• Title/Summary/Keyword: Polytetrafluoroethylene (PTFE)

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Electric and Mechanical Properties of CMC+PTFE Binary Binder Electrode for Electric Double Layer Capacitor (EDLC용 CMC+PTFE 혼합바인더 전극의 전기적, 기계적 특성)

  • Kim, Ick-Jun;Lee, Sun-Young;Moon, Seong-In
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.10
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    • pp.1079-1084
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    • 2004
  • This work describes the effect of electrode binder on the characteristics of electric double layer capacitor. Among carboxymethylcellulose (CMC), Polyvinylpyrrolidone (PVP), Polyvinyl Alcohol (PVA), and Polyvinylidene Fluoride (PVDF), the unit cell using CMC showed good rate capability at current densities between 2.5 mA/$\textrm{cm}^2$~100 mA/$\textrm{cm}^2$. However, CMC as a binder is incongruent, because the electrode bound with CMC is rigid and easy to crack during a press and winding process for fabrication of capacitor. The unit cell capacitor using the electrode bound with binary binder composed of CMC and Polytetrafluoroethylene (PTFE), especially in composition CMC : PTFE =60 : 40 wt.%, has exhibited the better mechanical properties than those of the unit cell with CMC. On the other hand, the mechanical properties of CMC+PTFE electrode, coated on underlayer composed of CMC and carbon black, were much improved.

Reactive Ion Etching을 이용한 PTFE 발수특성

  • Baek, Cheol-Heum;Seo, Seong-Bo;;Kim, Hwa-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.292-292
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    • 2013
  • 최근, 자연의 기능성 표면을 모사하여 우리 생활에 응용하기 위한 연구가 활발하다. 초-발수 특성을 가지는 대표적인 예인 연꽃잎은 마이크로-나노 크기의 거친 미세돌기(papillae)를 가지고 있으며 그 위에 낮은 표면 에너지를 가지는 왁스(wax)가 발달 되어 항상 깨끗한 상태를 유지한다. 본 실험에서는 이를 모사하여 RIE (Reactive Ion Etching)방법을 이용하여 기판인 Poly silicon wafer를 Sf6가스를 사용하여 Metal mash로 거칠기를 만들어 주었고, RF-magnetron sputtering 장치를 사용하여 $6{\times}10^{-3}$ Torr의 진공도에서 낮은 표면에너지를 가지는 PTFE (polytetrafluoroethylene)를 증착하여 표면 구조와 발수특성에 대하여 조사하였다. SSME(Surface shape measurement equipment)측정결과 0.24~0.36 um RSa 값이 측정되었고, 12 uL의 Di-water로 접촉각을 측정 한 결과 RIE 10분 처리를 한 기판 위에 PTFE를 3분 증착하였을 때 가장 높은 $153^{\circ}$의 초-발수 특성이 나타났으며, 4주의 시간이 지났을 때에도 접촉각이 유지가 되었다. XPS 측정결과 초-발수 표면에서 나타나는 CF2와 CF3 피크 값이 측정되었다. Reactive Ion Etching을 이용한 PTFE 발수 특성은 방수, 스마트 윈도우, 자가세정(Self-Cleaning), 디스플레이 표시장치, 김서림 방지(Anti-Fogging), 대전방지 코팅 등에 다각적으로 응용 가능할 것이라 사료된다.

