• 한국건축시공학회지
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• 제15권1호
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• pp.1-7
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• 2015

본 연구의 목적은 ALC 블록대체를 위한 고성능 기포콘크리트 배합설계를 개발하는 것이다. 대기양생 하에서 기포콘크리트의 고강도 발현(특히 초기재령에서)을 위하여 결합재 및 혼화제를 사전연구에서 다음과 같이 설계하였다. 규산3칼슘이 60% 이상인 보통포틀랜드시멘트에 무수석고 3%를 첨가하였으며, 폴리카르본산계 감수제에서 폴리알킬에테르 성분을 28%로 조절하였다. 이들 재료를 사용하여 물-결합재비와 단위결합재양을 변수로 기포콘크리트 11배합을 실험하였다. 배합된 기포콘크리트의 품질 및 실용성은 KS 규격의 ALC 블록의 요구조건 및 기존의 일반 기포콘크리트와 비교하였다. 실험결과 본 연구의 고성능 기포콘크리트는 ALC 블록의 요구조건을 만족하면서 높은 실용가능성을 보였다.

• Biotechnology and Bioprocess Engineering:BBE
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• 제6권4호
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• pp.205-212
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• 2001

One of the important characteristics of biological systems os their ability to change im-portant properties in response to small environmental signals. The molecular mechanisms that biological molecules utilize to sense and respond provide interesting models for the development of "smart" polymeric biomaterials with biomimetic properties. An important example of this is the protein coat of viruses, which contains peptide units that facilitate the trafficking of the virus into the cell via endocytosis, then out of the endosome into the cytoplasm, and from there into the nucleus, We have designed a family of synthetic polymers whose compositions have been de-signed to mimic specific peptides on viral coats that facilitate endosomal escape. Our biomimetic polymers are responsive to the lowered pH whinin endosomes, leading to distruption of the en-dosomal membrane and release of important biomolecular druges such as DNA, RNA, peptides and proteins to the cytoplasm before they are trafficked to lysosomes and degraded by lysosomal en-zymes. In this article, we review our work on the design, synthesis and action of such smart, pH-sensitive polymers.

• Restorative Dentistry and Endodontics
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• 제16권2호
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• pp.189-196
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• 1991

The purpose of this study was to observe the inital acidity of zinc phosphate cements(Confit and Super Cem), poly carboxylate cement(Unident and Poly F), zinc oxide engenol cement(Stailine Super EBA) and g1ass ionomer cement(Fuji ionomer) Each cement was manuplated in accordance with each manufacturer's direction. All cements were mixed at the room temperature of $23^{\circ}{\pm}$, $5^{\circ}C$, and the electrode of pH meter(Ionanalyzer) was inserted in the mixed cement, and the acidity of cement were measured for 20 minutes from begining of cement mixing at $23^{\circ}C$ and $37^{\circ}C$ Results were as follows 1. The acidity of all cements ranges from pH 3, 5 to 4, 5 at 2 minutes after the start of mixing 2. The value of pH at $23^{\circ}C$ was higher than the value of pH at $37^{\circ}C$ in all cements. 3. As the time elapsed, the pH in all cements rose. The 20 minutes after the start of mixing the range of acidity was from pH 5 to pH 6 except Poly F. 4. In polycarboxylate cement, the different value of acidity at $23^{\circ}C$ and $37^{\circ}C$ was greatest. 5. The curve pattern of acidity in Unident was similar to that in Poly F cement The pH value of Unident was higher then that of Poly F, and value of pH in the curve pattern of acidity in Confit were similar to those in Super cement.

• 대한치과보철학회지
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• 제37권4호
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• pp.465-473
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• 1999

Bond strength of luting cements to dentin is a critical consideration for success of complete cast crowns. This study was performed to evaluate the relationship between surface characteristics of teeth prepared for complete cast crowns and retention of cemented restorations. Eighty artificial crowns were cast for standardized complete crown tooth preparations accomplished with the use of a special device on recently extracted human teeth. Coarse diamond(#102R, Shofu) and superfine finishing diamond(#SF102R, Shofu) burs of similar shape were used. Crowns in each group were randomly subdivided into few subgroups of 10 for luting cements selected for this study: zinc phosphate cement (FLECK' S), polycarboxylate cement (Poly-F), rein-forced glass ionomer cement (Fuji PLUS). and adhesive resin cement (Panavia 21). Retention was evaluated by measuring the tensile load required to dislodge the artificial crown from tooth preparations with an Instron testing machine, and analysed by one-way ANOVA and Student's t-test. The obtained results were as follows ; 1. When tooth preparation was done with coarse diamond bur, retentive force was diminished in order of Panavia 21 Fuji PLUS, FLECK'S, and Poly-F. Retentive forces showed the significant difference between Fuji PLUS group and FLECK'S group(p<0.001). 2. When tooth preparation was done with superfine diamond bur, retentive force was diminished in order of Fuji PLUS, Panavia 21, FLECK'S, and Poly-F. Retentive forces showed the significant difference between Panavia 21 group and FLECK'S group(p<0.001). 3. Retentive force in coarse tooth surfaces was significantly higher than that in superfine tooth surface with all luting cements(p<0.001), and cement residues were almost retained with-in the cast crown in all groups.

