• 제목/요약/키워드: Polyvinyl alcohol(PVA)

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분산제 PVA에 따른 수퍼커패시터용 이산화망간전극의 전기 화학적 특성 (Electrochemical Properties of MnO$_2$electrode for supercapactor wish a Diffuser (Polyvinylalcohol))

  • 이상오;김한주;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.753-756
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    • 2001
  • This research made a study of MnO$_2$electrode for supercapacitor with a diffuser (Polyvinyl alcohol). Manganese dioxide was used as active material. We tried to increase specific surface area by adding PVA. Manganese dioxide was synthesized by a sol-gel method using fumaric acid and oxalic acid in low temperature with high yield. Therefore, We prepared Manganese dioxide powder. This powder was used by active materials. The electrode was made by a mixture of active material, ketjen-black which is a large specific surface area, and PVdF-co-HFP as binder agent with using Nickel mesh as current collector. Here we reported on the synthesis and electrochemical performance of a enhanced material. All active materials have been submitted to X-ray diffraction and Scanning electron microscopy.

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폴리머 모르타르의 기계적 특성 (Mechanical Properties of Cement Mortar with Polymers)

  • 정민철;정윤중
    • 한국세라믹학회지
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    • 제31권7호
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    • pp.745-752
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    • 1994
  • A polymer reinforced grouts using ordinary portland cement mortar and water soluble polymer{polyvinyl alcohol(PVA), styrene-butadiene rubbre(SBR), etylene-vinyl acetate copolymer(EVA)} were made. The mechanical properties of the hardened specimens were investigated through the observation of the microstructure and application of fracture mechanics. When the PVA, SBR and EVA was added with 1.5 wt% to the grouts, the compressive strength were about 54 MPa, 63 MPa and 68 MPa respectively, and the flexural strength was about 11 MPa, 12.8 MPa, and 13.6 MPa respectively, and Young's modulus was about 3.8 GPa, 4.4 GPa and 4.6 GPa respectively, and critical stress intensity was about 0.73 MNm-1.5, 0.85 MNm-1.5 and 0.9 MNm-1.5 respectively. It can be considered that the strength improvement of polymer mortar grouts may be due to the removal of macropores and the increase of various fracture toughness effects, such as grain bridging, frictional interlocking and polymer bridging.

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Flow and Engineering Properties of Fiber Reinforced Hwangtoh Mortars

  • Mun, Ju-Hyun;Yang, Keun-Hyeok;Hwang, Hye-Zoo
    • 한국건축시공학회지
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    • 제12권3호
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    • pp.332-339
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    • 2012
  • In this study, six mortar mixes were tested in order to examine the significance and limitations of hydrophilic fiber in terms of its capacity to enhance the tensile resistance of Hwangtoh mortar. Lyocell, polyamide and polyvinyl alcohol (PVA) fibers were selected for the main test parameters. The tensile capacity of mortars tested was evaluated based on the splitting tensile strength and the modulus of fracture, while their ductility was examined using the toughness indices specified in ASTM. Test results showed that the addition of lyocell and PVA fibers had little influence on the flow of the Hwangtoh mortars. To enhance the tensile capacity and toughness index of Hwangtoh mortar, it is proposed that fiber spacing above 0.0003 is required, regardless of the type of fiber.

염색공장 폐수중 PVA 분해세균의 분리 및 생물학적 처리효과 (Studies on the Biological Treatment of Dye Waste Water and Degration of Polyvinyl Alcohol)

  • 강선태;서승교;권오억
    • 한국환경보건학회지
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    • 제16권1호
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    • pp.21-28
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    • 1990
  • As a research for treatment of waste water by biological method, we investigated general characteristics of waste water and isolated some useful bacteria which effectively treated waste water. Compositions of waste water were analyzed to give COD 2060 ppm, PVA 560 ppm, T-N 50 ppm, T-P 3.3 ppm and PH 12. Also, we inverstigated optimum nutrients requirement and growth conditions by mixed culture as well as the effect of coagulants. The COD removal rate reached maximum state for 48 hrs culture at pH 7.0 and 30$^{\circ}$C. Alum as the coagulated was the most effective. The COD removal rate was also increased by supplementing 10 ppm phosphorous sources as additional nutrients. The COD of waste water was reduced to 10% of its initial value by the continuous culture. As a result of overall experiments the COD of effluents became about 100 ppm and final pH 7.