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Study on Two Step Plasma Treatment for Electroless Cu Plating of Fluoropolymer (불소수지의 무전해 동도금을 위한 단계적 플라즈마 전처리법에 관한 연구)

  • Shin, Seung-Han;Han, Sung-Ho;Kim, Young-Seok
    • Journal of the Korean institute of surface engineering
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    • v.38 no.3
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    • pp.118-125
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    • 2005
  • Low temperature plasma treatment with different gases and rf powers were performed to improve the adhesion strength between polytetrafluoroethylene(PTFE) and electroless deposited copper. According to the research, $H_2$ plasma having hydrogen radical was more effective in surface polarity modification than $O_2$ plasma due to the defluorination reaction. However, surface roughness of PTFE was more increased with $O_2$ than $H_2$ plasma. PTFE treated with $120W-O_2$ plasma and $250w-H_2$ plasma, consecutively showed rougher surface than single step $250w-H_2$ plasma treated one and more hydrophilic than single step $120W-O_2$ plasma treated one. And it showed 5B tape test grade, which is better adhesion property than 1B or 3B obtained by single step plasma treatment. In addition, adhesion strength between PTFE and Cu deposit is also deeply affected by residual water on its interface.

Membrane Based Triboelectric Nanogenerator: A Review (막 기반 마찰전기 나노 발전기: 총설)

  • Rabea Kahkahni;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.2
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    • pp.53-60
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    • 2023
  • Mechanical energy can be harvested by triboelectric nanogenerators (TENG) from biological and environmental systems. In wearable electronics, TENG has a lot of significance as biomechanical energy can be harvested from the motion of humans, which is applied in vibrational sensors. Wearable TENG is prone to moisture and polytetrafluoroethylene (PTFE) is an excellent hydrophobic material used in these applications. The presence of highly electronegative fluorine atoms leads to very low surface energy. At the same time, the performance of the device increases due to the efficient capture of the electrons on the microporous membrane surface. This similar behavior occurs with polyvinylidene fluoride (PVDF) due to the presence of fluoride atoms, which is relatively less as compared to PTFE.

Arc Resistance and Light Reflectance of PTFE for Circuit Breaker (차단기용 PTFE의 내아크성과 광반사율)

  • Park, Hoy-Yul;Kang, Dong-Pil;Ahn, Myeong-Sang;Lee, Tae-Joo;Lee, Tae-Hui;Myung, In-Hae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.200-203
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    • 2003
  • A study on the arc resistance and light reflectance of PTFE (polytetrafluoroethylene) nozzle for circuit breaker is presented. PTFE has been used widely as a material for circuit breaker nozzle. PTFE has excellent electrical resistivity, high melt viscosity, chemical inertness, heat resistance and low loss factor. PTFE melts at $327\;^{\circ}C$ but the viscosity is very high above the melting point. In the arcing environment in a circuit breaker, the fraction of the power is emitted out of the arc and reaches the nozzle wall by radiation, causing ablation at the surface and in the depth of the wall. Some fraction of the radiation power emitted out of the arc directly break up the chemical bonds at the surface while some fraction of the radiation power penetrates into the wall, heats up the material to evaporation temperature and causes damages deeper inside the volume of the nozzle. In this paper, some fillers that have endurance in the high temperature arc environment were added into PTFE. Adding some fillers into PTFE was expected to be efficient in improving the endurability against radiation. The light reflectance and arc resistance of PTFE composites were investigated.

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Ultrasonication-Induced Changes in Physicomechanical and Tribotechnical Properties of PTFE Composites

  • Argunova, Anastasiia G.;Petrova, Pavlina N.;Okhlopkova, Aitalina A.;Shadrinov, Nikolay V.;Gogoleva, Olga V.;Cho, Jin-Ho
    • Journal of the Korean Chemical Society
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    • v.59 no.3
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    • pp.233-237
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    • 2015
  • The effect of ultrasonication on PTFE and its composites with zeolite and fluoroplast F-4NTD-2 was studied. Ultrasonication was found to cause changes in the supramolecular structure, and consequently, the tensile strength, relative elongation, and mass wear rate. Changes in the topology of the materials following ultrasonication were investigated by scanning electron microscopy. The optimum enhancement of the desired properties was found in the PTFE composite containing 2% activated zeolite.

