• 제목/요약/키워드: Polymer viscosity

검색결과 658건 처리시간 0.032초

셀룰로오스를 이용한 전도성 체이스트의 개발 (Novel Conductive Paste based on Cellulose Acetate Butyrate)

  • 김태현
    • 대한화학회지
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    • 제51권2호
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    • pp.171-177
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    • 2007
  • 고분자를 바탕으로 한 전도성 페이스트는 전원과 기기를 연결하는 전도 통로를 제공하여 준다. 이러한 전도성 페이스트는 고분자 바인더와 전도성 금속의 두 부분으로 이루어져 있다. 본 연구에서는 낮은 점도와 우수한 금속 피막성을 가지는 셀룰로오스 아세테이트 부타이레이트를 바인더로 사용하여 새로운 전도성 페이스트를 개발하였다. 전도도 측정 결과 안정된 전도도를 보였을 뿐 아니라, 균일한 코팅성과 유연성을 나타내었다.

광학재료로서 triazine기를 갖는 플라스틱 고분자에 대한 연구 (Study about Plastic Polymer bearing Triazine Group as Optical Material)

  • 이용희;김재종;서명교;이영세
    • 한국산업융합학회 논문집
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    • 제6권3호
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    • pp.171-176
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    • 2003
  • The poly(triazine bissulfide) synthesized from 6-dibutylamino-1,3,5-triazine-2,4-dithiol with bis(4-chloro-3-nitrophenyl) sulfone in the presence of the phase transfer catalyst, the maximum algebra viscosity (0.57 dL/g) is stable at reaction temperature of $60^{\circ}C$ overall. We could not acquire the good result about solubility, thermal property, and molecular weight to make cast film, we made base for the synthesis of functionalization polymer material.

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비상용성 고분자 블렌드의 전단응력과 법선응력 (Steady Shear and normal Stresses of Immiscible Polymer Blends)

  • 이항목
    • 유변학
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    • 제9권2호
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    • pp.81-87
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    • 1997
  • 비상용성 고분자는 그 계면의 특성에 의해서 복잡한 유변학적 거동을 갖는데 그러 한 거동을 해석하기 위해서 최근에 제안된 구성방정식을 토대로 소폭 진동 전단 흐름장에서 의 유변학적 물성과 몰폴로지 전개를 예측한 바 있다. Takahashi[2]등은 이런 흐름하에서의 계면은 거의 변하지 않음을 보여주었고 따라서 이경우는 상대적으로 쉬운편이었다. 본연구 에서는 정상전단흐름장하에서의 몰폴로지 전개에 대한 구성방정식을 간단한 형태로 표현함 으로써 실제 산업계에서 이용될수 있도록 하였다. 그러한 해석을 통하여 원래의 모델에서 제시되었던 3개의 실험변수를 2개로 줄일수 있었으며 계면의 특성을 잘 나타내 주는 새로운 변수($textsc{k}$)를 도입하였다. 계면의 특성을 잘 나타내 주는 이새로운 변수를 통하여 그 계면의 영향을 예측할수 있었다. 한편 분산상의 파괴, 변형, 합체 메카니즘을 모델에 제시되었던 변 수값들을 통하여 해석하였고 이를 실험적인 데이터와 비교해 보았다.

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UV경화성 수지와 Alkyd수지 복합재료의 경화거동과 동적 점탄성에 관한 연구 (A Study on the dynamic viscoelasticity of UV curing polymer and alkyd resin composite materials)

  • 정원식;최정병;김용욱
    • 한국인쇄학회지
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    • 제16권3호
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    • pp.29-41
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    • 1998
  • The ultraviolet(UV)-curable materials wildly have been used as a ink and coating materials. A according to measure UV polymerization phase separation of acryl groups 2,3,4-functional monomer, a few experiments were performed gel fraction, dynamic viscosity of alkyd resin blend system. Dependence of photoiniator concentration and various monomer, alkyd resin content investigated structural changes of films cured by UV irradiation. Curing rate measured UV irradiation under $25^{\circ}C$, cell gap 7cm and film thickness 100${\mu}{\textrm}{m}$. In results, it was through that the viscoelastic properties of films cured with increasing the ratios of monomer/alkydresin contents are network polymer in properties such as viscoelasticity.

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핫엠보싱 공정에서 PMMA의 마이크로/나노 레올로지 특성 (Micro/Nano Rheological Characteristics of PMMA in Hot Embossing Process)

  • 김병희;김광순;반준호;신재구;김헌영
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2004년도 춘계학술대회 논문집
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    • pp.259-264
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    • 2004
  • The hot embossing process as a method for the fabrication of polymer is becoming increasingly important because of its simple process, low cost, high replication fidelity and relatively high throughput. In this paper, we carried out experimental studies and numerical simulations in order to understand the viscous flow of polymer film during hot embossing process. As the initial step of quantitating the hot embossing process, simple parametric studies for the embossing conditions have been carried out using high resolution masters which patterned by DRIE process. Under different embossing times and pressures, the viscous flow of PMMA films into micro/nano cavities has been investigated. Also, the viscous flow during the hot embossing process has been simulated by the continuum based FDM analysis considering micro/nano effect, such as surface tension and contact angle.

