• Electrical & Electronic Materials
• /
• v.10 no.9
• /
• pp.876-880
• /
• 1997

In this paper we investigated the transcription of liquid crystal (LC) alignment method by using memory effect of nematic(N) LCon polymide(PI) surface with side chain as for non-rubbing alignment techniques. That the monodomain alignment of aligned NLC is observed by microscope textures in the cells on PI surface with side chain. We obtained that the pretilt angle of NLC are generated about 3.7$^{\circ}$on PI surface. We suggest that the LC alignment by using transcription alingnment method is attributed to memory effect of NLC on PI surface.

• Proceedings of the KIEE Conference
• /
• 1999.07d
• /
• pp.1759-1761
• /
• 1999

The generation of pretilt in nematic liquid crystal(NLC)and electro-optical(EO) characteristics of photo-aligned twisted nematic (TN)-LCD with oblique p-polarized ultraviolet (UV) light irradiation on the two kinds of the soluble polyimide (PI) surfaces containing trifluoromethyl moieties were investigated. The generated pretilt angle of NLC is about $2.5^{\circ}$ with p-polarized UV light irradiation of $20^{\circ}$ on PI-3 surface at 20 min.; However pretilt angle of about $0.5^{\circ}$ are observed on PI-1 and PI-2 surfaces. The generated pretilt angle of NLC on PI-3 surface may be attributed to the trifluoromethyl moieties attached to the lateral benzene rings. The voltage-transmittance and response time characteristics of photo-aligned TN-LCD with p-polarized UV light irradiation of $20^{\circ}$ on PI-1 surfaceat at 20 min were almost same in comparison with the rubbing-aligned TN-LCD. However, the high threshold voltage and slow response are observed on PI-3 surface. Also, the decay time $\tau_d$ of photo-aligned TN-LCD is attributed to the anchoring energy of NLC.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2002.08a
• /
• pp.891-894
• /
• 2002

We studied characteristics of polyimide (PI) about Liquid Crystal on Silicon (LCOS) microdisplay. In order to compare two kinds of PI and choose one PI, we measured some items. First, we measured thermal imidization of SE-7492, SE-5291 (Nissan) PI using FT-IR. The results of thermal imidization are same 85%for SE-7492 and 86% for SE-5291. The second, we measured voltage-holding ratio (VHR) of LCOS imager using two kinds PI and one liquid crystal (LC) that is a mixture developed by Merck. The third, we measured contrast ratio (C/R) of LCOS imager using function generator from ov to 4V. The results of VHR and C/R are higher LCOS imager using SE-7492 than LCOS imager using SE-5291. And last we measured response time and the result is same two types LCOS Imagers. So, we choose PI of LCOS imager and concluded that LC is much better matched of PI using SE-7492.

• Applied Chemistry for Engineering
• /
• v.23 no.3
• /
• pp.266-270
• /
• 2012

A series of polyimide was prepared by reacting 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) as the anhydride monomer and 2,2'-bis(trifluoromethyl)benzidine (TFB), 2,2'-bis(3-aminophenyl)hexafluoropropane (BAFP), 2,2'-bis(3- amino- 4-methylphenyl) hexafluoropropane (BAMF), bis(3-aminophenyl)sulfone (APS), p-xylyenediamine (p-XDA), or m-xylyenediamine (m-XDA) as the amine monomer in N,N-dimethylacetamide (DMAc). Colorless and transparent polyimide (PI) films were obtained by casting the poly(amic acid)s (PAAs) solution at various heat treatment temperatures. The thermal properties of the PI films were examined using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and thermomechanical analysis (TMA) and the mechanical properties were investigated using universal tensile machine (UTM), Their optical transparencies were also investigated using ultraviolet-visible (UV-vis.) spectrophotometry and colorimetry. The yellow index (YI) and coefficient of thermal expansion (CTE) values of all PIs were in the range 0.98~2.76 and 25.73~55.23 $ppm/^{\circ}C$, respectively.

• Applied Chemistry for Engineering
• /
• v.32 no.2
• /
• pp.143-148
• /
• 2021

A thermally conductive 200 ㎛ thick polyimide-based film was made from a polyamic acid (PAA) precursor containing graphene prepared from graphite rod using an electrostatic discharge method in order to improve the thermal conductivity and expand the applicability of polyimide (PI) film. Properties of graphene produced by electrostatic discharge were measured by Raman spectroscopy, transmission electron microscopy and X-ray photoelectron spectroscopy (XPS). As a result of Raman spectrum and XPS analyses of as-prepared graphene, the ID/IG ratio was 0.138 and C/O value was 24.91 which are excellent structural and surface chemical properties. Moreover, thermal conductivities of polyimide films increased exponentially according to graphene contents but when the graphene content exceeded 40%, the polyimide film could not maintain its shape. The thermal conductivity of carbonized PI film made from PAA containing 40 wt% of graphene was 51 W/mK which is greatly enhanced from the pristine carbonized PI film (1.9 W/mK). This result could be originated from superior properties of graphene prepared from the electrostatic discharge method.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 1999.11a
• /
• pp.88-94
• /
• 1999

