• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.161-162
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• 2022

The purpose of this study is to determine the viscosity of the polymer-cement composites(PCCs) for crack repair of RC structures and to investigate its compaction. According to the study on the viscosity and compaction property of PCCs for crack repair, the viscosity of PCCs varies greatly depending on the polymer type and polymer cement ratio, and by mixing silica fume into PCCs, appropriate viscosity and excellent flow can be controlled without separation of cement and water. As a result of this study, basic data on the viscosity, fluidity, and compaction properties of PCCs for crack repair of RC structure can be obtained.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.166-167
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• 2021

The purpose of this study is to evaluate the viscosity and flowability of polymer-cement composites for repairing cracks of RC structures. The viscosity and flowability of the polymer cement composites differed greatly depending on the type of polymer and the polymer cement ratio, and the polymer cement composites could be produced that could repair fine cracks in the RC structure without material separation by adjusting the proper water-cement ratio. In particular, the mixing of high viscosity EVA-modified polymer composites could be adjusted.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.10
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• pp.4673-4678
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• 2011

In this paper, studies on a mixing characteristic and viscosity measurement of polymer/graphite composites for a bipolar plate of the polymer electrolyte membrane fuel cell were presented. Since the materials for the bipolar plate should be electrically conductive, contents of solid graphite in the composite are very high. As a consequence, a viscosity of the polymer/graphite composite used for the bipolar plate is very high and the measurement of the viscosity is difficult. Viscosity measurements of the polymer/graphite composites were not possible because pressure drops were continuously fluctuated during the viscosity measurements when a conventional capillary die was used. After the die design was optimized, the steady state pressure drop could be achieved, but the viscosity thus measured was not reproducible. After many trials with different experimental techniques, it was found that melt blending of the grinded powder mixtures of both PET and graphite provides reproducible viscosity measurements and electric conductivities of the polymer/graphite composites.

• Fibers and Polymers
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• v.3 no.3
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• pp.103-108
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• 2002

The viscosity effect of matrix polymer on melt exfoliation behavior of an organoclay in poly($\varepsilon$-caprolactone) (PCL) was investigated. The viscosity of matrix polymer was controlled by changing the molecular weight of poly($\varepsilon$-eaprolactone), the processing temperature, and the rotor speed of a mini-molder. Applied shear stress facilitates the diffusion of polymer chains into the gallery of silicate layers by breaking silicate agglomerates down into smaller primary particles. When the viscosity of PCL is lower, silicate agglomerates are not perfectly broken into smaller primary particles. At higher viscosity, all of silicate agglomerates are broken down into primary particles, and finally into smaller nano-scale building blocks. It was also found that the degree of exfoliation of silicate layers is dependent upon not only the viscosity of matrix but thermodynamic variables.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.132-132
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• 2006

Filler loading (fiber or particulate) usually increases the melt viscosity of polymers. In contrast, the addition of these fillers and fibrillation of thermotropic liquid crystalline polymer (LCP) jointly decreased the viscosity of polymer melts to lower than those of pure component polymers, filler-loaded or LCP-blended ones; and even decreased the viscosity with increasing filler loading. Termed as rheological hybrid effect, this phenomenon correlated well with the LCP fibrillation in these ternary systems. Research taking fillers of various shapes and sizes showed that the filler addition promoted the LCP fibrillation, depending upon thermodynamic and dynamic factors involved.

• Polymer(Korea)
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• v.29 no.6
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• pp.565-570
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• 2005

Melt processing characteristics of nylon 6 (N6) has been investigated by controlling the melt viscosity in melt impregnation process. Calcium stearate (CaST) was introduced as a lubricant for N6 and the melt viscosity of N6 decreased with adding only 1 wt$\%$ of CaST. In addition, reactive blending with polycaprolactone (PCL) was carried out by lowering the melt viscosity in N6. It was found that the melt viscosity of N6 could be controlled and further melt viscosity drop could be obtained by applying phenyl phosphite (PP) and diphenyl phosphite (DPP) to enhance the transesterification between N6 and PCL. Our approaches show that the melt viscosity of N6 could be reduced without loss of thermal stability which is the critical problem in high temperature melt impregnation process of N6.

