열차운전규제기준 개발)

  • Kim, Hyun-Ki;Lee, Jin-Wook;Shin, Min-Ho
    • Proceedings of the KSR Conference
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    • 2003.10b
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    • pp.397-402
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    • 2003
  • Infiltration of rainfall causes railway embankment to be unstable and may result in failure. Basic relationship between the rainfall and stability of railway embankment are defined to analyze the stability of embankment by rainfall. An experimental study for defining of infiltration rate of rainfall into slope is conducted in the lab. The results of Rainfall infiltration show that rainfall infiltration is not equal to infiltration as like reservoir because rate of rainfall infiltration is controlled by slope angle. Based on these results, boundary condition of rainfall is altered and various numerical analysis are performed. The variation of shear strength, the degree of saturation and pore-water pressure for railway slope during rainfall can be predicted and the safety factor of railway slope can be expressed as the function of rainfall amount, namely rainfall index. Therefore, it is judged that this rainfall index can be a good tool for the rail-transport operation control.

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Effects of Heat Treatments of Aluminum Substrate on Nanopore Arrays in Anodic Alumina (열처리가 알루미나 나노기공의 배열에 미치는 영향)

  • Cho, S.H.;Oh, H.J.;Kim, S.S.;Joo, E.K.;Yoo, C.W.;Chi, C.S.
    • Korean Journal of Materials Research
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    • v.12 no.11
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    • pp.856-859
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    • 2002
  • To investigate effects of heat treatments including grain size control in substrate aluminum on nanopore arrays in anodic alumina template, aluminum was heat treated at $500^{\circ}C$ for 1h. The heat treated aluminum was anodized by two successive anodization processes in oxalic solution and the nanopore arrays in anodic alumina layer were studied using TEM and FE-SEM. The highly ordered porous alumina templates with 110 nm interpore distance and 40 nm pore diameter have been observed and the pore array of the anodic alumina has a uniform and closely-packed honeycomb structure. In the case of alumina template obtained from heat treated aluminum substrate, the well- ordered nanopore region in anodic alumina increased and became more homogeneous compared with that from non-heattreated one.

High-energy-density activated carbon electrode for organic electric-double-layer-capacitor using carbonized petroleum pitch

  • Choi, Poo Reum;Kim, Sang-Gil;Jung, Ji Chul;Kim, Myung-Soo
    • Carbon letters
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    • v.22
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    • pp.70-80
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    • 2017
  • Activated carbons (ACs) have been used as electrode materials of electric double-layer capacitors (EDLC) due to their high specific surface areas (SSA), stability, and ecological advantages. In order to make high-energy-density ACs for EDLC, petroleum pitch (PP) pre-carbonized at $500-1000^{\circ}C$ in $N_2$ gas for 1 h was used as the electrode material of the EDLC after KOH activation. As the pre-carbonization temperature increased, the SSA, pore volume and gravimetric capacitance tended to decrease, but the crystallinity and electrode density tended to increase, showing a maximum volumetric capacitance at a medium carbonization temperature. Therefore, it was possible to control the crystalline structure, SSA, and pore structure of AC by changing the pre-carbonization temperature. Because the electrode density increased with increasing of the pre-carbonization temperature, the highest volumetric capacitance of 28.4 F/cc was obtained from the PP pre-carbonized at $700^{\circ}C$, exhibiting a value over 150% of that of a commercial AC (MSP-20) for EDLC. Electrochemical activation was observed from the electrodes of PP as they were pre-carbonized at high temperatures above $700^{\circ}C$ and then activated by KOH. This process was found to have a significant effect on the specific capacitance and it was demonstrated that the higher charging voltage of EDLC was, the greater the electrochemical activation effect was.

