• Title/Summary/Keyword: Polymer specimen

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Flame Retardant Properties of Polymer Cement Mortar Mixed with Light-weight Materials for 3D Printing (3D 프린팅용 경량재료 혼입 폴리머 시멘트 모르타르의 난연특성)

  • Son, Bae-Geun;Song, Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.330-337
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    • 2021
  • 3D printing is not only at the fundamental study and small-scale level, but has recently been producing buildings that can be inhabited by people. Buildings require a lot of cost and labor to work on the form work, but if 3D printing is applied to the building, the construction industry is received attention from technologies using 3D printing as it can reduce the construction period and cost. 3D printing technology for buildings can be divided into structural and non-structural materials, of which 3D printing is applied to non-structural materials. Because 3D printing needs to be additive manufacturing, control such as curing speed and workability is needed. Since cement mortar has a large shrinkage due to evaporation of water, cement polymer dispersion is used to improve the hardening speed, workability, and adhesion strength. The addition of polymer dispersion to cement mortar improves the tensile strength and brittleness between the cement hydrate and the polymer film. Cement mortar using polymer materials can be additive manufacturing but it has limited height that can be additive manufacturing due to its high density. When light-weight materials are mixed with polymer cement mortar, the density of polymer cement mortar is lowered and the height of additive manufacturing, so it is essential to use light-weight materials. However, the use of EVA redispersible polymer powder and light-weight materials, additional damage such as cracks in cement mortar can occur at high temperatures such as fires. This study produced a test specimen incorporating light-weight materials and EVA redispersible polymer powder to produce exterior building materials using 3D printing, and examined flame resistance performance through water absorption rate, length change rate, and cone calorimeter test and non-flammable test. From the test result, the test specimen using silica sand and light-weight aggregate showed good flame resistance performance, and if the EVA redispersible polymer powder is applied below 5%, it shows good flame resistance performance.

A Correlation Between Crack Growth and Abrasion for Selected Rubber Compounds

  • Lee, Hyunsang;Wang, Wonseok;Shin, Beomsu;Kang, Seong Lak;Gupta, Kailash Chandra;Nah, Changwoon
    • Elastomers and Composites
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    • v.54 no.4
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    • pp.313-320
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    • 2019
  • A typical wear pattern was reported to resemble the fatigue crack growth behavior considering its mechanism, especially for amorphous rubbers such as styrene-butadiene rubber (SBR). In this study, the wear and crack growth rates were correlated using two separate experiments for carbon black and silica-reinforced selected rubber compounds. The wear rate was determined using a blade-type abrasion tester, where the frictional energy input during wearing was measured. The crack propagation rate was determined under different tearing energy inputs using a home-made fatigue tester, with a pure-shear test specimen containing pre-cracks. The rates of abrasion and crack propagation were plotted on a log-log scale as a function of frictional and tearing energies, respectively. Reasonable agreement was observed, indicating that the major mechanism of the abrasion pattern involved repeated crack propagation.

Tensile Properties of Plain Weave Glass Fabric Reinforced Epoxy Resin Laminates at Low Temperatures (평직유리섬유 강화 에폭시 적층판의 저온 인장 특성)

  • Kim, Yon-Jig
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.9
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    • pp.788-795
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    • 2008
  • To understand the tensile behaviors of GFRP at low temperature, three types of specimen have been used in this study. Tensile properties and fracture mechanisms for three orthogonal orientations of plain weave glass fabric reinforced epoxy resin laminate were investigated at temperature range of about -30 to $15^{\circ}C$. The tensile properties of axial and edge type specimen decrease slightly with decreasing temperature to $-20^{\circ}C$. However, at $-30^{\circ}C$ the decreases in the tensile properties increased considerably. Below $-20^{\circ}C$, thickness type specimen showed a marked decreases in the tensile properties. It was obvious that the fracture manner of thickness type specimen was adhesive failure at above $-10^{\circ}C$ and a mixed adhesive and cohesive failure at below $-20^{\circ}C$.

