• Title/Summary/Keyword: Polymer material

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Characterization and Experimental Verification of Solid Polymer Electrolyte for Conductive Polymer Actuator Operated in Air (공기 중에서 동작하는 전도성 고분자 액추에이터용 고체전해질의 특성 분석 밑 실험적 검증)

  • An, Ho-Jeong;Lee, Seung-Gi;Park, Jeong-Ho
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.3
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    • pp.125-133
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    • 2002
  • In order to fabricate stable conductive polymer actuators which can be operated in air, conductivity and solidity of polymer electrolyte materials have been studied. It was found that Nafion+LiCl is appropriate material to be used for conductive polymer actuator. Using the Nafion+LiCl solid polymer electrolyte, single layer PPy actuators have been fabricated and their deflection was measured. Double layer PPy actuators make up for shortcoming of single layer PPy actuator and displacement and frequency response can be improved by fabrication of double layer PPy actuator. This kind of all-solid-polymer actuator can be used for practical applications.

Burn-up Characteristics of Polymer-Modified Cement Mortar Used for Building Repair (고온시에서의 폴리머 시멘트 모르타르의 연소특성에 관한 연구)

  • Kim, Hyung-Jun;Noguchi, Takahumi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.295-298
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    • 2012
  • Repair and strengthening is necessary to extend the service life of existing buildings. Polymer-modified cement mortar (PCM) has been extensively used as a high performance material particularly for finishing and repairing works in concrete building because of itsexcellent adhesion, waterproofing, resistance to chemical attack, and workability. As PCM contains organic polymer, it is necessary to clarify its properties at high temperature under fire, on which sufficient data are not available. This paper evaluated the burn-up characteristics of polymer-modified cement mortar with cone calorimeter test, non-combustibility test and flammability test with experimental parameters such as the types of polymer, unit-polymer content, polymer-cement ratio and thickness of the specimen.

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A Study on the Viscosity and Flowability of Polymer-Cement Composites for Repairing Cracks of RC Structures (RC 구조물의 균열 보수용 폴리머 시멘트 복합체의 점도와 유동성에 관한 연구)

  • Hong, Dae-Won;Kim, Sang-Hyuk;Kwon, Woo-Chan;Jo, Young-Kug
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.166-167
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    • 2021
  • The purpose of this study is to evaluate the viscosity and flowability of polymer-cement composites for repairing cracks of RC structures. The viscosity and flowability of the polymer cement composites differed greatly depending on the type of polymer and the polymer cement ratio, and the polymer cement composites could be produced that could repair fine cracks in the RC structure without material separation by adjusting the proper water-cement ratio. In particular, the mixing of high viscosity EVA-modified polymer composites could be adjusted.

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Dental Properties of Hydroxyapatite Filled Polymer Composite (수산화인회석이 충전된 고분자 복합체의 치과적 물성)

  • Seo, Kitaek;Yoon, Jingu;Kim, Juhwan;Kim, Ohyoung
    • Applied Chemistry
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    • v.9 no.2
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    • pp.25-28
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    • 2005
  • To evaluate the dental restorative application of polymer composites filled with hydroxyapatite (HAP) which is an inorganic component of human bone material, dental properties of the polymer composites were investigated. A visible light system was utilized to activate the acrylate resin matrix of the composites. Maximum loading percentage of HAP in composite was 65 wt% and the depth of cure was 6.0 mm which can be applicable for dental restoration. With increasing the HAP content, degree of conversion of polymer composites was slightly decreased, however, polymerization shrinkage value was not varied. Diametral tensile strength value was enhanced with an increase of HAP content, however, there was no strict trend between flexural strength and HAP concentration. Anyhow, polymer composites prepared herein have superior mechanical properties sufficient specifications applicable to dental materials.

Preparation and Property of POSS-Based Organic-Inorganic Hybrid Filler and Polyamide Thermoplastic Elastomer (PA-TPE)/POSS Nanocomposite (POSS 기반 유-무기 하이브리드 충전제와 폴리아미드계 TPE로 이루어진 나노복합체의 제조 및 특성)

  • Han, Jae Hee;Kim, Hyung Joong
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.34-40
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    • 2013
  • Commercially available polyamide thermoplastic elastomer (PA-TPE) was blended with hybrid filler which was prepared by means of the reaction between polyhedral oligomeric silsesquioxane (POSS) containing amine group and toluene diisocyanate (TDI)-caprolactam (CL) to explore the effect of blending the hybrid filler with the TPE. The chemical structure of the filler was identified by using FTIR and $^1H$ NMR. The composites, PA-TPE/POSS-(TDI+CL), which were the blends of TDI+CL modified POSS filler and PA-TPE up to 7 wt%, showed better elastic recovery delivered from lower tension setting compared to the PA-TPE and the PA-TPE/octaphenyl POSS blend. In addition the tensile strength and the initial modulus increased with increasing the hybrid filled content. Consequently it was assumed that the POSS-(TDI+CL) filler was a suitable material for enhancing strength and modulus without loss of elastic properties for the original PA-TPE.

Evaluation of Engineering Properties in Synthetic Polymer-Silica Sol Grout (합성폴리머 실라카졸 그라우트의 공학적 특성 평가)

  • Jang, Seong-Min;Jung, Hyuk-Sang;Kim, Jeong-Han;Min, Byung-Chan;Lee, Byeong-Seok
    • Journal of the Korean Geosynthetics Society
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    • v.21 no.3
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    • pp.29-39
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    • 2022
  • The engineering characteristics of synthetic polymer-silica sol, which has the effect of reducing leakage, was evaluate and compared with typical grouting material, the water glass-based SGR injection material in this study. The result of the laboratory tests on strength and durability about the synthetic polymer-silica sol showed more than twice as high as LW-based injection materials in uniaxial compressive strength, significantly lower values in shrinkage rate and permeability. The result of pH was less than 8.5 (the drinking water quality standard). As a result of the leaching test, the Na2O elution amount of the synthetic polymer-silica sol was measured to be 3 to 4 times smaller than that of the water glass grout. These results be assumed that the synthetic polymer-silica sol has better durability and permeability than those of the typical water glass-based grout.

