• Applied Chemistry for Engineering
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• v.8 no.5
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• pp.837-843
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• 1997

In oxidized polyethylene wax preparation, the effects of main parameters such as the property of used wax, oxidation time, oxidation temperature, air feed rates on the change of acid-numbers were investigated. The change in polymer property was also investigated. The results showed under given reaction conditions, the acid numbers with oxidation temperature increased upto $160^{\circ}C$, but at higher temperature, it decreased. The base resin which was lower molecular weight had higher acid number. The result showed molecular weight as a experimental parameter was more effective than density in oxidation experiment. In milder condition, free radical initiator was used for catalyst to get higher acid-numbers, which was successful in comparison to the non-catalyst system. Also the catalyst with longer half-life was efficient, in order of DCPO, HOPO and BPO.

• Polymer(Korea)
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• v.39 no.1
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• pp.23-32
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• 2015

Phase change materials based on ultra high molecular weight of polyethylene (UHMWPE) blended with paraffin wax (mp $65^{\circ}C$) were studied in this paper. In addition, this paper reviews recent studies on the preparation of shape stabilized phase change materials (SSPCM), such as SSPCM from UHMWPE and paraffin wax (mp $65^{\circ}C$), their basic properties and possible applications to latent heat storage. The preparation method was an absorption method. Also, SSPCM composites were prepared by using a hot press at $200^{\circ}C$ for 10 min. The analysis for the shape ability of SSPCM to improve heat efficiency was measured by FTIR, SEM, DSC, XRD, and ARES. UHMWPE composites with 30 wt% paraffin wax (mp $65^{\circ}C$) demonstrated less deterioration of physical property and effective thermal property compared with other conditions. As a result, these SSPCMs could be used for the heat storage and release materials for various products.

• The Korean Journal of Pesticide Science
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• v.9 no.3
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• pp.243-249
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• 2005

The chemical and toxicological studies were conducted with acetamiprid 2% granules including different controlling agents for development of controlled-release acetamiprid 2% granule. The fundamental formulation recipe of acetamiprid 2% granule was prepared by the insoluble matrix using polyethylene wax. Starch, cellulose and mineral (calcium carbonate) were used as controlling agents. As a result of studies, release rate of active ingredient from granules into water static condition at $25^{\circ}C$ was increased by addition of starch and cellulose, but was decreased by addition of calcium carbonate. We could select calcium carbonate as controlling agent and make three granules which there were difference in release profiles of active ingredient according to contents of polyethylene wax. 24 hours-release rates of acetamiprid from three granules into water static condition at $25^{\circ}C$ were respectively 75, 50 and 25% when contents of wax were 2, 10 and 20%. The granule which 24 hours-release rate was 25% showed lower acute toxicity against mice and rats.

• Korean journal of applied entomology
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• v.54 no.4
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• pp.369-374
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• 2015

Grapholita molesta (GM) has been considered as a major problem to apple and peach orchards. Mating disrupters have been applied to control the pest over the world as an Integrated Pest Management [IPM] tool. Various types of dispensers releasing mating disrupters have been developed with different formulation of wax, polyethylene tube and aerosol. In this study, the dispensers that were composed of ester waxes and polypropylene (PP) film were used as dispenser materials to analyze release pattern of GM pheromone compared with paraffin wax and polyethylene (PE) film. The release pattern in PP film group was consistent with time while PE film group irregular. Based on these results, Japan wax_PP film dispenser (Japan_PP) was manufactured and showed the mating disruption effect of 98% during 5months in peach orchard.

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.827-833
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• 2005

This study focused on the establishment of optimum formulation of polyamide based hot melt adhesive through adhesive synthesis, study of physical property, and adhesion study. In the previous study, the optimum formulation of base resins (CM831, 843P) and tackifying resin (terpene resin) was determined. The weight ratio of CM831, 843P, and terpene resin was 75, 25, and 10, respectively. Based on the optimum formulation, the effect of wax and filler addition was examined in this study. According to the results, the maximum adhesion strength with the steel could be obtained by the addition of 5 wt% of polyethylene wax although the melt viscosity of adhesive decreased continuously with the addition of wax. In the case of filler, the optimum adhesion property could be achieved by the addition of 10 wt% of talc. However, the addition of filler caused little increase of melt viscosity of adhesive.

• The Korean Journal of Rheology
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• v.11 no.1
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• pp.44-49
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• 1999

Effects of particulate size and frictional characteristics were examined on the melting behavior of PP (polypropylene) in a batch mixer. Powder and pellet types of PP were used and each component was blended with PE (polyethylene) wax and clay, respectively. It was observed that small size particulates, i.e. powder systems exhibit accelerated melting behavior; and it was also found that the abrasive additive acts as an effective agent for fast melting of PP powder. Retardation of melting due to the reduced friction was observed in PP pellet/PE wax blends, while melting rate of PP powder was increased by addition of PE wax.