Stress Block of High Strength Polymer Concrete Flexural Members (고강도 폴리머 콘크리트 휨부재의 응력블럭)

  • 김관호;김남길;연규석
    • Journal of the Korea Concrete Institute
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    • v.14 no.5
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    • pp.638-644
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    • 2002
  • The stress-strain relationship of polymer concrete flexural member was evaluated using C-shaped polyester concrete specimen, the compressive strength of which is 1400 kgf/$\textrm{cm}^2$. Eccentric compression test was performed to estimate the parameters, ${\alpha}$, ${\beta}$1, ${\gamma}$ for equivalent rectangular stress block. The ultimate moment strength ware obtained from the bending test on reinforced polymer concrete beams which were prepared with S different tensile steel ratios with a shear span ratio of 4.0. These values were compared with theoretical ultimate moment strengths, which were obtained using the parameters ${\alpha}$=0.61 and ${\beta}$1=0.73 from stress-stain curves of C-shaped specimens. The results showed that, when tensile steel ratio was over 0.50 $\rho$b, the experimentally obtained moment strengths were well matched with theoretically calculated values. In order to develop accurate criteria for polymer concrete flexural members, however, many other expermental studies for parameter determination are necessary using C-shaped specimens which have various compressive strengths and different sizes.

Mechanical Properties of High Strength Polymer Concrete Using Unsaturated Polyester Resin (불포화 폴리에스터 수지를 이용한 고강도 폴리머 콘크리트의 역학적 특성)

  • 연규석;김관호;이필호;김동수;박윤제
    • Magazine of the Korea Concrete Institute
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    • v.6 no.3
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    • pp.131-141
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    • 1994
  • This study was carried out to develop a procedural method to produce high strength polymer concrete using unsaturated polyt.ster resin and to examine its mechanical properties. Various mechanical properties were analyzed with respect to materials and additives. A method to produce high strength polymer concrete was successfully developed. Comperssive strength of $1,291~1,445 kg/cm^2$, splitting tensile strength of $106~145 kg/cm^2$ and flexural strength of $182~235 kg/cm^2$, at age of 7days wer-e achieved from the cylinderical ;md beam specimen prepared with the method. Modulus of elasticity. Poisson's rntio and the ultirnate corn pressive strain of cylinderical specimen were $2.8~3.8{\times}10^5\;kg/cm^2$. 0.21~0.32, and 0.005~0. 0065, respectively. Modulus of elasticity of the polymer concrete was smaller than that of hlgh strength cement concrete while the maximum compressive strain was very larger than that of high strength cement concrete.

Annealing Effect in the Cold-Plastic Deformation of Amorphous PET Material (무정형 PET 재료의 플라스틱 냉간 변형에서의 열처리 효과)

  • Lee, Jong-Young;Park, Seong-Soo
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.56-62
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    • 2001
  • When polyethylene terephthalate(PET) film specimen were stepwise elongated under tension with various speeds of about 0.5~500 mm/min, the necking area, consisted of transparent and opaque bands, was formed during plastic deformation. Stress oscillation was apparently obtained in the stress-strain curve of above specimen. However, stress oscillation was not obtained in the stress-strain curve of annealing specimen. Microstructure was examined dynamically using an optical microscopy and thermal analysis was carried out in a differential scanning calorimeter at a heating rate of 10${\circ}$/min. Also, orientation and crystallization were examined using monochromatic-pinhole technique and elastic modulus was measured by a dynamic mechanical analyzer in the temperature range of -150~70 ${\circ}$ with the frequency of 1 Hz. Transparent PET products were fabricated by use of the PET pellets annealed at 83${\circ}$ for 30 min in an electric furnace.

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Hot Water Resistance of Polymer Mortar Composites Depending on Unsaturated Polyester Resin Types (불포화폴리에스테르 수지의 형태에 따른 폴리머 모르타르 복합재료의 내열수성)

