• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.07a
• /
• pp.255-258
• /
• 2000

The new approach for synthesis of novel condensation monomers and polyimides on the basis of them was developed. The correlation between synthesis regularities, structure and properties of monomers and polyimides was studied. The areas of industrial application of synthesized polymer were determined.

• Journal of Adhesion and Interface
• /
• v.3 no.4
• /
• pp.44-52
• /
• 2002

Composite materials are created by combining two or more component to achieve desired properties which could not be obtained with the separate components. The use of reinforcing fillers, which can reduce material costs and improve certain properties, is increasing in thermoplastic polymer composites. Currently, various inorganic fillers such as talc, mica, clay, glass fiber and calcium carbonate are being incorporated into thermoplastic composites. Nevertheless, lignocellulose fibers have drawn attention due to their abundant availability, low cost and renewable nature. In recent, interest has grown in composites made from lignocellulose fiber in thermoplastic polymer matrices, particularly for low cost/high volume applications. In addition to high specific properties, lignocellulose fibers offer a number of benefits for lignocellulose fiber/thermoplastic polymer composites. These include low hardness, which minimize abrasion of the equipment during processing, relatively low density, biodegradability, and low cost on a unit-volume basis. In spite of the advantage mentioned above, the use of lignocellulose fibers in thermoplastic polymer composites has been plagued by difficulties in obtaining good dispersion and strong interfacial adhesion because lignocellulose fiber is hydrophilic and thermoplastic polymer is hydrophobic. The application of lignocellulose fibers as reinforcements in composite materials requires, just as for glass-fiber reinforced composites, a strong adhesion between the fiber and the matrix regardless of whether a traditional polymer matrix, a biodegradable polymer matrix or cement is used. Further this article gives a survey about physical and chemical treatment methods which improve the fiber matrix adhesion, their results and effects on the physical properties of composites. Coupling agents in lignocellulose fiber and polymer composites play a very important role in improving the compatibility and adhesion between polar lignocellulose fiber and non-polar polymeric matrices. In this article, we also review various kinds of coupling agent and interfacial mechanism or phenomena between lignocellulose fiber and thermoplastic polymer.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.7 no.4
• /
• pp.445-451
• /
• 2019

In this study, we evaluated the durability of concrete produced with recycled polymer that could replace synthetic polymer, which is the main raw material of bridge deck concrete pavement. As a result of the slump and air content test, the requirements of the Korea Highway Corporation Standard were satisfied with all mixing conditions. The slump was lowered when incorporating the recycled bio-polymer, compared to other mix proportions concrete. In contrast, the compressive strength was increased by 6.3~24.4% when the recycled bio-polymer was mixed, compared to the concrete produced with synthetic polymer. It should be noted that the compressive strength was lowered when synthetic polymer was added to concrete mixture. Durability test results showed the best durability when incorporating synthetic polymer. The durability of concrete also increased as the amount of recycled bio-polymer increased, however, the impact was slightly smaller than that of synthetic polymer.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2022.11a
• /
• pp.71-72
• /
• 2022

In this paper, the performance evaluation of the vibration damping ratio according to the polymer mixing ratio of the polymer modified mortar used as the floor finishing material of the apartment building structure was evaluated. To compare the vibration damping rate, ordinary potland cement (OPC) mortar and polymer modified mortar (PMM) were prepared. In addition, the mixed polymer was mixed with Styrene Butadiene Rubber (SBR) liquid polymer with a solid content of about 49%. Accordingly, the W/C of the test specimen was adjusted and compounded, and the experiment was conducted by mixing 5 types of the test specimen: OPC-60, PMM-5%, PMM-10%, PMM-15%, and PMM-20%. In addition, in order to adjust the W/C of the specimen, the fluidity of each specimen was set as 210 (±5) mm. The specimens measured density and flow in fresh mortar and after curing for 28 days, flexural strength, compressive strength and ultrasonic pulse were measured. The attenuation rate was shown. The experimental results showed that the density increased according to the mixing of the polymer, the flexural strength increased as the mixing rate of the polymer increased, and the compressive strength was decreased. In addition, it was shown that the vibration damping rate increases with the increase in the amount of polymer incorporated.