• The Journal of Advanced Prosthodontics
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• 제12권2호
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• pp.75-82
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• 2020

PURPOSE. The aim of this study was to investigate the shear bond strength of luting cements used with implant retained restorations on to titanium specimens after different surface treatments. MATERIALS AND METHODS. One hundred twenty disc shaped specimens were used. They were divided into three groups considering the surface treatments (no treatment, sandblasting, and oxygen plasma treatment). Water contact angle of specimens were determined. The specimens were further divided into four subgroups (n=10) according to applied cement types: polycarboxylate cement (Adhesor Carbofine-AC), temporary zinc oxide free cement (Temporary CementZOC), non eugenol provisional cement for implant retained prosthesis (Premier Implant Cement-PI), and non eugenol acrylic-urethane polymer based provisional cement for implant luting (Cem Implant Cement-CI). Shear bond strength values were evaluated. Two-way ANOVA test and Regression analysis were used to statistical analyze the results. RESULTS. Overall shear bond strength values of luting cements defined in sandblasting groups were considerably higher than other surfaces (P<.05). The cements can be ranked as AC > CI > PI > ZOC according to shear bond strength values for all surface treatment groups (P<.05). Water contact angles of surface treatments (control, sandblasting, and plasma treatment group) were 76.17° ± 3.99, 110.45° ± 1.41, and 73.80° ± 4.79, respectively. Regression analysis revealed that correlation between the contact angle of different surfaces and shear bond strength was not strong (P>.05). CONCLUSION. The retentive strength findings of all luting cements were higher in sandblasting and oxygen plasma groups than in control groups. Oxygen plasma treatment can improve the adhesion ability of titanium surfaces without any mechanical damage to titanium structure.

• 대한안전경영과학회지
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• 제12권3호
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• pp.121-128
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• 2010

This is to show some basic data for introducing both circulated aggregate and recycled powder producing waste concrete. Standard-mixing design for 24MPa has been basically used and added and replaced normal aggregate with recycled powder made of waste concrete. In addition, polycarboxylate high-range water reducing agent has been used because recycled powder is missing adhesive strength and it is not compare with cement's adhesive strength. Compressive strength with powder mixture of 2%, 4%, 6%, 8%, and 10% has been decreased down to 80% of normal concrete material strength without recycled powder mixture. $200^{\circ}C$, $400^{\circ}C$ and $600^{\circ}C$ heated concrete were compressively tested in order to find out concrete strength resistant to high temperature. heat capacity was also tested, based on the expectancy of its low conductivity. In addition, thermal conduction test was tested in order to find out concrete insulation. According to this test, when concrete was tested by fire resistance, it using the circulation aggregate was same resulted by concrete using the natural aggregate. also, recycle powder was not effecting insulation performance. but it is fit to standard on concrete insulation of building law.

• 콘크리트학회논문집
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• 제13권4호
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• pp.354-361
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• 2001

폴리카르본산계 고분자는 분산성이 양호하고 시멘트계 재료에서 분산 유지성이 뛰어나므로 최근 콘크리트용 혼화제로 크게 주목을 끌고 있다. 따라서 본 연구에서는 시멘트콘크리트용 분산제로서 수평균 분자량(Mn)이 적당한 poly(acrylate-co-methyla-crylate)를 합성하여 시멘트 모르타르의 분산성과 기계적 물성에 미치는 영향에 대하여 연구하였다. 폴리카르본산계 고분자의 수평균 분자량이 2,000~3,000 보다 5,000 정도로 비교적 큰 polycarboxylate가 시멘트계 재료의 물성을 크게 향상시키며, 최적 첨가량은 시멘트 중량의 0.6% 이다. 그러나 poly(acrylate-co-methylacrylate)계 고분자는 시멘트 모르타르 반죽에서 흐름도의 경시변화가 큰 것으로 나타났으며, 이러한 현상은 폴리카르본산계 서방성 고분자가 시멘트계 재료에 사용되었을 때, 알칼리성 분위기에서 카르복실기의 서방성에 의해서 분산성이 지속적으로 유지된다는 기존의 이론과 다르다.