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Effect of Chitosan Addition on the Surface Properties of Kenaf (Hibiscus cannabinus) Paper

  • Ashori Alireza;Raverty Warwick D.;Harun Jalaluddin
    • Fibers and Polymers
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    • 제6권2호
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    • pp.174-179
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    • 2005
  • The present paper studies the effect of chitosan, cationic starch and polyvinyl alcohol (PVA) as sizing agents to enhance surface properties of kenaf paper. The polymers were incorporated into the sheets by spray application. The results clearly showed that the addition of chitosan to a sheet formed from beaten fibers had excellent improvement in surface properties, compared to the effect of other additives. Sizing quality of cationic starch fairly matched with the sizing quality of chitosan, however, it was able to reduce the water absorption potential of paper more than chitosan at a same concentration. In most other properties, particularly the most important property for printing papers, surface smoothness, chitosan-sized papers are superior to the paper sized with cationic starch or PVA.

Effect of SDS on Retention of Nucleic Acid Components in High-Performance Liquid Chromatography

  • Kim Yong-Nam;Choi Kyeung-Soo;Lee Dai-Woon;Phyllis R. Brown
    • Bulletin of the Korean Chemical Society
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    • 제13권3호
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    • pp.240-245
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    • 1992
  • The effect of the addition of sodium dodecyl sulfate (SDS) to a buffered mobile phase (pH 3.4) on the retention of nucleotides, nucleosides and bases was investigated with a polyvinyl alcohol (PVA) column. Depending on the concentration of SDS, two different trends in the retention of nucleosides and bases containing an $NH_2$ group were observed. If the concentration of SDS was less than 5.5 mM, the retention of compounds containing an $NH_2$ group increased as the concentration of SDS in the mobile phase increased. In contrast, if the concentration was greater than 5.5 mM, the retention of compounds containing an $NH_2$ group decreased. Thus, the SDS acted as an ion-pairing reagent at lower concentration but formed micelles at higher concentrations. The retention behavior of the nucleosides and bases in the presence of a micellar concentration of SDS in the mobile phase on the PVA column was compared to the retention behavior on other types of columns.

가교된 PVA 분리막을 이용한 1, 2 hexanediol/water 혼합물의 투과증발 탈수 특성 연구 (Assessing the Dehydration Pervaporation Performance for Purification of Industrially Significant 1, 2 Hexanediol/Water Mixtures Using Crosslinked PVA Membrane)

  • 시브샹카 샤우드하리;조세욱;손민영
    • 멤브레인
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    • 제33권6호
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    • pp.369-376
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    • 2023
  • 본 연구에서는 에너지 소모가 큰 기존 진공 증류 공정의 대안으로 친환경이면서 에너지 효율적인 투과증발 분리공정을 이용하여 1,2 hexane diol/water (1,2 HDO/water) 혼합물에서 물을 분리하는 데 적용되었다. 사용한 분리막은 glutaraldehyde (GA)로 가교된 PVA를 알루미나 중공사 막(Al-HF) 내부에 코팅하여 사용하였다. 1,2 HDO/water 투과증발 분리공정에서는 PVA/GA 비율, 경화 온도 및 투과증발 분리공정 운전 조건에 대한 막의 최적화를 연구하였다. 장기 안정성 시험에서 PVA/GA (몰 비율 = 0.08, 경화 온도 = 80℃) 로 코팅된 Al-HF 막이 공정온도 40℃에서 1.90~2.16 kg/m2h 범위의 투과도를 보였으며, 투과용액의 수분 함량은 99.5% (separation factor = 68) 이상이었다.

