• Title/Summary/Keyword: Polyvinyl alcohol (PVA)

Search Result 299, Processing Time 0.024 seconds

Vascular Endothelial Growth Factor Has Beneficial Effect Independent of Serum Components throughout Oocyte Maturation and Early Embryonic Development in Cattle

  • Luo, Hailing;Kimura, Koji;Hirako, Makoto
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.19 no.4
    • /
    • pp.495-499
    • /
    • 2006
  • In our previous studies, we demonstrated that Vascular Endothelial Growth Factor (VEGF) enhances bovine oocyte maturation and early embryonic development in serum supplemented media. In this experiment, to determine the synergistic effect of VEGF with serum components on early embryonic development in vitro in cattle, 1 mg/ml polyvinyl-alcohol (PVA) was replaced with foetal bovine serum (FBS) in maturation and culture media. Bovine oocytes were matured in Synthetic Oviduct Fluid (SOF) supplemented with PVA, PVA+5 ng/ml of VEGF, FBS, or FBS+VEGF. Fertilized oocytes were cultured in the same conditions for 8 days. The development of embryos was examined at 48 h post- insemination and on days 6, 7 and 8. The results were analyzed using repeated measures two- factor ANOVA, in which the effects of VEGF and serum were assigned as two factors. The development rate to 4- to 8-cell embryos at 48 h was significantly higher in the PVA+VEGF group than in the PVA group (44.7% and 31.5%, respectively). However, the highest development rate to 4- to 8-cell embryos was obtained from the FBS+VEGF group (58.8%). On day 8, the blastocyst rates were higher in the PVA+VEGF (22.8%), FBS (32.1%, p<0.05) and FBS+VEGF (42.1%, p<0.05) groups than in the PVA group (17.1%). Two- factor ANOVA of the development rates indicates that VEGF had a significant effect, but had no synergistic effect with serum components on early embryonic development. The results of the present study demonstrate that VEGF improves the in vitro developmental competence of bovine oocytes and/or embryos independent of the effect of serum components.

Synthesis of stable colloidal zirconia sol by adsorption of polyvinyl alcohol (PVA 흡착에 의한 안정한 콜로이드 지르코니아 졸의 합성)

  • Lee, Jong-Kook;Moon, Gi-Dong;Kim, Hwan
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.5 no.2
    • /
    • pp.165-174
    • /
    • 1995
  • A stable suspension with a colloidal $ZrO_2$ particle was prepared by an adsorption of PV A and investigated to the effects of PV A on the dispersion and particle growth within suspension. With a suspension added the optimum concentration of PYA (about 500 ppm in this study), it was shown the property of a stable sol due to the formation of adsorbed PV A layer on surface and the reduction of an agglomeration among the particles. Most of nucleation in colloidal $ZrO_2$ were occured in the early stage of hydrolysis reaction and the plate-like monoclinic $ZrO_2$ particle were grown with an aging time. The rate of particle growth and yield for a reaction were decreased with an addition of PV A. The compact prepared from well- dispersed suspension by an addition of PV A was contained the homogeneous particle arrangement and pore distribution.

  • PDF

Production of Polypyrrole Coated PVA Nanoweb Electroconductive Textiles for Application to ECG Electrode (심전도용 전극으로의 적용을 위한 폴리피롤 코팅 PVA 나노웹 전기전도성 텍스타일의 제조)

  • Kim, Jae-Hyun;Yang, Hyuk-Joo;Cho, Gil-Soo
    • Fashion & Textile Research Journal
    • /
    • v.21 no.3
    • /
    • pp.363-369
    • /
    • 2019
  • This study developed electroconductive textiles by coating polypyrrole to PET nonwoven-based Polyvinyl Alcohol (PVA) nanoweb made by electrospinning and applying the developed electrotextiles as ECG Electrodes. To find the optimum coating conditions for high electrical conductivity, the ratios of 2.6-Naphthalenedisulfonic acid with Disodium Salt (NDS) vs Ammonium Persulfate (APS) as an oxidant and a doping agent in the solution were changed from 3:7 to 7:3; the immersion time of the specimen in the solution was 1 hour. PVA nanowebs coated with polypyrrole under various conditions were filmed with FE-SEM. FT-IR analysis was also performed to examine the presence of polypyrrole nanoparticles in the PVA nanoweb. The electrical resistance of the treated specimens were measured with a Multimeter. Consequently, the PVA Nano Web was undamaged even after heat treatment that allowed for coating. Uniform polypyrrole nanoparticles then formed on the surface of the PVA nanoweb after coating. The measured electrical resistance was shown to be at least $12K{\Omega}/{\Box }$ from a maximum of $3,456K{\Omega}/{\Box }$. The proper amount of NDS content had a positive effect on the conductivity improvement of electroconductive textiles; in addition, the highest electrical conductivity was achieved with a ratio of 3:7 between NDS and APS.

