• Journal of Pharmaceutical Investigation
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• v.25 no.3
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• pp.213-221
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• 1995

The steady shear flow properties of six kinds of commercial toothpastes were measured using a concentric cylinder type rheometer. In this paper, the shear rate and temperature dependencies of their flow behavior were investigated and the validity of the Casson and Herschel-Bulkley models was examined. Further, the flow properties over a wide temperature range were quantitatively evaluated by calculating the various material parameters. Main results obtained from this study can be summarized as follows: (1) Toothpastes are plastic fluids with a yield stress and their flow behavior shows shear-thinning characteristics. (2) With increasing temperature, the degree of shear-thinning becomes weaker and the Newtonian flow behavior occurs at a lower shear rate range. (3) The Herschel-Bulkley model is more effective than the Casson model in predicting their flow behavior. (4) As the temperature increases, the yield stress, plastic viscosity and consistency index become smaller, on the contrary, the flow behavior index becomes larger.

• Bulletin of the Korean Chemical Society
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• v.20 no.12
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• pp.1479-1482
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• 1999

We have studied the behavior of interdiffusion between partially miscible polymer pair from a theoretical viewpoint by applying the reptation model for collective interdiffusion and spinodal decomposition in polymer mixtures with different molecular weights. We find that our predictions agree well with the experiments of Klein and co-workers, where the exponent α of the initial increase of interfacial width with time in $t^{\alpha}$ is significantly lower than 0.5 for free diffusion.

• Macromolecular Research
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• v.14 no.5
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• pp.530-538
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• 2006

There are three important components in tissue engineering: the cells, signaling factors (cytokines and growth factors), and scaffolds. To obtain finely engineered tissue, all three components should perform their individual functions and be fully integrated with each other. For the past few years, we have studied the characteristics of photodimerizable HA (CHA)/alginate (CA) composite materials. CHA/CA complex hydrogels, which were irradiated under UV light and, then treated with calcium ions, were found to have good biocompatibility, mechanical properties and water resistance for implantable tissue scaffolds. In this study, we introduced a cell growth factor (basic fibroblast growth factor; bFGF) into the CHA/CA scaffolds and studied its release behavior. We also introduced tetracycline hydrochloride and flurbiprofen into the same scaffolds as model activation factors and evaluated their release behaviors from the scaffolds. The drug release rate from the materials was influenced by various parameters, such as the degree of crosslinking, the cross linker type, the physico-chemical properties of the drug, and the amount of the drug in the polymer. The results indicated that the negatively charged CHA/CA composite materials showed sustained release behavior and that HA has a particularly strong negative charge, making it attractive toward tetracycline hydrochloride and bFGF, but repulsive toward flurbiprofen.

• Computers and Concrete
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• v.20 no.2
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• pp.215-227
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• 2017

A finite element model (FEM) for predicting early-age behavior of reinforced concrete (RC) bridge deck slabs with fiber-reinforced polymer (FRP) bars is presented. In this model, the shrinkage profile of concrete accounted for the effect of surrounding conditions including air flow. The results of the model were verified against the experimental test results, published by the authors. The model was verified for cracking pattern, crack width and spacing, and reinforcement strains in the vicinity of the crack using different types and ratios of longitudinal reinforcement. The FEM was able to predict the experimental results within 6 to 10% error. The verified model was utilized to conduct a parametric study investigating the effect of four key parameters including reinforcement spacing, concrete cover, FRP bar type, and concrete compressive strength on the behavior of FRP-RC bridge deck slabs subjected to restrained shrinkage at early-age. It is concluded that a reinforcement ratio of 0.45% carbon FRP (CFRP) can control the early-age crack width and reinforcement strain in CFRP-RC members subjected to restrained shrinkage. Also, the results indicate that changing the bond-slippage characteristics (sand-coated and ribbed bars) or concrete cover had an insignificant effect on the early-age crack behavior of FRP-RC bridge deck slabs subjected to shrinkage. However, reducing bar spacing and concrete strength resulted in a decrease in crack width and reinforcement strain.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2009.10a
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• pp.45-52
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• 2009

The research on miniature devices based on non-silicon materials, in particular polymeric materials has been attracting more and more attention in the research field of the micro/nano fabrication in recent years. Lost of applications and many literatures have been reported. However, the study on the micro thermal imprint process of glassy polymer is still not systematic and inadequate. The aim of this research I to obtain a numerical material model for an amorphous glassy polymer, polycarbonate (PC), which can be used in finite element analysis (FEA) of the micro thermal imprint process near the glass transition temperature (Tg). An understanding of the deformation behavior of the PC specimens was acquired by performing tensile stress relaxation tests. The viscoelastic material model based on generalized Maxwell model was introduced for the material near Tg to establish the FE model based on the commercial FEA code ABAQUS/Standard with a suitable set of parameters obtained for this material model form the test data. As a result, the feasibility of the established viscoelastic model for PC near Tg was confirmed and this material model can be used in FE analysis for the prediction and improvement of the micro thermal imprint process for pattern replication.