Preparation and Characterization of Plasmid DNA Encapsulated in Liposomes (플라스미드 유전자를 함유한 리포좀의 제조 및 특성)

  • Park, Hyo-Min;Chung, Soo-Yeon;Go, Eun-Jung;Lee, Hwa-Jeong
    • Journal of Pharmaceutical Investigation
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    • v.33 no.3
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    • pp.209-213
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    • 2003
  • The objective of this study was to construct the pegylated liposomes containing plasmid DNA with optimal encapsulation efficiency. Plasmid DNA $(pGL2\;clone\;753,\;{\sim}6\;kb)$ was encapsulated by the freeze/thawing method into liposomes composed of 1-palmitoyl-2-oleyl-sn-glycerol-3-phosphocholine (POPC), didodecyl dimethyl ammonium bromide (DDAB), distearoylphosphatidyl ethanolamine polyethylene glycol 2000 (DSPE-PEG 2000) and DSPE-PEG 2000-male-imide. The liposomes containing plasmid DNA were then extruded through two stacked polycarbonate filters with series of different pore sizes to control the liposome size. The plasmid DNA entrapped in the liposomes was separated from free plasmid DNA by Sephadex CL-4B column chromatography. The decreased pore size of polycarbonate filters resulted in the decreased size of liposomes. The encapsulation efficiency was markedly affected by the cationic lipid (DDAB) concentration, but to a low degree by the size of liposomes and by the amount of plasmid DNA.

Effect of Strontium Carbonate Content on Flexural Strength of Clay-Based Membrane Supports

  • Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.467-472
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    • 2015
  • The effect of $SrCO_3$ content on the microstructure, porosity, flexural strength, and pore size distribution of clay-based membrane supports was investigated. Green compacts prepared from low cost materials such as kaolin, bentonite, talc, sodium borate, and strontium carbonate were sintered at $1000^{\circ}C$ for 8 h in air. It was possible to control the porosity of the clay-based membrane supports within the range of 33% to 37% by adjusting the $SrCO_3$ content. The flexural strength of the clay-based membrane supports was found to strongly depend on their porosity. In turn, the porosity was affected by the $SrCO_3$ content. The average pore size and flexural strength of the clay-based membrane supports containing 4 wt% $SrCO_3$ were $0.62{\mu}m$ and 33 MPa at 34% porosity.

A Study on the Reaction Characteristics of Steam Reforming Reaction over Catalyzed Porous Membrane (다공성 촉매 분리막을 이용한 수증기 개질 반응 특성 연구)

  • Hong, Sung Chang;Lee, Sang Moon
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.198-203
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    • 2014
  • In this study, steam reforming reaction and surface characteristics of Ni metal foam plate were investigated. Valence state of Ni could be changed by pretreatment, and metallic Ni species exposed on surface as a active site play important role in steam reforming reaction. Porous catalytic membrane also was prepared by mixing of Ni metal foam plate and Ni-YSZ catalyst to control the pore size and assign the catalytic function in Ni metal foam plate. In SEM analysis results, Pore size of Ni metal foam plate could be controlled and Ni-YSZ catalyst well dispersed on surface. Ni based porous catalytic membrane had a similar steam reforming activity regardless of space velocity.

Geochemical Investigation of Fluoride Migration in the Soil Affected by an Accidental Hydrofluoric Acid Leakage (불산 누출사고 지역 토양수의 지구화학적 특성을 통한 불소 거동 및 확산 잠재성 연구)

  • Kwon, Eunhye;Lee, Hyun A;Kim, Doyoung;Lee, Junseok;Lee, Sanghoon;Yoon, Hye-On
    • Journal of Soil and Groundwater Environment
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    • v.20 no.3
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    • pp.65-73
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    • 2015
  • The hydrofluoric acid (HF) leakage accident occurred on September 2012 in Gumi, Korea affected the surrounding soils and plants. In this study, we investigated fluoride migration in Gumi area through geochemical properties of soil-liquid phase (pore water F and water-soluble F). The concentrations of porewater F and water-soluble F were obtained from N.D (Not detected) to 9.79 mg/L and from 0.001 to 21.4 mg/L, respectively. F in pore water seemed to be affected by artificial and natural origin, and PHREEQC results implied that fluorite is F control factor. F concentrations of soil and soil-liquid phase did not exceed concern level of regulatory criteria and showed similar trends compared by previous studies. Therefore, F contents remained in the soil and soil-liquid phase were considered to be not affected by HF leakage accident.

