• Journal of Microbiology and Biotechnology
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• 제11권6호
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• pp.928-933
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• 2001

Approximately 0.1 mg/ml of polyvinyl alcohol (PVA) was degraded by the growing cell, Brevibacillus laterospours, for 30 h, and 0.2 mg/ml of PVA was degraded by the cell-free extract that was isolated from Brevibacillus laterosporus. Approximately $0.29{\mu}g$/ml of acetic acid was produced from PVA by using the cell-free extract as a catalyst for 40 min. $V_{max}\;and\;K_m$ value of purified PAV-degradation enzyme was 3.75g/l and 2.75 g/l/min in reaction with EDTA and 3.99 g/l and 2.98 g/l/min in reaction without EDTA, respectively. Molecular weight of the purified enzyme determined by SDS-PAGE was 63,000 Da. Alcohol dehydrogenase and aldehyde dehydrogenase activities were qualitatively detected on a native acrylamide gel by an active staining method, indicating the existence of the metabolic pathway to use PVA as a substrate.

• 대한환경공학회지
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• 제35권11호
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• pp.815-820
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• 2013

본 연구의 목적은 알루미늄판에 활성탄을 얇게 박판으로 코팅하여 분진제거를 위한 활성탄 전극을 제조함에 있다. 전극을 제조하기위하여 알루미늄판에 활성탄을 부착시키기 위한 적정 결합제 선정 그리고 결합제 사용에 따른 활성탄 세공의 막힘방지 그리고 제조된 제극의 분진제거능력 등을 알아보는 연구를 수행하였다. 알루미늄판에 활성탄 부착을 위한 결합제로는 비닐계의 PVA (polyvinyl acetate)가 적정하였고, 결합제 사용에 따른 활성탄 세공의 막힘을 방지하기 위해서는 우선 먼저 활성탄 세공에 결합제의 용매제를 충진하고 나중에 결합제와 활성탄을 혼합 후 고온에서 휘발시키는 방법이 적정하였다. 그리고 활성탄이 코팅된 전극판은 알루미늄 전극판보다 약 두배의 분진부착능력을 보여주었다.

• 한국응용과학기술학회지
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• 제27권2호
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• pp.216-221
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• 2010

Polyvinyl acetate (PVAc) prepared by emulsion polymerization has broad applications for additive such as paint binder, adhesive for wood and paper due to its low glass transition temperature which help to plasticize substrate resins. Since emulsion polymerization has a disadvantage that surfactant and ionic initiator degrade properties of the product polymer, poly (vinyl acetate-eo-ethyl acrylate) (VAc-EA) was synthesized using potassium persulfate as catalyst and polyvinylalcohol (PVA) as protective colloid to prevent the degradation. The copolymer latex product was internally plasticized and has enhanced adhesion, water resistance during VAc-EA emulsion polymerization. No coagulation and complete conversion occur with the reactant mixture of 10 mmol/L potassium persulfate, 10 mmol/L poly ( vinyl alcohol) (PVA 17). As the concentrations of PVA increase, the viscosity becomes increase.

• 한국세라믹학회지
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• 제28권7호
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• pp.509-516
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• 1991

The effect of various polymers on the freeze-thaw resistance of hardened cement mortar was investigated. For this study, styrene butadiene rubber (SBR), ethylene vinyl acetate (EVA), polyvinyl alcohol (PVA) were used to prepare cement mortar specimen, and then freeze-thaw experiment was carried out. By adding SBR adn EVA to the specimen, the freeze-thaw resistance of specimens was improved, but when PVA was added to the specimen, its freeze-thaw resistance was lowered. Particularly, the specimens which were added 5, 10% of SBR and 5% of EVA showed excellent freeze-thaw resistance in the salt environment.

• 한국구조물진단유지관리공학회 논문집
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• 제23권1호
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• pp.102-112
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• 2019

본 연구는 PVA(polyvinyl alcohol) 섬유와 VAE(vinyl acetate ethylene) 분말 폴리머를 사용한 시멘트복합체의 압축 휨강도 와 온도변화에 따른 충격파괴거동을 연구하였다. 충격시험은 $-35^{\circ}C$, $0^{\circ}C$ 및 $35^{\circ}C$의 선정된 온도조건에서 실시하였다. 본 실험에서는 시멘트 복합체와 일반 모르타르에 대한 충격파괴 에너지와 변위, 시간을 얻기 위해 낙하 충격시험기(Ceast 9350)를 사용하여 충격시험을 수행하였다. 강도시험결과, PVA 섬유와 VAE 분말 폴리머의 휨강도는 모두 증가하였다. PVA 섬유보강 시멘트복합체의 경우 재령 28일에서의 압축강도는 약간 감소하였으나, 휨강도는 일반 모르타르 강도보다 24.4% 증가하였다. 낙하 충격시험 결과, PVA 섬유보강 시멘트복합체 시편은 섬유의 가교역할로 인한 균열발생의 억제와 에너지 분산에 의한 미세균열이 발생하였으며, 충격에 의한 배면파괴와 관통에 대하여 억제되었다. 반면 VAE 분말 폴리머 시멘트복합체와 일반 모르타르의 시편은 대부분 큰 균열이나 관통파괴 되었다. 충격하중을 받는 시멘트복합체와 일반 모르타르의 시편은 대부분 국부적인 취성파괴거동을 보이며, PVA 섬유보강에 의한 휨성능 증진으로 인해 충격에 대한 저항성능이 크게 향상되었다.