• Composites Research
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• v.30 no.4
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• pp.247-253
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• 2017

In this study, the mechanical behavior and interface properties of boron nitride nanotube-poly(methyl methacrylate) nanocomposites are predicted using the molecular dynamics simulations and the double inclusion model. After modeling nanocomposite unit cell embedding single-walled nanotube and polymer, the stiffness matrix is determined from uniaxial tension and shear tests. Through the orientation average of the transversely isotropic stiffness matrix, the effective isotropic elastic constants of randomly dispersed microstructure of nanocomposites. Compared with the double inclusion model solution with a perfect interfacial condition, it is found that the interface between boron nitride nanotube and polymer matrix is weak in nature. To characterize the interphase surrounding the nanotube, the two step domain decomposition method incorporating a linear spring model at the interface is adopted. As a result, various combinations of the interfacial compliance and the interphase elastic constants are successfully determined from an inverse analysis.

• Macromolecular Research
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• v.10 no.1
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• pp.18-23
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• 2002

We theoretically consider blends of two monodisperse one-end-functionalized homopolymers (denoted by A and B) capable of forming clusters between functional groups (stickers) using weak segregation theory. In this model system resulting molecular architectures via clustering resemble star copolymers having many A- and B-arms. Minimizing the total free energy with respect the cluster distribution, the equilibrium distribution of clusters is obtained and used for RPA (Random Phase Approximation) equations as input. For the case that polymers are functionalized by only one kind of sticker, the phase diagrams show that the associations promote the macrophase separation. When there is strong affinity between stickers belonging to the different polymer species, on the other hand, the phase diagram show a suppression of the macrophase separation at the range of high temperature regime, as well as the phase coexistence between a disordered and a mesoscopic phase at the relatively lower temperatures.

• Journal of the Korean Applied Science and Technology
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• v.21 no.2
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• pp.132-139
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• 2004

Film forming behavior of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. The film forming behavior was evaluated using pseudo on-line measurements of the cumulative weight loss, the UV transmittance, and the tensile fracture energy. Each stages of film formation I, II were not sensitive to the morphology of model latexes, but stage-ill was largely dependent on the morphology of model latexes. The chain mobility of polymer which composed the shell component was found to dominantly determine the behavior of film forming stage-III.

• Journal of the Korean Society of Safety
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• v.26 no.2
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• pp.62-69
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• 2011

This paper presents a new simple two-dimensional frame finite element able to accurately estimate the load-carrying capacity of reinforced concrete beams flexurally strengthened externally bonded fiber reinforced polymer (FRP) strips and plates. The proposed analysis model considers distributed plasticity with layer-discretization of the cross-sections and the bond-slip behavior of epoxy layer. The proposed model is used to predict the load-carrying capacity and the applied load-midspan deflection response of RC beams subjected to bending loading. Numerical simulations and experimental measurements are compared based on numerous tests available in the literature and published by different authors. The numerically simulated response agree remarkably well with the corresponding experimental results. Thus, the proposed model is suitable for efficient and accurate modeling and analysis of flexural strengthening of RC beams with externally bonded FRP sheets/plates and for practical use in design-oriented parametric studies.

• International Journal of Concrete Structures and Materials
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• v.11 no.2
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• pp.247-259
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• 2017

This paper presents a fatigue assessment model that was developed for corroded reinforced concrete (RC) beams strengthened using prestressed carbon fiber-reinforced polymer (CFRP) sheets. The proposed model considers the fatigue properties of the constituent materials as well as the section equilibrium. The model provides a rational approach that can be used to explicitly assess the failure mode, fatigue life, fatigue strength, stiffness, and post-fatigue ultimate capacity of corroded beams strengthened with prestressed CFRP. A parametric analysis demonstrated that the controlling factor for the fatigue behavior of the beams is the fatigue behavior of the corroded steel bars. Strengthening with one layer of non-prestressed CFRP sheets restored the fatigue behavior of beams with rebar at a low corrosion degree to the level of the uncorroded beams, while strengthening with 20- and 30%-prestressed CFRP sheets restored the fatigue behavior of the beams with medium and high corrosion degrees, respectively, to the values of the uncorroded beams. Under cyclic fatigue loading, the factors for the strengthening design of corroded RC beams fall in the order of stiffness, fatigue life, fatigue strength, and ultimate capacity.