• The Journal of Korean Academy of Prosthodontics
• /
• v.43 no.6
• /
• pp.717-726
• /
• 2005

Statement of problem. One of the common problems of provisional crown and fixed partial denture materials is that when they are subjected to constant loads for a long period of time, they exhibit a dimensional change (creep). Purpose. The aim of this study was to investigate the viscoelastic behaviour of polymer-based provisional crown and fixed partial denture materials with time at constant compressive load. Material and methods. Three dimethacrylate-based materials (Protemp 3 Garant, Temphase, Luxatemp) and one monomethacrylate-based material (Trim) were selected. Dimensional changes of the specimens were recorded by a LVDT to evaluate their viscoelastic behavior and creep strain. For all specimens, two loading procedures were used. At first, static compressive stress of 4 MPa was applied for 30 minutes and followed by 1 hour of strain recovery. Then, after 24 hours of water storage, the specimens were loaded again. The creep values between materials were statistically analyzed using one-way ANOVA and multiple comparison $Scheff\acute{e}$ test. Independent samples t-test was also used to identify the difference of creep strain between first and secondary loading conditions at the significance level of 0.05. Results. Following application of the first loading, Trim showed the highest maximum creep strain (32.7%) followed by Luxatemp, Protemp 3 Garant and Temphase, with values of 3.78%, 2.86% and 1.77%, respectively. Trim was significantly different from other materials (P<0.05), while there were no significant differences among Luxatemp, Protemp 3 Garant and Temphase (P>0.05). The highest recovery and permanent set of Trim, were significantly different from those of others (P<0.05). At the secondary loading of the dimethacrylate-based materials, creep deformation, recovery and permanent set decreased and the percentage of recovery increased, while in Trim, all values of the measurements increased. This result showed that the secondary loading at 24 hours produced a significant creep magnitude. Conclusion. The dimethacrylate-based provisional crown and fixed partial denture materials showed significantly higher creep resistance and lower deformation than the monomethacrylate-based material. Thus, monomethacrylate-based materials should not be used in long-term stress-bearing situations.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.25 no.1
• /
• pp.35-41
• /
• 2017

The use of engineering plastics in automotive components is increasing with the trend towards improving the car strength and reducing weight. Among the different choices of materials, engineering plastic emerged as the necessary material for achieving lower costs, reduced weight and improved production efficiency. To produce the automotive parts, it is important to predict defect and validation of injection molding prior to design. Injection molding analysis and structural analysis are widely applied as a part of the design process when developing automotive parts. Injection molding analysis, in particular, involves a highly complicated mechanism that requires deep knowledge of polymer properties as well as an analytic approach different from that used for a general isotropic material when the molded material is used as a structural material. This is because the parts made of polymer have pre-stress factors such as intrinsic deformation and residual stress. The most important factors for injection molded plastic products are injection molding condition and cavity design, taking into account ease of molding, mass production and application. Despite optimal injection molding conditions and cavity design, however, glass fiber orientation is critically linked to strength reduction. The application of injection molding and structural coupled analysis provides a low-cost solution for product molding and structural validation, all prior to the actual molding. The purpose of this study involves the validation, pre-study, and solution of defect in injection-molded polymer automotive parts using the simulation software for injection molding and structural coupled analysis. Finally, this thesis provides validation of an injection molding and structural coupled analytic mechanism that can demonstrate the effect of glass fiber orientation on mechanical strength. Design improvement ideas for the injection molded product of PPS (Poly Phenylene Sulfide)+40% glass fiber are also suggested.