A Study on the Development of Sound Absorption Material Using Perlite for Noise Barrier Wall (펄라이트를 이용한 방음벽의 흡음소재 개발에 관한 기초적 연구)

  • Jo, Young-Kug;Yang, Ju-Kyung
    • Journal of the Korea Concrete Institute
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    • v.20 no.5
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    • pp.653-660
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    • 2008
  • The purpose of this study is to analyze the optimal mix design of the sound absorption material that is made from perlite and various binder systems for noise barrier wall. The polymer cement slurry which is made from two types of polymer dispersions, and silicone type inorganic material are used as binder. The test specimens are prepared with various polymer cement ratios, binder ratios, and tested for strengths, freezing and thawing and sound absorption performance by the tube and the reverberation room methods. From the test results, the difference of sound absorption coefficient by the tube method is a little recognized, however, noise reduction coefficient (NRC) of test specimens bound by the polymer cement slurry is in the ranges of 0.48 to 0.51. They are a little higher than those bound by cement only, and are lower values than recommended value of 0.7 by the Ministry of Environment. However, the sound absorption coefficient of test specimens at low frequency range of 250 to 500 Hz by reverberation room method shows very high values as 0.84 to 1.00, and 0.57 to 0.77 at the high frequency. The test specimens with polymer cement slurry binder have a good balance between performance and cost, and have proper properties in strengths, freezing and thawing resistance as sound absorption material for noise barrier wall. It is apparent that the good sound absorption material can be produced according to the optimum mix design that is recommended from this study.

Effect of Surfactant and Anti-foaming Agent on the Properties of Silicone Rubber Impression Material (계면활성제와 소포제가 실리콘 고무인상재의 물성에 미치는 영향)

  • Kim, Kyoung-Nam;Cho, Lee-Ra;Oh, Young-Il;Kang, Seung-Kyung;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.36 no.2
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    • pp.102-110
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    • 2001
  • The three types of surfactants such as nonylphenoxy poly(ethylene) ethanol homologues, caster oil poly(ethylene) ethanol homologues, and sodium perfluoroalkyl carboxylates are used to improve the wettability of rubber impression material. Among the surfactants, the usage of sodium perfluoroalkyl carboxylates containing fluoro group resulted in the lowest surface energy of impression material and the result gave the positive effect on the wettability of rubber impression material to teeth. Also, the anti-foaming agents were used to reduce or remove the hydrogen gas generating on the impression material by reaction. In the case of rubber impression material containing sodium perfluoroalkyl carboxylate as a surfactant, it was found that the tear strength of rubber impression material increased over 3 N/mm with the addition of anti-forming agent. Therefore, the anti-foaming agent could contribute to the mechanical property of rubber impression material without the change of surface property.

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Fabrication and Mechanical Properties of Carbon Fiber Reinforced Polymer Composites with Functionalized Graphene Nanoplatelets (기능기화 된 그래핀 나노플레이틀릿이 첨가 된 탄소섬유 강화 고분자 복합소재의 제조 및 기계적 특성 연구)

  • Cha, Jaemin;Kim, Jun Hui;Ryu, Ho Jin;Hong, Soon H.
    • Composites Research
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    • v.30 no.5
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    • pp.316-322
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    • 2017
  • Carbon fiber is a material with excellent mechanical, electrical and thermal properties, which is widely used as a composite material made of a polymer matrix. However, this composite material has a weak point of interlaminar delamination due to weak interfacial bond with polymer matrix compared with high strength and elasticity of carbon fiber. In order to solve this problem, it is essential to use reinforcements. Due to excellent mechanical properties, graphene have been expected to have large improvement in physical properties as a reinforcing material. However, the aggregation of graphene and the weak interfacial bonding have resulted in failure to properly implement reinforcement effect. In order to solve this problems, dispersibility will be improved. In this study, functionalization of graphene nanoplatelet was proceeded with melamine and mixed with epoxy polymer matrix. The carbon fiber reinforced polymer composites were fabricated using the prepared graphene nanoplatelet/epoxy and flexural properties and interlaminar shear strength were measured. As a result, it was confirmed that the dispersibility of graphene nanoplatelet was improved and the mechanical properties of the composite material were increased.

Synthesis and Characterization of a Tetrathiafulvalene-Based Polymer

  • Lee, Se-Hyun;Wang, Lei;Hwang, Seok-Ho;Lee, Myong-Hoon;Jeong, Kwang-Un
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1451-1456
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    • 2012
  • A novel tetrathiafulvalene (TTF)-based main-chain polymer (6TTF-polymer) was successfully synthesized via a condensation polymerization between a newly synthesized dihydroxy TTF derivative and a malonyl chloride, and its chemical structure was characterized by spectroscopic techniques. Molecular weight of the 6TTF-polymer (9,030 g/mol by gel permeation chromatography) was large enough to form the ductile film. The electrochemical and optical properties of the 6TTF-polymer were further estimated by cyclic voltammetry, ultraviolet and photoluminescence spectroscopes. The highest occupied molecular orbital level ($E_{HOMO}$=-4.79 eV) and band-gap energy ($E_g$=1.91 eV) of the 6TTF-polymer suggested that TTF-based polymer could act as a good electron donating material for the optoelectronic applications.