Humidity Properties of Sintered MnWO4 with a Low Temperature Firing Frit (저온소성 프릿이 첨가된 MnWO4의 소결체의 습도특성)

  • Jung, Byung-hae;So, Ji-young;Kim, Hyung-sun
    • Korean Journal of Materials Research
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    • v.13 no.2
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    • pp.120-125
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    • 2003
  • A low melting borosilicate glass frit was used as an adhesion promoter, which enables $MnWO_4$to be sintered with in a reasonable sintering temperature range ($800∼1000^{\circ}C$). The glass was evaluated for glass transition temperature ($Τ_{g}$ X) and thermal expansion coefficient($\alpha$). Mechanical property (Vickers hardness), grain growth, the comparison of lattice parameter and pore distribution of sintered $MnWO_4$ with the frit were methodically discussed. As sintering temperature increased, a typical liquid phase sintering showed the rapid grain growth and high densification of X$MnWO_4$grain, improvement of hardness (until $920^{\circ}C$) and different pore size distribution. Resistance of sintered $MnWO_4$varied from 450k$\Omega$ to 8.8M$\Omega$ under the measuring humidify ranging from 30 to 90%. Thus, the results will contribute to the application of glass frit containing sensor materials and their future use.

Effect of Foaming Temperature on Cell Structure of 606X Series Aluminum Alloy Metallic Foams (Foaming 온도에 따른 606X계 발포 알루미늄의 제조 특성)

  • Song, Yeong-Hwan;Park, Soo-Han;Jeong, Min-Jae;Kang, Kwang-Jung;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.28 no.2
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    • pp.79-84
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    • 2008
  • Metal foam is one of the most interesting materials with various multi-functional properties such as light weight, energy absorption, high stiffness and damping capability. Among them, energy absorption property has keen interests in the field of automotives for passenger protection. Nowadays, researches about pore size and porosity control of the foam are increased to correspond them. However, though energy absorption properties are improved, these results are not cost-effective process. In present research, however, as a part of improving the energy absorption property of metallic foams, 606X aluminum alloy was used for cell wall material which has higher strength than pure aluminum. And its morphological features are characterized. As a results, porosity and pore size are uniformity distribution with increasing foaming temperature in the case of 6061 alloy foams. 6063 alloy foam specimens have opposite tendency because of the influence of alloying element and viscosity of the molten melt.

Interaction of Solid Particles with the Solidifying Front in the Liquid-Particle Mixture (액상-고체입자 혼합물의 응고 시 응고계면에서의 입자의 거동)

  • Lee, Ho-Suk;Lee, Kyu-Hee;Oh, Sung-Tag;Kim, Young Do;Suk, Myung-Jin
    • Journal of Powder Materials
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    • v.25 no.4
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    • pp.336-339
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    • 2018
  • A unique porous material with controlled pore characteristics can be fabricated by the freeze-drying process, which uses the slurry of organic material as the sublimable vehicle mixed with powders. The essential feature in this process is that during the solidification of the slurry, the dendrites of the organic material should repel the dispersed particles into the interdendritic region. In the present work, a model experiment is attempted using some transparent organic materials mixed with glass powders, which enable in-situ observation. The organic materials used are camphor-naphthalene mixture (hypo- and hypereutectic composition), salol, camphene, and pivalic acid. Among these materials, the constituent phases in camphor-naphthalene system, i.e. naphthalene plate, camphor dendrite, and camphor-naphthalene eutectic exclusively repel the glass powders. This result suggests that the control of organic material composition in the binary system is useful for producing a porous body with the required pore structure.