• Composites Research
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• 제21권1호
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• pp.40-45
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• 2008

자동차용 유압브레이크 고무호스 어셈블리 제품은 자동차에 장착되어 실제로 사용 중에 가압, 굽힘, 비틀림, 열하중 등의 복합적인 스트레스를 받는다. 고무호스의 재질은 EPDM(ethylene-propylene diene monomer)고무와 PVA(polyvinyl acetate)섬유 보강층 그리고 중간고무로 NR(natural rubber)고무가 사용되고 있다. 고무호스 어셈블리 제품의 내구성과 파괴 메커니즘을 조사하기 위해 굽힘과 비틀림의 반복하중 사이클 수가 10만, 20만, 30만, 40만, 최종파열 사이클 수까지 되도록 시험하였다. 유압브레이크 고무호스의 초기크랙 발생을 알아보기 위해 제품 시험편을 다이아몬드 휠커터를 이용하여 수직 절단하여 폴리싱한 후 광학현미경과 주사형 전자현미경(SEM)으로 단면을 관찰하였다. 40만 사이클의 피로하중을 받은 시험편을 보면 외면고무와 PVA섬유 사이의 계면을 따라 길이 1mm의 층간분리가 일어났으며, 이러한 손상은 외면고무의 표피층으로 균열을 진전시켜 고무호스를 최종적으로 찢어지게 하는 것이다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 추계학술대회 논문집
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• pp.253-253
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• 2009

Electrospinning is one of the simple, cost- efficient methods to produce long continuous semiconducting oxide nanofibers. Polyvinyl Alcohol (PVA) and zinc acetate were used. PVA/Zinc acetate aqueous solutions were electrospun into nonwoven webs. CCD camera, with a lens of long working distance and digital video board were used in capturing the drop and web deposition. The diameter and morphology of nanofibers were analyzed with a Field-emission scanning electron microscopy (FE-SEM). In this study, the average diameter and morphology of nanofibers have been explorered.

• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3733-3737
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• 2013

Polyacrylonitrile (PAN)-based ultrafine fibers and carbon fibers were produced by wet-spinning, and the crystal sizes and thermal and mechanical properties of the fibers were investigated. Scanning electron microscopy revealed that the superfine fibrils in the surfaces of the PAN/polyvinyl acetate (PVA) blend fibers increased slightly with increasing PAN content before removal of the PVA. Differential scanning calorimetry indicated that the PAN and PVA in the blend fibers do not mix and, therefore, each maintains their inherent thermal characteristics. The crystal sizes of the blend fibers prepared by removing PVA with water increased at 5 wt % water. The extent of the reaction of the PAN carbon fibers, as calculated from the FT-IR spectra, is maximized at the stepwise temperature of $230^{\circ}C$, and the density increased significantly above this temperature. The carbon fibers had relatively good mechanical properties, as shown by their tensile strength and modulus values of 2396 MPa and 213 GPa, respectively.

• 한국세라믹학회지
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• 제31권7호
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• pp.745-752
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• 1994

A polymer reinforced grouts using ordinary portland cement mortar and water soluble polymer{polyvinyl alcohol(PVA), styrene-butadiene rubbre(SBR), etylene-vinyl acetate copolymer(EVA)} were made. The mechanical properties of the hardened specimens were investigated through the observation of the microstructure and application of fracture mechanics. When the PVA, SBR and EVA was added with 1.5 wt% to the grouts, the compressive strength were about 54 MPa, 63 MPa and 68 MPa respectively, and the flexural strength was about 11 MPa, 12.8 MPa, and 13.6 MPa respectively, and Young's modulus was about 3.8 GPa, 4.4 GPa and 4.6 GPa respectively, and critical stress intensity was about 0.73 MNm-1.5, 0.85 MNm-1.5 and 0.9 MNm-1.5 respectively. It can be considered that the strength improvement of polymer mortar grouts may be due to the removal of macropores and the increase of various fracture toughness effects, such as grain bridging, frictional interlocking and polymer bridging.

• 한국가구학회지
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• 제11권1호
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• pp.25-29
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• 2000

This study was carried out to analyze the ultrasonic properties of sound board which was glued with various adhesives and to evaluate which adhesive is the best for the acoustic radiation of the musical instrument. The results are as follows: 1. Animal glue is the best adhesive for the sound board with respect to the acoustic radiation ratio of the musical instruments. Epoxy resin and polyvinyl acetate resin are the next group, urea formaldehyde resin and Hot melt are the third group, polychloroprene(CR) resin is the lowest. 2. Epoxy resin, animal glue and Titebond(PVA) give the highest shear strength and the highest wood failure relatively Hot melt and polychloroprene(CR) resin do not meet the standard because of low wood failure.