Recently, PTFE-polyimide composites are being used self-lubricating parts for industrial field. Thus, this study is mainly concerned with friction and wear properties for the piston ring of non-lubricating air compressor which made of PTFE-polyimide composites. The friction and wear test was carried out for the different composition ratio under the atmosphere room temperature and constant load of 7.69N and their friction and wear properties were compared with each other at various sliding speed. Notable results are summarized as follows. PTFE 100% showed that friction coefficient was almost same values at 0.94 and 1.88m/s but the value was decreased at 2.83m/s because the friction temperature is higher than low speed. PTFE 80%-PI 20% showed the lowest mean friction coefficient at 2.83m/s. PTFE 20%-PI 80% showed the highest friction coefficient at 0.94m/s and the value was decreased at high speed but the value is higher than other materials except PTFE 100 %. PI 100% showed the highest friction coefficient at 0.94 and 1.88m/s because adhesive wear mainly occurred that speed. PTFE 100% showed highest specific wear rate on the whole. Specific wear rate of PTFE 80%-PI 20% was almost the same value with PTFE 20%-PI 80%. PI 100% showed the lowest value at high sliding speed because the friction surface was thicken and carbonated by high friction temperature.

• Elastomers and Composites
• /
• v.45 no.1
• /
• pp.40-43
• /
• 2010

In this study, polyimide(PI) nanofibers mats were prepared by electrospinning and three different fiber morphologies of random, uniaxial, and biaxial orientation were prepared by controlling the speed of drum-shaped collector and other parameters. The SEM studies reveal that the aforesaid morphologies were obtained on the nano-fibrous mats prepared. The ionic conductivity was measured using an in-plane type conductivity tester for the PI mats soaked in the mixture of 1M lithium trifluoro-methane-sulfonate and tetra-ethylene glycol dimethyl ether. The ionic conductivity was surprisingly higher for the biaxial PI mats. For the uniaxially-oriented mats, the ionic conductivity was found to be higher in the parallel direction compared to the perpendicular direction of the fiber orientation. A curious cyclic fluctuation was found in the ionic conductivity with time. The observed behavior was explained by considering the distance between fibers and transport speed of ions used in this study.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.28 no.11
• /
• pp.698-703
• /
• 2015

In this study, we fabricated the dual gate (DG) ion-sensitive field-effect-transistor (ISFET) with flexible polyimide (PI) extended gate (EG). The DG ISFETs significantly enhanced the sensitivity of pH in electrolytes from 60 mV/pH to 1152.17 mV/pH and effectively improved the drift and hysteresis phenomenon. This is attributed to the capacitive coupling effect between top gate and bottom gate insulators of the channel in silicon-on-transistor (SOI) metal-oxide-semiconductor (MOS) FETs. Accordingly, it is expected that the PI-EG based DG-ISFETs is promising technology for high-performance flexible biosensor applications.

• Journal of the Korean Applied Science and Technology
• /
• v.23 no.3
• /
• pp.238-242
• /
• 2006

Polyimide is a well-known organic dielectric material, which has not only high chemical and thermal stability but also good electrical insulating and mechanical properties. In this research, the electric conduction mechanism of PI Ultra-Thin Films was investigated at room temperature. At low electric field, ohmic conduction $(I{\propto}V)$ was observed and the calculated electrical conductivity was about $4.23{\times}10^{-15}{\sim}9.81{\times}10^{-15}\;S/cm$. At high electric field, nonohmic conduction $(I{\propto}V^2)$ was observed and the conduction mechanism was explained by space charge limited region effect. The dielectric constant of PI Ultra-Thin Films was about 7.0.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.56 no.1
• /
• pp.139-141
• /
• 2007

Thin films of polyimide (Pl) were fabricated by a vapor deposition polymerization method (VDPM) and studied for the photosensitive characteristic. Polyamic acid (PAA) thin films fabricated by vapor deposition polymerization (VDP) from 6FDA and 4-4' DDE were converted to PI thin films by thermal curing. From AFM and Ellipsometer experimental, the films thickness was decreased and the reflectance was increased as the curing temperature was increased. Those results implies that thin film is uniform. From UV-Vis spectra, PI thin films showed high absorbance in 225 $\sim$ 260 [nm] region.