• Title/Summary/Keyword: Polymer-Cement Ratio

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Adhesion in Flexure of SBR-Modified Mortars with Fly Ash (플라이애쉬와 SBR을 혼입한 폴리머 시멘트 모르타르의 휨접착강도)

  • Jo, Young-Kug
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.162-163
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    • 2019
  • The purpose of this study is to evaluate the adhesion in flexure of SBR-modified mortar adding Fly Ash(FA). From the test results, the adhesion in flexure is seriously affected by polymer-binder ratios and adding content of FA. The maximum adhesion in flexure of SBR- modified mortar is about 1.46 times, the plain cement mortar. It is apparent that the adhesion in flexure of SBR-modified mortars by polymer-binder ratios is much more improved than that by adding contents of AF.

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Corrosion-Inhibition and Durability of Polymer-Modified Mortars Using Bisphenol A and F Type Epoxy Resin with Calumite (비스페놀 A 및 F형 에폭시수지와 칼루마이트를 병용한 폴리머 시멘트 모르타르의 방청성 및 내구성)

  • Kim, Joo-Young;Kim, Wan-Ki
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.517-524
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    • 2014
  • Nitrite-Type hydrocalumite (calumite) is a material that can adsorb chloride ions ($Cl^-$) that cause corrosion of reinforce bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete. In this study, polymer-modified mortars using two types of epoxy resin with calumite are prepared with various polymer binder-ratios of 0, 5, 10, 15, 20% and calumite contents of 0, 5%. The specimens are tested for chloride ion penetration, carbonation, drying shrinkage and corrosion inhibition. As a result, the chloride ion penetration and carbonation depth of PMM using epoxy resin somewhat increases with increasing calumite contents, but those remarkably decreases depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to decrease with increasing polymer-binder ratio and calumite content. Unmodified mortars with calumite content of 5% did not satisfy quality requirement by KS. However, it was satisfied with KS requirement by the modification of epoxy resin in cement mortar. On the whole, the carbonation and chloride ion penetration depth of epoxy-modified mortars with calumite is considerably improved with an increase in the polymer-binder ratio regardless of the calumite content, and is remarkably improved over unmodified mortar. And, the replacement of the portland cement with the calumite has a marked effect in the corrosion-inhibiting property of the epoxy-modified mortars.

Study on Elevator Induced Structural Vibration Reduction Performance Using Polymer Concrete (폴리머 콘크리트를 이용한 엘리베이터 기인 구조 진동저감 성능 연구)

  • Yeom, Jihye;Kim, Jeong-Jin;Park, Junhong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.6
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    • pp.90-94
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    • 2021
  • With the increased interest on quiescent place for residential place, the noise generation from facilities needs to be minimized. One important noise source include sounds from operation of elevators. The elevator operates between floors and generates significantly annoying sounds to the nearby living spaces. It is recognized as the significant contributor inducing noise annoyance to residents. Elevator is supported to the building structure at several locations for movements between floors. In this study, the vibration reduction by use of polymer concrete on the support location was demonstrated. By measuring and comparing the vibration generation when supported on cement and polymer concrete, the noise reduction performance was evaluated. The polymer concrete was made in the form of being inserted into the wall that imitates the hoistway. The impact vibration was induced to the bracket and vibration transfer magnitude was measured. The damping ratio was evaluated through normalization and curve fitting of transient response, and comparison was performed for each resin mixing ratio. By use of polymer concrete, it was possible to reduce the vibration generation in an effect manner without sacrifice on the structural rigidity.

Experimental study on the behavior of CFT stub columns filled with PCC subject to concentric compressive loads

  • Kang, Hyun-Sik;Lim, Seo-Hyung;Moon, Tae-Sup;Stiemer, S.F.
    • Steel and Composite Structures
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    • v.5 no.1
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    • pp.17-34
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    • 2005
  • This paper presents an experimental study and its findings of the behavior of circular and square stub columns filled with high strength concrete ($f_c^{\prime}$=49MPa) and polymer cement concrete (PCC) under concentric compressive load. Twenty-four specimens were tested to investigate the effects of variations in the tube shape (circular, square), wall thickness, and concrete type on the axial strength of stub columns. The characteristics of CFT stub columns filled with two types of concrete were investigated in order to collect the basic design data for using the PCC for the CFT columns. The experimental investigations included consideration of the effects of the concrete fill on the failure mode, ultimate strength, initial stiffness and deformation capacity. One of the key findings of this study was that circular section members filled with PCC retain their structural resistance without reduction far beyond the ultimate capacity. The results presented in this paper will provide experimental data to aid in the development of design procedures for the use of advanced concretes in CFT columns. Additionally, these results give structural designers invaluable insight into the realistic behavior of CFT columns.

