• 제목/요약/키워드: Polymer networks

검색결과 142건 처리시간 0.027초

Epoxy/Silicon Epoxy/Urethane계 IPN 복합재료의 개발에 관한 연구 (A study on the Dielectric Properties of IPN based on the Epoxy/Silicon and Epoxy/Urethane)

  • 신중흥;정은식;박정후
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1987년도 정기총회 및 창립40주년기념 학술대회 학회본부
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    • pp.504-507
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    • 1987
  • Interpenerating Polymer Networks (IPNs) are unique type of polymer blend, synthesized by swelling a crossed polymer (Epoxy) with second polymer (Silicon) and also we adopted Urethane as the second polymer. The relationship between dielectric and mechanical properties of high temperature curing IPNs(E/S, E/U) are investigated. The ratios of weight that we formed we re two kind of thing, one (E/S) about 1[wt%]. 3[wt%], 5[wt%], 7[wt%], 10[wt%], and the other (E/U) about 5[wt%], 15[wt%], 25[wt%]. It was heat-cured for 24hours at $100^{\circ}C$ 48 hours at $10^{\circ}C$, 5 hours at $130^{\circ}C$, 15hours at $130^{\circ}C$ in E/S and also for 5 hours at $130^{\circ}C$ in E/U. From the viewpoint of dielectric and mechanical properties, the optimum condition is obtained from the sample cured for 5hours at $130^{\circ}C$ for 1[wt%] in the E/S, and also obtained from the sample cure d for 5 hours at $130^{\circ}C$ in E/U.

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폴리머 네트워크가 형성된 TN 액정셀의 고속응답 특성 (Fast Switching of a Polymer-networked Twisted Nematic Liquid Crystal Cell)

  • 진혜정;김기한;백종인;김재창;윤태훈
    • 한국광학회지
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    • 제21권2호
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    • pp.69-73
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    • 2010
  • 본 논문에서는 광학적으로 비등방성인 폴리머를 이용하여 $90^{\circ}$ TN(Twisted Nematic) 액정셀의 응답시간을 향상시키는 방법을 제안하였다. 액정과 비등방성 폴리머를 일정 비율로 혼합하여 TN 액정셀에 주입한 뒤 UV를 조사하여 폴리머 네트워크를 형성시킴으로써 투과율에 영향을 주지 않고 응답시간을 향상시킬 수 있다. 폴리머 네트워크가 형성되지 않은 TN 액정셀의 turn-off 시간이 16 ms인데 반해 제안된 방법에서는 액정과 비등방성 폴리머의 혼합 비율이 3, 5, 10 wt%로 증가할 때 12, 11, 9 ms로 고속 turn-off가 구현될 수 있다. 또한, turn-off 동작 시 TN 액정셀에서 발생하였던 delay time과 backflow가 폴리머 네트워크의 형성에 의해 크게 개선됨을 확인하였다.

마이크로파를 응용한 Rubber Compound의 가황 - (I) 마이크로파에 의한 White Carbon의 가열특성 - (Microwave Application to the Vulcanization of Rubber Compound -(I) The Heating Characteristics of While Carbon by Microwave-)

  • 박찬영;김정곤;민성기
    • Elastomers and Composites
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    • 제32권5호
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    • pp.318-324
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    • 1997
  • Since the rigid and continuous networks of high-purity silica(white carbon) were relatively transparent to microwaves, high purity silica coupled with microwaves using a zirconia susceptor at room temperature and it was then heated to its melting temperature. The low-purity silica, contained small amount of impurities, yielded greater microwave absorption owing to easy motion of the interstitial alkali ions and it was then heated to its melting temperature. X-ray diffraction patterns of the low-purity silica were broader than those of the high-purity silica due to higher concentration of non-bridging bond and more deformed random network structure. In the vulcanization process of whitened or coloured rubber compound which is employing low-purity silica(white carbon) as a reinforcing filler, vulcanizate could be obtained effectively by microwave heating energy.

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Structure Formation in Multilayered Films Prepared by the Layer-by-Layer Deposition using PAA and HM-PEO

  • Seo, Jin-Hwa;Lutkenhaus Jodie L..;Kim, Jun-Oh;Hammond Paula T.;Char Kook-Heon
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.295-295
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    • 2006
  • In present study, poly(acrylic acid) (PAA) and hydrophobically modified poly(ethylene oxide) (HM-PEO) multilayers based on the hydrogen bonding between the component polymer pair have been prepared by the LbL deposition method. Dip assembled HM-PEO/PAA multilayers yield unique film morphologies in comparison with PEO/PAA multilayers due to the micellar formation of HM-PEO owing to the hydrophobic attraction between alkyl chains end-capped with the PEO chains. Individual HM-PEO micelles were connected through the bridging PEO chains to form temporary networks on multilayer surface and induced peculiar surface morphology on HM-PEO/PAA multilayers above the critical number of bilayers.