Development of Extrusion Catalyst for Natural Gas Steam Reforming (천연가스 개질촉매 압출 성형방법의 개발)

  • Jung, You-Shick;Rhee, Young-Woo;Koo, Kee-Young;Jung, Un-Ho;Youn, Wang-Lai;Seo, Yong-Seog
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2009.06a
    • /
    • pp.735-738
    • /
    • 2009
  • 촉매 생산에서 마지막으로 중요한 단계는 촉매성형이다. 여기서 압출성형은 촉매 성형방법 중 저렴하고 비교적 간단한 방법 중 하나이다. 여기서 중요한 것은 바인더의 선택과 입자 사이즈가 가장 중요한 요인이 된다. 촉매 압출성형에서 많이 쓰이는 바인더로 PVA(Polyvinyl Alcohol)와 MC(Methyl Cellulose), CMC(Carboxymethyl Cellulose)가 있다. CMC 바인더의 경우, 촉매의 접착력이 현저히 떨어져 촉매의 바인더로 사용하기 어려웠다. PVA, MC 바인더의 경우, 촉매의 접착력이 우수하고 압출성형이 잘 되었다. 그러나 PVA 바인더의 경우, 열중량 분석을 통해 재 소성과정에서 바인더가 완전히 제거되지 않아서 촉매의 물성 변화 및 활성에 좋지 않은 영향을 주었다. 그러나 MC의 경우에는 재소성과정에서 바인더가 완전히 제거되어 촉매의 물성변화에 영향을 주지 않았으며, 촉매의 활성 변화에도 영향을 주지 않았다. 그래서 메탄 수증기 개질 촉매의 압출 성형에 적합한 바인더로 MC가 적합하다고 판단된다. 그리고 압출용 반죽 제조를 위한 미분쇄된 촉매 입자의 사이즈에서 너무 작은 입자를 사용하게 되면 반죽은 잘 되나 촉매의 물성변화로 인해 촉매 활성이 저하되는 것을 알 수 있었다. 그래서 볼밀로 정밀하게 입자 사이즈를 $10{\mu}m$ 이하로 조절하면 촉매 활성에 영향이 거의 없는 압출성형 촉매를 제조할 수 있다.

  • PDF

Automatic On-line BOD Measurement System Using A Microbial Membrane Electrode (미생물막 전극을 이용한 BOD 자동화 측정장치)

  • Oh, Hyuk;Kim, Hai Dong
    • Analytical Science and Technology
    • /
    • v.8 no.3
    • /
    • pp.335-340
    • /
    • 1995
  • Automatic biochemical oxygen demand(BOD) measurement system has heen developed using a microbial membrane electrode, prepared from Bacillus subtilis and polyvinyl alcohol(PVA). The automatic BOD measurement system showed a linear response curve up to BOD 60 ppm using a glucose/glutamic acid standard solution, and all the BOD measurement processes are carried out automatically to calculate BOD whithin 10 min after each sample injection. The response times of the microbial electrode was 5 minutes with a 5 min recovery time between measurements and the relative error of the BOD estimation was within 10%.

  • PDF

Spatting Resistance of High Strength RC Column Covering Spray-on Materials of Fiber Composite Spray Mortar(FCSM) (섬유복합모르터의 뿜칠마감에 의한 고강도콘크리트 기둥부재의 폭렬방지)

  • Song Yong-Won;Han Dong-Yeob;Lee Gun-Cheol;Goh Kyoung-Taek;Kim Jin-Soo;Han Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2006.05a
    • /
    • pp.5-8
    • /
    • 2006
  • High strength concrete has been increasingly used in high rue building and it is very obvious re consider fire resistance performance of that. Unlike the normal strength concrete, high strength concrete in sudden elevating temperature at fire is susceptible to spalling with severe explosion and surface split, due to high density of concrete. In order to endure the spalling, inner space temperature of concrete should be control less than certain point. Therefore this study investigated the influence of covering materials on high strength concrete finishing spray-on materials of fiber composite spray mortar(FCSM). Both polypropylene(PP) and polyvinyl alcohol(PVA) fiber were used in this test. Test showed that concrete, covering 18mm mortar containing PVA fiber and confining metal lath 2.3mm thickness, decreased 50% of main bar ambient temperature. compared with control concrete. In addition, concrete covering 18mm mortar without fiber caused falling of covering materials and then it was exposed in elevating temperature. As a result, spatting of the concrete occurred same as control concrete. However, concrete covering spray-on mortar containing PVA or PP fiber resisted spatting occurrence.

