• Proceedings of the Korea Association of Crystal Growth Conference
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• 1996.06b
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• pp.129-153
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• 1996

In aqueous slurry processing of silicon nitride, the interaction of dispersant and binder on the surface of particles was studied to identify the effect of these additives on ceramic powder processing. Polymethacrylic acid (PMAA) and polyvinyl alcohol (PVA) were used as dispersant and binder, respectively. the adsorption isotherms of PMAA and PVA for the silicon nitride suspension were determined, while the adsorption of PMAA was differentiated in the mixed additive system by ultraviolet spectroscopy. These experiments were done in order to investigate the effect of these organic additives on the physicochemical properties of silicon nitride suspensions. The electrokinetic behavior of silicon nitride was subsequently measured by electrokinetic sonic amplitude (ESA). As PMAA adsorbed onto silicon nitride, the isoelectric point (pHicp) shifted from pH=6.7 to acidic pH, depending on the surface coverage of PMAA. However, adsorption of PVA did not change the pHicp of suspensions, but did decrease the surface potential of silicon nitride moderately. The rheological behavior of silicon nitride suspensions was measured to assess the stability of particles in aqueous media, and was correlated with the electrokinetic behavior and adsorption isotherm data for silicon nitride.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.653-656
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• 2006

High performance fiber-reinforced cementitious composite(HPFRCC) encompass a wide variety of cementitious composites whose behavior in tension is significantly more ductile than that of traditional fiber-reinforced concrete. Fibers in HPFRCC are increasingly being used for the reinforcement of cementitious matrix to enhance the toughness and energy absorption capacity and to reduce the cracking sensitivity of the matrix. In the past decade, HPFRCC have evolved with intensified research. HPFRCC for structural applications has been developed under the performance driven design approach. It is the aim of this study to obtain development of HPFRCC using polyvinyl-alcohol fiber(PVA). It was targeted a requirement of economic mixing and apply to structure member.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.51.2-51.2
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• 2011

A novel electrospun nanofiber membrane was fabricated using combined poly (vinylphosphonic acid) (PVPA) and polyvinyl alcohol (PVA) intended for bone tissue engineering applications. PVPA is a proton-conducting polymer used as primer for bone implants and dental cements to prevent corrosion and brush abrasion. The phosphonate groups of PVPA have the ability to crosslink and attach itself to the hydroxyapatite surface facilitating faster integration of the biomaterial to the bone matrix. PVA was combined with PVPA to provide hydrophilicity, biocompatibility and improve its spinnability. To improve its mechanical strength, PVPA/PVA and neat PVA mixtures were combined to produce a multilayer scaffold. The physical and chemical properties of the of the fabricated matrix was investigated by SEM and TEM morphological analyses, tensile strength test, XRD, FT-IR spectra, swelling behavior and biodegradation rates, porosity and contact angle measurements. Biocompatibility was also examined in vitro by cytotoxicity and cell proliferation studies with MTT assay and cell adhesion behavior by SEM and confocal microscopy.

• Journal of the Korean Chemical Society
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• v.19 no.3
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• pp.198-206
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• 1975

Polymers with photosensitive functional groups, the naphthoquinone-1,2-diazide-5-sulfonyl esters(PGND, BEND and PVAND) of polyglyceryl phthalate(PG), bisphenol A-epichlorohydrin polycondensate(BE) and polyvinyl alcohol(PVA), were prepared. The molecular weights of the starting materials were determined by the cryoscopic method, i.e., in the range of 650${\sim}$1200 for PG and 780${\sim}$1320 for BE, PGND, BEND and PVAND were prepared by esterification of PG, BE and PVA with naphthoquinone-1,2-diazidie-5-sulfonyl chloride, and the replacements of such a functional groups were confirmed by the infrared absorption spectra and elemental analyses. The good agreement between the observed values of elemental analyses (PGND, BEND and PVAND) and the calculated values, indicated that the degree of polymerization did not change in the course of esterification of PG, BE and PVA.

• Journal of the Korea Institute of Building Construction
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• v.8 no.1
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• pp.43-48
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• 2008

Fifteen concrete specimens were mixed and tested to explore the significance and limitation of appling the polyvinyl alcohol (PVA) fiber and steel fiber with end hook to concrete. Main parameters investigated were volume fraction and length of the fibers. The measured mechanical properties of fiber reinforced concrete are analyzed according to the equivalent fiber amount index explaining the adding amount and length of fibers. Test results showed that compressive strength of fiber reinforced concrete was higher than that of concrete with no fiber by $10{\sim}20%$. The normalized splitting tensile strength and flexural strength of PVA fiber reinforced concrete were similar to those of concrete with no fiber, whereas those of steel fiber reinforced concrete increased with the increase of the equivalent fiber amount index. In particular, much higher ductile behavior was observed in steel fiber reinforced concrete than in PVA reinforced concrete, indicating that the slope of descending branch of load-displacement relationship of steel fiber reinforced concrete decreased with the increase of the volume fraction and length of the fiber.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.208-209
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• 2018

In this study, the tensile properties of hybrid fiber reinforced cementitious composites under the high strain rate was evaluated. Experimental results, the HSF1.5PVA0.5 shown the highest tensile strength because the PVA fiber suppressed the micro cracks in the matrix around the hooked steel fiber and improved the pull-out resistance of hooked steel fiber. Thus, DIF of strain capacity and fracture toughness of HSF1.5PVA were greatly improved. Also, the fracture toughness was greatly improved because the tensile stress was slowly decreased after the peak stress by improvement of the pull-out resistance performance of hooked steel fiber at strain rate 10¹/s.