Avoiding Venous Anastomotic Dehiscence of an Arteriovenous Graft in a Super-Obese Patient

  • Bae, Miju
    • Journal of Chest Surgery
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    • v.53 no.6
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    • pp.417-419
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    • 2020
  • Surgeons avoid creating arteriovenous fistulae in obese patients owing to deep vessels, cannulation complications, and inconsistent outcomes. We describe placing an arteriovenous polytetrafluoroethylene (PTFE) graft between the brachial artery and axillary vein to avoid these complications. A 39-year-old super-obese woman with end-stage renal disease had undergone several hemodialysis access procedures on both arms. We traced the course of the arteriovenous graft course with the patient sitting and lying down. The ideal course was more accurate with the patient sitting; thus, the patient sat when the course was drawn, before lying on the operating bed. The PTFE graft was placed between the right brachial artery and axillary vein, according to the course in the opposite arm. No anastomotic dehiscence or pseudoaneurysm has taken place during 2 years of follow-up. In super-obese patients, the ideal course for arteriovenous grafts should be drawn while they are sitting, avoiding skin folds. This tip could avoid anastomotic dehiscence and pseudoaneurysm between the axillary vein and a PTFE graft.

Compaction of Hydrogen Storage Alloy Powders Using Polymer Binders (고분자 결합제를 이용한 수소저장합금 분말의 성형)

  • Song, Kyu-Tae;Kim, Chan-Jung;Choi, Byung-Jin;Kim, Dai-Ryong
    • Transactions of the Korean hydrogen and new energy society
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    • v.5 no.1
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    • pp.51-57
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    • 1994
  • Compaction techniques of hydrogen storage alloy 'powders, to solve the problems due to disintegration during the cyclic hydriding and dehydriding, by using polytetrafluoroethylene (PTFE) and silicon sealant as a polymer binder were studied. Optimum conditions of compaction were as follows. Binder content, 10 % for PTFE and 5 % for silicon sealant ; particle size of alloy powders, $-25{\mu}m$ ; compacting pressure, $4ton/cm^2$. Compacts obtained were easily activated and had a good strength even after 30 cycles of hydriding and dehydriding. PTFE added compacts showed very good rate capability, however, in the silicon added compacts hydrogen absorption rate was somewhat slow because of higher elasticity and adhesiveness of the binder.

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Infrasonic Detection using PTFE Electret (PTFE 일렉트롯트를 이용한 초저주파 검출)

  • 김충혁;김기준;홍진웅;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1989.06a
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    • pp.114-117
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    • 1989
  • An infrasonic wide band transducer fabricated by polytetrafluoroethylene(PTFE)is studied experimentally. The sensitivity of the transducer depends largely on the surface charge of the Electret and is typically between-50 and -62[dBV] for a sound-pressure level of 1[ubar]. The sensitivity of the transducer does not decay over periods of the order of years at room temperature. The frequency response is within 1.5[dB] from 1 to 6,000[Hz] and within 12[dB] from 0.05[Hz] to 1[Hz] respectively. The resonance frequency of the element is 510 [Hz]. We conjectures that the element is applicable to accustics, communication system, seismological observation and other similar filed.

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Stress Behavior Analysis of O-rings and Packing for a LPG Filling Nozzle (LPG 충전노즐용 O-링과 패킹의 응력거동해석에 관한 연구)

  • Kim, Chung-Kyun
    • Tribology and Lubricants
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    • v.22 no.1
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    • pp.20-25
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    • 2006
  • The stress behavior analysis of a-rings and packing for a LPG filling unit has been presented using a finite element analysis technique by non-linear MSC/MARC program. The sealing performance and endurance of a-rings and packing are affected by working conditions such as filling pressure, friction coefficient, compression ratio, and material properties. The elastomeric polymers of O-rings and packing are nitrile butadiene rubber (NBR) and polytetrafluoroethylene (PTFE), which are selected as proper materials of a-rings and packing based on the stress analysis results. The calculated FEM results showed that the proper material of O-ring is NBR as a secondary sealing component and the recommended material of packing is PTFE as a primary sealing unit during a LPG filling process.