• Polymer(Korea)
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• v.27 no.1
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• pp.84-89
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• 2003

Pyrolysis of high density polyethylene(HDPE) was carried out to find the effects of temperature and time on the pyrolysis. The starting temperature and activation energy of HDPE pyrolysis increased with increasing heating rate. In general, conversion and liquid yield continuously increased with pyrolysis temperature and pyrolysis time. This tendency is very sensitive with pyrolysis time, especially at 45$0^{\circ}C$. Pyrolysis temperature has more influence on the conversion than pyrolysis time. Each liquid product formed during pyrolysis was classified into gasoline, kerosene, light oil and wax according to the distillation temperature based on the petroleum product quality standard of Korea Petroleum Quality Inspection Institute. As a result, the amount of liquid products produced during HDPE pyrolysis at 45$0^{\circ}C$ was in the order of light oil > wax > kerosene > gasoline, and at 475$^{\circ}C$ and 50$0^{\circ}C$, it was wax > light > oil > kerosene > gasoline.

• Korean Journal of Agricultural Science
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• v.25 no.1
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• pp.12-18
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• 1998

This study was conducted to examine the effect of several postharvest treatments on the storable quality of three apple cultivars, 'Tsugaru', 'jonagold', and 'Hokudo' which are difference in harvest season. Ethylene evolution level showed cultivar-dependent pattern during storage and there was no correlation between the amount of ethylene evolution and storage period among cultivars. Polyethylene film(PE) wrapping was effective in the inhibition of water loss and functional ceramic film was also effective in the prevention of ethylene accumulation inside the wrap during 1 to 3 months of cold storage compared to those of simple PE wrapping. Ethylene scrubber and wax treatment positively contributed to keep the fruit firmness 10% higher than that of control fruit during storage. Waxing enhanced the appearance of 'jonagold' even after simulated marketing period through inhibiting wax accumulation on the fruit surface.

• Journal of Food Hygiene and Safety
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• v.32 no.4
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• pp.284-289
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• 2017

Oxidized polyethylene wax (OPEW) is, one of the food additives, used as a coating agent in citrus fruits and nuts. OPEW is authorized to quantum satis in EU, USA, and is acceptable less than 250 mg/kg in Australia and New Zealand. But OPEW is unauthorized as a food additive in Korea. This study was to establish the analytical method of OPEW and demonstrate the effective application of various food samples. We first conducted to compare the various analytical method including acid value (AV), high temperature gel permeation chromatography (HT-GPC), matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF/MS), gas chromatography flame ionization detector (GC-FID) and fourier transform infrared spectroscopy (FT-IR). This result indicated that FT-IR spectrum of OPEW treated food sample displayed absorption bands for carbonyl group (C=O, $1714cm^{-1}$), ester group (C-O, $1463cm^{-1}$), aliphatic group (C-H, $2916cm^{-1}$). Furthermore, IR spectrum of OPEW treated food sample showed similar tendency with IR spectrum of OPEW standard. Therefore, it is confirmed that analytical method using FT-IR can be detected on analysis of OPEW in food. As a result of monitoring of 111 samples using established analytical method, OPEW was not detected in the food samples.

• Proceedings of the Korean Institute Of Construction Engineering and Management
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• autumn
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• pp.255-266
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• 2000

Since 1993, Seohae grand bridge has been continued construction for 7 years and will be completed late this year. The bridge is a part of west sea castal highway and consists of 3 types of bridge including precast segmental method, free cantilever method and cable stayed bridge. A cable stayed bridge is the core of this bridge and it consists of 5 span, symetrical cable-stayed bridge with a total length of 990 m. The main span between two H-shaped pylons extending approximately 180 M above massive foundation of a cable stayed bridge is 470 m long and an approach span of that is 260 m long respectively. The circular cofferdam with 16 ea of 25 m diameter flat type sheet pile had been applied to construct foundation. The slipform method had been applied for forming of con'c of two H-shaped pylons with 3 cross beams respectively which is varied horizontally and vertically. The deck has been erected with balanced cantilever method using movable derrick crane. The stay cables is a bundle of parallel individually protected, 7 wire high tensile strands. The strands is hot deep galvanized and sheathed with a tight high density polyethylene coating. A petroleum wax fills all the inter-wire voids. The bundle of strands to prevent from deterioration due to the ambient problem covered with high density polyethylene pipe. The Isotension method has been applied for the stressing of cable strands to ensure uniformity of force in all the strands of a syay and such works has been performed on the stay specially provided in the pylon.