• Membrane and Water Treatment
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• v.9 no.2
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• pp.105-113
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• 2018

Maillard reaction products like melanoidins present in industrial fermentation wastewaters are complex compounds with various functional properties. In this work, novel ultrafiltration (UF) mixed matrix membrane (MMM) composed of polysulfone (PSF) and nanocomposites was prepared through a phase inversion process for the recovery of melanoidins. Nanocomposites were prepared with acid functionalized multiwalled carbon nanotubes (MWCNTs) as the reinforcing filler for chitosan-thermoplastic starch blend. Higher nanocomposites content in the PSF matrix reduced the membrane permeability and melanoidins retention indicating tighter membrane with surface defects. The membrane surface defects could be sealed with dilute polyvinyl alcohol (PVA) solution. The best performing membrane (1% nanocomposites in 18% PSF membrane sealed with 0.25% PVA coating) resulted in uniform melanoidins retention of 98% and permeability of 3.6 L/m2 h bar over a period of 8h. This demonstrates a low fouling PSF membrane for high melanoidins recovery.

• Applied Chemistry for Engineering
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• v.30 no.5
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• pp.562-568
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• 2019

Cylindrical shape extrudates of calcium silicate hydrate (CSH) were prepared using different percentages of polyvinyl alcohol (PVA) / sodium alginate (SA) mixtures as binders and an aqueous solution containing 6% $H_3BO_3$ and 3% $CaCl_2$ was used as a cross linking agent. As the quantity of alginate increases, the phosphate removal efficiency and capacity were decreased. Among four different extrudate samples, the sample prepared by 8% PVA + 2% SA showed the highest phosphate removal efficiency (59.59%) and capacity (29.97 mg/g) at an initial phosphate concentration of 100 ppm and 2.0 g/L adsorbent dosage. Effects of the adsorbent dosage, contact time and initial phosphate concentration on the sample were further studied. The removal efficiency and capacity obtained by a 4.0 g/L adsorbent dose at an initial phosphate concentration of 100 ppm in 3 h were 79.38% and 19.96 mg/g, respectively. The experimental data of kinetic and isotherm measurements followed the pseudo-second-order kinetic equation and Langmuir isotherm model, respectively. These results suggested that the phosphate removal was processed via a chemisorption and a monolayer coverage of phosphate anions was on the CSH surface. The maximum adsorption capacity ($q_{max}$) was calculated as 23.87 mg/g from Langmuir isotherm model.

• Computers and Concrete
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• v.24 no.1
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• pp.19-35
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• 2019

In this paper, the effect of the type and amount of fibers on the physicomechanical properties of concrete containing fine recycled refractory brick (RRB) and natural aggregate subjected to elevated temperatures was investigated. For this purpose, forta-ferro (FF), polypropylene (PP), and polyvinyl alcohol (PVA) fibers with the volume fractions of 0, 0.25, and 0.5%, as well as steel fibers with the volume fractions of 0, 0.75, and 1.5% were used in the concrete containing RRB fine aggregate replacing natural sand by 0 and 100%. In total, 162 concrete specimens from 18 different mix designs were prepared and tested in the temperature groups of 23, 400, and $800^{\circ}C$. After experiencing heat, the concrete properties including the compressive strength, ultrasonic pulse velocity (UPV), weight loss, and surface appearance were evaluated and compared with the corresponding results of the reference (unheated) specimens. The results show that using RRB fine aggregate replacing natural fine aggregate by 100% led to an increase in the concrete compressive strength in almost all the mixes, and only in the PVA-containing mixes a decrease in strength was observed. Furthermore, UPV values at $800^{\circ}C$ for all the concrete mixes containing RRB fine aggregate were above those of the natural aggregate concrete specimens. Finally, regarding the compressive strength and UPV results, steel fibers demonstrated a better performance relative to other fiber types.

• Journal of Powder Materials
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• v.31 no.3
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• pp.263-271
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• 2024

This study focused on improving the solubility of silodosin, a drug poorly soluble in water, by utilizing solid dispersions. Three types of dispersions were examined and compared against the drug powder: surface-attached (SA), solvent-wetted (SW), and solvent-evaporated (SE). Polyvinyl alcohol (PVA) was identified as the most effective polymer in enhancing solubility. These dispersions were prepared using spray-drying techniques with silodosin and PVA as the polymer, employing solvents such as water, ethanol, and a water-acetone mix. The physicochemical properties and solubility of the dispersions were evaluated. The surface-attached dispersions featured the polymer on a crystalline drug surface, the solvent-wetted dispersions had the amorphous drug on the polymer, and the solvent-evaporated dispersions produced nearly round particles with both components amorphous. Testing revealed that the order of improved solubility was: solvent-evaporated, solvent-wetted, and surface-attached. The results demonstrated that the preparation method of the solid dispersions significantly impacted their physicochemical properties and solubility enhancement.

