• 제목/요약/키워드: Polyethylene terephthalate

검색결과 393건 처리시간 0.024초

Experimental analysis of damage in short-fiber-reinforced composite waste polyethylene terephthalate as a pile foundation material

  • Jang, Hongseok;Seo, Segwan;Cho, Daesung
    • Steel and Composite Structures
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    • 제45권1호
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    • pp.147-157
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    • 2022
  • This study assessed the compressive and tensile strengths and modulus of elasticity of waste polyethylene terephthalate (PET) using the ASTM standard tests. In addition, short carbon and glass fibers were mixed with waste PET to examine the improvements in ductility and strength during compression. The bonding was examined via field-emission scanning electron microscopy. The strength degradation of the waste PET tested under UV was 40-50%. However, it had a compressive strength of 32.37 MPa (equivalent to that of concrete), tensile strength of 31.83 MPa (approximately ten times that of concrete), and a unit weight of 12-13 kN/m3 (approximately half that of concrete). A finite element analysis showed that, compared with concrete, a waste PET pile foundation can support approximately 1.3 times greater loads. Mixing reinforcing fibers with waste PET further mitigated this, thereby extending ductility. Waste PET holds excellent potential for use in foundation piles, especially while mitigating brittleness using short reinforcing fibers and avoiding UV degradation.

Polyethylene terephthalate 중의 가동이온의 계면특성과 이동도에 관한 연구 (A study on the characteristics of interlace and Mobility of Movable Ion in polyethylene Terephthalate)

  • 이호섭;오금곤;국상훈
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1988년도 추계학술대회 논문집 학회본부
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    • pp.233-235
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    • 1988
  • This study investigate that the behavior of movable ion in PET effect on the characteristics of the insulting materials. This examine that movable ion signal to. participation of $Ca^2\;Sb^3$ resulting catalyst refuse and characteristics of activation energy that is need to reionization of movable ion type and neutralized case as measuring characteristics of polarity reversal current or thermally stimulated current.

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Reduction of reflection from PET (polyethylene terephthalate) film surface by natural plasma etching

  • Oh, Hoon;Song, Yu-Jin;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1419-1424
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    • 2006
  • We could reduce the reflection from PET(polyethylene terephthalate) film surface by natural plasma etching which does not use etch masks. The plasma etched PET film showed lower reflectance and higher transmittance which is resulted by making subwavelength structure(SWS) on the film surface by the plasma etch rate difference between the amorphous and crystalline region in the surface of PET film.

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형상기억능을 갖는 polyethylene terephthalate-polyethylene glycol 공중합체를 이용한 laminate 복합재료의 제조 (I) (Preparation of composite laminate utilizing shape memory pohrethylene terephthalate-pohrethylene glycol copolymer (I))

  • 차상혁;박명주;정용찬;조재환;전병철
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2001년도 가을 학술발표회 논문집
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    • pp.195-198
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    • 2001
  • 최근 지능재료에 관한 연구가 형상기억합금, 반도체 재료, 의료용 재료, 고분자 재료 등에서 활발히 이루어지고 있다. 지능재료 중 형상기억재료는 형상기억, 형상고정, 충격흡수 등의 효과를 갖기 때문에 열적, 역학적, 전기적 및 자기적(magnetic) 자극을 감지함으로써 형상, 위치, 탄성계수, damping, 마찰 등의 특성변화를 통하여 응답을 할 수 있어 응용이 다양하다 형상기억고분자의 경우 가볍고 형상회복률이 높으며 가공성이 우수한 장점을 가지고 있다. (중략)

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Cu, Mn/γ-Al2O3 촉매상에서 polyethylene telephthalate 단량체의 회수 연구 (Recovery of Polyethylene Telephthalate Monomer over Cu or Mn/γ-Al2O3 Catalysts)

  • 심재욱;김승수
    • 공업화학
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    • 제28권4호
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    • pp.485-489
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    • 2017
  • Polyethylene terephthalate (PET)는 화학적 안정성과 높은 기계적 강도를 가지고 있어 식품, 의류 등 다양한 분야에서 사용되고 있으며, 이로 인해 PET는 주요 폐플라스틱 폐기물 중 하나이다. 본 연구에서 PET를 재활용하기 위해 ethylene glycol (EG)와 glycolysis의 반응을 이용하여 단량체 회수에 관한 연구를 수행하였다. 마이크로 튜빙 반응기를 사용하여 EG/PET비율 1~4, 반응시간 15~90 min, 반응온도 $250{\sim}325^{\circ}C$에서 망간, 구리 촉매 조건하에서 연구를 진행하였다. 10 wt% $Cu/{\gamma}-Al_2O_3$ 촉매에서 반응온도, 시간과 EG/PET의 비가 각각 $300^{\circ}C$, 30 min와 1 : 2였을 때 가장 높은 89.46%의 bis (2-hydroxyethyl) terephthalate monomer (BHET) 수율을 나타내었다.

