• Title/Summary/Keyword: Polyvinyl

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Immobilization of Alchidine on Polyvinyl Alcohol Gels

  • Soh, Dea-wha
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.1
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    • pp.11-14
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    • 2003
  • The regularities of immobilization of natural medicinal substances - alchidine on gels of poly(vinyl alcohol) - are investigated. It is shown that the polymer components of alchidine interact with nonionic polymer with formation of interpolymer complexes. The influence of the different factors on the properties of complexes is considered and the constants of alchidine distribution in the system gel - water are calculated.

Study on the Preparation of Polyvinyl Chloride Anion Exchange Membrane as a Separator in the Alkaline Water Electrolysis (알칼리 수전해용 격막으로서 폴리염화비닐(polyvinyl chloride) 음이온교환막의 제조에 관한 연구)

  • Park, Jong-Ho;Bong, Soo-Yeon;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.23 no.6
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    • pp.469-474
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    • 2013
  • An anion exchange membrane was prepared for a separator in the alkaline water electrolysis. An anion exchange membrane was prepared by the chloromethylation and amination of polyvinyl chloride (PVC) used as a base polymer. The membrane properties of the prepared anion exchange membrane such as the membrane resistance and ion exchange capacity were measured. The minimum membrane resistance of the prepared anion exchange membrane was $2.9{\Omega}{\cdot}cm^2$ in 1M NaOH aq. solution. This membrane had 2.17 meq./g-dry-membrane and 43.4% for the ion exchange capacity and water content, respectively. The membrane properties of the prepared anion exchange membrane was compared with that of the commercial anion exchange membrane. The membrane resistance decreased in the order; AHT>IOMAC> Homemade membrane> AHA>APS=AFN. The ion exchange capacity decreased in the order; Homemade membrane>AFN>APS>AHT>AHA>IOMAC.

Thermal distribution change in polyvinyl alcohol gel caused by focused ultrasound (폴리비닐알코올 젤의 집속초음파에 의한 온도분포 변화)

  • Kim, Jungsoon;Kim, Moojoon
    • The Journal of the Acoustical Society of Korea
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    • v.39 no.6
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    • pp.576-584
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    • 2020
  • In order to obtain basic information for using polyvinyl alcohol (PVA) gel as a tissue mimicking phantom for temperature visualization, the temperature change characteristics due to the focused ultrasound were examined for different concentration of PVA. To obtain the basic acoustic characteristics, the speed of sound, the attenuation coefficient, and the density depending on the PVA concentration were measured, and the thermodynamic characteristics, such as thermal conductivity and heat capacity, were measured. The range of temperature rising in the vicinity of the focal point due to the focused ultrasound was observed using a thermochromic film that changes color at 30 degree or more, and the discolored area was obtained by image processing of the recorded image. As the concentration of PVA increases in the given range of 2 wt% ~ 16 wt%, the area that rises above 30 degree inside the gel increases linearly. It is confirmed that the discolored area increases as the power applied to the focused ultrasonic transducer increases. These results showed good agreement with the simulation results using the finite element method.

Efficacy of Starch and PVA (polyvinyl alcohol) for the Suppression of Soil Dust Emissions from Large-scale Construction Sites in Urban Areas (도심 대형사업장의 토양 입자 비산 억제를 위한 Starch와 PVA(polyvinyl alcohol)의 효율성 평가)

  • Choi, Jong-Soo;Kim, Dong-Su;Choi, Yu-Lim;Kim, Jung-Eun;Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Soil and Groundwater Environment
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    • v.24 no.6
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    • pp.9-15
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    • 2019
  • Soil dust emitted from large scale construction sites in urban areas has posed a significant health threats to local residents by exacerbating air quality. Water-spraying (moistening) is commonly practiced to lower the dust emission in construction sites, but its long term effectiveness is highly questionable. In this study, the utility of starch and PVA(polyvinyl alcohol) was investigated in suppression of the soil dust emissions in construction sites in Seoul areas. The efficiency of the two suppressants was tested with test soil sample in a lab-scale wind tunnel box under different concentrations of suppressants and soil textures. Starch and PVA showed the superior ability to suppress soil dust emission as compared to moistening, resulting in PM10 and PM2.5 lower than the daily limit values of 30 and 15 ㎍/㎥ respectively. PVA showed higher suppression capability than starch for all conditions. The test soils mixed with suppressants also showed dramatically enhanced aggregate stability compared to the non-treated soil.

A Study on Combustion Gases Toxicity Evaluation of Polymeric Material (고분자재료의 연소가스 독성평가에 관한 연구)

  • 박영근
    • Fire Science and Engineering
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    • v.15 no.3
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    • pp.7-13
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    • 2001
  • In this paper, we had analyzed comsbustion gases according to pyrolysis $600^{\circ}c$, $800^{\circ}c$ and $1000^{\circ}c$ for polymeric material using a GASTEC colorimetric gas detector tube in order to combustion gases toxicity evaluation for flame retardant untreated ply wood, flame retardant treated ply wood, flexible polyvinyl chloride and flexible polyurethane foam of polymeric material. As a result, comsbustion gases producted from small specimens of polymeric material had reached fatal to man at a 30 minute exposure time that had possesed toxicity index. Toxicity index at pyrolysis $800^{\circ}c$ of flexible polyvinyl chloride was 31.74. Flexible polyvinyl chloride was the highest toxicity index of flame retardant untreated ply wood, flame retardant treated ply wood, flexible polyvinyl chloride and flexible polyurethane foam. The comsbustion gases producted commonly no concern with pyrolysis temperature had analyzed carbon dioxide($CO_2$) and carbon monoxide(CO). Toxicity index had investigated differently according to pyrolysis temperature even a similar materal.