感光性 樹脂에 關한 硏究 (第11報). Naphthoquinone-1,2-diazide-5-sulfonyl Esters의 光分解反應 (Studies on Photosentitive Polymers (XI). Studies on Photodegradative Reaction of Naphthoquinone-1,2-diazide-5-sulfonyl Esters)

  • 심정섭;강두환
    • 대한화학회지
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    • 제19권4호
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    • pp.280-285
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    • 1975
  • Polyglyceryl phthalate, bisphenol A-epichlorohydrin 縮重合物 및 polyvinyl alcohol의 naphthoquinone-1,2-diazide-5-sulfonyl esters(PGND, BEND 및 PVAND)에 대해 未增感 및 增感한 경우의 IR 스펙트럼을 측정하여 그들의 光分解機構를 硏究하였다. o-quinonediazide에 기인하는 C=N= 및 C=0의 흡수가 露光에 의해 減少내지는 消失하고있었고 또한 indene carboxylic acid의 C=0 흡수강도가 증가되고 있는 것으로 보아 o-quinonediazide group 이 光에 依하여 分解하여 알카리 수용액에 가용성인 indene carboxylic acid로 분해되는 것으로 추정된다. 한편, 露光時間에 대한 增感 및 未增感試料의 吸收强度의 變化를 측정하므로서 增感劑의 增感效果도 아울러 검토하였다.

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첨가제 종류에 따른 탄소나노튜브 금속복합재료 소결코팅 영향 (Influences to Additive Type on Carbon Nanotube metal composite)

  • 김대해;정희여;김민수;박찬우
    • Composites Research
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    • 제25권5호
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    • pp.159-163
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    • 2012
  • 냉매의 비등이나 응축같은 열전달 향상을 위하여 금속 표면위에 탄소나노튜브(CNT)를 코팅하는 것을 연구하였다. 분산제와 PVA(polyvinyl alcohol) 용액으로 분산 처리된 다중벽 탄소나노튜브/CuO의 복합 분말 코팅액을 구리기판위에 도포한 후 소결을 하였다. 본 논문에서는 CNT/CuO 소결 코팅시 다양한 분산제를 사용하여 소결 전후의 조직 형상 변화 및 특징을 실험적으로 평가하였다. 분산제로는 THF(Tetrahydrofuran), SDBS(Dodecylbenzenesulfonic acid sodium salt), SDS(Sodium dodecy sulfate)가 사용되었다. 각각의 시편들은 주사전자현미경, 열중량분석, 시차주사열량측정법, 라만분광법을 사용하여 분석하였다.

Bending performance and calculation of reinforced beam with hybrid fiber and CaCO3 whisker

  • Li Li;Yapeng Qin;Mingli Cao;Junfeng Guan;Chaopeng Xie
    • Computers and Concrete
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    • 제31권3호
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    • pp.197-206
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    • 2023
  • In this paper, the bending performance of a MSFRHPC (containing steel fiber, polyvinyl alcohol (PVA) fiber, and CW)-reinforced beam was studied for the first time. Introducing a multiscale fiber system increased the first crack load (up to 150%), yield load (up to 50%), and peak load (up to 15%) of reinforced beams. The multiscale fiber system delays cracking of the reinforced beam, reduces crack width of the reinforced beam in normal use, and improves the durability of the beam. Considering yield load and peak load, the reinforcing effect of multiscale fiber on the high-reinforcement ratio beam (1.00%) is better than that on the low-reinforcement ratio beam (0.57%). Introducing fibers slowed the development of cracks in the reinforced beam under bending. With the added hybrid fiber, the deformation concentration of reinforced beams after yield was more significant with concentration in 1 or 2 cracks. A model for predicting the flexural capacity of MSFRHPC-reinforced beams was proposed, considering the action of multiscale hybrid fibers. This research is helpful for structure application of MSFRHPC-containing CW.