• Korea-Australia Rheology Journal
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• v.15 no.4
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• pp.179-185
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• 2003

Associating polymers act as flocculants in colloidal suspensions, because the hydrophobic groups (hydrophobes) can adsorb onto particle surfaces and create intermolecular cross-linking. The steady-shear viscosity and dynamic viscoelasticity were measured for suspensions flocculated by multichain bridging of associating polymers. The effects of surfactant on the suspension rheology are studied in relation to the bridging conformation. The surfactant molecule behaves as a displacer and the polymer chains are forced to desorb from the particle surfaces. The overall effect of surfactant is the reduction of suspension viscosity. However, the additions of a small amount of surfactant to suspensions, in which the degree of bridging is low, cause a viscosity increase, although the number of chains forming one bridge is decreased by the forced desorption of associating polymer. Since the polymer chains desorbed from one bridge can form another bridge between bare particles, the bridging density over the system is increased. Therefore, the surfactant adsorption leads to a viscosity increase. The surfactant influences the viscosity in two opposing ways depending on the degree of bridging.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.1 s.244
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• pp.67-73
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• 2006

This investigation deals with the spin-up flows in a circular container of aspect ratio, 2.0. Shear front is generated in the transient spin-up process and propagating from the side wall to the central axis in a rotating container. Propagation of the shear front to the axis in a rotating container means the region acquires an angular momentum transfer from the solid walls. Propagating speed of the shear front depends on the apparent viscosity of polymer solution. Two kinds of polymer solutions are considered as a working fluid: one is CMC and the other is CTAB solution. CMC solution has larger apparent viscosity than that of water, and CTAB shows varying apparent viscosities depending on the applied shear rates. Transient and spatial variations of the apparent viscosities of the present polymer solutions (CTAB and CMC) cause different speeds of the propagating shear front. In practice, CMC solution that has larger values of apparent viscosity than that of water always shows rapid approach to the steady state in comparison of the behavior of the flows with water. However, for the CTAB solution, the speed of the propagating of the shear front changes with the local magnitude of its apparent viscosity. Consequently, the prediction of Wedemeyer's model quantitatively agrees with the present experimental results.

• Journal of the Society of Disaster Information
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• v.6 no.1
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• pp.10-24
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• 2010

In this paper, warm asphalt binder was proposed as a substitute for the polymer-modified asphalt binder to get higher viscosity than that of the polymer-modified at the same temperature. Performance grade test and rotational viscosity of warm asphalt binder were conducted to evaluate the property variations due to the addition of admixture. Research results showed that the viscosity of warm asphalt binder at $100^{\circ}C$ was similar to that of the conventional asphalt binder. The performance and durability of warm asphalt binder were also comparable to those of the polymer-modified. It is considered that the active applications of warm asphalt binder can reduce environmental damages due to less diffusions of carbon dioxide compared to the conventional.

• Korea-Australia Rheology Journal
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• v.18 no.2
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• pp.83-90
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• 2006

Supercritical carbon dioxide ($scCO_2$) has advantages of being incorporated in polymer with high solubility and of being recovered easily by depressurizing. $scCO_2$ reduces the viscosity of polymer melt and it is expected to be use as a plasticizing agent. In this work, we studied on the effect of $scCO_2$ on the rheological properties of polymer melts during extrusion process. Slit die attached to twin screw extruder was used to measure the viscosity of polymer melts plasticized by supercritical $CO_2$. A gas injection system was devised to accurately meter the supercritical $CO_2$ into the extruder barrel. Measurements of pressure drop within the die, confirmed the presence of a one phase mixture and a fully developed flow during the measurements. The viscosity measurement of polypropylene was performed at experimental conditions of various temperatures, pressures and $CO_2$ concentrations. We observed that melt viscosity of polymer was dramatically reduced by $CO_2$ addition.