• Title/Summary/Keyword: Polytetrafluoroethylene (PTFE)

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Surface Modification of Polytetrafluoroethylene by Using Low Energy Hydrogen Ion Beam (저에너지 수소 이온빔을 이용한 polytetrafluoroethylene 표면 개질)

  • Lee, Jung-Hwan;Kim, Dong-Hwan;Yeo, Woon-Jung;Han, Young-Gun;Cho, Jun-Sik;Kim, Hyun-Joo;Koh, Seok-Jeun
    • Journal of the Korean Vacuum Society
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    • v.15 no.6
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    • pp.612-618
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    • 2006
  • Surface modification of PTFE by ion irradiation was performed to improve its surface properties, In the case where argon was used to irradiate the PTFE films, an increase in the adhesion strength was observed when the ion fluence was over $1\times10^{15}\;ions/cm^2$, but the surface morphology dramatically changed to a needle-shaped one. However, when we used hydrogen ions under $O_2$ environmental gas, the adhesion strength increased at an ion fluence of $5\times10^{16}\;ions/cm^2$ and the surface morphology by the hydrogen irradiation was not needle-shaped. The surface morphology and adhesion strength of the hydrogen modified PTFE was influenced by the oxygen flow rate. It was confirmed by reflectance measurements that the surface properties of the hydrogen ion irradiated PTFE were superior to those of the argon ion irradiated PTFE.

Permeation and diffusion of gases through polytetrafluoroethylene membrane (Polytetrafluoroethylene막을 통한 기체의 투과 및 확산)

  • 김형민;김남인;이우태
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.10a
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    • pp.34-35
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    • 1994
  • 기체혼합물의 분리및 정제기술은 에너지 절약의 관점과 새로운 기능성 고분자의 개발로 고분자막에 의한 분리법이 관심을 끌게되었다. 공기로부터 산소부화, 방사성 크세논 및 크립론의 제거, 제련소 폐가스증의 수소분리, 천연가스로부터 헬륨의 회수분야등은 실제로 산업적으로 실용화되고 있다. 그러나 고분자막은 일반적으로 투과성과 선택성이 서로 상반되는 경향을 나타내므로, 투과성과 분리성이 좋은 기능성 고분자막의 개발에 다양한 연구가 필요로 하고있다. 본 연구에서 사용한 PTFE(polytetrafluoroethylene)는 결정성 고분자로서 넓은 온도범위에서 낮은 마찰계수, 우수한 전기적 절연특성, 강한 Carbon-fluorine 겹합에 기인한 높은 열적 안정성, 화확적 불활성때문에 공업용 고분자 재료로서 독특한 위치를 차지하고 있다. 최근에 미국과 일본을 주축으로 상용화딘 공기전지(Zinc-air battery)는 PTFE막의 뛰어난 소수성과 화학적 저항성으로 수은 전지의 대체품으로 주목받고 있는데, 장기 방전시 성능 저하가 따르므로 막을 통한 산소투과성을 방전에 필요한 최소값으로 감소시키는 것이 중요한 과제가 되고있다.

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Characterization of PTFE Electrode Made by Bar-Coating Method Using Alcohol-Based Catalyst Slurry (알코올계 촉매 슬러리를 활용한 바 코팅으로 제조된 PTFE 전극의 형성 및 특성 조사)

  • JUNG, HYEON SEUNG;KIM, DO-HYUNG;PAK, CHANHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.3
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    • pp.276-283
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    • 2020
  • Alcohol-based solvents including ethanol (EtOH) and tert-butyl alcohol (TBA) are investigated instead of isopropanol (IPA), which is a common solvent for polytetrafluoroethylene (PTFE), as an alternative solvent for preparing the catalyst slurry with PTFE binder. As a result, the performance at 0.2 A/㎠ from the single cells from using catalyst slurries based on EtOH and TBA showed very similar value to that from the slurry using IPA, which implies the EtOH and TBA can be used as a solvent for the catalyst slurry. It is also confirmed by the very close values of the total resistance of the membrane electrode assemblies from the slurries using different solvents. In the energy dispersive spectrometry (EDS) image, the shape of crack and dispersion of PTFE are changed according to the vapor pressure of the solvent.