코로나방전에 의한 polyethylene terephthalate 필름의 표면처리 (Surface treatment of polyethylene terephthalate films by corona discharge)

  • 김명룡
    • E2M - 전기 전자와 첨단 소재
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    • 제8권3호
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    • pp.316-323
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    • 1995
  • A vital step in magnetic tape manufacturing is the surface modification of polymer substrate prior to ink application. A critical element for good adhesion of magnetic ink on polymeric substrate is the ability to join ink in cost-effective manner. Corona discharging is one of the effective methods of modifying polymer surface to improve adhesion while maintaining the desirable properties of the film itself. Surface treatment by corona which is exposure of film surface to electron or ion bombardment, rather than mere exposure to active species, like atomic oxygen or ozone, can enhance adhesion by removing contaminant, electret, roughening surface, and/or introducing reactive chemical groups. Reactive neutrals, ions, electron and photons generated during the corona treatment interact simultaneously with polymers to alter surface chemical composition, wettability, and thus film adhesion. However, it is highly recommended that extensive chains scission be avoided because it can lead to side-effect by forming sticky matter, resulting in dropouts. This paper reviews principles of surface preparation of polymer substrate by corona discharging. In addition, the experimental section provides a description of parameter optimization on corona discharging treatment and its side-effect. Experimental results are discussed in terms of surface wetting as determined by contact angle measurements.

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온도변화에 따른 폴리에틸렌텔레프탈레이트 박막의 체적고유저항 특성 (Volume Resistivity Properties of Polyethylene Terephthalate Film due to Temperature Variation)

  • 윤정일;고길영;신현택;신종열;이충호;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.224-227
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    • 2002
  • In this paper, we have investigated the physical properties and electrical conduction properties of polyethylene terephthalate film due to temperature variation, and the measurement of volume resistivity used to highmegohm meter is measured from 1 to 10 minutes when the specimen applied the voltage accroding to the step voltage appling method. From FT-IR spectrum as an analysis of physical properties, the strong absorption in wavenumbers $1019[cm^{-1}]$, $1266[cm^{-1}]$ and $1752[cm^{-1}]$ observed by the C=O and benzene ring. From the analysis of DSC, the crystalline melting points of the specimen observed in the temperature $80[^{\circ}C]$ and $263[^{\circ}C]$, respectively.

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Kinetic Analysis for the Catalytic Pyrolysis of Polyethylene Terephthalate Over Cost Effective Natural Catalysts

  • Pyo, Sumin;Hakimian, Hanie;Kim, Young-Min;Yoo, Kyung-Seun;Park, Young-Kwon
    • 공업화학
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    • 제32권6호
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    • pp.706-710
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    • 2021
  • In the current research, thermal and catalytic thermogravimetric (TG) analysis of polyethylene terephthalate (PET) over natural zeolite (NZ), olivine, bentonite, HZSM-5, and HAl-MCM-41 were investigated using a TG analyzer and model-free kinetic analysis. Catalytic TG analysis of PET was carried out at multi-heating rates, 10, 20, 30, and 40 ℃/min, under nitrogen atmosphere. Apparent activation energy (Ea) values for the thermal and catalytic pyrolysis of PET were calculated using Flynn-Wall-Ozawa method. Although natural catalysts, NZ, olivine, and bentonite, could not lead the higher PET decomposition efficiency than synthetic zeolites, HZSM-5 and HAl-MCM-41, maximum decomposition temperatures on the differential TG (DTG) curves for the catalytic pyrolysis of PET, 436 ℃ over olivine, 435 ℃ over bentonite, and 434 ℃ over NZ, at 10 ℃/min, were definitely lower than non-catalytic pyrolysis. Calculated Ea values for the catalytic pyrolysis of PET over natural catalysts, 177 kJ/mol over olivine, 168 kJ/mol over bentonite, and 171 kJ/mol over NZ, were also not lower than those over synthetic zeolites, however, those were also much lower than the thermal decomposition, suggesting their feasibility as the proper and cost-effective catalysts on the pyrolysis of PET.

폴리에틸렌 테레프탈레이트의 해중합을 위한 초음파 박리법 기반의 코발트 수산화물 나노시트의 제조 (Synthesis of Cobalt Hydroxide Nanosheets based on Sonication-induced Exfoliation for Depolymerization of Polyethylene Terephthalate)

  • 진세빈;손선규;정재민;최봉길
    • 공업화학
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    • 제31권6호
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    • pp.668-673
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    • 2020
  • 본 논문에서는 수산화코발트[Co(OH)2] 층간 소재를 초음파(sonication) 액상 박리 공정을 사용하여 얇은 2차원 나노시트(nanosheet)로 박리하였다. 상기의 Co(OH)2 촉매는 27.5 ㎡ g-1의 넓은 비표면적을 갖는 한 장의 육각 나노시트로 박리 되었다. 또한, 특성 분석 및 PET 해중합(depolymerization) 반응의 촉매로서 사용되어 고활성을 증명하였다. 해당 촉매를 사용한 PET 해중합 반응은 200 ℃에서 30 min 이내에 100%의 높은 PET전환율과 100%의 높은 BHET 수율을 보여주었다. 박리된 Co(OH)2의 재사용성을 확인하기 위해 반응 후 필터를 사용해 촉매를 회수하여 PET 해중합 반응을 진행하였다. 총 4번의 재사용 동안 100%의 PET 전환율과 100%의 BHET 수율을 보여주어 촉매의 우수한 안정성을 증명하였다.