Properties of St/BA Modified Cellular Lightweight Concrete as Sandwich Panel Core (샌드위치패널심재로 활용한 St/BA 개질 다공성 경량 콘크리트의 특성)

  • 강내민;노정식;도정윤;문경주;소양섭
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.31-34
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    • 2003
  • Sandwich panel is composed of the facing sheets which support the external load, the cellular core with the low thermal conductivity and the adhesive agent to bond them. The cellular core was produced by binding lightweight cellular aggregates with cement and two types of acrylic base St/BA emulsion were added with a view to improving the workability ion due to high absorption of light weight aggregate and to develope more strength, respectively. This investigation is to comprehend the effect of the addition of two types of St/BA on thermal conductivity, calorific value and exhaustion content of noxious gas in addition re compressive and flexural strength. Flexural strength of the specimen made with St/BA-2 ranged 20kgf/cm2 to 25kgf/cm2 and was about 50% to 100% as high as that of the non-fiber specimen. Thermal conductivity was recorded from 2.0 to 3.0 kcal/mh$^{\circ}C$ and calorific value of St/BA modified specimen was much lower than that of commercial sandwich panel core of EPS and urethane. Careful caution has to be taken because generation of noxious gas such as CO, NO and SO2 tend to increase with addition of polymer cement ratio.

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Addition of Polymeric Materials to Binders for Solidification of Heavy Metal Contaminated Mine Tailings (폴리머 물질 첨가를 통한 중금속 오염 광미의 고형화 처리)

  • Kim, Tae-Poong;Min, Kyoung-Won;Lee, Hyun-Cheol;Seo, Eui-Young;Lee, Won-Sup
    • Journal of Industrial Technology
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    • v.30 no.A
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    • pp.37-43
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    • 2010
  • Polymeric materials in addition to Portland cement and hydrated limes were used to solidify heavy metal contaminated tailings from five abandoned metal mines in Korea. Mine tailings were mixed separately with Portland cement and hydrated lime at a concentration of 20-30 wt% and 6-9 wt%, respectively and Ethylene Vinyl Acetate(EVA) powder was added to each specimen at a ratio of 2.5 and 5.0 wt% to binders. Polymer-added and polymer-free solidified forms were evaluated for their appropriateness in accordance with the suggested test methods. Regardless of addition of polymeric materials, all solidified forms satisfy the uniaxial compressive strength(UCS) requirements(0.35MPa) for land reclamation and show remarkably reduced leaching concentrations of heavy metals such as As, Cd, Cu, Pb and Zn less than the toxicity criteria of Korean standard leaching test(KSLT). The addition of polymeric materials increased the UCS of solidified forms to improve a long-term stability of solidified mine tailings.

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Effect of PCE superplasticizers on rheological and strength properties of high strength self-consolidating concrete

  • Bauchkar, S.D.;Chore, H.S.
    • Advances in concrete construction
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    • v.6 no.6
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    • pp.561-583
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    • 2018
  • A variety of polycarboxylate ether (PCE)-based superplasticizers are commercially available. Their influence on the rheological retention and slump loss in respect of concrete differ considerably. Fluidity and slump loss are the cardinal features responsible for the quality of concrete. These are related to the dispersion of cement particles and the hydration process which are greatly influenced by type of polycarboxylate ether (PCE)-based superplasticizers. On the backdrop of relatively less studies in the context of rheological retention of high strength self-consolidating concrete (HS-SCC), the experimental investigations were carried out aiming at quantifying the effect of the six different PCE polymers (PCE 1-6) on the rheological retention of HS-SCC mixes containing two types of Ordinary Portland Cements (OPC) and unwashed crushed sand as the fine aggregate. The tests that were carried out included $T_{500}$, V-Funnel, yield stress and viscosity retention tests. The supplementary cementitious materials such as fly ash (FA) and micro-silica (MS) were also used in ternary blend keeping the mix paste volume and flow of concrete constant. Low water to binder ratio was used. The results reveal that not only the PCEs of different polymer groups behave differently, but even the PCEs of same polymer groups also behave differently. The study also indicates that the HS-SCC mixes containing PCE 6 and PCE 5 performed better as compared to the mixes containing PCE 1, PCE 2, PCE 3 and PCE 4 in respect of all the rheological tests. The PCE 6 is a new class of chemical admixtures known as Polyaryl Ether (PAE) developed by BASF to provide better rheological properties in even in HS-SCC mixes at low water to binder mix. In the present study, the PCE 6, is found to help not only in reduction in the plastic viscosity and yield stress, but also provide good rheological retention over the period of 180 minutes. Further, the early compressive strength properties (one day compressive strength) highly depend on the type of PCE polymer. The side chain length of PCE polymer and the fineness of the cement considerably affect the early strength gain.

