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Humidity Properties of Sintered MnWO4 with a Low Temperature Firing Frit

저온소성 프릿이 첨가된 MnWO4의 소결체의 습도특성

  • Jung, Byung-hae (Department of Materials Science and Metallurgical Engineering, Sunchon National University) ;
  • So, Ji-young (Department of Electrical Control Engineering, Sunchon National University) ;
  • Kim, Hyung-sun (Department of Materials Science and Metallurgical Engineering, Sunchon National University)
  • 정병해 (순천대학교 재료ㆍ금속공학과) ;
  • 소지영 (순천대학교 전기제어공학과) ;
  • 김형순 (순천대학교 재료ㆍ금속공학과)
  • Published : 2003.02.01

Abstract

A low melting borosilicate glass frit was used as an adhesion promoter, which enables $MnWO_4$to be sintered with in a reasonable sintering temperature range ($800∼1000^{\circ}C$). The glass was evaluated for glass transition temperature ($Τ_{g}$ X) and thermal expansion coefficient($\alpha$). Mechanical property (Vickers hardness), grain growth, the comparison of lattice parameter and pore distribution of sintered $MnWO_4$ with the frit were methodically discussed. As sintering temperature increased, a typical liquid phase sintering showed the rapid grain growth and high densification of X$MnWO_4$grain, improvement of hardness (until $920^{\circ}C$) and different pore size distribution. Resistance of sintered $MnWO_4$varied from 450k$\Omega$ to 8.8M$\Omega$ under the measuring humidify ranging from 30 to 90%. Thus, the results will contribute to the application of glass frit containing sensor materials and their future use.

Keywords

References

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