• Composites Research
• /
• v.29 no.3
• /
• pp.91-97
• /
• 2016

In this paper, impulse-momentum theory was coupled to a constitutive equation both for implementing quasi-static and impact characteristics of EPP (Expanded polypropylene). Also, parameters which have physical meanings were expressed as functions of relative density. Simultaneous nonlinear Newton-Raphson method was applied to find the proper values for parameters in the constitutive equation along with quasi-static test data. Results from the impulse-momentum theory coupled constitutive equation showed good agreement with experimental data and the potential to be applied to different material type polymeric foam.

• Composites Research
• /
• v.27 no.3
• /
• pp.103-108
• /
• 2014

Fiber reinforced polymer plastic (FRP) structural members are recently available in construction industries due to various material properties such as high specific strength and stiffness, light-weight, and corrosionresistance. The floating PV generation structure can also be an illustration for applying FRP in construction applications. The floating PV generation structure has been recently issued as a representative item for the low carbon and green growth campaign and many related studies have been conducted for the structural safety and commercial viability. Moreover, the floating PV generation structures for the commercial purpose have been constructed. In this paper, the investigation and development processes of elements for the floating PV generation structure are presented during commercialization.

• Composites Research
• /
• v.30 no.1
• /
• pp.41-45
• /
• 2017

Magnetite nanoparticles were synthesized by adding an ammonium hydroxide to a mixed solution of iron (II) and (III) chlorides. A silicon surfactant of ${\alpha},{\omega}$-(3-aminopropyl)polydimethylsiloxane was adsorbed on the particles as dispersant and a polydimethylsiloxane polymer was used to prepare ferrofluids of silicone oil base. Fluorinated surfactants of anionic ammoniated perfluoroalkyl sulfonamide and nonionic fluoroaliphatic polymeric esters were applied to the particles and a perfluoropolyether was used to prepare ferrofluids of fluorine oil base. The experimental conditions were used for preparing the ferrofluids with concentrations of 200, 300 and 400 mg/mL, and density, magnetization and viscosity of the products were characterized. The density values increased in proportion to the concentration, indicating 1.11-1.27 g/mL for silicone-oil-based fluids and 1.95-2.10 g/mL for fluorine-oil-based fluids in the range of 200-400 mg/mL. The saturation magnetization of the silicone-oil-based and fluorine-oil-based fluids indicated 14.7, 24.4, and 30.7 mT and 15.8, 23.3, and 33.7 mT for 200, 300, and 400 mg/mL, respectively, depending on the content of magnetic particles in the fluid. The viscosity of the silicone-oil-based ferrofluids was highly stable compared to that of the fluorine-oil-based with increasing temperatures. The ferrofluids are usually applied to seals and speakers with the silicone base and to seals with the fluorine base.

• Composites Research
• /
• v.26 no.2
• /
• pp.105-110
• /
• 2013

In this study, we suggest the new floating PV generation structure which is improved the structural and economical efficiency compared with the system developed in the previous research. Pultruded FRP has superior physical and chemical material properties compared with those of conventional structural materials. Especially, pultruded FRP has an excellent corrosion-resistance, light-weight, and it also has high specific strength and stiffness which are highly appreciated for the design and fabrication of floating PV generation structure under harsh environmental condition. In this study, structural analysis using the finite element method has been performed to investigate the safety of new floating PV generation structure and newly applied structural members.

• The Journal of Korean Academy of Prosthodontics
• /
• v.38 no.6
• /
• pp.782-790
• /
• 2000

The mainly used polymeric material for the denture is PMMA because of its cost and easiness to handle. So it was widely used material among dentists for past decades. But the acrylic-based denture materials have several common weak points such as shrinkage after curing and lack of strength. In order to solve these problems, we adapted one of hybrid system using acrylic polymer and vinyloligosilsesquioxane(POSS). POSS, which is a well known expandable monomer during polymerization process, may eventually suppress volumetric shrinkage. And the hybrid system makes it possible for the polymer to be stable in various severe conditions. Eight different kinds of samples were designed and synthesized. Each samples were characterized with dynamic mechanical analyser(DMA) to confirm their thermodynamic properties, fractured to analyze the cross-sectional morphology of the samples. And elongation, flexural and impact tests were also executed to evaluate the mechanical properties of the samples. From the results, hybrid composites had well defined crosslinked network structure compared to the widely used denture materials, and the mechanical strength improved without changing any surface condition as increment with POSS ratio in hybrid system. Fractured morphology showed homogeneous surfaces in spite of mutli component system, therefore we can conclude that the adoption of the POSS brought the reinforcement of the denture resin.

• Composites Research
• /
• v.29 no.1
• /
• pp.7-15
• /
• 2016

The quality of polymeric automotive parts depends highly on an injection molding process, which causes various defects, such as warpage, sink marks, weld lines, shrinkage, residual stress, etc. This study is to determine the optimum processing parameters, such as packing pressure, mold temperature, melting temperature, and packing time for the manufacture of polycarbonate buttons in cars on the basis of FEM, the Taguchi method, and analysis of variance (ANOVA). As a result, the optimum processing parameters of buttons made of polycarbonate material were obtained as follows: 140 MPa of packing pressure, $105^{\circ}C$ of mold temperature, $292.5^{\circ}C$ of melting temperature and 1 second of packing time. A gain of S/N (signal to noise) ratio, 10.2, was obtained with the optimum values. Moreover, the melting temperature was found to be the most significant factor followed by the mold temperature.