Guidelines for Joint Depth Determination and Timing of Contraction Joint Sawcutting for JCP Analyzed with Fracture Mechanics

  • Yang, Sung-Chul;Hong, Seung-Ho
    • International Journal of Concrete Structures and Materials
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    • v.18 no.3E
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    • pp.145-150
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    • 2006
  • An experiment with the objective of providing guidelines for joint depth determination and timing of contraction joint sawcutting to avert uncontrolled cement concrete pavement cracking has been conducted. Theoretical analysis and laboratory tests were performed to help in understanding and analyzing the field observation. Using two-dimensional elastic fracture mechanics, the influence of several parameters on crack propagation was delineated by a parametric study, involving initial notch ratio, joint spacing, Young's modulus and thermal expansion coefficient of concrete, temperature gradient, and modulus of subgrade reaction. Bimaterials made of rock plus cement mortar and rock plus polymer mortar were applied to the concrete in a field test section, and they were subjected to fracture tests. These tests have shown that fracture mechanics is a powerful tool not only in judging the quality of the jointed cement concrete pavement but also in providing a criterion for crack propagation and delamination. Based on fracture mechanics, a method is proposed to determine the joint depth, sawcut timing, and spacing of the jointed cement concrete pavement. This method has successfully been applied to a test section in Seohaean expressway. This study also summarizes the research results obtained from a field test for jointed plain concrete pavement, which was also carried out on the Seohaean expressway.

Study on Improving Properties of Tile Cement Mortar by Mixing of Additives (Additives의 혼합에 의한 Tile Cement Mortar 물성향상 연구)

  • Lee, Moo-Jin;Shin, Young-Jo
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.486-490
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    • 1999
  • In this study, to improve the required properties of tile cement mortar such as excellent water retention capacity (WRC), workability, open time, sag resistance, and tile adhesive strength, tile cement mortars containing the several additives with different ratio were compared and analyzed. By adding small amount of synthesized starch to hydroxypropyl methylcellulose (HPMC) which is used for improving WRC, the decrease of moisture evacuation from mortar surface was observed and the workability of mortar was improved with long open time. Polyacrylamide (PAAm) and ethylencvinyl acetate (EVAc) were also added in order to increase the adhesion of tile. As a results, the saggings of mortar itself and tile were decreased and the adhesive strength of mortar between base and tile was enhanced. By adding melment, the workability was improved by increasing the fluidity of mortar. It is postulated that the properties of tile cement mortar was improved by adding 0.80~1.20% of HPMC, 0.10~0.15% of starch, 0.001~0.015% of PAAm, 0.05~0.10% of EVAc and 0.003~0.005% of melment to the cement mortar.

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Synthesis and Application of cPSMA-PSMA Microcapsule Absorbent for Cement Mortars (시멘트 모르타르용 cPSMA-PSMA 마이크로캡슐 흡수제 제조 및 적용)

  • Hwang, Ki-Seob;Jang, Seok-Soo;Jung, Yong-Wook;Lee, Seung-Han;Ha, Ki-Ryong
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.216-222
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    • 2012
  • We synthesized microcapsule absorbent with crosslinked poly(styrene-$alt$-maleic anhydride) (PSMA) as a core and PSMA as a shell by a precipitation polymerization method for the delayed absorption of excess water in cement mortar. cPSMA-PSMAs with core-shell structure were synthesized with ratios of 1/1, 1/2 and 1/3 as core monomer mass to shell monomer mass to control shell thickness. We observed the hydrolysis of PSMA in cement-saturated aqueous solution by a FTIR spectrometer. We observed good core-shell structure microcapsules for 1/2(cPSMA #3), but observed incomplete core-shell structure for 1/1(cPSMA #2) and 1/3(cPSMA #4) of core/shell monomer ratios. The swelling ratio of cPSMA #3 in cement-saturated aqueous solution was increased until 20 min. After that it was decreased until 2 hrs swelling time, and they started to increase again. The viscosities of cement paste with cPSMA #3 microcapsules were very slowly increased until 1 hr and increased fast after 1.5 hrs. Cement mortar with 0.5 wt% cPSMA #1 having only core part showed about 5% increase in compressive strength compared to that of plain cement mortar. cPSMA #3 added cement mortar showed the highest compressive strength with 7% increase.