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Image Analysis: A Novel Technique to Determine the Efficiency of Wiping Cloths

  • Lee Jae-Hyung;Kim Seong-Hun;Oh Kyung-Wha
    • Fibers and Polymers
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    • 제7권1호
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    • pp.73-78
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    • 2006
  • The ability to absorb liquid and the dust removal performance are important factors for wiping cloths used to remove contaminants. We have developed a method that can determine the contaminant removal performance of wiping cloths. In the gravimetric method, experimental errors are unavoidable because the contaminant plate is much heavier than the contaminant material. However, we used image analysis to reduce the experimental errors, and did not use the heavy contaminant plate. The correlation coefficient between the image. analysis and the gravimetric methods was very high, at R=0.97, with a significance level of 95%. From the correlation analysis and empirical data, the image analysis method is a useful tool for measuring wiping efficiency. The wiping efficiency measured using image analysis has a close relationship to the wiping speed, viscosity of the contaminant, and wiping pressure, at the significance level of 95%.

MMA 개질 강화 플라스틱 복합관의 휨강성 (Flexural Rigidity of MMA-Modified Fiberglass Reinforced Plastic Composite Pipe)

  • 연규석;최종윤;백종만;권택정;정중호
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.429-432
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    • 2003
  • MMA-modified fiberglass-reinforced plastic composite pipe was produced by using the binder of MMA-modified unsaturated polyester resin in which low viscosity MMA was added to unsaturated polyester resin. Sixteen specimens were made of polymer mortar and fiberglass-reinforced plastic by the centrifugal method. For these specimens the external strength tests were carried out by taking the core thickness consisting of polymer mortar and the fiberglass content per unit area as experimental variables to figure out the effect of variations of these variables influencing on flexural rigidity that is an important property for the composite pipe. Results of this study are believed to provide the basic data for more economical and practical design of MMA-modified fiberglass-reinforced plastic composite pipe.

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입자유동시스템에 의한 스프링콜릿 버의 디버링 효과 (Effect on the Deburring of Spring Collet Burr by Abrasive Flow System)

  • 김정두
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 1998년도 추계학술대회 논문집
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    • pp.192-197
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    • 1998
  • Abrasive flow machining is useful to abrasive polish a internal or external surface of the free shape dimensional parts, which are used in many fields such as machine tool parts, semi-conductor, and medical component industries. The machining process is that two hydraulic cylinders, which are located surface to surface, are enforce media to the passage between workpiece and tooling part alternately, and then the abrasives included in the media pass the passage and polish the surface of workpiece. The media which is made of polymer and abrasive plays complex have workpiece by its viscoelastic characteristics. In this study, the media for AMF was made by mixing viscoelastic polymer with alumina and silicon carbide abrasive respectively. As a result, alumina include media is also the experiments of deburring the inside burr of in order to analyse the deburring machinability of abrasive flow machining according to various machining parameters which were media flow rate extrusion pressure, passage gap, media viscosity, abrasive content, and abrasive grain size.

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Silicate dispersion and rheological properties of high impact polystyrene/organoclay nanocomposites via in situ polymerization

  • Kim, Byung-Chul;Lee, Seong-Jae
    • Korea-Australia Rheology Journal
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    • 제20권4호
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    • pp.227-233
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    • 2008
  • High impact polystyrene (HIPS)/organoclay nanocomposites via in situ polymerization were synthesized and their rheological properties were investigated. For the study, two types of organoclays were used: a commercially available organoclay, Cloisite 10A (C10A), and a laboratory-prepared organoclay having a reactant group, vinylclay (ODVC). The X-ray diffraction and transmission electron microscopy experiments revealed that the HIPS/ODVC nanocomposite achieved an exfoliated structure, whereas the HIPS/C10A nanocomposite achieved an intercalated structure. In the small-amplitude oscillatory shear experiments, both storage modulus and complex viscosity increased with increasing organoclay. A pronounced effect of the organoclay content was observed, resulting in larger storage modulus and stronger yield behavior in the low frequency region when compared to neat HIPS. The crossover frequencies associated with the inverse of a longest relaxation time decreased as the organoclay content increased. Over a certain value of ODVC content, a change of pattern in rheological properties could be found, indicating a solid-like response with storage modulus greater than loss modulus at all frequencies.

Fluorescence Characterization of LaRC PETI-5, BMI, and LaRC PETI-5/BMI Blends

  • Cho, Donghwan;Yang, Gyeongmo
    • Fibers and Polymers
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    • 제3권2호
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    • pp.60-67
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    • 2002
  • In the present study, the fluorescence behavior ova phenylethynyl-terminated imide (LaRC PETI-5) resin, a bismaleimide (BMI) resin, and various LaRC PETI-5/BMI blends with different blend compositions has been characterized as a function of heat-treatment temperature, using a steady-state fluorescence technique with a front-face illumination method far solid-state films. It is observed that there are distinguishable changes in the spectral shape, size, and position of fluorescence with varying heat-treatment temperature in the pure and blend samples. The result is qualitatively explained in terms of charge transfer complex formation as well as microenvironmental change with local mobility and viscosity occurring in the LaRC PETI-5, BMI, and their blends during the cure process. The result also implies that a steady-state fluorescence technique may be a useful tool to understand the processing conditions of polyimides and their blends in the film form on the basis of their thermo-photophysical responses.