• Applied Chemistry for Engineering
• /
• v.5 no.6
• /
• pp.981-989
• /
• 1994

For the development of new material used bentonite in ceramic/organic material composite, ABS(acrylonitrile-butadiene-styrene) material was used as a matrix polymer and a series of bentonite was blended together. This bentonite, filler like talc or mica for plastic material, was used since natural bentonite(Ca type) is easily obtainable in Korea, Na-bentonite changed from natural bentonite by $Na_2CO_3$ based on the specified compositions, changes in the static and dynamic mechanical properties. It was discovered that the increased content of natural and Na- bentonite results in higher modulus with reduced impact strength. And Rockwell hardness was constant. And Na- bentonite filled polymer showed improvement in impact strength and lower in modulus as the natural bentonite filled polymer. The storage modulus(E') of Na- bentonite filled ABS resin was higher than that of Ca- bentonite filled ABS resin, while higher temperature, storage modulus(E') decreased. At higher frequency, tan ${\delta}$ peak was shifted at high temperature.

• Journal of Korean Society of Water and Wastewater
• /
• v.32 no.5
• /
• pp.399-409
• /
• 2018

Prussian blue is known as a superior material for selective adsorption of radioactive cesium ions; however, the separation of Prussian blue from aqueous suspension, due to particle size of around several tens of nanometers, is a hurdle that must be overcome. Therefore, this study aims to develop granule type adsorbent material containing Prussian blue in order to selectively adsorb and remove radioactive cesium in water. The surface of granular activated carbon was grafted using a covalent organic polymer (COP-19) in order to enhance Prussian blue immobilization. To maximize the degree of immobilization and minimize subsequent detachment of Prussian blue, several immobilization pathways were evaluated. As a result, the highest cesium adsorption performance was achieved when Prussian blue was synthesized in-situ without solid-liquid separation step during synthesis. The sample obtained under optimal conditions was further analyzed by scanning electron microscope-energy dispersive spectrometry, and it was confirmed that Prussian blue, which is about 9.7% of the total weight, was fixed on the surface of the activated carbon; this level of fixing represented a two-fold improvement compared to before COP-19 modification. In addition, an elution test was carried out to evaluate the stability of Prussian blue. Leaching of Prussian blue and cesium decreased by 1/2 and 1/3, respectively, compared to those levels before modification, showing increased stability due to COP-19 grafting. The Prussian blue based adsorbent material developed in this study is expected to be useful as a decontamination material to mitigate the release of radioactive materials.

• Composites Research
• /
• v.30 no.6
• /
• pp.416-421
• /
• 2017

The structural adhesive have been manufactured for improvement of bonding process between CFRP and metal. The optimal condition for bonding process were investigated by evaluating the lap shear strength with amount of adhesive and curing time and the surface treatment of the CFRP. To confirm proper adhesion conditions, the fracture sections between CFRP and metal was observed using reflection microscope. Not only the improvement of the adhesion condition was important, but surface treatment on CFRP was also important. The optimal curing temperature was at $180^{\circ}C$ for 20 minutes. The improvement for adhesive property was confirmed After surface treatment on CFRP. The optimal amount of structural adhesive for bonding between CFRP and metal was $1.5{\times}10^{-3}g/mm^2$. Through the optimization of bonding process, the improvement of mechanical property over 10% is confirmed in comparison with existing adhesive.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.20 no.4
• /
• pp.192-196
• /
• 2010

This paper describes the effects of modified sulfur polymer content on the compressive strength and chemical resistance of Portland cement concrete with and without the modified sulfur polymer. The Portland cement concrete which contained modified sulfur had much higher strength than the Portland cement concrete without modified sulfur, workability is stabled at $55^{\circ}C$. Alkali tolerance test was evaluated by immersing these concrete specimens in 13 % $CaCl_2$ solutions. In the alkali tolerance test, the resistance of Portland cement concrete with modified sulfur to $CaCl_2$ increased compared with Portland cement concrete without modified sulfur.