• Membrane and Water Treatment
• /
• v.9 no.4
• /
• pp.221-231
• /
• 2018

A new procedure to produce poly(vinylidene fluoride)/boron nitride hybrid membrane is presented for application in membrane distillation (MD) process. The influence of hexagonal boron nitride (h-BN) incorporation on the performance of the polymeric membranes is studied through the present investigation. For this aim, h-BN nanopowders were successfully synthesized using the simple chemical vapor deposition (CVD) route and subsequent solvent treatments. The resulting h-BN nanosheets were blended with poly(vinylidene fluoride) (PVDF) solution. Then, the prepared composite solution was subjected to phase inversion process to obtain PVDF/h-BN hybrid membranes. Various examinations such as scanning electron microscopy (SEM), wettability, permeation flux, mechanical strength and liquid entry pressure (LEP) measurements are performed to evaluate the prepared membrane. Moreover, Air gap membrane distillation (AGMD) experiments were carried out to investigate the salt rejection performance and the durability of membranes. The results show that our hybrid PVDF/h-BN membrane presents higher water permeation flux (${\sim}18kg/m^2h$) compared to pristine PVDF membrane. In addition, the experimental data confirms that the prepared nanocomposite membrane is hydrophobic (water contact angle: ${\sim}103^{\circ}$), has a porous skin layer (>85%), as well competitive fouling resistance and operational durability. Furthermore, the total salt rejection efficiency was obtained for PVDF/h-BN membrane. The results prove that the novel PVDF/h-BN membrane can be easily synthesized and applied in MD process for salt rejection purposes.

• Transactions of the Korean hydrogen and new energy society
• /
• v.17 no.2
• /
• pp.149-157
• /
• 2006

Hydrogen as new energy sources is highly efficient and have very low environmental emissions. The proton exchange membrane fuel cell (PEMFC) is an emerging technology that can meet these demands. Therefore, the preparation of stable polymeric membranes with good proton conductivity and durability are very important for hydrogen production via water electrolysis with PEM at medium temperature above $80^{\circ}C$. Currently Nafion of Dupont and Aciflex of Asahi, etc., solid polymer electrolytes of perfluorosulfonic acid membrane, are the best performing commercially available polymer electrolytes. However, these membrane have several flaws including its high cost, and its limited operational temperature above $80^{\circ}C$. Because of this, significant research efforts have been devoted to the development of newer and cheaper membranes. In order to make up for the weak points and to improve the mechanical characteristics with cross -linking, acid-base complexes were prepared by the combination PSf-co-PPSS-$NH_2$ with PEEK-$SO_3H$. The results showed that the proton conductivity decreased in 17.6% and 40% but tensile strength increased in 78% and 98%, about $20.65\;{\times}\;10^6N/m^2$, in comparison with SBPSf/HPA and SPEEK/HPA complex membrane.

• Journal of Korean Society on Water Environment
• /
• v.38 no.3
• /
• pp.143-149
• /
• 2022

Membrane distillation (MD) has emerged as a sustainable desalination technology to solve the water and energy problems faced by the modern society. In particular, the surface wetting properties of the membrane have been recognized as a key parameter to determine the performance of the MD system. In this study, a novel surface modification technique was developed to induce a Janus-type hydrophilic/hydrophobic layer on the membrane surface. The hydrophilic layer was created on a porous PVDF membrane by vapor phase polymerization of the pyrrole monomer, forming a thin coating of polypyrrole on the membrane walls. A rigid polymeric coating layer was created without compromising the membrane porosity. The hydrophilic coating was then followed by the in-situ growth of siloxane nanoparticles, where the condensation of organosilane provided quick loading of hydrophobic layers on the membrane surface. The composite layers of dual coatings allowed systematic control of the surface wettability of porous membranes. By the virtue of the photothermal property of the hydrophilic polypyrrole layer, the desalination performance of the coated membrane was tested in a solar MD system. The wetting properties of the dual-layer were further evaluated in a direct-contact MD module, exploring the potential of the Janus membrane structure for effective and low-energy desalination.

• Journal of Ginseng Research
• /
• v.46 no.5
• /
• pp.621-627
• /
• 2022

Background: Panax ginseng (ginseng) is a traditional medicine that is reported to have cardioprotective effects; ginsenosides are the major bioactive compounds in the ginseng root. Methods: Magnetic molecularly imprinted polymer (MMIP) nanoparticles might be useful for both the extraction of the targeted (imprinted) molecules, and for the delivery of those molecules to cells. In this work, plant growth regulators were used to enhance the adventitious rooting of ginseng root callus; imprinted polymeric particles were synthesized for the extraction of ginsenoside Rb₁ from root extracts, and then employed for subsequent particle-mediated delivery to cardiomyocytes to mitigate hypoxia/reoxygenation injury. Results: These synthesized composite nanoparticles were first characterized by their specific surface area, adsorption capacity, and magnetization, and then used for the extraction of ginsenoside Rb₁ from a crude extract of ginseng roots. The ginsenoside-loaded MMIPs were then shown to have protective effects on mitochondrial membrane potential and cellular viability for H9c2 cells treated with CoCl₂ to mimic hypoxia injury. The protective effect of the ginsenosides was assessed by staining with JC-1 dye to monitor the mitochondrial membrane potential. Conclusion: MMIPs can play a dual role in both the extraction and cellular delivery of therapeutic ginsenosides.