• Title/Summary/Keyword: Polymer behavior model

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Application of the Polymer Behavior Model to 3D Structure Fabrication (3차원 미세 구조물 제작을 위한 폴리머 유동 모델의 적용)

  • Kim, Jong-Young;Cho, Dong-Woo
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.12
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    • pp.123-130
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    • 2009
  • This study presents the application of a polymer behavior model that considers fluid mechanics and heat transfer effects in a deposition system. The analysis of the polymer fluid properties is very important in the fabrication of precise microstructures. This fluid behavior model involves the calculation of velocity distribution and mass flow rates that include the effect of heat loss in the needle. The effectiveness of the proposed method was demonstrated by comparing estimated mass fluid rates with experimental values. The mass fluid rates under various process conditions, such as pressure, temperature, and needle size, reflected the actual deposition state relatively well, and the assumption that molten polycaprolactone(PCL) is a non-Newtonian fluid was reasonable. The successful fabrication of three-dimensional microstructures demonstrated that the model is valid for predicting the polymer behavior characteristics in the microstructure fabrication process. The results of this study can be used to investigate the effect of various parameters on fabricated structures before turning to experimental approaches.

Tension Creep Model of Recycled PET Polymer Concrete with Flexural Loading (휨 하중을 받는 재생 PET 폴리머 콘크리트의 인장크리프 모델)

  • Chae, Young-Suk;Tae, Ghi-Ho
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.117-125
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    • 2012
  • In recent years, polymer concrete based on polyester resin have been widely generalized and the research of polymer concrete have been actively pursued by the technical innovations. Polymer concrete is a composite consisting of aggregates and an organic resin binder that hardens by polymerization. Polymer concrete are stronger by a factor of three or more in compression, a factor of four to six in tension and flexural and a factor of two in impact when compared with portland cement concrete. In view of the growing use of polymer concrete, it is important to study the physical characteristics of the material, emphasizing the short term properties as well as long term mechanical behavior. If polymer concrete is to be used in flexural load-bearing application such as in beam, it is imperative to understand the deformation of the material under sustained loading conditions. This study is proposed to empirical and mechanical model of polymer concrete tension creep using long-term experimental results and mathematical development. The test results showed that proposed model has been used successfully to predict creep deformations at a stress level that was 20 percent of the ultimate strength and viscoelastic behavior of recycled-PET polymer concrete is linear of stress level up to 30 percent. It is expected that the present model allows more realistic evaluation of varying stresses in polymer concrete structures with a constant loading.

Development of 3D Meso-Scale finite element model to study the mechanical behavior of steel microfiber-reinforced polymer concrete

  • Esmaeili, J.;Andalibia, K.
    • Computers and Concrete
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    • v.24 no.5
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    • pp.413-422
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    • 2019
  • In this study, 3D Meso-scale finite-element model is presented to study the mechanical behavior of steel microfiber-reinforced polymer concrete considering the random distribution of fibers in the matrix. The composite comprises two separate parts which are the polymer composite and steel microfibers. The polymer composite is assumed to be homogeneous, which its mechanical properties are measured by performing experimental tests. The steel microfiber-polymer bonding is simulated with the Cohesive Zone Model (CZM) to offer more-realistic assumptions. The CZM parameters are obtained by calibrating the numerical model using the results of the experimental pullout tests on an individual microfiber. The accuracy of the results is validated by comparing the obtained results with the corresponding values attained from testing the steel microfiber-reinforced polymer concrete incorporating 0, 1 and 2% by volume of microfibers, which indicates the excellent accuracy of the current proposed model. The results show that the microfiber aspect ratio has a considerable effect on the mechanical properties of the reinforced polymer concrete. Applying microfibers with a higher aspect ratio improves the mechanical properties of the composite considerably especially when the first crack appears in the polymer concrete specimens.