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Computation of dilute polymer solution flows using BCF-RBFN based method and domain decomposition technique

  • Tran, Canh-Dung;Phillips, David G.;Tran-Cong, Thanh
    • Korea-Australia Rheology Journal
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    • 제21권1호
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    • pp.1-12
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    • 2009
  • This paper reports the suitability of a domain decomposition technique for the hybrid simulation of dilute polymer solution flows using Eulerian Brownian dynamics and Radial Basis Function Networks (RBFN) based methods. The Brownian Configuration Fields (BCF) and RBFN method incorporates the features of the BCF scheme (which render both closed form constitutive equations and a particle tracking process unnecessary) and a mesh-less method (which eliminates element-based discretisation of domains). However, when dealing with large scale problems, there appear several difficulties: the high computational time associated with the Stochastic Simulation Technique (SST), and the ill-condition of the system matrix associated with the RBFN. One way to overcome these disadvantages is to use parallel domain decomposition (DD) techniques. This approach makes the BCF-RBFN method more suitable for large scale problems.

망목 구조 변화에 따른 에폭시 수지의 유전 특성에 관한 연구 (A Study on the Dielectric Characteristics in Epoxy Resins due to Variation of Network Structures)

  • 김재환;손인환;심종탁;김경환;김명호;최병옥
    • E2M - 전기 전자와 첨단 소재
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    • 제10권7호
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    • pp.651-658
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    • 1997
  • In this paper, effect of interpenetrating polymer network(IPN) introduction on the dielectric properties, heat proof properties, internal structure and defects of the Epoxy/SiO$_2$composite materials, were investigated. we reported a relation between network structures and electrical properties, especially dielectric characteristics with variation of network structures for epoxy composite materials. According to experimental results, the specimens which have single network structures have lower dielectric constant than interpenetrating polymer network(IPN) specimens, but have relatively larger dependency to variation of temperature and frequency. It was confirmed that change of structures is attained by introducing of IPN to insulating materials. Therefore it is counted that introduction of multiple structure including IPN is necessary to improve heat proof and electrical properties.

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3-3형 복합압전체 초음파 센서를 이용한 3차원 수중 물체인식 (3-D Underwater Object Recognition Using Ultrasonic Sensor fabricated with 3-3 Type Piezoelectric Composites)

  • 조현철
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1682-1684
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    • 2000
  • In this study, 3-D underwater object recognition using ultrasonic sensor fabricated with porous PZT-polymer 3-3 composites and SCL neural networks are presented. The recognition rates for the training data and the testing dara were 100 and 94.6% respectively.

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Crystallization of Poly(vinylidene fluoride)-SiO2 Hybrid Composites Prepared by a Sol-gel Process

  • Cho, Jae Whan;Sul, Kyun Il
    • Fibers and Polymers
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    • 제2권3호
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    • pp.135-140
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    • 2001
  • Organic-inorganic hybrid composites consisting of poly(vinylidene fluoride) (PVDF) and SiO$_2$ were prepared through a sol-gel process and the crystallization behavior of PVDF in the presence of $SiO_2$ networks was investigated by spectroscopic, thermal and x-ray diffraction measurements. The hybrid composites obtained were relatively transparent, and brittleness increased with increasing content of tetraethoxysilane (TEOS). It was regarded from FT-lR and DSC thermal analyses that at least a certain interaction existed between PVDF molecules and the $SiO_2$ networks. X-ray diffraction measurements showed that all of the hybrid samples had a crystal structure of PVDF ${\gamma}$-phase. Fresh gel prepared from the sol-gel reaction showed a very weak x-ray diffraction peak near 2$\theta$=$21^{\circ}$ due to PVDF crystallization, and Intensity increased grade-ally with time after gelation. The crystallization behavior of PVDF was strongly affected by the amount of $SiO_2$ networks. That is, $SiO_2$ content directly influenced preference and disturbance fur crystallization. In polymer-rich hybrids, $SiO_2$ networks had a favorable effect on the extent of PVDF crystallization. In particular, the maximum portent crystallinity of PVDF occurred at the content of 3.7 wt% $SiO_2$ and was higher than that of pure PVDF. However. beyond about 10 wt% $SiO_2$, the crystallization of PVDF was strongly confined.

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