• Journal of Korean Society of Water and Wastewater
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• v.20 no.6
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• pp.875-883
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• 2006

The carbon and nitrogen removal process using PVA-gel (Polyvinyl Alcohol) immobilized microorganisms was studied. The process has been operated under diverse process conditions for 12 months. The process consists of denitrification with internal recycle of 300%, nitrification, aerobic digestion reactors and settling tank. Nitrificatoin and nitrogen removal efficiency according to gel packing ratio and temperature were studied. Yield for Heterotrophs ($Y_H$), decay coefficient for Heterotrophs($b_H$) in aerobic digestion reactor were determined to seize sludge reduction mechanism and compared with typical data of activated sludge process. Then SRT in aerobic digestion reactor was determined on an experimental basis and sludge reduction efficiency was calculated. The process was implemented successfully with sludge reduction efficiency of 92.0~98.5% on a basis of biomass.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.23 no.1
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• pp.9-15
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• 2017

To identify applicability for packaging material of polyvinyl alcohol (PVA)/boric acid (BA) coating solution with highly-enhanced water vapor and oxygen barrier properties, the PET/PVA-BA/OPP multi-layer films were prepared through comma coating and lamination process. The oxygen and water vapor permeabilities, and tensile strength of as-prepared multi-layer films were investigated before and after pressure cooker test (PCT). Although oxygen and water vapor permeabilites, and mechanical properties of PET/PVA-BA/OPP multi-layer films was decreased after PCT, their properties were highly enhanced as increase of BA contents in PVA matrix. This is strongly related with enhanced cross-linking density in PVA-BA layer. In storage test of seasoned-laver, the PET/PVA-BA/OPP multi-layer films were comparatively effective to suppress the increase in peroxide value originating from oxidation of seasoned-laver. Comparing the commercially available PP/Al-metallized PP for seasoned-laver packaging, however, PET/PVA-BA/OPP multi-layer films did not show any advantage in water activity. This is due to higher water vapor permeation properties of as-prepared multi-layer films. Therefore, further studies are required to enhance the water vapor permeation in PET/PVA-BA/OPP multi-layer films.

• Journal of the Korean Geotechnical Society
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• v.32 no.8
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• pp.27-33
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• 2016

In this study, Polyvinyl alcohol (PVA) fiber was used to increase strength (unconfined compressive strength and tensile strength) of bio-cemented sand using microorganism. Ottawa sand was mixed with PVA fibers having three fiber contents (0, 0.4, and 0.8%). The fiber mixed sand was treated 14 times by using Microbially Induced Calcite Precipitation (MICP) which included culture (2 times per day) during 7 days to improve its engineering properties. The Bacillus Sporosarcina pasteurrii (Bacillus sp.) was used for urease activity. The specimen was prepared as a cylindrical specimen of 5 cm in diameter and 10 cm in height. Unconfined compressive strength and tensile strength were measured after cementation. Moreover, calcium carbonate content and SEM analyses were performed with a piece of sample. An average value of unconfined compressive strength increased and then slightly decreased but an average value of tensile strength ratio increased with increasing carbonate content the in same condition. Unconfined compressive strength and tensile strength increased about 30% and 160%, respectively. A strength ratio of unconfined compressive strength to tensile strength representing the brittleness decreased from 8 to 4 when fiber content increased from 0.0 to 0.8%. Such bio-cemented sand can be applied into slope area to prevent its shear failure or increase its tensile strength.

• Journal of the Korean Wood Science and Technology
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• v.39 no.3
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• pp.197-205
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• 2011

Cellulose nanofibrils (CNF) with 50~100 nm diameter were manufactured from micro-size cellulose by an application of a high-pressure homogenizer at 1,400 bar. High strength nanopapers were prepared over a filter paper by a vacuum filtration from CNF suspension. After reinforcing and dispersing CNF suspension, hydroxypropyl cellulose (HPC) and polyvinyl alcohol (PVA)-based composites were tailored by solvent- and film-casting methods, respectively. After 2, 4, 6 and 8 passes through high-pressure homogenizer, the tensile strength of the nanopapers were extremely high and increased linearly depending upon the pass number. Chemical modification of 1H, 1H, 2H, 2H-perfluorodecyl-triethoxysilane (PFDTES) on the nanopapers significantly increased the mechanical strength and water repellency. The reinforcement of 1, 3, and 5 wt% CNF to HPC and PVA resins also improved the mechanical properties of the both composites.