Linear viscoelastic behavior of acrylonitrile-butadiene-styrene(ABS) polymers in the melt: Interpretation of data with a linear viscoelastic model of matrix/core-shell modifier polymer blends

  • Park, Joong-Hwan;Ryu, Jong-Hoon;Kim, Sang-Yong
    • Korea-Australia Rheology Journal
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    • v.12 no.2
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    • pp.135-141
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    • 2000
  • The linear viscoelastic behavior of acrylonitrile-butadiene-styrene (ABS) polymers with different rubber content has been investigated in the frame of a linear viscoelastic model, which takes into account the inter-connectivity of the dispersed rubber particles. The model developed in our previous work has been shown to properly predict the low frequency plateau for the storage modulus, which is generally observed in polymer blends containing core-shell-type impact modifiers. In the present study, further experiments have been carried out on ABS polymers with different rubber content to verify the validity of our linear viscoelastic model. It has been found that our model describes quite properly the rheological behavior of ABS polymers with different rubber content, especially at low frequencies. The experimental data confirm that our model describes the rheological properties of rubber-modified thermoplastic polymers with strong adhesion at the particle/matrix interface more accurately than the Palierne model.

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Irregular Failures at Metal/polymer Interfaces

  • Lee, Ho-Young
    • Journal of Surface Science and Engineering
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    • v.36 no.4
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    • pp.347-355
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    • 2003
  • Roughening of metal surfaces frequently enhances the adhesion strength of metals to polymers by mechanical interlocking. When a failure occurs at a roughened metal/polymer interface, the failure prone to be cohesive. In a previous work, an adhesion study on a roughened metal (oxidized copper-based leadframe)/polymer (Epoxy Molding Compound, EMC) interface was carried out, and the correlation between adhesion strength and failure path was investigated. In the present work, an attempt to interpret the failure path was made under the assumption that microvoids are formed in the EMC as well as near the roots of the CuO needles during compression-molding process. A simple adhesion model developed from the theory of fiber reinforcement of composite materials was introduced to explain the adhesion behavior of the oxidized copper-based leadframe/EMC interface and failure path. It is believed that this adhesion model can be used to explain the adhesion behavior of other similarly roughened metal/polymer interfaces.

Finite Element Analysis of the Room Temperature Nanoimprint Lithography Process with Rate-Dependent Plasticity (변형률속도를 고려한 상온 나노임프린트 공정의 유한요소해석)

  • Song J. H.;Kim S. H.;Hahn H. Thomas;Huh H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.10a
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    • pp.63-66
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    • 2005
  • Nanoimprint lithography (NIL) process at room temperature has been newly proposed in recent years to overcome the shape accuracy and sticking problem induced in a conventional NIL process. Success of the room temperature NIL relies on the accurate understand of the mechanical behavior of the polymer. Since a conventional NIL process has to heat a polymer above the glass transition temperature to deform the physical shape of the polymer with a mold pattern, viscoelastic property of polymer have major effect on the NIL process. However, rate dependent behavior of polymer is important in the room temperature NIL process because a mold with engraved patterns is rapidly pressed onto a substrate coated with the polymer by the hydraulic equipment. In this paper, finite element analysis of the room temperature NIL process is performed with considering the strain rate dependent behavior of the polymer. The analyses with the variation of imprinting speed and imprinting pattern are carried out in order to investigate the effect of such process parameters on the room temperature NIL process. The analyses results show that the deformed shape and imprint force is quite different with the variation of punch speed because the dynamic behavior of the polymer is considered with the rate dependent plasticity model. The results provide a guideline for the determination of process conditions in the room temperature NIL process.

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Experimental Study on Interfacial Behavior of CFRP-bonded Concrete

  • Chu, In-Yeop;Woo, Sang-Kyun;Lee, Yun
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.127-134
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    • 2015
  • Recently, the external bonding of carbon fiber reinforced polymer (CFRP) sheets has come to be regarded as a very effective method for strengthening of reinforced concrete structures. The behavior of CFRP-strengthened RC structure is mainly governed by the interfacial behavior, which represents the stress transfer and relative slip between concrete and the CFRP sheet. In this study, the effects of bonded length, width and concrete strength on the interfacial behavior are verified and a bond-slip model is proposed. The proposed bond-slip model has nonlinear ascending regions and exponential descending regions, facilitated by modifying the conventional bilinear bond-slip model. Finite element analysis results of interface element implemented with bond-slip model have shown good agreement with the experimental results performed in this study. It is found that the failure load and strain distribution predicted by finite element analysis with the proposed bond-slip are in good agreement with results of experiments.