  • PDF

Fiber blending Ratio Effect on Tensile Properties of Hybrid Fiber Reinforced Cement-based Composites under High Strain Rate (고변형속도 조건에서 섬유 혼합비가 하이브리드 섬유보강 시멘트복합체의 인장특성에 미치는 영향)

  • Son, Min-Jae;Kim, Gyu-Yong;Lee, Bo-Kyeong;Lee, Sang-Kyu;Kim, Gyeong-Tae;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2017.11a
    • /
    • pp.147-148
    • /
    • 2017
  • In this study, the tensile properties of mono and hybrid fiber reinforced cement-based composite according to fiber blending ratio under the high strain rate was evaluated. Experimental results, the HSF1.5PVA0.5 shown the highest tensile strength because the PVA fiber suppressed the micro cracks in the matrix around the hooked steel fiber and improved the pull-out resistance of hooked steel fiber. Thus, DIF of strain capacity and fracture toughness of HSF1.5PVA were greatly improved. Also, the fracture toughness was greatly improved because the tensile stress was slowly decreased after the peak stress by improvement of the pull-out resistance of hooked steel fiber at strain rate 101/s.

  • PDF

Effect of Fiber Types on Fundamental Properties of Pavement Concrete (섬유 종류가 도로포장용 콘크리트의 기초적 특성에 미치는 영향)

  • Han, Cheon-Goo;Park, Jong-Sup;Jung, Woo-Tai;Jeon, Kyu-Nam
    • Journal of the Korea Concrete Institute
    • /
    • v.22 no.4
    • /
    • pp.473-479
    • /
    • 2010
  • The objective of the paper is to experimentally investigate the effect of commercially avaliable fiber types such as polypropylene (PP), nylon (NY), polyvinyl alcohol (PVA) and cellulose (CL) on the engineering properties of concrete for pavement application. The results, showed the fluidity tends to decrease with fibers addition compared to that of plain concrete. As for the effect of fiber types on fluidity loss, use of NY appear to give the most favorable results among all of the fiber types investigated in this study while the effect of the fibers on air content was negligible. For the properties of hardened concrete, compressive and flexural strengths increased with fibers compared to plain concrete. The contribution of NY fibers to strength was the highest followed in the order by NY, PVA, PP, and CL. However, in the case of the splitting tensile strength, its values were increased with NY and PP only. For porosity based on MIP(mercury intrusion penetration) method, the number of around 1 was observed when NY was mixed resulting in increased cumulated amounts of porosity compared with that of plain mix. Thus, based on the consideration of fluidity and strength it was found that the addition of NY fiber showed the optimal results under the conditions applied in this study.

Preparation of Gas Sensor from Pitch-based Activated Carbon Fibers and Its Toxic Gas Sensing Characteristics (피치계 활성탄소섬유기반 가스센서 제조 및 유해가스 감응 특성)

  • Kim, Min Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
    • /
    • v.25 no.2
    • /
    • pp.193-197
    • /
    • 2014
  • The electrode for gas sensor was prepared by using pitch-based activated carbon fibers and polyvinyl alcohol (PVA) to investigate the toxic gas sensing characteristics. The physicochemical properties of activated carbon fibers electrode for gas sensor were analyzed with SEM and BET. Toxic gases sensing property of the electrode was also identified by different toxic gases such as $NH_3$, NO and $CO_2$. The specific surface area of activated carbon fibers electrode for gas sensor was decreased by 33% owing to PVA used as a binder compared with the activated carbon fibers. However, its pore size distribution of the ACF electrode was not greatly influenced by PVA. The activated carbon fibers electrode for gas sensor responded to toxic gases by electron hopping unlike semiconductor based gas sensors. In this study, activated carbon fibers electrode was decreased to 7.5% in resistance for the NH3 gas of the 100 ppm concentration and its $NH_3$ gas sensing property was confirmed the most excellent compared with other toxic gases.

Possibility Analysis on Reducing Formwork Leakage of High-fluidity Mortar by Using PVA and Borax (PVA 및 붕사를 사용한 고유동 모르타르의 거푸집 누출량 저감 가능성 분석)

  • Kim, Young-Ki;Lee, Yu-Jeong;Heo, Jun-Ho;Han, Dongyeop
    • Journal of the Korea Institute of Building Construction
    • /
    • v.22 no.2
    • /
    • pp.125-136
    • /
    • 2022
  • This research is to reduce the formwork leakage of high-fluidity concrete caused by insufficient accuracy of formwork fabrication widely used for high-fluidity concrete to general strength concrete. However, in the actual construction site, because of the insufficient accuracy of formwork fabrication may cause leaking concrete of mortar through a gab of the formwork. Therefore, in this research, which builds on previous research into providing thixotropy with PVA and Borax, the use of thixotropy to reduce high-fluidity mortar leakage was evaluated. The results of the experiment proved that the use of thixotropy with PVA and Borax can contribute to reduction of the formwork leakage of high-fluidity mortar. This finding is expected to lead to further research on reducing leakage of high-fluidity concrete.