The Effect of e-PTFE Membrane Exposure on the Initial Healing of Periodontal Tissue in GTR Procedure (e-PTFE 차단막을 이용한 조직유도재생술시 e-PTFE 차단막의 노출이 치주조직의 초기치유에 미치는 영향)

  • Moon, Ik-Sang;Kim, Ji-Eun;Song, Kun-Young
    • Journal of Periodontal and Implant Science
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    • v.29 no.3
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    • pp.553-560
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    • 1999
  • The aim of the present study was to evaluate the effect of the expanded polytetrafluoroethylene (e-PTFE) membrane exposure on the initial healing of the periodontal tissue in guided tissue regeneration (GTR) procedure. 90 sites selected from 90 patients were treated with gingival flap surgery supported by an e-PTFE membrane. The material included angular bony defects with probing attachment loss of > 5mm or degree II furcation involvement. Treated sites were classified with membrane exposure group and non-exposure group at membrane removal and evaluated healing type. The results were obtained as follows. 1. e-PTFE membrane was exposed at 61 sites (67.8%) among 90 sites. 2. Thirteen sites (14.4%) depicted rapid healing type, 65 sites (72.2%) depicted typical healing type, 9 sites (10%) showed delayed healing type and 3 sites (3.3%) were categorized as adversed healing type. 3. In e-PTFE membrane exposure group, 1 site (1.6%), 51 sites (83.6%), 6 sites (9.8%) and 3 sites (4.9%) showed rapid healing type, typical healing type, delayed healing type and adverse healing type respectively. 4. In e-PTFE membrane non-exposure group, 12 sites (41.3%), 14 sites (48.3%) and 3 sites (10.3%) showed rapid healing type, typical healing type and delayed healing type respectively. Adverse healing type was not observed. 5. The rate of favourable healing between e-PTFE membrane exposure group and non-exposure group was not statistically significant(p=0.56). These results suggest that the prevention of membrane exposure may be important to obtain rapid healing type. However favourable healing could be obtained with stringent infection control program even if membrane was exposed.

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Performance Analysis of Friction Pendulum System using PVDF/MgO Friction Material (PVDF/MgO 마찰재를 이용한 마찰면진장치의 성능 분석)

  • Kim, Sung-Jo;Kim, Ji-Su;Han, Tong-Seok
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.4
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    • pp.213-219
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    • 2021
  • Polytetrafluoroethylene (PTFE) is a commercialized friction material in friction pendulum systems used for earthquake hazard mitigation in structures, and it has excellent chemical resistance and frictional performance. However, PTFE has a relatively low wear resistance for the friction pendulum systems in service. As an alternative to PTFE, a cost-effective frictional material, polyvinylidene fluoride (PVDF) strengthened by magnesium oxide (MgO), with enhanced wear resistance performance is proposed in this study. The frictional performance of the developed PVDF/MgO was evaluated through experiments and compared with that of PTFE. Accordingly, a friction pendulum system was designed using the measured friction coefficient. The performance of this friction pendulum system was evaluated via nonlinear time history analyses of bridges. Subsequently, the plausibility of using PVDF/MgO as an alternative to PTFE as a friction material for friction pendulum systems was discussed.

Systemic-Pulmonary Shunts Using Microporous Polytetrafluoroethylene Prosthesis [Early and Late Results] (Polytetrafluoroethylene 인조혈관을 이용한 체-폐동맥 단락술의 조기성적 및 원격 성적)

  • 장병철
    • Journal of Chest Surgery
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    • v.19 no.1
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    • pp.50-57
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    • 1986
  • Sixty-nine patients with various types of cyanotic congenital heart disease underwent systemic-pulmonary artery shunts with a microporous polytetrafluoroethylene [PTFE] prosthesis between 1979 and 1985. Their ages ranged from 2 months to 39 years [mean$\pm$SD: 5.2$\pm$7.4, median: 3.3 years]. Diagnosis included the following: Tetralogy of Fallot, 45: Double outlet right or left ventricle, 11: Single ventricle, .5: Transposition of great vessels, 4: Tricuspid atresia, 3 and Pulmonary atresia with intact ventricular septum, 1. Forty-eight patients had subclavian-pulmonary artery anastomosis, 12 patients aorta-right pulmonary artery anastomosis, 6 patients aorta-main pulmonary artery anastomosis, and 3 patients descending aorta-pulmonary artery anastomosis. The PTEE graft of 3 mm in diameter was used in 1, 4 mm in 29, 5 mm in 35 and 6 mm in 4 patients. Ten patients were died within 30 days after operation [mortality rate: 14.5%]. Among them, 6 patients were operated in urgency due to cardiac arrest or severe anoxic spell after cardiac catheterization, and so surgical mortality of elective operation is 9.5%. The 59 survivors showed improvement of the arterial oxygen saturation [65.4% - 9.8%] and hemoglobin [18.8 gm/dl - 16.0 gm/dl] values [V<0.01]. The follow up period ranged from 1 month to 67 months, [752 patient-months] and during this periods there were 4 late shunt failures after 3 months postoperatively with 4 mm graft, and 2 with 5 mm graft. The over-all patency rate of 4 mm PTFE was 85.9$\pm$9.2% [SEM] in 12 months and 40.9$\pm$22.5% in 24 months. The over-all patency rate of 5 mm PTFE was 87.5$\pm$9.6% in 12 months and 58.3$\pm$24.6% in 36 months. The lowest systolic pressure in death group was 64.9$\pm$15.0 mmHg and in survival group, 86.4$\pm$12.1 mmHg [P<0.001]. We think that the PTFE graft is useful in palliative shunt operation, but the effectiveness of the 4 mm PTFE graft may be limited. The blood pressure also may play an important role in patency of Prosthesis.