• Journal of the Korean Ceramic Society
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• v.41 no.9
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• pp.663-669
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• 2004

Mullite and cordierite, which were stable oxides having excellent thermal and chemical characteristics, were widely used as an engineering and electronic materials. However, thermal shock resistance of the mullite was detriorated, and strength of the cordierite was also reduced at high temperatures. The mullite-cordierite composite powders were synthesized for solving these problems in this study. The mullite-cordierite composite powders were manufactured by the solution-polymerization method using mixtures of fused silica, aluminium nitrate, magnesium nitrate, and PVA. Crystallinity, phase formation, density, and surface area of the synthesis powders were characteristics. Fine mullite-cordlerite composite powders were successfully synthesized at 1300$^{\circ}C$ and their surface areas were about 20㎡/g after planetary milling for 1h. With increasing the milling time, surface area increased to 23 ㎡/g for 4h ana 24㎡/g for 8h.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.6
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• pp.4007-4012
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• 2014

This study examined the fabrication and thermal properties of fumed silica/ceramic wool inorganic composites. A predetermined quantity of fumed silica and ceramic wool was mixed uniformly into a slurry state and stabilized in the mold at room temperature, and converted to a massive foamed body through a complete drying process at $150^{\circ}C$. Although the samples without polyvinyl alcohol (PVA) as an interfacial adhesive showed a bulk density of 0.6-0.8 $g/cm^3$ in the range, 10-70wt% fumed silica, those samples with 3wt% PVA exhibited remarkably lower bulk densities with enhanced mechanical and thermal insulation properties, without thermal cracking even above $800^{\circ}C$. The K-factor of the samples was lower in proportion to the fumed silica contents, showing good thermal insulation properties of ca. 0.08 $W/m^{\circ}K$ at $500^{\circ}C$ for the sample with 30wt% fumed silica.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.1
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• pp.84-89
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• 2015

Basalt fiber has many advantages as a reinforcing fiber such as high tensile strength and similar density to concrete. This study investigated the bonding property and the effect of fiber orientation on tensile strength of basalt fiber. Single fiber pullout tests for basalt and polyvinyl alcohol (PVA) fibers were performed to evaluate the bonding property between basalt fiber and mortar. And then tensile strength of basalt, PVA, and polyethylene (PE) fibers according to fiber orientation were measured. From the test results, it was exhibited that the chemical bond, frictional bond, and slip-hardening coefficient of basalt fiber were 1.88, 1.03, 0.24 times of PVA fibers, respectively. And the strength reduction coefficient of basalt fiber was 9 times of PVA fiber and 3 times of PE fiber.

• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.1
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• pp.37-45
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• 2013

In this study, the resistance of various reinforced concrete (RC) slabs subjected to contact detonation was assessed. In order to enhance the blast resistance, fibers and external FRP sheets were reinforced to RC slabs. In the experiment, the $2,000{\times}1,000{\times}100mm$ sized RC slabs were fabricated using normal concrete (NC), steel fiber reinforced concrete (SFRC), polyvinyl alcohol fiber reinforced cementitious composite (PVA FRCC), and ultra-high performance cementitious composites (UHPCC). The damage levels of RC slabs subjected to contact detonation were evaluated by measuring the diameter and depth of crater, spall and breach. The experimental results were compared to the analyzed data using LS-DYNA program and three different prediction equations. The diameter and depth of crater, spall and breach were able to be predicted using LS-DYNA program approximately. The damage process of RC slabs under blast load was also well expressed. Three prediction equations suggested by other researchers had limitations to apply in terms of empirical approaches, therefore it needs further research to set more analytical considerations.

• Journal of Embryo Transfer
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• v.24 no.2
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• pp.97-104
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• 2009

The objective of this study was to examine the effect of macromolecule in a maturation medium on nuclear maturation, intracellular glutathione (GSH) level of oocytes, and embryonic development after parthenogenetic activation (PA) and somatic cell nuclear transfer (SCNT) in pigs. Immature pig oocytes were cultured in maturation medium that was supplemented with each polyvinyl alcohol (PVA), pig follicular fluid (pFF) or newborn calf serum (NBCS) during the first 22 h and the second 22 h. Oocyte maturation was not influenced by the source of macromolecules during in vitro maturation (IVM). Embryo cleavage and cell number in blastocyst after PA was altered by the source of macromolecule but no difference was observed in blastocyst formation among treatments. Oocytes matured in PVA-PVA medium showed lower rates of oocyte-cell fusion (70.4% vs. 77${\sim}$82%) and embryo cleavage (75% vs. 86${\sim}$90%) after SCNT than those matured in other media but blastocyst formation was not altered (13${\sim}$27%) by different macromolecules. pFF added to IVM medium significantly increased the intracellular GSH level of oocytes compared to PVA and NBCS, particularly when pFF was supplemented during the first 22 h of IVM. Our results demonstrate that source of macromolecule in IVM medium influences developmental competence of oocytes after PA and SCNT, and that pFF supplementation during the early period (first 22 h) of IVM increases intracellular GSH level of oocytes.

• Journal of the Korea Concrete Institute
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• v.23 no.6
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• pp.809-815
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• 2011

An experimental investigations on the bond-slip properties of the steel and Glass Fiber Reinforced Polymer(GFRP) bars in engineered cementitious composite (ECC) with Polyvinyl Alcohol (PVA) fibers are presented. Total of 8 beam specimens prepared according to the Rilem procedures with 2% of PVA and PE fiber volume percentage and steel and GFRP reinforcements significantly changed the failure mechanism and slightly improved bond strength. The main objective of the tests was to evaluate the load versus displacement and load versus slip behaviors and the bond strength for the following parameters: concrete type (normal and fiber concrete) and bar diameter (10 and 13 mm). The study results showed that ordinary concrete and ECC specimens showed similar behavior for steel reinforced specimen. However, GFRP reinforced specimen showed different behavior that the steel specimen. The code analytical results showed more accuracy compared to the experimental results as expected in conservative code provisions. Based on the obtained results, it is safe to conclude that the new parameters need to be adopted to ensure safe usage of ECC for construction applications.