  • Hwang, Eui-Hwan;Song, Min-Kyu;Kim, Yong-Yeon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.201-208
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    • 2018
  • The ortho- and iso- type unsaturated polyester resins were synthesized and used as a polymer binder of the polymer mortar composite. Styrene monomer and acrylonitrile were used as a diluent for the unsaturated polyester resin. Methyl ethyl ketone peroxide (MEKPO) and cobalt octoate (CoOc) were used as a curing agent and an accelerator, respectively. Four kinds of unsaturated polyester resins were prepared according to types of the resin and diluent, and used as a polymer binder in the preparation of the specimen. A total of 16 polymer mortar specimens were prepared according to the added amount of the polymer binder and subjected to a hot water resistance test, followed by compressive and flexural strength tests, and pore and SEM analyses. As a result, it was found that the strength of the specimen using the iso-type unsaturated polyester resin as the polymer binder was better than that of using the ortho-type unsaturated polyester resin. The total pore volume and diameter measured after the hot water resistance test were reduced compared to the values before the test. In the micrographs observed before the hot water resistance test, the polymer binder, filler and fine aggregate were firmly combined to the co-matrix, but the polymer binder was mostly decomposed in the micrographs observed after the test.

A Evaluation of Environmental Resistance for Bio-Polymer Concretes (바이오 폴리머 콘크리트의 환경 저항성 평가 연구)

  • Kim, Je Won;Kim, Tae Woo;Park, Hee Mun;Kim, Bu Il
    • International Journal of Highway Engineering
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    • v.15 no.5
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    • pp.75-79
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    • 2013
  • PURPOSES : The objective of this study is to evaluate the environmental resistance of bio-polymer concrete for use of pavement materials developed for reducing the carbon-dioxide. METHODS : The compression, tension, and bending strength tests were conducted on the bio-polymer concrete specimens with and without environmental conditioning. The specimens were conditioned using the freezing-thaw and accelerated weathering process for long period of time. To assess the resistance against chloride, the chloride ion penetration resistance tests were carried out on the bio-polymer concrete specimens. RESULTS : Test results show that the maximum difference in strength between specimens with and without conditioning is about 2.6MPa indicating that the effect of environmental conditioning on specimen strength is negligible. Based on the chloride ion penetration resistance test, the penetration quantity of electric charge of the specimens is zero and there is no ion penetration within the bio-polymer concrete. CONCLUSIONS : It is found from this study that there is slight change in strength of bio-polymer concretes before and after environmental conditioning process and no chloride ion penetration observed in these specimens. Therefore, the developed bio-polymer concretes can be applied effectively as pavement materials due to the small change of physical properties with environment change.

Evaluation of Strengthening Capacity of Axial Member Using Admixture-Modified Mortar (혼화재 첨가 모르터를 이용한 압축부재의 보강성능 평가)

  • 박준명;양동석;박선규
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.417-422
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    • 2002
  • Strength and Durability of reinforced concrete exposed at deteriorated environment are decreased by cover spatting and corrosion of reinforcement. The purpose of this paper is to evaluate capacity of strengthening axial member using admixture-modified mortar. To investigate the capacity of strengthened axial member, behavior and strength of strengthening specimens were compared with a monolithic basic specimen. Admixture-modified mortar was prepared with silica fume, zeolite, polymer as cement modifier. From the result of this experiment, strengthening specimens using polymer-modified mortar have apparrent strengthening capacity because of good flexural strength and tensile strength.

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$MoSi_2$/SiC Ceramic Composites Prepared by Polymer Pyrolysis (고분자 열분해에 의한 $MoSi_2$/SiC 세라믹 복합체)

  • 김범섭;김득중;김동표
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.805-810
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    • 2000
  • The formation, microstructure and properties of MoSi2/SiC ceramic composites by polymer pyrolysis were investigated for the application of heating element material. Polymethylsiloxanes were mixed with Si, SiC, MoSi2 as filler and ceramic composites prepared by pyrolysis in N2 atmosphere at 1320~145$0^{\circ}C$ were studied. Dimensional change, density variation and phases were analyzed and correlated to the resulting material properties. Microstructures of ceramic composite prepared by polymer pyrolysis were composed of MoSi2, SiC and silicon oxycarbide glass matrix. Depending on the pyrolysis conditions, ceramic composites with a density of 86~90 TD%, a fracture strength of 213~284 MPa, a thermal expansion coefficient of 4~7$\times$10-6 were obtained. The electrical resistivity of the specimen decreased with increasing of temperature up to 50$0^{\circ}C$.

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