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Formation of Fine Pitch Solder Bumps on Polytetrafluoroethylene Printed Circuit Board using Dry Film Photoresist (Dry Film Photoresist를 이용한 테프론 PCB 위 미세 피치 솔더 범프 형성)

  • Lee Jeong Seop;Ju Geon Mo;Jeon Deok Yeong
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2003.11a
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    • pp.169-173
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    • 2003
  • We demonstrated the applicability of dry film photoresist (DFR) in photolithography process for fine pitch solder bumping on the polytetrafluoroethylene (PTFE/Teflon) printed circuit board (PCB). The copper lines were formed with $100\;{\mu}m$ width and $18\;{\mu}m$ thickness on the PTFE test board, and varying the gaps between two copper lines in a range of $100-200\;{\mu}m$. The DFRs of $15\;{\mu}m$ thickness were laminated by hot roll laminator, by varying laminating temperature from $100^{\circ}C\;to\;150^{\circ}C$ and laminating speed. We found the optimum process of DFR lamination on PTFE PCB and accomplished the formation of indium solder bumps. The optimum lamination condition was temperature of $150^{\circ}C$ and speed of about 0.63 cm/s. And the smallest size of indium solder bump was diameter of $50\;{\mu}m$ with pitch of $100\;{\mu}m$.

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Moist Corrosion and Surface Protection of YBCO HTS

  • Lim, Byong-Jae;Soh, Dea-Wha;Fan, Zhanguo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.256-259
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    • 2002
  • The critical currents of sintered $YBa_{2}Cu_{3}O_{6.5+\delta}$ were measured as the variables with the corrosive time in the humid air. The corrosive process was studied by means of the current changes. Ag coating on the textured YBCO and polytetrafluoroethylene (PTFE) coating on the sintered YBCO were prepared. The critical current densities of different YBCO samples with and without coatings were compared. Both Ag coating and PTFE coating can well protect YBCO from moisture and $CO_{2}$.

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Development of PTFE Membrane Bio-reactor (MBR) for Integrating Wastewater Reclamation and Rainwater Harvesting (PTFE막을 이용한 빗물 중수 통합형 MBR 시스템 개발 및 성능 평가)

  • Lee, Taeseop;Kim, Youngjin;Ham, Sangwoo;Hong, Seungkwan;Park, Byungjoo;Shin, Yongil;Jung, Insik
    • Journal of Korean Society on Water Environment
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    • v.28 no.2
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    • pp.269-276
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    • 2012
  • The surface characteristics and performance of PTFE (polytetrafluoroethylene) hollow fiber membranes have been systematically investigated at lab- and pilot-scale to assess their application to membrane-bioreactor, particularly for integrating wastewater reclamation and rainwater harvesting. The PTFE membrane expressed some surface features, such as hydrophobicity, which might enhance membrane fouling. However, lab-scale performance and cleaning experiments under various conditions demonstrated that the PTFE membrane could produce the desirable water flux with good cleaning efficiency, implying easy operation and maintenance due to superior chemical resistance of PTFE membranes. Most of effluent water qualities were met with Korean standard for discharge and reuse, except color. Color level was further reduced by blending with rainwater at 75:25 ratio. Based on the lab-scale experimental results, the pilot plant was designed and operated. Pilot operation clearly showed sTable performance with satisfactory water quality, suggesting that PTFE membrane could be applied for decentralized MBR integrated with rainwater use.