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Characteristics of the symbionts Pseudomonas sp. J2W strain and Xanthomonas sp. J2Y strain which utilize polyvinyl alcohol (Polyvinyl alcohol 이용 공생균 Pseudomonas sp. J2W와 Xanthomonas sp. J2Y의 특성)

  • Jo, Youn-Lae
    • Applied Biological Chemistry
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    • v.35 no.1
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    • pp.30-35
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    • 1992
  • Two strains J2W and J2Y which were isolated from soil can utilize polyvinyl alcohol(PVA) as a sole carbon source. PVA was utilized symbiotically by the mixed culture of these two strains which could not utilize PVA in each respective pure culture. Effect of degree of PVA polymerization on the its utilization was examed, and there was remarkable difference among three kind of PVA(PVA 500, 1500 and 2000). The reconstruction of there two strains was carried out with other symbionts Pseudomonas sp. PW and Pseudomonas sp. G5Y which were able to utilize PVA. PVA utilization occured in each remixed culture of J2Y strain with Pseudomonas sp. PW J2W strain with Pseudomonas sp. G5Y, respectively. Identification of bacteria was based on morphological and biological chatacteristics, J2W and J2Y strain were similar to a strain of Pseudomonas pseudimallei and Xanthomonas campestris, respectively.

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Preparation of Copper Fine Particles from Waste Copper by Chemical Reduction Method (폐동분으로부터 화학환원법에 의한 Cu 미립자 제조)

  • Kim, Yoon-Do;Song, Ki Chang;Song, Jong-Hyeok
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.560-565
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    • 2007
  • Copper fine particles, ranging from $0.11{\mu}m$ to $0.64{\mu}m$ in average size, were prepared by a chemical reduction method using hydrazine ($N_2H_4$) as a reduction agent in waste copper solutions. The effect of the amount of hydrazine addition was investigated on the properties of the obtained powders. Also, the effect of the addition of dispersing agents [Polyvinyl alcohol (PVA), polyvinyl pyrrolidone (PVP)] during particle synthesis was studied. The powders, obtained from 1 M waste copper solutions, showed the mixtures of Cu and $Cu_2O$ crystals at low hydrazine addition amounts of 0.8 mol and 1.0 mol, while those exhibited pure Cu crystals at adequate hydrazine addition amount of 0.12 mol. The average size of the Cu powders decreased with increasing the concentrations of hydrazine and dispersing agents. The addition of PVA to the solutions as a dispersing agent was more effective than that of PVP in preventing the aggregation of particles.

Development of Polyvinyl Alcohol (PVA) Non-woven Separator Coated with ZrO2 Ceramic Nanoparticles for Improving Electrochemical Performance and Thermal Property of Lithium Ion Batteries (열 특성 및 전기화학 특성이 향상된 리튬이차전지용 ZrO2 코팅 PVA (Polyvinyl Alcohol) 복합 부직포 분리막 개발)

  • Kim, Ki Jae
    • Journal of the Korean Electrochemical Society
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    • v.20 no.3
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    • pp.49-54
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    • 2017
  • We develop a ceramic composite separator prepared by coating $ZrO_2$ nanoparticles with a poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) copolymer on a polyvinyl alcohol (PVA) mechanical support prepared by electrospinning technique to improve thermal properties. The gurley number of the ceramic composite separator shows much lower value than that of a PE separator even though it possesses the polymeric coating layer with ceramic nanoparticles. In addition, the proposed sample shows higher electrolyte uptake than PE separator, leading to enhancing the ionic conductivity of the proposed sample and, by extension, the rate discharge properties of lithium ion batteries. Thermal stability of the ceramic composite separator is dramatically improved without any degradation in electrochemical performance compared to the performance of conventional PE separators.

Improvement of Bending Performances by Sloped Finger-Joint Method in Pinus densiflora S. et Z. (I) (경사핑거접합법에 의한 소나무재의 휨강도성능개량 (I))

  • Byeon, Hee-Seop;Park, Han-Min;Kim, Jong-Man
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.4
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    • pp.61-67
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    • 1997
  • The bending performances of sloped finger-joints in Pinus densiflora S. et Z. were tested in order to improve the strength properties of finger-joint Sloped finger-cut pieces were jointed with four kinds of adhesives(resorcinol-phenol, oilic urethane, polyvinyl acetate, and polyvinyl-acryl acetate resin). The slope ratios of finger joints were 0, 0.5, 1.0, 2.0. The MOE, MOR and defletion to maximum load in bending of sloped finger-joints and solid wood specimen were measured. The results were: 1. The efficiencies of MOE to finger and sloped finger-joints were 82% or greater in every kind of adhesives except polyvinyl-acryl acetate resin adhesive and there were some effect of slope on the MOE in a sloped finger-joint for polyvinyl-acryl acetate and oilic urethane resin adhesives. 2. The effects of slope on the MOR to sloped finger-joints were showed in every kind of adhesive, because the efficiencies of MOR increased with increasing slope ratio in sloped finger-joints. The efficiencies of MOR to slope ratios of 0 and 2.0 ranged 43~65% and 76~82%, respectively. There was almost no effect of the kinds of adhesives on the MOR to the slope ratio of 2.0. 3. It was found impossible to estimate the bending strength of sloped finger-jointed Pinus densiflora S. et Z. by using MOE. The correlation coefficient(0.124) between MOE and MOR was very low and not significant at 5% level.

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