• 대한치과보철학회지
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• 제35권3호
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• pp.504-516
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• 1997

Ultrasonic instruments transfer electrical energy to mechanical energy resulting in vibration used for various dental treatments. If we could know the effect of ultrasonic instruments on the dental cements within the cast crown, we could take care when conducting periodontal surgery and when using the ultrasonic instrument to remove cast crown, it would be much more convenient. The purpose of this study was to compare the bond strength of several dental cements according to ultrasonic instrumentation time. In this study 4 types of cements were used to cement the specimens. they were treated with ultrasonic instrumentation for 0-5 minutes and the change in bond strength were statistically compared. The results were as followed. 1. The tensile bond strength of zinc phosphate cement decreased according to the increase in time of ultrasonic instrument and showed significant difference between 0 minutes and the others and between 1 minute and 2,3,4,5 minutes (p<0.05). 2. The tensile bond strength of polycarboxylate cement decreased according to the increase in time of ultrasonic instrument and showed significant difference between 5 minutes and the others and between 4 minutes and 0 minutes (p<0.05). 3. The tensile bond strength of zinc phosphate cement decreased according to the increase in time of ultrasonic instrument and showed significant difference between 5 minutes and the others (p<0.05). 4. The tensile strength of resin cements showed no statistically differences according to the ultrasonic instrumentation time. In conclusion, it is considered that zinc phosphate cements is most affected by ultrasonic instrumentations and resin cement is the least affected. When using ultrasonic instruments the result avove should be used as an index.

• 한국산학기술학회논문지
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• 제12권9호
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• pp.4223-4238
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• 2011

최근 환경에 대한 관심이 증대되면서 지반보강 재료의 친환경성이 강조되며, 이에 따라 각종 지반주입 재료가 개발되고 있으나 건설현장에서는 대부분 물유리계 재료가 활용되고 있다. 또한 최근 선진국에서는 물유리계 지반 주입재의 단점인 내구성 문제를 해결하기 위하여 여러 가지 공법을 개발하고 있는 실정이다. 본 연구에서는 기존 그라우트 재료의 문제점을 향상시키기 위하여 친환경적인 무기계 가소성그라우팅 재료에 대한 실내 시험을 통해 그라우팅 재료의 공학적 특성을 파악하고자 하였다. 실내시험에서는 그라우팅 재료의 사용량에 따른 점성, 가소성, 압축강도 및 환경영향평가에 대한 검토를 수행하여 최적 배합에 대한 범위를 설정하고, 설정된 배합의 현장적용을 통해 기존의 그라우팅 재료보다 경제적, 공학적으로 우수한 그라우트 재료에 대하여 평가하고자 한다.

• Advances in concrete construction
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• 제3권3호
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• pp.203-221
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• 2015

This paper presents the results of a study undertaken to investigate the enhancement of concrete strength using Silpozz and Rice Husk Ash (RHA). The total percentage of supplementary cementitious material (SCM) substituted in this study was 20%. Six different concrete mixes were prepared such as without replacement of cement with silpozz and RHA (0% silpozz and 0% RHA) is treated as conventional concrete, whereas in other five concrete mixes cement was replaced by 20% of silpozz and RHA as (0% silpozz and 20% RHA), (5% silpozz and 15% RHA), (10% silpozz and 10% RHA), (15% silpozz and 5% RHA) and (20% silpozz and 0% RHA) with decreasing water-binder (w/b) ratio i.e. 0.375, 0.325 and 0.275 and increasing super plasticiser dose. New generation polycarboxylate base water reducing admixture i.e., Cera Hyperplast XR-W40 was used in this study. The results of this research indicate that as w/b decreases, super plasticiser dose need to be increased so as to increase the workability of concrete. The effects of replacing cement by silpozz and RHA on the compressive strength, split tensile strength and flexural strength were evaluated. The concrete mixture with different combination of silpozz and RHA gives higher strength as compared to control specimen for all w/b ratios and also observed that the early age strength of concrete is more as compared to the later age strength. It is also observed that the strength enhancement of concrete mixture prepared with the combination of cement, silpozz and RHA is higher as compared to the concrete mixture prepared with cement and silpozz or cement and RHA.