Multiscale approach to predict the effective elastic behavior of nanoparticle-reinforced polymer composites

  • Kim, B.R.;Pyo, S.H.;Lemaire, G.;Lee, H.K.
    • Interaction and multiscale mechanics
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    • v.4 no.3
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    • pp.173-185
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    • 2011
  • A multiscale modeling scheme that addresses the influence of the nanoparticle size in nanocomposites consisting of nano-sized spherical particles embedded in a polymer matrix is presented. A micromechanics-based constitutive model for nanoparticle-reinforced polymer composites is derived by incorporating the Eshelby tensor considering the interface effects (Duan et al. 2005a) into the ensemble-volume average method (Ju and Chen 1994). A numerical investigation is carried out to validate the proposed micromechanics-based constitutive model, and a parametric study on the interface moduli is conducted to investigate the effect of interface moduli on the overall behavior of the composites. In addition, molecular dynamics (MD) simulations are performed to determine the mechanical properties of the nanoparticles and polymer. Finally, the overall elastic moduli of the nanoparticle-reinforced polymer composites are estimated using the proposed multiscale approach combining the ensemble-volume average method and the MD simulation. The predictive capability of the proposed multiscale approach has been demonstrated through the multiscale numerical simulations.

A Constitutive Model for the Rate-dependent Deformation Behavior of a Solid Polymer (속도 의존적인 폴리머 거동에 대한 구성적 모델)

  • Ho, K.
    • Transactions of Materials Processing
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    • v.22 no.4
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    • pp.216-222
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    • 2013
  • Solid polymers exhibit rate-dependent deformation behavior such as nonlinear strain rate sensitivity and stress relaxation like metallic materials. Despite the different microstructures of polymeric and metallic materials, they have common properties with respect to inelastic deformation. Unlike most metallic materials, solid polymers and shape memory alloys (SMAs) exhibit highly nonlinear stress-strain behavior upon unloading. The present work employs the viscoplasticity theory [K. Ho, 2011, Trans. Mater. Process. 20, 350-356] developed for the pseudoelastic behavior of SMAs, which is based on unified state variable theory for the rate-dependent inelastic deformation behavior of typical metallic materials, to depict the curved unloading behavior of polyphenylene oxide (PPO). The constitutive equations are characterized by the evolution laws of two state variables that are related to the elastic modulus and the back stress. The simulation results are compared with the experimental data obtained by Krempl and Khan [2003, Int. J. Plasticity 19, 1069-1095].

Influences of Core Materials during Impact The Bulging Behavior of Sleeved Polymer Projectiles (슬리브드 폴리머 발사체의 충격시 벌징 거동 패턴에 미치는 코어 재료의 영향)

  • Shin, Hyung-Seop;Park, Sung-Taek;Jung, Yoon-Chul
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.198-203
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    • 2008
  • In the present study, the deformation behavior of both of metal and polymer combination on impact was investigated. They have showed a different deformation behavior when the co-axially combined projectile was impacted on rigid target. The theory according to Taylor's simplified approach assumes an ideally rigid-plastic material model exhibiting rate-independent behavior and simple one-dimensional wave propagation concepts that neglect radial inertia. In the case of impact with polymeric materials, elastic strain in general are not negligible compared with plastic strain; and the rigid-plastic material behavior assumed by Taylor for metallic materials cannot be applied any more. Since, the sleeve and the core materials have widely different mechanical properties, they will produce a significant difference of mechanical impedance with each other. Therefore these impedance mismatch influences on the deformation behavior sleeved polymer projectile on impact. As a result, sleeved projectiles will generate a very interesting impact behavior. Therefore, the according to sleeved metal material and core polymer material can see expected. The objective of this study was to investigate the factors which influences on deformation behavior pattern of sleeve materials surface.

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